Search Results (808)

This research contributes to advance the sustainable production of biofuels and provides insights into the energy and exergy assessment of bio-oil, which is essential for developing environmentally friendly energy production solutions. Energy and exergy analyses were performed to evaluate the pyrolysis of beech wood biomass at 500 °C in an Auger reactor. To improve the quality of the obtained bio-oil, its catalytic deoxygenation was performed within an in-line fluidized catalytic bed reactor using a catalyst based on HZSM5 zeolite modified with 5 wt.% Iron (5%FeHZSM-5). A thermodynamic analysis of the catalytic and non-catalytic pyrolysis system was carried out, as well as a comparative study of the calculation methods for the energy and exergy evaluation for bio-oil. The required heat for pyrolysis was found to be 1.2 MJ/kg_biomass in the case of non-catalytic treatment and 3.46 MJ/kg_biomass in the presence of the zeolite-based catalyst. The exergy efficiency in the Auger reactor was 90.3%. Using the catalytic system coupled to the Auger reactor, this efficiency increased to 91.6%, leading to less energy degradation. Calculating the total energy and total exergy of the bio-oil using two different methods showed a difference of 6%. In the first method, only the energy contributions of the model compounds, corresponding to the major compounds of each chemical family of bio-oil, were considered. In contrast, in the second method, all molecules identified in the bio-oil were considered for the calculation. The second method proved to be more suitable for thermodynamic analysis. The novelties of this work concern the thermodynamic analysis of a coupled system of an Auger biomass pyrolysis reactor and a fluidized bed catalytic deoxygenation reactor on the one hand, and the use of all the molecules identified in the oily phase for the evaluation of energy and exergy on the other hand. Full article

Alkyd resins are among the most common coatings used for exterior wood joinery. In Romania, solvent-borne alkyd coatings are widely used to finish wood. The study aims to compare the performance after 7 years of outdoor exposure of two types of alkyd coatings, a semi-transparent brown stain with micronized pigments (Alk1) and an opaque white enamel (Alk2), applied directly on wood or wood pre-treated with three types of resins: acryl-polyurethane (R1), epoxy (R2), and alkyd-polyurethane (R3). Fir (Abies alba) wood served as the substrate. Cracking, coating adhesion, and biological degradation were periodically assessed through visual inspection and microscopy. Additionally, a cross-cut test was performed, and the loss of coating on the directly exposed upper faces was measured using ImageJ. The results indicated that resin pretreatments somewhat reduced cracking but negatively affected coating adhesion after long-term exposure. All samples pretreated with resins and coated with Alk1 lost more than 50% (up to 78%) of the original finishing film by the end of the test. In comparison, coated control samples lost less than 50%. The Alk2 coating exhibited a film loss between 2% and 12%, compared to an average loss of 9% for the coated control. Overall, samples pretreated with alkyd-polyurethane resin (R3) and coated with alkyd enamel (Alk2) demonstrated the best performance in terms of cracking, adhesion, and discoloration. Full article

The development of sustainable and functional nanocomposites has attracted considerable attention in recent years due to their broad spectrum of potential applications, including wood preservation. Also, a global goal is to reuse the large volumes of waste for environmental issues. In this context, the aim of the study was to obtain soda lignin particles, to graft ZnO nanoparticles onto their surface and to apply these hybrids, embedded into a biodegradable polymer matrix, as protection/preservation coating for oak wood. The organic–inorganic hybrids were characterized in terms of compositional, structural, thermal, and morphological properties that confirm the efficacy of soda lignin extraction and ZnO grafting by physical adsorption onto the decorating support and by weak interactions and coordination bonding between the components. The developed solution based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and lignin-ZnO was applied to oak wood specimens by brushing, and the improvement in hydrophobicity (evaluated by water absorption that decreased by 48.8% more than wood, humidity tests where the treated sample had a humidity of 4.734% in comparison with 34.911% for control, and contact angle of 97.8° vs. 80.5° for untreated wood) and UV and fungal attack protection, while maintaining the color and aspect of specimens, was sustained. L.ZnO are well dispersed into the polymer matrix, ensuring a smooth and less porous wood surface. According to the results, the obtained wood coating using both a biodegradable polymeric matrix and a waste-based preservative can be applied for protection against weathering degradation factors, with limited water uptake and swelling of the wood, UV shielding, reduced wood discoloration and photo-degradation, effective protection against fungi, and esthetic quality. Full article

