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Keywords = dacitic magma

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30 pages, 17519 KB  
Article
Cl-Bearing Mineral Microinclusions in Arc Lavas: An Overview of Recent Findings with Some Metallogenic Implications
by Pavel Kepezhinskas, Nikolai Berdnikov, Irina Voinova, Nikita Kepezhinskas, Nadezhda Potapova and Valeria Krutikova
Geosciences 2026, 16(1), 40; https://doi.org/10.3390/geosciences16010040 - 12 Jan 2026
Viewed by 296
Abstract
Quaternary lavas (ankaramite, basalt, basaltic andesite, andesite, dacite) from the Kamchatka, Kurile, Ecuador and Cascade volcanic arcs contain Cl-bearing mineral microinclusions in rock-forming minerals and groundmass volcanic glass. They are represented by chlorargyrite (with a variable amount of native Ag), Cu, Ag, Sn, [...] Read more.
Quaternary lavas (ankaramite, basalt, basaltic andesite, andesite, dacite) from the Kamchatka, Kurile, Ecuador and Cascade volcanic arcs contain Cl-bearing mineral microinclusions in rock-forming minerals and groundmass volcanic glass. They are represented by chlorargyrite (with a variable amount of native Ag), Cu, Ag, Sn, and Zn compounds with Cl and S, Sn- and Pb-Sb oxychlorides compositionally similar to abhurite and nadorite, as well as bismoclite and Cl-F-apatite. The Cl-bearing compounds with chalcophile metals are best approximated by mixtures of chlorargyrite with Cu sulfides, malachite, or azurite. Some Cl-bearing solid microinclusions in magmatic rock-forming minerals could have formed from Cl-rich melts exsolved from arc magmas during differentiation. Alternatively, specific magmatic microinclusions may record the decomposition of primary sulfides in the presence of Cl-bearing magmatic volatiles. Post-magmatic Cl microminerals found in fractures, pores, grain contacts, and groundmass glass are most probably precipitated from hydrothermal fluids accompanying their emplacement at the surface and post-eruption transformations in active fumarole fields. Assemblages of Cl-bearing microminerals with native metal, alloy, sulfide, oxide, and sulfate microinclusions in arc lavas potentially record late-magmatic to post-magmatic stages of formation of the epithermal and possibly porphyry mineralization beneath arc volcanoes. Full article
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23 pages, 8271 KB  
Article
Petrography, Geochemistry, and Magmatic Processes of Oligocene-Miocene Tuzla Volcanics, Biga Peninsula, NW Türkiye
by Didem Kiray and Oya Cengiz
Minerals 2026, 16(1), 23; https://doi.org/10.3390/min16010023 - 24 Dec 2025
Viewed by 457
Abstract
The Tuzla area, located in the Ayvacık district of Çanakkale (Biga Peninsula, northwestern Türkiye), hosts a Oligocene-Miocene volcanic system comprising andesitic, dacitic, rhyolitic lavas, trachyandesite, pyroclastics, and ignimbrites, and the Kestanbol Pluton. Petrographic and X-ray diffraction (XRD) analyses indicate that the altered volcanic [...] Read more.
The Tuzla area, located in the Ayvacık district of Çanakkale (Biga Peninsula, northwestern Türkiye), hosts a Oligocene-Miocene volcanic system comprising andesitic, dacitic, rhyolitic lavas, trachyandesite, pyroclastics, and ignimbrites, and the Kestanbol Pluton. Petrographic and X-ray diffraction (XRD) analyses indicate that the altered volcanic units are dominated by porphyritic dacitic/rhyodacitic and trachyandesitic rocks, with silicification, iron oxide formation, and opacification. XRD results reveal smectite, smectite–illite/mica, illite–mica, kaolinite, cristobalite–opal, K-feldspar, plagioclase, dolomite, hematite, and quartz as the principal mineral phases. Geochemical data, including rare earth elements (REEs), suggest that fractional crystallization of primary mineral phases played a major role in controlling magmatic evolution. Chondrite-normalized REE patterns display enrichment in light REEs relative to heavy REEs, indicating derivation from a common magma source. K2O–Na2O and (Na2O + K2O)–FeOᵗ–MgO (AFM) diagrams show high-K calc-alkaline, calc-alkaline, and tholeiitic affinities, with most rhyodacite/dacite and all trachyandesite samples plotting in the tholeiitic field. Tectonic discrimination diagrams indicate formation in both volcanic arc and intraplate tectonic settings. Moderate enrichments in Ba and Sr reflect magmatic evolution and source characteristics, whereas the highest concentrations are attributed to post-magmatic fluid–rock interaction. Overall, the Tuzla volcanic rocks originated from a collision-related enriched lithospheric mantle source and subsequently evolved through fractional crystallization and assimilation processes, accompanied by crustal contamination and variable hydrothermal overprint. Full article
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19 pages, 7428 KB  
Article
Petrology of the 1952 Eruption and Ancient Lava and Pyroclastic Flows of Krenitsyn Peak Volcano, Onekotan Island, Kuril Arc, Russia
by Vesta O. Davydova, Anton A. Nuzhdaev, Ilya E. Bolshakov, Ruslan A. Kuznetsov, Andrey B. Ermolinskiy, Elena S. Zhitova and Vasiliy O. Yapaskurt
Geosciences 2025, 15(9), 358; https://doi.org/10.3390/geosciences15090358 - 12 Sep 2025
Viewed by 1674
Abstract
Krenitsyn Peak is one of the two active volcanoes on Onekotan Island (Greater Kuril Ridge). The inaccessibility of the island, along with the volcano being situated within a sizeable (7 km in diameter) and cold (3.7 °C) caldera lake, has led to minimal [...] Read more.
