Search Results (20)

Hydrogen, a promising alternative to conventional fuels, presents significant combustion hazards due to its low minimum ignition energy (MIE) and wide flammability range (4–75 vol.%). The risks are amplified with liquid hydrogen (LH₂), which has an extremely low boiling point (20.3 K) and high diffusivity. Once released, LH₂ vaporizes rapidly and mixes with ambient air. This process forms a cryogenic and highly flammable cloud, which significantly increases ignition and explosion hazards. Therefore, a comprehensive understanding of the MIE of cryogenic hydrogen–air mixtures is crucial for quantitative risk assessment. This work develops and validates a numerical algorithm for predicting the MIE of hydrogen–air mixtures at cryogenic temperatures (down to 93 K) across a wide range of hydrogen concentrations (10~50 vol.%) and oxygen concentration ratios [O₂/(O₂ + N₂) = 21~52%]. By coupling a detailed H₂/O₂ reaction mechanism with a large eddy simulation (LES) turbulence model, this algorithm demonstrates high reliability and accuracy. The results indicate (1) an exponential increase in MIE with decreasing initial temperature; (2) a U-shaped dependence of MIE on hydrogen concentration, with the minimum occurring near 25% hydrogen concentration; (3) an asymptotic dependence of MIE on oxygen concentration ratio, particularly at 40% hydrogen concentration. The initial temperature has the greatest influence on MIE; hydrogen concentration is the second; and the oxygen concentration ratio has the weakest influence. This study provides a theoretical framework and a practical computational tool for assessing and mitigating cryogenic ignition associated with LH₂ leakage, thereby enabling safer application of liquid hydrogen technologies. Full article

This study investigates the sealing performance of marine vent valves in low-temperature environments (−30 °C to −40 °C) via thermo-mechanical coupling analysis. Polytetrafluoroethylene (PTFE) was selected as the sealing material for its excellent cryogenic toughness, corrosion resistance, and cost-effectiveness. The total minimum specific sealing pressure ($q_{total}$) of PTFE, corrected for marine vibrations (15–60 Hz), was 3.702 MPa. Using ANSYS Workbench 2022, finite element simulations of a DN200 globe valve showed that low temperatures caused non-uniform thermal contraction, reducing the gasket-poppet contact width (2.5 mm to 1.75 mm) and maximum specific pressure (16.967 MPa to 13.352 MPa), leading to leakage risks. Optimizing the stem preload to 36,000 N restored effective sealing: the maximum specific pressure rebounded to 16.601 MPa, with no pressure below 3.702 MPa. This research provides a method for evaluating low-temperature sealing performance and supports safe vessel operation in cold waters. Full article

Hydrogen serves as a key clean-energy carrier, with the main hurdles lying in safe, efficient transport and storage (gas or liquid) and in end-use energy conversion. Liquid hydrogen (LH), as a high-density method of storage and transportation, presents cryogenic insulation as its key technical issues. In LH storage tanks, the performance of high vacuum multilayer insulation (HVMLI) will decline due to hydrogen release and leakage from the microscopic pores of steel, which significantly destroy the vacuum layer. The accumulation of residual gases will accelerate thermal failure, shorten the service life of storage tanks and increase safety risks. Adsorption is the most effective strategy for removing residual gases. This review aims to elucidate materials, methods, and design approaches related to hydrogen storage. First, it summarizes adsorbents used in liquid hydrogen storage tanks, including cryogenic adsorbents, metal oxides, zeolite molecular sieves, and non-volatile compounds. Second, it explores experimental testing methods and applications of hydrogen adsorbents in storage tanks, analyzing key challenges faced in practical applications and corresponding countermeasures. Finally, it proposes research prospects for exploring novel adsorbents and developing integrated systems. Full article

The thermal insulation performance of liquid hydrogen (LH₂) storage tanks is critical for long-distance transportation. The active cooled shield (ACS) technologies, such as the liquid nitrogen cooled shield (LNCS) and the vapor hydrogen cooled shield (VHVCS) are important thermal insulation methods. Many researchers installed the VHVCS inside the multilayer insulation (MLI) and obtained the optimal position. However, the MLI layer is often thinner than the vacuum interlayer between the inner and outer tanks, and there is a large vacuum interlayer between the outermost side of MLI and the inner wall of the outer tank. It is unknown whether the insulation performance can be improved if we install ACS in the mentioned vacuum interlayer and separate a portion of the MLI to be installed on the outer surface of ACS. In this configuration, the number of inner MLI (IMLI) layers and the ACS position are interdependent, a coupling that has not been thoroughly investigated. Therefore, thermodynamic models for MLI, MLI-LNCS, and MLI-VHVCS schemes were developed based on the Layer-by-Layer method. By applying Robin boundary conditions, the temperature distribution and heat leakage of the MLI scheme were predicted. Considering the coupled effects of IMLI layer count and ACS position, a co-optimization strategy was adopted, based on an alternating iterative search algorithm. The results indicate that for the MLI-LNCS scheme, the optimal number of IMLI layers and LNCS position are 36 layers and 49%, respectively. For the MLI-VHVCS scheme, the optimal values are 21 layers and 39%, respectively. Compared to conventional MLI, the MLI-LNCS scheme achieves an 88.09% reduction in heat leakage. However, this improvement involves increased system complexity and higher operational costs from LN₂ circulation. In contrast, the MLI-VHVCS scheme achieves a 62.74% reduction in heat leakage, demonstrating that using sensible heat from cryogenic vapor can significantly improve the thermal insulation performance of LH₂ storage tanks. The work of this paper provides a reference for the design and optimization of the insulation scheme of LH₂ storage tanks. Full article

