Search Results (9)

Investigations carried out on 72 fluid samples from 59 sites spread over the area surrounding the Sea of Marmara show that their geochemical and isotopic features are related to different segment settings of the North Anatolian Fault Zone (NAFZ). We collected fluids from thermal and mineral waters including bubbling and dissolved gases. The outlet temperatures of the collected waters ranged from 14 to 97 °C with no temperature-related geochemical features. The free and dissolved gases are a mixture of shallow and mantle-derived components. The large variety of geochemical features comes from intense gas–water (GWI) and water–rock (WRI) interactions besides other processes occurring at relatively shallow depths. CO₂ contents ranging from 0 to 98.1% and helium isotopic ratios from 0.11 to 4.43 Ra indicate contributions, variable from site to site, of mantle-derived volatiles in full agreement with former studies on the NAFZ. We propose that the widespread presence of mantle-derived volatiles cannot be related only to the lithospheric character of the NAFZ branches and magma intrusions have to be considered. Changes in the vertical permeability induced by fault movements and stress accumulation during seismogenesis, however, modify the shallow/deep ratio of the released fluids accordingly, laying the foundations for future monitoring activities. Full article

In the warm season of 2024, we conducted sampling and measurements of gas-geochemical parameters in seawater, including dissolved methane, helium, and hydrogen, in the Gulf of Patience and the eastern shelf of Sakhalin Island in the Sea of Okhotsk during cruise 71 of R/V Akademik Oparin. We identified a large area of bottom degassing, indicating high potential for oil and gas in this region. The fields of increased methane concentrations extend from the seabed to the lower boundary of the seasonal thermocline but do not extend into deeper parts of the Sea of Okhotsk due to the strong stratification of water in the bay. Cold, dense water lies at the bottom, and warmer, less-saline water is on the surface, creating a barrier which prevents movement of dissolved methane into the upper layer. The formation of mesoscale eddies over the continental slope to the southeast of the Gulf of Patience also contributes to preventing methane reaching the water and spreading into the deep Kuril Basin during the warm season. Full article

Our paper deals with gas-geochemical measurements of CH₄ and CO₂, as well as the first measurements of dissolved H₂ and He in the waters of the eastern shelf of Sakhalin Island, obtained during cruise 68 on the R/V Akademik Oparin (OP68) on 12–18 August 2023. The shallow eastern shelf has high concentrations of dissolved methane and helium in the water. The combined anomalies of methane and helium indicate the presence of an ascending deep fluid. The sources of methane in the studied area are the underlying oil- and gas-bearing rocks extending to the coast of the island. The deep faults of the region and the minor discontinuities that accompany them along the eastern coast of Sakhalin Island create a fluid-permeable geological environment both on the shallow shelf and on the coastal part of the island. East Sakhalin current and counter-current influence gases that migrate from lithospheric sources; these currents form a special hydrological regime that ensures high solubility of the gases released and their transfer under the lower boundary of the seasonal pycnocline to the east, where they are involved in the general circulation of the Sea of Okhotsk. Full article

Dissolved methane coming from its various sources is an important component of seawater. Finding these probable sources allows for the determination of potential oil and/or gas deposit areas. From an ecological point of view, methane transport studies can reveal probable pollution areas on the one hand and biological communities, being the lower part of the food chain commercial species, on the other hand. Moreover, the methane transport mechanism can help to obtain a better understanding of the contribution of the World’s oceans to global greenhouse gas emissions. Our research combines gas geochemistry and oceanography. In comparing the research results of both branches, we show the mechanism of methane transport. The features of the dissolved methane on oceanographic sections in the southern part of the Tatar Strait are discussed. The CH₄ intake from the bottom sediment and the transport of dissolved methane by the currents in the Tatar Strait are shown. The absolute maximum concentration of CH₄ (155.6 nM/L) was observed on the western Sakhalin Island shelf at the near-bottom layer at a depth of 65 m. The local maximum, 84.4 nM/L, was found north of the absolute maximum in the jet current under the seasonal pycnocline. A comparison of the simulated surface seawater origin and dissolved methane in the 4 m depth distribution shows methane transport with the currents in the Tatar Strait. Another studied section is along 134° E in the Japan Basin of the Japan (East) Sea. Here, the East Korean Warm Current close to the Yamato Rise slope and a quasi-stationary mesoscale anticyclonic eddy centered at 41° N intersect. The local maximum methane concentration of 8.2 nM/L is also observed under the seasonal pycnocline. In a mesoscale anticyclonic eddy at 134° E in the deep part of the Japan Basin, a local methane maximum of 5.2 nM/L is detected under the seasonal pycnocline as well. Full article

Detection of dissolved gases in oceans is critically needed for global carbon cycle investigation. However, most in situ optical detection techniques, as far as we know, have restricted measurement efficiency due to large gas consumption. Herein, we develop a sub-mL photoacoustic gas sensor with a simple configuration. A single-mode fiber directly guides the incident laser into the photoacoustic cell without any other free-space optics. Thus, a reduced inner size of 12 mm × 6 mm × 4 mm enables the effective detection of limited dissolved gas. We employ methane (CH₄) as an example to demonstrate its sensing performance. The sensor achieves a good linear response with an R-square value of 0.9989 and a minimum detection limit of 1.1 ppmv, corresponding to a normalized noise equivalent absorption coefficient of 7.75 × 10⁻⁸ W·cm⁻¹·Hz^−1/2. Full article