Krenitsyn Peak is one of the two active volcanoes on Onekotan Island (Greater Kuril Ridge). The inaccessibility of the island, along with the volcano being situated within a sizeable (7 km in diameter) and cold (3.7 °C) caldera lake, has led to minimal research on the area. We present the first detailed characterization of the rocks from the only historical eruption of Krenitsyn Peak (November 1952) and a brief description of the ancient lava and pyroclastic density current (PDC) deposits that make up the building of the volcano. The 1952 eruptive products are represented by two-pyroxene andesites (59.2–63.3 wt.% SiO2), and the older lava and pyroclastic flow rocks consist of two-pyroxene andesites and dacites (62–67.6 wt.% SiO2). Almost all samples belong to the calc-alkaline, medium-K, and medium-Fe series, and the pumiceous lapilli from the 1952 eruption fall into the low-Fe series. The minerals exhibit signs of magma mingling, including relic high-Ca (up to An92) plagioclase cores with signs of dissolution and recrystallization, and oscillatory-zoned pyroxene. Full article
(This article belongs to the Section Geochemistry)
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22 pages, 17789 KB  
Article
Mafic Enclaves Reveal Multi-Magma Storage and Feeding of Shangri-La Lavas at the Nevados de Chillán Volcanic Complex
by Camila Pineda, Gloria Arancibia, Valentina Mura, Diego Morata, Santiago Maza and John Browning
Minerals 2025, 15(4), 418; https://doi.org/10.3390/min15040418 - 17 Apr 2025
Cited by 1 | Viewed by 1388
Abstract
The Nevados de Chillán Volcanic Complex is one of the most active of the Southern Volcanic Zone. It is formed by NW-SE-aligned eruptive centers divided into two subcomplexes, namely Cerro Blanco (basaltic andesitic) and Las Termas (dacitic), and two satellite cones (to the [...] Read more.
The Nevados de Chillán Volcanic Complex is one of the most active of the Southern Volcanic Zone. It is formed by NW-SE-aligned eruptive centers divided into two subcomplexes, namely Cerro Blanco (basaltic andesitic) and Las Termas (dacitic), and two satellite cones (to the SW and NE of the main alignment). Our study of the Shangri-La volcano, which is located between the two subcomplexes, in alignment with the satellite cones, and which produced dacitic lavas with basaltic andesitic enclaves, sheds light on the compositional and structural diversity of the volcanic complex. Detailed petrography along with mineral chemistry allows us to suggest partial hybridization between the enclaves and the host lavas and that mixing processes are related to the generation of the Shangri-La volcano and to other volcanic products generated in the complex. This is supported by mixing trends between the enclaves and the most differentiated units from Las Termas. We argue the presence of two main magma storage areas genetically related to crustal structures. A dacitic reservoir (~950 °C) is fed along NW-SE structures, whereas a deeper mafic reservoir (>1100 °C) utilizes predominantly NE-SW structures. We suggest that the intersection between these sets of structures facilitates magma ascent and controls the Nevados de Chillán plumbing system dynamics. Full article
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39 pages, 48972 KB  
Article
Volcanic Response to Post-Pan-African Orogeny Delamination: Insights from Volcanology, Precise U-Pb Geochronology, Geochemistry, and Petrology of the Ediacaran Ouarzazate Group of the Anti-Atlas, Morocco
by Mohamed Achraf Mediany, Nasrrddine Youbi, Mohamed Ben Chra, Oussama Moutbir, Ismail Hadimi, João Mata, Jörn-Frederik Wotzlaw, José Madeira, Miguel Doblas, Ezz El Din Abdel Hakim Khalaf, Rachid Oukhro, Warda El Moume, Jihane Ounar, Abdelhak Ait Lahna, Moulay Ahmed Boumehdi and Andrey Bekker
Minerals 2025, 15(2), 142; https://doi.org/10.3390/min15020142 - 31 Jan 2025
Cited by 1 | Viewed by 3436
Abstract
Post-collisional volcanism provides valuable insights into mantle dynamics, crustal processes, and mechanisms driving orogen uplift and collapse. This study presents geological, geochemical, and geochronological data for Ediacaran effusive and pyroclastic units from the Taghdout Volcanic Field (TVF) in the Siroua Window, Anti-Atlas Belt. [...] Read more.