Permanent magnetic couplings provide critical advantages for deep-sea systems through static-sealed, contactless power transmission. However, conventional metallic isolation sleeves incur significant eddy current losses, limiting efficiency and high-speed operation. Limited torque capacities fail to meet the operational demands of harsh marine environments. This study presents a novel permanent magnet coupling featuring a ceramic isolation sleeve engineered for deep-sea cryogenic ammonia submersible pumps. The ceramic sleeve eliminates eddy current losses and provides exceptional corrosion resistance in acidic/alkaline environments. To withstand 3.5 MPa hydrostatic pressure, a 6-mm-thick sleeve necessitates a 10 mm operational air gap, challenging magnetic circuit efficiency. To address this limitation, an improved 3D magnetic equivalent circuit (MEC) model was developed that explicitly accounts for flux leakage and axial end-effects, enabling the accurate characterization of large air gap fields. Leveraging this model, a Taguchi method-based optimization framework was implemented by balancing key parameters to maximize the torque density. This co-design strategy achieved a 21% increase in torque density, enabling higher torque transfer per unit volume. Experimental validation demonstrated a maximum torque of 920 Nm, with stable performance under simulated deep-sea conditions. This design establishes a new paradigm for high-power leak-free transmission in corrosive, high-pressure marine environments, advancing applications from deep-sea propulsion to offshore energy systems. Full article

This article uses FLUENT to construct a two-dimensional axisymmetric numerical model of a cryogenic hydrogen charging pipeline. By loading with initial temperature gradient and transient initial pressure disturbance, the basic characteristics of low-temperature hydrogen Taconis thermoacoustic oscillation are calculated, including temperature, heat flux density distribution, pressure amplitude, and frequency. The instability boundary of hydrogen TAO is also obtained. The results show that (1) the temperature distribution and flow characteristics of the gas inside the pipeline exhibit significant periodic changes. In the first half of the oscillation period, the cold-end gas moves towards the end of the pipeline. Low-viscosity cold hydrogen is easily heated and rapidly expands. In the second half of the cycle, the expanding cold gas pushes the hot-end gas to move towards the cold end, forming a low-pressure zone and causing gas backflow. (2) Thermoacoustic oscillation can also cause additional thermal leakage on the pipeline wall. The average heat flux during one cycle is 1150.1 W/m² for inflow and 1087.7 W/m² for outflow, with a net inflow heat flux of 62.4 W/m². (3) The instability boundary of the system is mainly determined by the temperature ratio of the cold and hot ends α, temperature gradient β, and length ratio of the cold and hot ends ξ. Increasing the pipe diameter and minimizing the pipe length can effectively weaken the amplitude of thermoacoustic oscillations. This study provides theoretical support for predicting thermoacoustic oscillations in low-temperature hydrogen transport pipeline systems and offers insights for system stability control and design verification. Full article

This study introduces an innovative annular sealing groove design inspired by the hierarchical structure of octopus suckers, addressing the limitations of conventional seals under extreme conditions in aerospace engineering. Using finite element analysis, eight bionic configurations with varying groove parameters (width, depth, number) were systematically evaluated under cryogenic (−196.25 °C) and high-pressure (2 MPa) scenarios. Results show that the optimized bionic6 configuration (seven grooves, 0.4 mm width, 0.4 mm depth) achieved a 21.71% improvement in average von Mises stress compared to the original design, demonstrating enhanced leakage resistance. Parameter interaction analysis revealed groove number as the most significant factor affecting performance, followed by width, while depth showed minimal influence. The hierarchical groove architecture effectively mimicked the multi-level sealing mechanism of octopus suckers, reducing leakage paths and improving adaptability to irregular surfaces. This work bridges biological inspiration and engineering application, providing a scalable solution for extreme environments. The identified optimal parameters lay a theoretical foundation for designing high-performance seals in aerospace, cryogenic storage, and advanced manufacturing. Full article