Paulownia elongata wood is characterized by rapid mass gain, but its limited mechanical strength hinders engineering applications. This study aimed to determine the effect of thermal modification in a steam atmosphere (at temperatures of 180 °C and 190 °C for 12 or 6 h with 3 or 6 h of steam dosing) on wood’s selected physicochemical and aesthetic properties. Color changes (CIELAB), chemical composition (FTIR), density, and compressive strength parallel to the grain were evaluated. The results showed a clear darkening of the wood, a shift in hues towards red and yellow, and an increase in color saturation depending on the treatment parameters. FTIR spectroscopy confirmed a reduction in hydroxyl and carbonyl groups, indicating thermal degradation of hemicelluloses and extractives. Wood density remained relatively stable, despite observed mass losses and reduced swelling. The most significant increase in compressive strength, reaching 27%, was achieved after 6 h of modification at 180 °C with a concurrent 6 h steam dosing time. The obtained results confirm that thermal treatment can effectively improve the functional and visual properties of paulownia wood, favoring its broader application in the furniture and construction industries. Full article

The Shenduntou Site, a significant Zhou Dynasty settlement in Anhui Province, provides rare insights into early Chinese woodcraft. This study examines exceptionally preserved wooden structures from Well J1, dating to the Western Zhou period (9th–8th c. BCE). Anatomical analysis identified the timber as Firmiana simplex (L.), indicating ancient selection of this locally available species for its water resistance and mechanical suitability in well construction. Comprehensive degradation assessment revealed severe structural deterioration: maximum water content (1100% ± 85% vs. modern 120% ± 8%) demonstrated extreme porosity from hydrolysis; X-ray diffraction (XRD) showed a 69.5% reduction in cellulose crystallinity (16.1% vs. modern 52.8%); Fourier Transform Infrared Spectroscopy (FTIR) spectroscopy confirmed near-total hemicellulose degradation, partial cellulose loss, and lignin enrichment due to chemical recalcitrance; Scanning Electron Microscopy (SEM) imaging documented multiscale damage including vessel thinning, pit membrane loss, and cell wall delamination from hydrolytic, microbial, and mineral degradation. These findings reflect Western Zhou inhabitants’ pragmatic resource utilisation while highlighting advanced material deterioration that poses significant conservation challenges, providing critical insights into Zhou-era woodcraft and human–environment interactions in the lower Yangtze region. Full article

Thermal modification applies to a technique for the enhancement of biological durability, stability, and appearance of wood. Much is known about its effects on the chemical and physical attributes of wood. However, there is a knowledge gap concerning the effects of heat treatment on surface coating performance of different wood species. The focus of this research is heat treatment regulation of 160 °C, 180 °C, and 200 °C for three commercially important wood species which are Populus (poplar), Quercus (oak), and Pinus (pine). These treatments were evaluated in relation to coating performance indicators adhesion, integrity, and visual stability during and after natural and artificial weathering. It was revealed that specific responses among species differences exist. Populus behaved differently and exhibited a steady loss in mass and volume. Quercus demonstrated gradual degradation alongside enhanced lignin stability. Pinus exhibited maintenance of volume and mass until 180 °C after which accelerated degradation was observed. Coating durability and adhesion exhibited dependence on thermal condition, wood species, porosity, surface chemistry and microstructural variations that occurred. The research results can be used to streamline finishing processes for thermally modified wood while underscoring the critical nature of precise treatment parameter adjustments guided by species-specific responses to ensure long-term stability. Full article

The thermal modification of wood has emerged as a sustainable and effective method for enhancing the physical, chemical, and mechanical properties of wood without the use of harmful chemicals. This review summarizes the current state-of-the-art in thermal wood modification, focusing on the mechanisms of wood degradation during treatment and the resulting changes in the properties of the material. The benefits of thermal modification of wood include improved dimensional stability, increased resistance to biological decay, and improved durability, while potential risks such as reduced mechanical strength, color change, and higher costs of wood under certain conditions are also discussed. The review highlights recent advances in process optimization and evaluates the trade-offs between improved performance and possible structural drawbacks. Finally, future perspectives are outlined for sustainable applications of thermally modified wood in various industries. Emerging trends and future research directions in the field are identified, aiming to improve the performance and sustainability of thermally modified wood products in construction, furniture, and other industries. Full article