Post-collisional volcanism provides valuable insights into mantle dynamics, crustal processes, and mechanisms driving orogen uplift and collapse. This study presents geological, geochemical, and geochronological data for Ediacaran effusive and pyroclastic units from the Taghdout Volcanic Field (TVF) in the Siroua Window, Anti-Atlas Belt. Two eruptive cycles are identified based on volcanological and geochemical signatures. The first cycle comprises a diverse volcanic succession of basalts, basaltic andesites, andesites, dacites, and rhyolitic crystal-rich tuffs and ignimbrites, exhibiting arc calc-alkaline affinities. These mafic magmas were derived from a lithospheric mantle metasomatized by subduction-related fluids and are associated with the gravitational collapse of the Pan-African Orogen. The second cycle is marked by bimodal volcanism, featuring tholeiitic basalts sourced from the asthenospheric mantle and felsic intraplate magmas. These units display volcanological characteristics typical of facies models for continental basaltsuccessions and continental felsic volcanoes. Precise CA-ID-TIMS U-Pb zircon dating constrains the volcanic activity to 575–557 Ma, reflecting an 18-million-year period of lithospheric thinning, delamination, and asthenospheric upwelling. This progression marks the transition from orogen collapse to continental rifting, culminating in the breakup of the Rodinia supercontinent and the opening of the Iapetus Ocean. The TVF exemplifies the dynamic interplay between lithospheric and asthenospheric processes during post-collisional tectonic evolution. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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30 pages, 9786 KB  
Article
Petrography and Geochemistry of the Upper Cretaceous Volcaniclastic Deposits of the Haţeg Basin (Southern Carpathians): Inferences on Petrogenesis and Magma Origin
by Violeta M. Vornicu and Ioan Seghedi
Minerals 2025, 15(2), 111; https://doi.org/10.3390/min15020111 - 23 Jan 2025
Cited by 1 | Viewed by 1909
Abstract
Upper Cretaceous volcaniclastic deposits of the Haţeg Basin (VDHB) (Southern Carpathians, Romania) consist of relatively poorly exposed products of multiple phreatomagmatic volcanic eruptions of andesitic to rhyolitic composition and crop out around Densuş, Răchitova, Peşteniţa, and Ciula Mică localities. These deposits are commonly [...] Read more.
Upper Cretaceous volcaniclastic deposits of the Haţeg Basin (VDHB) (Southern Carpathians, Romania) consist of relatively poorly exposed products of multiple phreatomagmatic volcanic eruptions of andesitic to rhyolitic composition and crop out around Densuş, Răchitova, Peşteniţa, and Ciula Mică localities. These deposits are commonly associated with the Late Cretaceous Neotethyan magmatic activity that developed in Central-Eastern Europe, forming the Apuseni–Banat–Timok–Srednogorie (ABTS) belt. Since the geochemistry of these deposits has been investigated very little so far, this study provides petrographic and whole-rock geochemical analysis for twenty new different volcaniclastic rock samples, out of which sixteen samples represent lava clasts and the other four are samples of pyroclastic flow deposits. According to our geochemical data, the VDHB have a calc-alkaline and high-K calc-alkaline character, similar to the majority of rock samples from all sectors of the ABTS belt. A comparison between the Haţeg rock samples and Banat and Apuseni samples reveals comparable major and trace element abundances and REE patterns, supporting the idea that they originate from similar magmas. Trace element patterns suggest that the parental magmas were mostly derived from the melting of a metasomatized lithospheric mantle source, previously modified by an earlier subduction event. A combination of crystal fractionation and variable degrees of crustal assimilation during storage at higher and lower pressures was the principal mechanism driving calc-alkaline differentiation. Our geochemical analyses indicate that the VDHB were produced by magmas generated during two different magmatic events. Older, silica-rich melts produced the Peştenita and Răchitova ignimbrite deposits, while the Densuş and Răchitova andesitic–dacitic–rhyolitic rock suite was generated by younger, intermediate magmas. The individual melt production episodes are evidenced by the emergence of two different crystal fractionation trends: an amphibole-controlled trend at mid-crustal levels and an upper-crust plagioclase-dominated trend. The hydrous, calc-alkaline magmas arguably occurred in a post-collisional setting, in agreement with the orogenic collapse model, among others, proposed for the origin of the ABTS magmatic activity. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 25703 KB  
Article
The Subduction-Related Metavolcanic Rocks of Maroua, Northern Cameroon: New Insights into a Neoproterozoic Continental Arc Along the Northern Margin of the Central African Fold Belt
by Pierre Christel Biakan à Nyotok, Merlin Gountié Dedzo, Diddi Hamadjoda Djamilatou, Nils Lenhardt, Moussa Ngarena Klamadji, Periclex Martial Fosso Tchunte and Pierre Kamgang
Geosciences 2024, 14(11), 298; https://doi.org/10.3390/geosciences14110298 - 5 Nov 2024
Viewed by 2239
Abstract
The metavolcanic rocks around Maroua in the Far North Region of Cameroon are located at the northern margin of the Central African Fold Belt (CAFB) and have not been studied to date. The petrographic and whole-rock geochemical data presented in this paper highlight [...] Read more.
