Search Results (166)

Metal–organic frameworks (MOFs) typically exist in the form of powders or dispersed crystals, which limits their direct application in practical engineering scenarios that require monolithic structures and processability. To address this issue, the present study successfully anchored MOF (zeolitic imidazolate framework-8, ZIF-8) nanocrystals within a porous silicon carbide (p-SiC) substrate via a facile in situ growth strategy, achieving both stable macroscopic loading and intimate microscopic interfacial bonding. The resulting ZIF-8/p-SiC composite exhibits a hierarchical porous structure, with a specific surface area approximately 183 times higher than that of the raw p-SiC, alongside a substantially enhanced CO₂ adsorption capacity. By utilizing a low-cost p-SiC support and mild ZIF-8 synthesis conditions, this work demonstrates excellent reproducibility and scalability, providing a facile and effective pathway for fabricating MOF/porous media composite systems that possess both superior mechanical properties and tailored pore structures. Additionally, the developed MOF/p-SiC composites can serve as controllable rock-analog porous media, offering new perspectives for investigating MOF-rock interfacial interactions and CO₂ geological sequestration mechanisms, thereby establishing an organic link between fundamental materials science and geological engineering applications. Full article

Unmanned Aerial Vehicles (UAVs) are increasingly used in civilian and military applications, making their communication and control systems targets for cyber attacks. The emerging threat of quantum computing amplifies these risks. Quantum computers could break the classical cryptographic schemes used in current UAV networks. This situation underscores the need for quantum-resilient, privacy-preserving security frameworks. This paper proposes a quantum-resilient federated learning framework for multi-layer cyber anomaly detection in UAV systems. The framework combines a hybrid deep learning architecture. A Variational Autoencoder (VAE) performs unsupervised anomaly detection. A neural network classifier enables multi-class attack categorization. To protect sensitive UAV data, model training is conducted using federated learning with differential privacy. Robustness against malicious participants is ensured through Byzantine-robust aggregation. Additionally, CRYSTALS-Dilithium post-quantum digital signatures are employed to authenticate model updates and provide long-term cryptographic security. Researchers evaluated the proposed framework on a real UAV attack dataset containing GPS spoofing, GPS jamming, denial-of-service, and simulated attack scenarios. Experimental results show the system achieves 98.67% detection accuracy with only 6.8% computational overhead compared to classical cryptographic approaches, while maintaining high robustness under Byzantine attacks. The main contributions of this study are: (1) a hybrid VAE–classifier architecture enabling both zero-day anomaly detection and precise attack classification, (2) the integration of Byzantine-robust and privacy-preserving federated learning for UAV security, and (3) a practical post-quantum security design validated on real UAV communication data. Full article

Magnesium phosphate cement (MPC) holds great potential for rapid repairs, yet its practical application is limited by its intense hydration exotherm. While many existing studies confirm paraffin (PA)’s ability to regulate hydration heat in other cement-based materials, the comparison of hydration heat regulation efficacy among PAs with different phase change temperatures and the accompanying performance trade-offs in MPC systems remain insufficiently explored. This study comprehensively evaluates the effects of three PAs with distinct phase change characteristics (n-C18, n-C20, n-C22) and their contents on the hydration heat regulation and performance of MPC. Direct incorporation of PAs was adopted to assess its practical feasibility, considering construction cost-effectiveness. Investigations were conducted using hydration heat release tests, temperature rise monitoring, DSC, mechanical tests, XRD, and SEM. Results show that all PAs significantly retarded heat release and suppressed temperature rise, with efficacy increasing with phase change temperature; a maximum exothermic peak reduction of 64% was achieved with 4% n-C22. PAs also introduced distinct temperature plateaus near their phase change temperature, further enhancing temperature regulation. As a key trade-off, compressive strength decreased with increasing PA content, but mixtures with n-C18 ≤ 8%, n-C22 ≤ 4%, and n-C20 = 2% still met the standard strength requirement for rapid repair, 3 h compressive strength ≥ 20 MPa. Microstructural analysis reveals that while regulating hydration heat, PA also hindered the hydration product formation and crystallization, underpinning the observed performance trade-offs. This study establishes a clear performance correlation between PAs with different phase change temperatures and MPC, clarifies the intrinsic trade-offs between heat regulation and mechanical properties, and offers actionable guidance for engineering applications—facilitating the development of high-performance PA/MPC composites with controllable heat release for rapid repair scenarios. Full article