Linerless composite pressure vessels, or type V pressure vessels, are gaining increased interest in the transportation industry because they offer improved storage volume and dry weight, especially for low-pressure cryogenic storage. Nevertheless, the design and manufacturing of this type of pressure vessel bring several challenges due to the inherent difficulties in the manufacturing process implementation, assembly, and related analysis of structural integrity due to the severe operating conditions at cryogenic temperatures that should be taken into consideration. In this work, a novel analysis procedure using a finite element model is developed to perform an end-to-end simulation of a linerless pressure vessel, including the relevant features associated with automated fiber placement manufacturing processes regarding thickness and tape profiles, followed by an analysis of the structural response under service conditions. The results show that residual stresses from manufacturing achieve values near 50% of the composite ply transverse strength, which reduces the effective ply transverse load carrying capacity for pressure loading. Transverse damage is triggered and propagated across the vessel thickness before fiber breakage, indicating potential failure by leakage, which was confirmed by hydrostatic tests in the physical prototype at 26 bar. The cryogenic condition analysis revealed that the thermal stresses trigger transverse damage before pressure loading, reducing the estimated leak pressure by 40%. These results highlight the importance of considering the residual stresses that arise from the manufacturing process and the thermal stresses generated during cooling to cryogenic conditions, demonstrating the relevance of the presented methodology for designing linerless cryogenic composite pressure vessels. Full article

An inducer is a key component in a cryogenic pump to improve its cavitation performance. The thermodynamic effects of the cryogenic medium make the cryogenic cavitation flow extremely complicated. For this reason, it is crucial to investigate the cryogenic cavitation flow of the inducer which is equipped upstream of the cryogenic pump. In this paper, the isothermal cavitation model is modified based on the law of heat conduction, and the cryogenic cavitation model of the inducer is developed by considering thermodynamic effects. The turbulence model is also modified to account for the compressibility of cryogenic cavitation flow. The methods of numerical calculations are performed to investigate the influence of thermodynamic effects on cryogenic cavitation of the inducer. The law of the spatio-temporal evolution of cryogen cavitation in the inducer is clarified. The initial position, development and collapse phenomenon of cavitation are obtained. The relationship between the generation and collapse of the cavitation and the work capacity of the inducer’s blade, the relationship between thermodynamic effects and the influence of the inducer’s blade tip leakage vortex and thermodynamic on cryogenic cavitation of the inducer are revealed. Full article

Due to the extensive utilization of liquid nature gas (abbreviated as LNG) resources and a multitude of considerations, LNG storage tanks are gradually transitioning towards smaller footprints and heightened safety standards. Consequently, underground LNG storage tanks are being designed and constructed. However, underground LNG storage tanks release a considerable quantity of cold into the ground under both accidental and normal conditions. The influence of cold results in the ground freezing, which further compromises the safety of the structure. Existing research has neglected to consider the effects of this. This oversight could potentially lead to serious safety accidents. In this work, a complete set of experiments using a novel LNG underground storage tank fluid-solid-thermal coupled cryogenic leakage scale model were conducted for the first time to simulate the effect of the tank on the soil temperature field, stress field, and displacement field and to analyze the development of the three fields and the results of the effect. This research helps the related personnel to better design, construct, and evaluate the LNG underground storage tanks to avoid the catastrophic engineering risks associated with cryogenic leakage and helps to improve the design process of LNG underground storage tanks. Full article

The reliability and stability of the seal at the fuel-supply end of a rocket-engine turbopump are important factors in determining safety. Conventional single-stage floating rings used for the isolation-sealing of cryogenic media are highly susceptible to operational instability during startup and shutdown, which places demands on the seals’ structure, size, and material properties. In this study, a two-stage floating-ring isolation seal with a non-slotted main sealing surface was designed using a tangential air-intake mode. Based on the full-size three-dimensional finite-volume model, the leakage characteristics of the floating ring during operation were calculated, taking into account the effect of the “inlet effect” on the seal’s performance. Combining the temperature and pressure distributions of the sealing system under cryogenic operating conditions, calculated using a numerical simulation, a reliability analysis of various inlet directions and two kinds of floating-ring schemes was carried out on a self-constructed service-performance test bench. The results indicate that the main wear location of the non-slotted floating ring occurs on the auxiliary sealing surface, with stable working performance. When the inlet direction and spindle-rotation direction are the same, this is more conducive to ensuring the stability of seal performance in practical applications. The results of the current research are instructive for designing floating-ring isolation seals for turbine pumps. Full article