The metavolcanic rocks around Maroua in the Far North Region of Cameroon are located at the northern margin of the Central African Fold Belt (CAFB) and have not been studied to date. The petrographic and whole-rock geochemical data presented in this paper highlight their magma genesis and geodynamic evolution. The lavas are characterized by basaltic, andesitic, and dacitic compositions and belong to the calc-alkaline medium-K and low-K tholeiite series. The mafic samples are essentially magnesian, while the felsic samples are ferroan. On a chondrite-normalized REE diagram, mafic and felsic rocks display fractionated patterns, with light REE enrichment and heavy REE depletion (LaN/YbN = 1.41–5.38). The felsic samples display a negative Eu anomaly (Eu/Eu* = 0.59–0.87), while the mafic lavas are characterized by a positive Eu anomaly (Eu/Eu* = 1.03–1.35) or an absence thereof. On a primitive mantle-normalized trace element diagram, the majority of the samples exhibit negative Ti and Nb–Ta anomalies (0.08–0.9 and 0.54–0.74, respectively). These characteristic features exhibited by the metavolcanic rocks of Maroua are similar to those of subduction-zone melts. This subduction would have taken place after the convergence between the Congo craton (Adamawa-Yadé domain) and the Saharan craton (Western Cameroonian domain). Petrological modelling using major and trace elements suggests a derivation of the Maroua volcanics from primitive parental melts generated by the 5–10% partial melting of a source containing garnet peridotite, probably generated during the interaction between the subducted continental crust and the lithospheric mantle and evolved chemically through fractional crystallization and assimilation. Full article
(This article belongs to the Section Geochemistry)
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21 pages, 15347 KB  
Article
Petrological Characteristics and Physico-Mechanical Properties of Dokhan Volcanics for Decorative Stones and Building Material Applications
by El Saeed R. Lasheen, Mabrouk Sami, Ahmed A. Hegazy, Hasan Arman, Ioan V. Sanislav, Mohamed S. Ahmed and Mohammed A. Rashwan
Buildings 2024, 14(11), 3418; https://doi.org/10.3390/buildings14113418 - 27 Oct 2024
Cited by 8 | Viewed by 2299
Abstract
Wide varieties of igneous rocks are extensively utilized as stones for decoration purposes and as a potential source for building. With the use of petrological (mineralogical and chemical) and physico-mechanical analyses, the current work accurately mapped the Dokhan Volcanics (DV) and utilized them [...] Read more.
Wide varieties of igneous rocks are extensively utilized as stones for decoration purposes and as a potential source for building. With the use of petrological (mineralogical and chemical) and physico-mechanical analyses, the current work accurately mapped the Dokhan Volcanics (DV) and utilized them as decorative stones and their prospective in building materials using Frattini’s test. Field observations indicate that metavolcanics, DV, and monzogranites are the principal rock units exposed in the studied area. The DV rocks are characterized by a dense series of stratified, rhyolitic to andesitic lava interspersed with a few pyroclastics. Andesite, andesite porphyry, dacite, and rhyolite are the primary representatives of the selected DV. The lack of infrequent appearance of mafic units in the current volcanic eruptions indicates that the primary magma is not mantle-derived. This is supported by their Mg# (17.86–33.57). Additionally, the examined DV rocks have Y/Nb ratios above 1.2, suggesting a crustal source. The role of fractionation is interpreted by their variation from andesite passing through dacite to rhyolite, which is indicated by gradual negative distribution groups between silica and TiO2, Fe2O3, CaO, MgO, Co, and Cu from andesite to rhyolitic lava. Additionally, a wide range of widely used DV rocks like Y/Nb, Rb/Zr, and Ba/Nb point to crustal contamination in the rhyolitic rocks. The partial melting of the lower crust can produce andesitic magma, which ascend to higher crustal levels and form lava of calc-alkaline. A portion of this lava may split, settle at shallow crustal depths, and undergo differentiation to create the DV rocks. Based on the results of physico-mechanical properties, the studied samples met the requirements for natural stone to be used as decorative stones, whether as interior or exterior installations. The pozzolanic assessment of the studied rocks revealed their usability as supplementary cementitious materials in the building sector. Full article
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19 pages, 13187 KB  
Article
Geochronology and Origin of Quaternary Dacites from the Daliuchong Volcano in the Tengchong Volcanic Field (TVF), SE Tibetan Plateau
by Jie Tong, Haibo Zou, Zipei Guo, Liwen Chang, Lizhu Wang and Yongwei Zhao
Minerals 2024, 14(10), 990; https://doi.org/10.3390/min14100990 - 30 Sep 2024
Cited by 1 | Viewed by 1718
Abstract
Quaternary volcanoes from the southeastern Tibetan Plateau occur at the Tengchong volcanic field (TVF). The Daliuchong volcano is the largest volcano in the TVF, which has the most felsic compositions with explosive eruptions. The eruption history and origin of the Daliuchong volcano are [...] Read more.