In this study, we investigate the relationship between the progressive lowering of the silicon (Si) anode potential during lithiation and the accompanying crystallization reaction to enable in situ electrochemical detection in Si-based full cells. Si–Li half cells were first analyzed by differential capacity (dQ/dV), revealing a crystallization feature near 0.05 V vs. Li⁺/Li, commonly associated with crystallization to Li₁₅Si₄. In the initial cycle, this signal was obscured by a dominant amorphization peak near 0.1 V; however, once amorphization was completed and the end-of-lithiation potential dropped below ~0.05 V in later cycles, a distinct crystallization peak became clearly resolvable. Under capacity-limited cycling that mimics full-cell operation, degradation-induced lowering of the Si-anode potential led to the appearance of the crystallization signal when the anode potential crossed this threshold. Based on these results, we extended the analysis to LiFePO₄–Si three-electrode full cells and, by reparameterizing dQ/dV as a function of charge time, separated electrode-specific contributions and identified the Si crystallization feature within the full-cell response when N/P ≈ 1. A simple degradation-modeling scenario further showed that in cells initially designed with N/P > 1, loss of anode active material can reduce the effective N/P, drive the Si potential into the crystallization window, and introduce a new peak in the full-cell dQ/dV curve associated with Si crystallization. These combined experimental and modeling results indicate that degradation-driven lowering of the Si-anode potential triggers crystallization and that this process can be detected in full cells via dQ/dV analysis. Practically, the emergence of the Si-crystallization feature provides an in situ marker that the effective N/P has drifted toward unity due to anode-dominated aging and may inform charge cut-off strategies to mitigate further Si-anode degradation. Full article

Distributed fiber-optic photoacoustic non-destructive testing (DFP-NDT) represents a paradigm shift from passive sensing to active probing, fundamentally transforming structural health monitoring through integrated fiber-based ultrasonic generation and detection capabilities. This review systematically examines DFP-NDT’s evolution by following the technology’s natural progression from fundamental principles to practical implementations. Unlike conventional approaches that require external excitation mechanisms, DFP-NDT leverages photoacoustic transducers as integrated active components where fiber-optical devices themselves generate and detect ultrasonic waves. Central to this technology are photoacoustic materials engineered to maximize conversion efficiency—from carbon nanotube-polymer composites achieving 2.74 × 10⁻² conversion efficiency to innovative MXene-based systems that combine high photothermal conversion with structural protection functionality. These materials operate within sophisticated microstructural frameworks—including tilted fiber Bragg gratings, collapsed photonic crystal fibers, and functionalized polymer coatings—that enable precise control over optical-to-thermal-to-acoustic energy conversion. Six primary distributed fiber-optic photoacoustic transducer array (DFOPTA) methodologies have been developed to transform single-point transducers into multiplexed systems, with low-frequency variants significantly extending penetration capability while maintaining high spatial resolution. Recent advances in imaging algorithms have particular emphasis on techniques specifically adapted for distributed photoacoustic data, including innovative computational frameworks that overcome traditional algorithmic limitations through sophisticated statistical modeling. Documented applications demonstrate DFP-NDT’s exceptional versatility across structural monitoring scenarios, achieving impressive performance metrics including 90 × 54 cm² coverage areas, sub-millimeter resolution, and robust operation under complex multimodal interference conditions. Despite these advances, key challenges remain in scaling multiplexing density, expanding operational robustness for extreme environments, and developing algorithms specifically optimized for simultaneous multi-source excitation. This review establishes a clear roadmap for future development where enhanced multiplexed architectures, domain-specific material innovations, and purpose-built computational frameworks will transition DFP-NDT from promising laboratory demonstrations to deployable industrial solutions for comprehensive structural integrity assessment. Full article