Research on carbon dioxide (CO₂) geological and biogeochemical cycles in the ocean is important to support the geoscience study. Continuous in-situ measurement of dissolved CO₂ is critically needed. However, the time and spatial resolution are being restricted due to the challenges of very high submarine pressure and quite low efficiency in water-gas separation, which, therefore, are emerging the main barriers to deep sea investigation. We develop a fiber-integrated sensor based on cavity ring-down spectroscopy for in-situ CO₂ measurement. Furthermore, a fast concentration retrieval model using exponential fit is proposed at non-equilibrium condition. The in-situ dissolved CO₂ measurement achieves 10 times faster than conventional methods, where an equilibrium condition is needed. As a proof of principle, near-coast in-situ CO₂ measurement was implemented in Sanya City, Haina, China, obtaining an effective dissolved CO₂ concentration of ~950 ppm. The experimental results prove the feasibly for fast dissolved gas measurement, which would benefit the ocean investigation with more detailed scientific data. Full article

Widespread cold seeps along continental margins are significant sources of dissolved carbon to the ocean water. However, little is known about the methane turnovers and possible impact of seepage on the bottom seawater at the cold seeps in the South China Sea (SCS). We present seafloor observation and porewater data of six push cores, one piston core and three boreholes as well as fifteen bottom-water samples collected from four cold seep areas in the northwestern SCS. The depths of the sulfate–methane transition zone (SMTZ) are generally shallow, ranging from ~7 to <0.5 mbsf (meters below seafloor). Reaction-transport modelling results show that methane dynamics were highly variable due to the transport and dissolution of ascending gas. Dissolved methane is predominantly consumed by anaerobic oxidation of methane (AOM) at the SMTZ and trapped by gas hydrate formation below it, with depth-integrated AOM rates ranging from 59.0 and 591 mmol m⁻² yr⁻¹. The δ¹³C and Δ¹⁴C values of bottom-water dissolved inorganic carbon (DIC) suggest discharge of ¹³C- and ¹⁴C-depleted fossil carbon to the bottom water at the cold seep areas. Based on a two-endmember estimate, cold seeps fluids likely contribute 16–26% of the bottom seawater DIC and may have an impact on the long-term deep-sea carbon cycle. Our results reveal the methane-related carbon inventories are highly heterogeneous in the cold seep systems, which are probably dependent on the distances of the sampling sites to the seepage center. To our knowledge, this is the first quantitative study on the contribution of cold seep fluids to the bottom-water carbon reservoir of the SCS, and might help to understand the dynamics and the environmental impact of hydrocarbon seep in the SCS. Full article

For the detection of deep-sea natural gas hydrates, it is very important to accurately detect the ¹³CO₂/¹²CO₂ isotope ratio of dissolved gas in seawater. In this paper, a ¹³CO₂/¹²CO₂ isotope ratio sensor is investigated, which uses a tunable diode laser absorption spectroscopy (TDLAS) technique at 4.3 μm. The proposed sensor consists of a mid-infrared interband cascade laser (ICL) operating in continuous wave mode, a long optical path multi-pass gas cell (MPGC) of 24 m, and a mid-infrared mercury cadmium telluride (MCT) detector. Aiming at the problem of the strong absorption intensity of the two absorption lines of ¹³CO₂ and ¹²CO₂ being affected by temperature, a high-precision temperature control system for the MPGC was fabricated. Five different concentrations of CO₂ gas were configured to calibrate the sensor, and the response linearity could reach 0.9992 for ¹²CO₂ and 0.9996 for ¹³CO₂. The data show that the carbon isotope measurement precision was assessed to be 0.0139‰ when the integration time was 92 s and the optical path length was 24 m. The sensor is combined with a gas–liquid separator to detect the ¹³CO₂/¹²CO₂ isotope ratio of CO₂ gas extracted from water. Results validate the reported sensor system’s potential application in deep-sea natural gas hydrate exploration. Full article

In this work, we investigated the molecular stable isotope compositions of hydrate-bound and dissolved gases in sediments of the Amazon deep-sea fan and adjacent continental slope, Foz do Amazonas Basin, Brazil. Some cores were obtained in places with active gas venting on the seafloor and, in one of the locations, the venting gas is probably associated with the dissociation of hydrates near the edge of their stability zone. Results of the methane stable isotopes (δ¹³C and δD) of hydrate-bound and dissolved gases in sediments for the Amazon fan indicated the dominant microbial origin of methane via carbon dioxide reduction, in which ¹³C and deuterium isotopes were highly depleted (δ¹³C and δD of −102.2% to −74.2% V-PDB and −190 to −150% V-SMOW, respectively). The combination of C1/(C2+C3) versus δ¹³C plot also suggested a biogenic origin for methane in all analysed samples (commonly >1000). However, a mixture of thermogenic and microbial gases was suggested for the hydrate-bound and dissolved gases in the continental slope adjacent to the Amazon fan, in which the combination of chemical and isotopic gas compositions in the C1/(C2+C3) versus δ¹³C plot were <100 in one of the recovered cores. Moreover, the δ¹³C-ethane of −30.0% indicates a thermogenic origin. Full article