Quaternary volcanoes from the southeastern Tibetan Plateau occur at the Tengchong volcanic field (TVF). The Daliuchong volcano is the largest volcano in the TVF, which has the most felsic compositions with explosive eruptions. The eruption history and origin of the Daliuchong volcano are a matter of debate. In the present paper, we report the groundmass K-Ar ages, whole-rock Sr-Nd-Pb-Hf isotopes, zircon U-Pb ages, and Hf-O isotopic compositions for the Daliuchong volcano to constrain its eruption history and petrogenesis. The groundmass K-Ar ages and zircon U-Pb ages indicate mid-Pleistocene (0.6 Ma to 0.3 Ma) eruptions. The presence of zircon phenocrysts with enriched mantle-like O-Hf isotopes (δ18O < 6‰, and εHf about −2) suggests the involvement of mantle-derived basaltic magmas. The whole-rock Pb isotope compositions and Sr-Nd isotope modeling reveal the involvement of magma from the lower crust. The zircon xenocrysts reveal previously unrecognized 20-Ma magmatic activity at the TVF and contamination of late Cretaceous (66–80 Ma) S-type granites during the formation of the Daliuchong dacites. The dacite magma at Daliuchong was formed by mixing of the mantle-derived magma and lower-crust-derived magma and subsequently contaminated by upper crustal materials, including late Cretaceous S-type granitic rocks. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 13649 KB  
Article
Zircon U-Pb Dating, Geochemistry, Lu-Hf Isotope Characteristics, and Geological Significance of Volcanic Rocks in Zhenghe Fozi Mountain National Geopark, Fujian, China
by Nan Chen, Dunpeng Li, Yanna Huang, Yihang Fu, Xiaomin Yang and Hanbin Wang
Minerals 2024, 14(6), 616; https://doi.org/10.3390/min14060616 - 17 Jun 2024
Viewed by 2442
Abstract
Fozi Mountain National Geopark is located in Zhenghe County in the northern region of Fujian Province, where the volcanic rocks of the Zhaixia Formation of the Shimaoshan Group are exposed. Zircon U-Pb dating and geochemical analysis were carried out to constrain its age [...] Read more.
Fozi Mountain National Geopark is located in Zhenghe County in the northern region of Fujian Province, where the volcanic rocks of the Zhaixia Formation of the Shimaoshan Group are exposed. Zircon U-Pb dating and geochemical analysis were carried out to constrain its age and tectonic environment. The results show that three zircon U-Pb dating samples have attained ages of 99.2 ± 1.0 Ma, 99.6 ± 0.8 Ma, and 99.7 ± 2.0 Ma. Volcanic rocks in the core scenic area of Fozi Mountain were formed during the Late Cretaceous period. Elemental analysis showed that these volcanic rocks were dominated by the shoshonite series. They include gray dacite porphyry, grayish-white breccia tuff, volcanic agglomerate, and gray tuffaceous sandstone. These rocks were characterized by high silicon, high alkali content, and rich potassium levels. Lu-Hf isotope analysis of zircons revealed that their εHf(t) values varied from −8.7 to −6.8. The corresponding TDM2 values were primarily distributed in the range of 1.71 Ga to 1.59 Ga. These findings indicated that the magma primarily originated from the partial melting of the Mesoproterozoic crystalline basement, accompanied by a small number of mantle-derived materials. Tectonic environment analysis indicated that these rocks were formed in the post-orogenic intraplate extensional environment, which was associated with the back-arc extension or lithospheric thinning caused by the subduction of the paleo-Pacific plate beneath the Eurasian plate. The formation of these volcanic rocks was attributed to post-orogenic magmatism. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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18 pages, 23050 KB  
Article
Age and Tectonic Setting of Layered Lead–Zinc Ore Bodies in the Xiaohongshilazi Deposit: Constraints from Geochronology and Geochemistry of the Volcanic Rocks in Central Jilin Province, NE China
by Qun Yang, Qingqing Shang, Yunsheng Ren and Zhongjie Yang
Minerals 2023, 13(11), 1371; https://doi.org/10.3390/min13111371 - 27 Oct 2023
Cited by 3 | Viewed by 2109
Abstract
The newly discovered Xiaohongshilazi deposit located in Panshi City, central Jilin Province, NE China, is a medium-scale Pb–Zn–(Ag) deposit. The Pb–Zn–(Ag) orebodies are divided into layered and vein-type orebodies, which have different ore geneses. The layered Pb–Zn orebodies are mainly hosted within and [...] Read more.