Background:Streptococcus pneumoniae is a well-known pathogen responsible for respiratory and invasive diseases; however, central nervous system (CNS) involvement in the form of bacterial myelitis is exceedingly rare, particularly in immunocompetent adults. Moreover, the association between pneumococcal infections and reactive arthritis is scarcely documented. We report an unusual case of pneumococcal myelitis complicated by reactive arthritis in an elderly patient with no evident immunosuppression. Case Presentation: A 68-year-old man with a medical history of hypertension, benign prostatic hyperplasia, multiple disc herniations, and a resected pancreatic neuroendocrine tumour presented to the emergency department with acute urinary retention and fever (38.5 °C). The neurological examination revealed lower limb weakness and decreased deep tendon reflexes. Spinal magnetic resonance demonstrated T2 hyperintense lesions suggestive of longitudinally transverse myelitis. Cerebrospinal fluid (CSF) analysis showed pleocytosis with elevated protein levels; the polymerase chain reaction (PCR) test resulted positive result for Streptococcus pneumoniae. The patient received intravenous antimicrobial and corticosteroid therapy with partial neurological improvement. Within days, he developed acute monoarthritis of the right ankle. Joint aspiration revealed sterile inflammatory fluid, negative for crystals and cultures, supporting a diagnosis of reactive arthritis. The articular symptoms resolved with the use of prednisone. An extensive immunological work-up was negative, and no other infectious or autoimmune triggers were identified. The patient underwent a structured rehabilitation program with gradual improvement in motor function over the following weeks. Conclusions: This case illustrates a rare clinical scenario of pneumococcal myelitis associated with reactive arthritis in a patient without overt immunosuppression. It highlights the importance of considering bacterial aetiologies in cases of acute transverse myelitis and the potential for unusual systemic immune responses such as reactive arthritis. Early recognition and the administration of appropriate antimicrobial and supportive therapies are crucial for improving neurological and systemic outcomes. To our knowledge, this is one of the first reported cases describing the co-occurrence of these two conditions in the context of S. pneumoniae infection. Full article

Electromagnetic phase reconfigurability is a critical functionality for many emerging applications in electronics, defence, and other disruptive technologies. This work addresses a significant challenge in developing nematic liquid crystal (NLC)-based phase shifters: inaccurate and ambiguous calculations of differential phase shift, which can jeopardise on-time, on-budget device development. We investigate and correct two vulnerable cases of these calculation errors, demonstrated using a 60 GHz strip line and a 300 GHz coaxial line. For completeness, we also present a third case—a 1 mm long 60 GHz strip line—that correctly calculates phase shift, illustrating a “false positive” scenario. A unique contribution of this paper is the statistical analysis of how often these different phase shift processing errors occur during NLC delay line parameterisation. This statistical insight provides practical guidance for research and development. By numerically testing common assumptions, we establish traceable know-how to support smarter design decisions for radiofrequency (RF) engineers and academics. This work aims to advance NLC devices beyond classical display applications towards commercial viability. It also serves as a valuable reference and educational resource for students, physicists, and designers working on the precise phase characterisation of NLC-based reconfigurable devices. Full article

This review critically surveys the emerging integration of Surface-Enhanced Raman Scattering (SERS) with photonic-crystal fibers (PCFs) for chemical and biological detection, an area still scarce in the literature. SERS exploits electromagnetic and chemical enhancement to overcome the intrinsic weakness of Raman scattering, while PCF offers low transmission loss and a strong evanescent field that further amplify the signal. The structural designs of PCF, encompassing solid-core and hollow-core variants, are discussed and their respective advantages in different sensing scenarios are presented. Applications in chemical detection, biomedicine, and explosive identification are detailed, demonstrating the versatility and potential of PCF-SERS sensors. Future efforts will focus on robust PCF geometries that guarantee stable and reproducible signals, AI-driven spectral algorithms, hybrid fibre architectures and scalable manufacturing. These advances are expected to translate PCF-SERS from bench-top demonstrations to routine deployment in environmental monitoring, clinical diagnostics and food-safety control. Full article