A key discovery of this study is the strong correlation (r = 0.96) between excitation and emission maxima across chemically distinct clusteroluminogens. All 157 evaluated peaks fall along a single regression line (Ex = 0.844 Em − 12 nm), a pattern that was not valid for conventional fluorophores. This suggests a general principle of clusteroluminescence. We show that in lignocellulosic materials, peak positions reflect chemical interactions: isolated lignin and cellulose showed short excitation and emission wavelengths, while native wood exhibited longer wavelengths. Fungal or photoinduced degradation led to a further red-shift. These effects are attributed to increased molecular heterogeneity, reducing the effective energy gap within the lignocellulosic complex. We conclude that the spectral position reflects the degree of molecular interaction rather than the chemical structure of individual molecules. It may serve as a novel analytical parameter for assessing purity and degradation in a wide range of polymers. Full article

The last decade has seen a transformative advancement in computational technologies, enabling the precise creation, evaluation, visualization, and reproduction of high-fidelity three-dimensional (3D) models of archaeological sites and artefacts. With the advent of 3D printing, both small- and large-scale objects can now be reproduced with remarkable accuracy and at customizable scales. Artefacts composed of organic materials—such as wood—are inherently susceptible to biological degradation and thus require extensive, long-term conservation employing costly methodologies. These procedures often raise environmental concerns and lead to irreversible alterations in the wood’s chemical composition, dimensional properties, and the intangible essence of the original artefact. In the context of public education and the dissemination of knowledge about historical technologies and objects, 3D replicas can effectively fulfill the same purpose as original artefacts, without compromising interpretative value or cultural significance. Furthermore, the digital data embedded in 3D surface and object models provides a wealth of supplementary information that cannot be captured, preserved, or documented through conventional techniques. Waterlogged wooden objects can now be thoroughly documented in 3D, enabling ongoing, non-invasive scientific analysis. Given these capabilities, it is imperative to revisit the philosophical and ethical foundations of preserving waterlogged wood and to adopt innovative strategies for the conservation and presentation of wooden artefacts. These new paradigms can serve educational, research, and outreach purposes—core functions of contemporary museums. Full article

Pedunculate oak (Quercus robur L.), an ecologically and economically important tree species has been significantly affected by oak dieback in recent years. Since one of the symptoms of oak dieback is crown defoliation, this research aimed to determine the quantity, quality, average tree value, and wood defects that influence grading in different stages of oak dieback indicated by tree crown defoliation degree. The research was conducted in a 62- and 116-year-old stand of the lowland Croatian forest. In total, 115 pedunculate oak trees were sampled and processed in 983 logs that were analyzed. The prescribed single-entry volume tables underestimate harvesting volume by 5.45% on site A and 6.16% on site B, while the calculation of net harvesting volume underestimates net volume by 0.26% on site A and overestimates net volume on site B by 4.59%. The analysis of wood defect presence showed that insect holes, rot, and covered knots were the main reasons for the degradation of quality class. Dead trees showed a decreased average tree value in DBH classes 32.5–42.5 cm compared to the healthy trees. Based on the findings of this research, tree crown defoliation degree could be used as a timber quality and average tree value indicator. Full article

This study investigates the impact of mild steaming (105 °C and 120 °C for 12 h) on the colour characteristics and chemical stability of beech wood (Fagus sylvatica L.) during natural indoor ageing. Untreated and steamed samples of mature wood and false heartwood were analysed for CIELAB and CIELCh colour parameters (L*, a*, b*, C*, h°) and chemical changes using ATR-FTIR spectroscopy. Steaming resulted in a significant decrease in lightness (L*) and increased a*, b*, and C* values, producing darker and more saturated reddish-brown tones. It also reduced the visual differences between mature wood and false heartwood, enhancing colour uniformity. During the light-induced ageing period, steamed wood—particularly at 105 °C—exhibited improved colour stability, maintaining chroma and hue more effectively than untreated samples. Statistically significant interaction effects between treatment, time, and tissue type revealed that the ageing-related colour changes were jointly influenced by thermal modification and the anatomical characteristics of the wood. In the FTIR spectra, the most pronounced changes were observed in the absorption bands of the aromatic skeleton and carbonyl groups (1504 and 1732 cm⁻¹). These findings confirm that mild steaming alters the original aesthetic properties and colour of beech wood when exposed to an indoor environment. Full article