The newly discovered Xiaohongshilazi deposit located in Panshi City, central Jilin Province, NE China, is a medium-scale Pb–Zn–(Ag) deposit. The Pb–Zn–(Ag) orebodies are divided into layered and vein-type orebodies, which have different ore geneses. The layered Pb–Zn orebodies are mainly hosted within and spatially controlled by the volcanic rocks. To constrain the age and tectonic setting of the layered Pb–Zn mineralization, we completed laser-ablation–ICP–MS zircon U–Pb dating and whole-rock major and trace element analyses of the ore-bearing volcanic rocks. The dacite samples were confirmed as belonging to the Daheshen Formation and were the main ore-bearing volcanic rocks for the layered orebodies. They yielded concordia U–Pb ages of 278.1 ± 1.8 Ma and 278.3 ± 1.8 Ma, respectively, indicating that the volcanic rocks from the Daheshen Formation and related layered Pb–Zn mineralization were formed in the early Permian. The andesite and rhyolite located above the layered orebodies yielded concordia U–Pb ages of 225.0 ± 1.1 Ma, 225.3 ± 1.5 Ma, and 224.7 ± 1.2 Ma, respectively; these substances are considered to be of the Sihetun Formation and were first reported in the area. The dacite samples associated with layered Pb–Zn mineralization were high in SiO2 (62.54–65.02 wt.%), enriched in LREEs and LILEs (e.g., Rb, Ba, and K), and showed depletion in HFSEs (e.g., P and Ti). It showed slightly negative Eu anomalies (δEu = 0.60–0.65) and negative Nb anomalies, with Th/Nb (1.12–1.21) and La/Nb (2.8–4.7) ratios, presenting subduction-related arc magma affinity formed in an active continental margin setting. In agreement with previous studies on zircon Hf isotopes (εHf (t) = +0.23~ +10.60) of the volcanic rocks from the Daheshen Formation, we infer that they were derived from the partial melting of the depleted lower crust. In conclusion, mineralization characteristics, geochronological data, geochemical features, and regional tectonic evolution suggest that two Pb–Zn–(Ag) mineralization stages from the Xiaohongshilazi deposit occurred: the layered VMS-type Pb–Zn mineralization associated with the marine volcanic rocks from the early Permian Daheshen Formation, which was induced by the subduction of the Paleo-Asian oceanic plate beneath the northern margin of the North China Craton, and the vein-type Pb–Zn–(Ag) mineralization caused by the subduction of the Paleo-Pacific Plate in the early Jurassic. Considering this, along with the mineralization characteristics of the same-type polymetallic deposits in this region, we propose that the early Permian marine volcanic rocks have great prospecting potential for the VMS-type Pb–Zn polymetallic deposits. Full article
(This article belongs to the Special Issue Genesis and Metallogeny of Non-ferrous and Precious Metal Deposits)
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26 pages, 24283 KB  
Article
Au-Cu Resources in Some Mines from Antiquity in the South Gabal Um Monqul and Gabal Al Kharaza Prospects, North Eastern Desert, Egypt
by Abdallah Atef, Adel A. Surour, Ahmed A. Madani and Mokhles K. Azer
Geosciences 2023, 13(9), 283; https://doi.org/10.3390/geosciences13090283 - 20 Sep 2023
Cited by 1 | Viewed by 3173
Abstract
Since Antiquity, sustainable resources of gold and copper have been mined at two prominent prospects in the north Eastern Desert of Egypt, namely the south Gabel Um Monqul (SGUM) and Gabal Al Kharaza (GKZ). Mineralization is hosted by Neoproterozoic shield rocks represented by [...] Read more.
Since Antiquity, sustainable resources of gold and copper have been mined at two prominent prospects in the north Eastern Desert of Egypt, namely the south Gabel Um Monqul (SGUM) and Gabal Al Kharaza (GKZ). Mineralization is hosted by Neoproterozoic shield rocks represented by dacite and monzo- to syenogranite at the SGUM prospect whereas they are diorite, granodiorite, and quartz feldspar porphyry at the GKZ prospect. These hosts have been emplaced in an island arc environment from calc-alkaline magmas with a peraluminous to metaluminous signature. They are hydrothermally altered including albitization, sericitization, silicification, epidotization, and chloritization. The Au and Cu mineralizations are confined to shear zones that lately filled with auriferous quartz veins adjacent to mineralized alteration zones. In the GKZ prospect, the old trenches trend mainly in a NW–SE direction whereas it is NE–SW and NW–SE in the SGUM prospect. Evidence of shearing ranges from megascopic conjugate fractures and shear planes in the outcrops to microscopic sheared and crumbled Au-Cu ore assemblages dominated by Fe-Cu sulfides, specularite, and barite. Microscopic investigation suggests that the formation of specularite is due to the shearing of early existing magnetite. The ore textures and paragenetic sequence indicate that pyrite in the alteration zones is oxidized, leading to the liberation of gold up to 3.3 g/t. The formulae of the analyzed electrum lie in the range Au74.5-76.8 Ag22.2-24.5. Integration of the field, geochemistry, and mineral chemistry data, combined with the gold fire assay data prove the presence of sustainable amounts of disseminated Au and Cu, not only in the mineralized quartz veins, but also in the alteration zones. Data materialized in our paper show similarities in the style of mineralization at the SGUM and the GKZ prospects with iron oxide-copper-gold (IOCG) deposits elsewhere in the Arabian-Nubian Shield (ANS) and other world examples. Full article
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20 pages, 5227 KB  
Article
In Situ LA-ICP-MS U-Pb Geochronology, Sr-Nd-Hf Isotope and Trace Element Analysis of Volcanic Rocks from the Gacun Volcanic-Hosted Massive Sulfide Deposit in Sichuan, China
by Kun Wang, Dan Yang, Ke-Jun Hou and Qian Wang
Minerals 2023, 13(7), 881; https://doi.org/10.3390/min13070881 - 29 Jun 2023
Cited by 1 | Viewed by 2065
Abstract
The Gacun deposit is a typical Volcanic Hosted Massive Sulfide (VHMS) associated with Late Triassic seafloor calc-alkaline felsic volcanics. Studies of zircon ages, petrology, major and trace element geochemistry, and Sr-Nd-Hf isotope geochemistry of volcanic rocks from the Northern Yidun arc were undertaken [...] Read more.