Flexible upconversion (UC) devices, owing to their unique combination of high–efficiency optical energy conversion and mechanical flexibility, have attracted increasing attention in the fields of optoelectronics, wearable devices, flexible displays, and biomedical applications. However, significant challenges remain in balancing optical performance, mechanical adaptability, long–term stability, and scalable fabrication, which limit their practical deployment. This review systematically introduces five representative upconversion mechanisms—excited–state absorption (ESA), energy transfer upconversion (ETU), energy migration upconversion (EMU), triplet–triplet annihilation upconversion (TTA–UC), and photon avalanche (PA)—highlighting their energy conversion principles, performance characteristics, and applicable scenarios. The article further delves into the flexible transition of upconversion devices, detailing not only the evolution of the luminescent layer from bulk crystals and nanoparticles to polymer composites and hybrid systems, but also the optimization of electrodes from rigid metal films to metal grids, carbon–based materials, and stretchable polymers. These developments significantly enhance the stability and reliability of flexible upconversion devices under bending, stretching, and complex mechanical deformation. Finally, emerging research directions are outlined, including multi–mechanism synergistic design, precise nanostructure engineering, interface optimization, and the construction of high–performance composite systems, emphasizing the broad potential of flexible UC devices in flexible displays, wearable health monitoring, solar energy harvesting, flexible optical communications, and biomedical photonic applications. This work provides critical insights for the design and application of high–performance flexible optoelectronic devices. Full article

This review addresses the environmental and health risks caused by antibiotic abuse, focusing on the inefficiency of traditional treatment methods and their tendency to cause secondary pollution, as well as the limitations of g-C₃N₄ in photocatalytic antibiotic degradation, such as insufficient visible light utilization and high carrier recombination rates. It systematically summarizes modification strategies and application advances of g-C₃N₄. Compared with previous reviews on carbon nitride, this work distinguishes itself by precisely targeting the cutting-edge application scenario of antibiotic-specific degradation, providing an in-depth analysis of how precursor selection and preparation methods regulate material properties, and emphasizing the role of modification approaches—including crystal optimization, element doping, surface modification, and heterojunction construction—in enhancing catalytic efficiency. It offers targeted and forward-looking insights for the practical application of this material in controlling antibiotic pollution in complex water environments. Full article

Traditional energy harvesting systems, such as photovoltaics and wind power, often rely on external environmental conditions and are typically associated with contact-based vibration wear and bulky structures. This study introduces light-fueled self-vibration to propose a self-harvesting system, consisting of liquid crystal elastomer fibers, two resistors, and two piezoelectric cantilever beams arranged symmetrically. Based on the photothermal temperature evolution, we derive the governing equations of the liquid crystal elastomer fiber–piezoelectric beam system. Two distinct states, namely a self-harvesting state and a static state, are revealed through numerical simulations. The self-oscillation results from light-induced cyclic contraction of the liquid crystal elastomer fibers, driving beam bending, stress generation in the piezoelectric layer, and voltage output. Additionally, the effects of various system parameters on amplitude, frequency, voltage, and power are analyzed in detail. Unlike traditional vibration energy harvesters, this light-fueled self-harvesting system features a compact structure, flexible installation, and ensures continuous and stable energy output. Furthermore, by coupling the light-responsive LCE fibers with piezoelectric transduction, the system provides a non-contact actuation mechanism that enhances durability and broadens potential application scenarios. Full article

Searching anode materials is an important task for the development of sodium-ion batteries. In this regard, bronze-phase titanium dioxide, TiO₂(B), has been considered as one of the promising materials, owing to its crystal structure with open channels and voids facilitating Na⁺ diffusion and storage. However, the electrochemical de-/sodiation mechanism of TiO₂(B) has not been clearly comprehended, and further experiments are required. Herein, in situ and ex situ observations by a combination of X-ray photoelectron spectroscopy, X-ray diffraction, Raman spectroscopy, gas chromatography–mass spectrometry was used to provide additional insights into the electrochemical reaction scenario of bronze-phase TiO₂ in Na-ion batteries. The findings reveal that de-/sodiation of TiO₂(B) occurs through a reversible intercalation reaction and without the involvement of the conversion reaction (no metallic titanium is formed and no oxygen is released). At the same time, upon the first Na⁺ uptake process, crystalline TiO₂(B) becomes partially amorphous, but is still driven by the Ti⁴⁺/Ti³⁺ redox couple. Importantly, TiO₂(B) has pseudocapacitive electrochemical behavior during de-/sodiation based on a quantitative analysis of the cyclic voltammetry data. The results obtained in this study complement existing insights into the sodium storage mechanisms of TiO₂(B) and provide useful knowledge for further improving its anode performance for SIBs application. Full article