This study presented experimental and numerical research to investigate the effect of cryogenic leakage on a plate structure of AH36-grade steel containing welded joints. To simulate the cryogenic leakage conditions, the welded plate was exposed to a temperature of −196 °C by supplying liquid nitrogen (LN₂) to the center of the steel plate. The time-dependent temperature history and strain variation were measured by using thermocouples and strain gauges attached to the plate surface. Additionally, the residual stress of the middle surface section before and after the cryogenic leakage process was measured by X-ray diffraction analysis (XRD). A three-dimensional finite element model was created with the use of a commercial finite element analysis (FEA) program to simulate the flux-cored arc welding process and cryogenic leakage process. The steel surface temperature dropped sharply and reached approximately −196 °C at 160 s after LN₂ supplement. After the first 650 s of the LN₂ leakage experiment, the outside of the trough reached approximately −75 °C and −25 °C, depending on the location of the thermal couples. Although there was a relative difference in the results, the experiment and numerical simulation results for temperature and stress distribution showed good agreement. The results could be utilized in the ship design stage adopting welded structures as a basic database. Full article

The infections caused by the HSV-1 virus induce lesions on the lips, mouth, face, and eye. In this study, an ethosome gel loaded with dimethyl fumarate was investigated as a possible approach to treat HSV-1 infections. A formulative study was conducted, evaluating the effect of drug concentration on size distribution and dimensional stability of ethosomes by photon correlation spectroscopy. Ethosome morphology was investigated by cryogenic transmission electron microscopy, while the interaction between dimethyl fumarate and vesicles, and the drug entrapment capacity were respectively evaluated by FTIR and HPLC. To favor the topical application of ethosomes on mucosa and skin, different semisolid forms, based on xanthan gum or poloxamer 407, were designed and compared for spreadability and leakage. Dimethyl fumarate release and diffusion kinetics were evaluated in vitro by Franz cells. The antiviral activity against HSV-1 was tested by plaque reduction assay in Vero and HRPE monolayer cells, while skin irritation effect was evaluated by patch test on 20 healthy volunteers. The lower drug concentration was selected, resulting in smaller and longer stable vesicles, mainly characterized by a multilamellar organization. Dimethyl fumarate entrapment in ethosome was 91% w/w, suggesting an almost total recovery of the drug in the lipid phase. Xanthan gum 0.5%, selected to thicken the ethosome dispersion, allowed to control drug release and diffusion. The antiviral effect of dimethyl fumarate loaded in ethosome gel was demonstrated by a reduction in viral growth both 1 h and 4 h post-infection. Moreover, the patch test demonstrated the safety of the ethosomal gel applied on the skin. Full article

In this work, the numerical simulation of a SiGe heterojunction bipolar transistor (HBT) for DC and AC performance operating at cryogenic temperature with a hydrodynamic carrier transport model is analyzed. A new modified temperature-dependent Si_1−xGe_x energy bandgap model was used. Using a simplified 2D TCAD design structure, the device characteristics on 55 nm SiGe HBT technology and the mobility model are calibrated with experimental data. Base current reversal due to induced impact-ionization at the collector-base junction is analyzed, where the estimated collector-emitter breakdown voltage with the base open (BV_CEO) is 1.48 V at 300 K. This reveals good voltage handling ability. At cryogenic temperatures, dopant incomplete ionization in the lightly doped collector region shows a 28% decrease in ionized dopant concentration at 50 K; this affects the base-collector depletion capacitance. The emitter electron barrier tunneling leakage on collector current is studied using a non-local e-barrier tunneling model at different temperatures that shows an improvement in peak DC gain at lower temperatures. Using the small-signal ac analysis, the cut-off frequency and the maximum oscillation frequency are extracted for high-frequency application, and the base widening effect is discussed. A comparison of this work with measured data on 90 nm SiGe HBT is also discussed in brief, which shows improvements in the simulated structure. Full article

Floating ring seals are widely used as a leakage control solution for turbomachines because they effectively operate with small clearances between the shaft and seal. The oxidizer pump of the 7 tonf liquid engine in the Korea Space Launch Vehicle II (KSLV-II) operates at high rotational speeds and under cryogenic conditions and has floating ring seals in the bearing cooling path to reduce leakages. In this study, we evaluated the frictional force acting on the nose of the floating ring in the oxidizer pump of the 7 tonf turbopump using numerical analysis, and we investigated the radial force on the floating ring induced by the vibration of the rotor and the flow characteristics around the floating ring seal. Through a comparison of the frictional and floating forces according to the change in the diameter of the floating ring noses, we also estimated the dynamic positioning of the floating ring. In addition, we examined the leakage of the floating ring seals with the rotational speed and gap size of the floating ring, and we used the results as data for designing a floating ring seal. Finally, we performed turbopump real-propellant tests with the floating ring seal of the high and the middle noses, finding that the test result was in good agreement with the results of numerical analysis. Full article