The Gacun deposit is a typical Volcanic Hosted Massive Sulfide (VHMS) associated with Late Triassic seafloor calc-alkaline felsic volcanics. Studies of zircon ages, petrology, major and trace element geochemistry, and Sr-Nd-Hf isotope geochemistry of volcanic rocks from the Northern Yidun arc were undertaken in this paper. We reshaped the Gacun magmatic system activity time, defined the origin of magma evolution, and proposed a metallogenic model of the deposit. Whole-rock major element compositions of the magmatic rocks in the Northern Yidun island arc indicate that they are a complete basalt–andesite–dacite–rhyolite assemblage, showing three obvious stages of composition evolution. They are enriched in large-ion lithophile and light rare earth elements, but depleted in high field-strength and heavy rare earth elements, with weak-to-negligible Eu anomalies (obvious in rhyolite). These geochemical features indicate that the Northern Yidun island arc is a magmatic arc based on ancient continental crust. The Ganzi–Litang oceanic subduction induced mantle melting and produced calc-alkaline basaltic magma, while the MASH processes at the bottom of the crust produced andesitic magma. Part of the andesite magma erupted to form andesite lava. The remaining part was mixed with magma produced via anatexis of ancient crust (approximately 20%–40% of the ancient crustal component), forming the ore-bearing rhyolite. Zircon U-Pb age data defines Gacun magmatic–hydrothermal mineralization sequence of events: At 238 Ma, arc magmatism led to the formation of andesite in the eastern part of the deposit. At 233 Ma, in the arc zone (the western part of Gacun deposit), a large-scale bimodal magmatism formed the main ore-bearing rock series of Gacun deposit, rhyolitic volcanic rocks. At 221 Ma, volcanic eruptions tended to end and sub-volcanic intrusion occurred, forming a lava dome, which was located under the ore-bearing rhyolitic volcanic rocks. The lava dome acted as a thermal engine and promoted hydrothermal circulation. The hydrothermal activity reached a peak at 217 ± 1 Ma, and the Gacun VHMS deposit was formed. Full article
(This article belongs to the Special Issue Isotope Geochemical Analysis Technology and Its Applications)
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30 pages, 24245 KB  
Article
Dynamics of Two Caldera-Forming Eruptions (Banda Besar and Naira) in the Marine Conservation Zone of Banda, Maluku, Indonesia
by Indranova Suhendro, Bachtiar W. Mutaqin, Dyan Primana Sobaruddin, Lestari Agustiningtyas, Hanik Humaida, Muh Aris Marfai and Danang Sri Hadmoko
Geosciences 2022, 12(11), 428; https://doi.org/10.3390/geosciences12110428 - 21 Nov 2022
Cited by 1 | Viewed by 5464
Abstract
This is the first study discussing the dynamics of two caldera-forming eruptions in the Banda volcanic complex (BVC) in the marine conservation zone of Banda, Maluku, Indonesia. The first and second caldera episodes are, hereafter, termed as Banda Besar and Naira, respectively. The [...] Read more.