We experimentally investigate the structural, magnetic, transport, and electronic properties of two d⁵ iridate double perovskite materials La₂BIrO₆ (B = Mg, Zn). Notably, despite similar crystallographic structure, the two compounds show distinctly different magnetic behaviors. The M = Mg compound shows an antiferromagnetic-like linear field-dependent isothermal magnetization below its transition temperature, whereas the M = Zn counterpart displays a clear hysteresis loop followed by a noticeable coercive field, indicative of ferromagnetic components arising from a non-collinear Ir spin arrangement. The local structure studies authenticate perceptible M/Ir antisite disorder in both systems, which complicates the magnetic exchange interaction scenario by introducing Ir-O-Ir superexchange pathways in addition to the nominal Ir-O-B-O-Ir super-superexchange interactions expected for an ideally ordered structure. While spin–orbit coupling (SOC) plays a crucial role in establishing insulating behavior for both these compounds, the rotational and tilting distortions of the IrO₆ (and MO₆) octahedral units further lift the ideal cubic symmetry. Finally, by measuring the Ir-L₃ edge resonant inelastic X-ray scattering (RIXS) spectra for both the compounds, giving evidence of spin–orbit-derived low-energy inter-J-state (intra t_2g) transitions (below ~1 eV), the charge transfer (O 2p → Ir 5d), and the crystal field (Ir t_2g → e_g) excitations, we put forward a qualitative argument for the interplay among effective SOC, non-cubic crystal field, and intersite hopping in these two compounds. Full article

The synthesis of two series of poly(lactic acid) (PLA)-based polymer nanocomposites (PNCs) filled with small amounts (0.5 and 1%) of Ag and Cu nanoparticles (NPs) was performed. Moreover, two methods for the PNC synthesis were performed, namely, ‘conventional mixing techniques’ and ‘in situ ring opening polymerization (ROP)’. The latter method was employed for the first time; moreover, it was found to be more effective in achieving very good NP dispersion in the polymer matrix as well as the formation of interfacial polymer–NP interactions. The in situ ROP for PLA/Cu was not productive due to the oxidation of Cu NPs being faster than the initiation of ROP. The presence of NPs resulted in suppression of the glass transition temperature, T_g (23–60 °C), with the effects being by far stronger in the case of ROP-based PNCs, e.g., exhibiting T_g decrease by tens of K. Due to that surprising result, the ROP-based PLA/Ag PNCs exhibited elevated ionic conductivity phenomena (at room temperature). This can be exploited in specific applications, e.g., mimicking the facilitated small molecules permeation. The effects of NPs on crystallinity (2–39%) were found opposite between the two series. Crystallinity was facilitated/suppressed in the mixing/ROP -based PNCs, respectively. The local and segmental molecular mobility map was constructed for these systems for the first time. Combining the overall data, a concluding scenario was employed, that involved the densification of the polymer close to the NPs’ surface and the free volume increase away from them. Finally, an exceptional effect was observed in PLA + 0.5% Ag (ROP). The crystallization involvement resulted in a severe suppression of T_g (−25 °C). Full article

In recent years, with the continuous advancement of technology and the expansion of application scenarios, AR has become a highly regarded field. However, AR still faces several challenges in practical usage. Notable shortcomings include inadequate image uniformity, low diffraction efficiency. Among these, the insufficient image uniformity stands out as a significant issue directly affecting user experience. The analysis of uniformity improvement in this study is limited to the simulated scenario of monochromatic blue light (LED light source), aiming to optimize the insufficient uniformity of the image output of the diffractive optical waveguide-based AR technology scheme. We improve the details of the input grating in the waveguide, such as the morphological characteristics of the grating, the detail parameter, etc. In addition, we propose to incorporate a photonic crystal film in the waveguide as an innovative study and find that the incorporation of the photonic crystal thin film significantly improves the uniformity of the output image in the diffractive optical waveguide scheme. In order to further verify the effect of the photonic crystal film on the uniformity of its image output, we also compare different types of coupled gratings and find that they all have a positive effect. Thus, the photonic crystal film demonstrated effective control over the diffraction optical waveguide scheme. This research offers new insights and design approaches for enhancing the output image uniformity based on diffraction optical waveguide technology, providing a new path for improving image uniformity in AR displays. Full article