The forestry industry, both primary (sawn wood production) and secondary (output of reels, pallets, boxes, cooperage, and tool handles), is growing in importance in Honduras. In 2023, exports from this industry were mainly destined for Central America (58.19%), followed by North America (22.92%) and the Caribbean region (17.20%), with hardly any Honduran wood reaching Asia or Europe. Objective: The goal of this paper is to analyze the current situation of the Honduran timber industry, which is defined by its environmental deterioration caused by the overexploitation of timber resources. Methodology: Using secondary data from official national and international sources regarding the forestry industry in Honduras, we conducted a Welch’s ANOVA analysis added to two post hoc tests (Tukey and Bonferroni), complemented by a linear regression analysis using JASP software, version 0.19.3.0. to carry on our analysis. Findings: The results of our analysis underscore the urgent need to implement a series of public policies in both the medium and short term to strengthen the forestry industry in Honduras. One of Honduras’ greatest strengths is its civil society, particularly its indigenous communities, which are actively working to protect their land from deforestation and soil degradation. If public policies are not implemented in collaboration with private firms to foster the Honduran forest industry cluster, it could lead to significant socioeconomic and environmental consequences. These may include increased pressure on natural forests, rising unemployment, and the loss of an essential income source for forest owners, ultimately exacerbating poverty. Full article

Climate variations impact the preservation of heritage buildings, necessitating a strategic understanding of potential effects to effectively guide preservation efforts. This study analyzes temperature- and precipitation-dependent climate-heritage indices in Trentino–South Tyrol using EURO-CORDEX regional climate models for the period 1971–2100 under RCP 4.5 and RCP 8.5 scenarios. The selected indices were calculated with climdex-kit and relied on bias-adjusted temperature and precipitation data with a 1 km spatial resolution. The obtained results indicate a geographically punctuated increase in biomass accumulation on horizontal surfaces, a slight decreasing trend in freeze–thaw events, an increase in growing degree days indicating a small, heightened insect activity, and a rise in heavy precipitation days. The Scheffer Index shows a significantly increased potential for wood degradation, particularly under the RCP 8.5 scenario, while the Wet-Frost Index remains consistently low. Finally, according to each identified hazard, adaptive solutions are suggested. These findings provide critical insights into future climate impacts on heritage buildings in the region, aiding stakeholders in planning targeted interventions. The study emphasizes the crucial role of integrating detailed climate data into heritage preservation strategies, advocating for the inclusion of future risk analysis in the “knowledge path” in order to enhance the resilience of buildings. Full article

Bio-polyurethane foam was synthesized in this study using bio-polyol derived from liquefied waste wood as a sustainable alternative to petroleum-based polyols. It has been widely reported that polyurethane foams incorporating liquefied wood exhibit biodegradability when buried in soil, with assessments typically relying on CO₂ emission measurements in a close system. However, this method cannot obtain any chemical bonding breakage information of the bio-polyurethane foam. On the other hand, our study investigated the biodegradation process by employing an elemental composition analysis using a CHN coder and functional group analysis through Fourier transform infrared (FT-IR) spectroscopy to capture chemical structure changing. The results demonstrated that biodegradation occurs in three different stages over time, even in the absence of significant early-stage weight loss. The gradual breakdown of urethane bonds was confirmed through changes in the elemental composition and functional group ratios, providing a more detailed understanding of the degradation mechanism. These findings suggest highlighting the importance of complementary chemical analytical techniques for a more accurate evaluation. On the other hand, TG data showed that bio-polyurethane foams remained thermally stable even after biodegradation occurred. Full article

In the face of accelerating urbanization and the growing demand for environmentally responsible materials and designs, this study presents the development and implementation of a modular parklet demonstrator fabricated using dual-material 3D printing. The structure integrates polylactic acid (PLA) and wood-filled PLA (wood/PLA), combining the mechanical robustness of pure PLA in the core with the tactile and aesthetic appeal of wood-based biocomposite on the surface. The newly developed dual-nozzle 3D printing approach enabled precise spatial control over material distribution, optimizing both structural integrity and sustainability. A comprehensive evaluation was conducted for developed filaments and printed materials, including optical microscopy, coupled thermogravimetry analysis and Fourier Transform Infrared Spectroscopy (TG/FTIR), differential scanning calorimetry (DSC), and chemical and mechanical resistance testing. Results revealed distinct thermal behaviors and degradation pathways between filaments and printed parts composed of PLA and PLA/wood. The biocomposite exhibited slightly increased sensitivity to aggressive chemical environments and mechanical wear, dual-material prints maintained high thermal stability and interlayer adhesion. The 3D-printed demonstrator bench and stools were successfully deployed in public spaces as a functional urban intervention. This work demonstrates the feasibility and advantages of using biocomposite materials and dual-head 3D printing for the rapid, local, and sustainable fabrication of small-scale urban infrastructure. Full article