This is the first study discussing the dynamics of two caldera-forming eruptions in the Banda volcanic complex (BVC) in the marine conservation zone of Banda, Maluku, Indonesia. The first and second caldera episodes are, hereafter, termed as Banda Besar and Naira, respectively. The formation of Banda Besar caldera (ca. 8 × 7 km) ejected homogeneous rhyolitic magmas (bulk-rock, 73.1–73.8 wt.% SiO2) in the following three stages: (1) sub-Plinian (BB-5a), (2) intra-sub-Plinian flow (BB-5b), and (3) caldera collapse (BB-5c and BB-5d). The BB-5a stage produced a reversely graded white pumice fall layer with moderate lithics (2–11%), which originated from a sub-Plinian eruption with an estimated plume height of 22–23 km. Subsequently, intensive erosion of wall rock (13–25%) causes conduit enlargement, leading to the partial collapse of the eruption columns, forming intra-sub-Plinian flow deposits (BB-5b). It is likely that conduit size surpassed the minimum threshold value for a buoyant plume during the final phase of the second stage, causing the complete formation of a pumice-rich pyroclastic density current (PDC) during the early-third stage (BB-5c). Finally, the evacuation of voluminous magma from the reservoir yields the first caldera collapse during the late-third stage, producing a lithic-dominated PDC with minor pumices (BB-5d). The formation of the Naira caldera (ca. 3 × 3 km) ejected homogeneous dacitic magmas (bulk-rock, 66.2–67.2 wt.% SiO2) in the following three stages: (1) early sub-Plinian (N-2a and 2b), (2) late sub-Plinian (N-2c, 2d, 2e), and (3) caldera collapse (N-2f). This research distinguishes the sub-Plinian into two stages on the basis of different vent locations (assumed from the isopach map). In particular, this research suggests that the early sub-Plinian stage (N-2a and 2b) erupted from the northern vent, producing 14 and 8 km eruption plume heights, respectively. Additionally, the late sub-Plinian stage (N-2c, 2d, 2e) was generated from a newly-formed conduit located in the relatively southern position, producing 12–17, 9, and 6 km eruption plume heights, respectively. Conduit enlargement is expected to occur during at both sub-Plinian stages, as lithic portions are considerably high (10–72%) and ultimately generate PDCs during the third stage (caldera collapse; N-2f). Because most of the erupted materials (for both caldera-forming eruptions) are emplaced in the ocean, estimating the erupted volume becomes difficult. However, with the assumption that the caldera dimension represents the erupted volume of magma (Vmagma), and that the total erupted volume (Vtotal) is a summation of Vmagma and the now-vanished pre-caldera island (Vvanished, represented by average lithic fractions), the first and second caldera might produce (at least) 35.2 and 2.4 km3 of erupted materials, scaling them as VEI (volcano explosivity index) 6 and 5, respectively. That VEI is more than enough to initiate a secondary hazard in the form of tsunamis triggered by volcanic activities. Full article
(This article belongs to the Special Issue Present and Past Submarine Volcanic Activity II)
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31 pages, 5450 KB  
Article
Petrogenesis, Sources, and Tectonic Settings of Triassic Volcanic Rocks in the Ela Mountain Area of the East Kunlun Orogen: Insights from Geochronology, Geochemistry and Hf Isotopic Compositions
by Zhongcui Pan, Fengyue Sun and Zhichao Cong
Minerals 2022, 12(9), 1085; https://doi.org/10.3390/min12091085 - 27 Aug 2022
Cited by 3 | Viewed by 3136
Abstract
The Ela Mountain area is located at the easternmost point of the East Kunlun Orogen, in which voluminous igneous rocks developed in the Triassic period, and it is a good place to investigate the tectonic evolution of the Paleo-Tethys Ocean. In this study, [...] Read more.
The Ela Mountain area is located at the easternmost point of the East Kunlun Orogen, in which voluminous igneous rocks developed in the Triassic period, and it is a good place to investigate the tectonic evolution of the Paleo-Tethys Ocean. In this study, petrological, geochemical, zircon U-Pb geochronology and zircon Hf isotope studies were carried out on the volcanic rocks in the Ela Mountain area. Dacite (239.3 ± 1.4 Ma) exhibits calc-alkaline I-type characteristics, and rhyolite (237.8 ± 2.1 Ma) is similar to high-K calc-alkaline highly fractionated I-type volcanic rock. The petrogenesis shows that both rhyolite and dacite originated from the partial melting of the mafic lower crust of the Mesoproterozoic under relatively high temperature and low pressure. Dacite and rhyolite were derived from the same or similar parent magma, and they are volcanic rocks with different differentiation degrees formed in the same magmatic pulse activity. Differing from rhyolite and dacite, basaltic andesite shows a relatively young age (234 ± 1.2 Ma), mainly originating from the partial melting of the lithospheric mantle modified by subducted slab-derived fluids; the magma was contaminated with a small amount of crustal source components and experienced the fractional crystallization of mafic minerals before the eruption to the surface. This study on the tectonic environment of these volcanic rocks shows that they were formed in the environment of slab failure in the late stage of syn-collision, and that they are different types of volcanic rocks from different sources under similar tectonic environments. The volcanic rocks of the Ela Mountain area in this contribution provide important evidence for Middle Triassic to Late Triassic syn-collisional magmatism in the slab failure stages. The results of this study constrain the lower age limit of the closure of the Paleo-Tethys Ocean and the initial time of extension of the late stage of syn-collision, providing important information regarding regional tectonic evolution processes and volcanic activity history. They can be applied to regional tectonic evolution, petrology, volcanic stratigraphy and mineral deposits related to volcanic rocks. Full article
(This article belongs to the Special Issue Isotopic Tracers of Mantle and Magma Evolution)
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