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Search Results (1,577)

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27 pages, 39231 KiB  
Article
Study on the Distribution Characteristics of Thermal Melt Geological Hazards in Qinghai Based on Remote Sensing Interpretation Method
by Xing Zhang, Zongren Li, Sailajia Wei, Delin Li, Xiaomin Li, Rongfang Xin, Wanrui Hu, Heng Liu and Peng Guan
Water 2025, 17(15), 2295; https://doi.org/10.3390/w17152295 (registering DOI) - 1 Aug 2025
Abstract
In recent years, large-scale linear infrastructure developments have been developed across hundreds of kilometers of permafrost regions on the Qinghai–Tibet Plateau. The implementation of major engineering projects, including the Qinghai–Tibet Highway, oil pipelines, communication cables, and the Qinghai–Tibet Railway, has spurred intensified research [...] Read more.
In recent years, large-scale linear infrastructure developments have been developed across hundreds of kilometers of permafrost regions on the Qinghai–Tibet Plateau. The implementation of major engineering projects, including the Qinghai–Tibet Highway, oil pipelines, communication cables, and the Qinghai–Tibet Railway, has spurred intensified research into permafrost dynamics. Climate warming has accelerated permafrost degradation, leading to a range of geological hazards, most notably widespread thermokarst landslides. This study investigates the spatiotemporal distribution patterns and influencing factors of thermokarst landslides in Qinghai Province through an integrated approach combining field surveys, remote sensing interpretation, and statistical analysis. The study utilized multi-source datasets, including Landsat-8 imagery, Google Earth, GF-1, and ZY-3 satellite data, supplemented by meteorological records and geospatial information. The remote sensing interpretation identified 1208 cryogenic hazards in Qinghai’s permafrost regions, comprising 273 coarse-grained soil landslides, 346 fine-grained soil landslides, 146 thermokarst slope failures, 440 gelifluction flows, and 3 frost mounds. Spatial analysis revealed clusters of hazards in Zhiduo, Qilian, and Qumalai counties, with the Yangtze River Basin and Qilian Mountains showing the highest hazard density. Most hazards occur in seasonally frozen ground areas (3500–3900 m and 4300–4900 m elevation ranges), predominantly on north and northwest-facing slopes with gradients of 10–20°. Notably, hazard frequency decreases with increasing permafrost stability. These findings provide critical insights for the sustainable development of cold-region infrastructure, environmental protection, and hazard mitigation strategies in alpine engineering projects. Full article
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32 pages, 1970 KiB  
Review
A Review of New Technologies in the Design and Application of Wind Turbine Generators
by Pawel Prajzendanc and Christian Kreischer
Energies 2025, 18(15), 4082; https://doi.org/10.3390/en18154082 (registering DOI) - 1 Aug 2025
Abstract
The growing global demand for electricity, driven by the development of electromobility, data centers, and smart technologies, necessitates innovative approaches to energy generation. Wind power, as a clean and renewable energy source, plays a pivotal role in the global transition towards low-carbon power [...] Read more.
The growing global demand for electricity, driven by the development of electromobility, data centers, and smart technologies, necessitates innovative approaches to energy generation. Wind power, as a clean and renewable energy source, plays a pivotal role in the global transition towards low-carbon power systems. This paper presents a comprehensive review of generator technologies used in wind turbine applications, ranging from conventional synchronous and asynchronous machines to advanced concepts such as low-speed direct-drive (DD) generators, axial-flux topologies, and superconducting generators utilizing low-temperature superconductors (LTS) and high-temperature superconductors (HTS). The advantages and limitations of each design are discussed in the context of efficiency, weight, reliability, scalability, and suitability for offshore deployment. Special attention is given to HTS-based generator systems, which offer superior power density and reduced losses, along with challenges related to cryogenic cooling and materials engineering. Furthermore, the paper analyzes selected modern generator designs to provide references for enhancing the performance of grid-synchronized hybrid microgrids integrating solar PV, wind, battery energy storage, and HTS-enhanced generators. This review serves as a valuable resource for researchers and engineers developing next-generation wind energy technologies with improved efficiency and integration potential. Full article
(This article belongs to the Special Issue Advancements in Marine Renewable Energy and Hybridization Prospects)
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13 pages, 13107 KiB  
Article
Ceramic Isolated High-Torque Permanent Magnet Coupling for Deep-Sea Applications
by Liying Sun, Xiaohui Gao and Yongguang Liu
J. Mar. Sci. Eng. 2025, 13(8), 1474; https://doi.org/10.3390/jmse13081474 - 31 Jul 2025
Abstract
Permanent magnetic couplings provide critical advantages for deep-sea systems through static-sealed, contactless power transmission. However, conventional metallic isolation sleeves incur significant eddy current losses, limiting efficiency and high-speed operation. Limited torque capacities fail to meet the operational demands of harsh marine environments. This [...] Read more.
Permanent magnetic couplings provide critical advantages for deep-sea systems through static-sealed, contactless power transmission. However, conventional metallic isolation sleeves incur significant eddy current losses, limiting efficiency and high-speed operation. Limited torque capacities fail to meet the operational demands of harsh marine environments. This study presents a novel permanent magnet coupling featuring a ceramic isolation sleeve engineered for deep-sea cryogenic ammonia submersible pumps. The ceramic sleeve eliminates eddy current losses and provides exceptional corrosion resistance in acidic/alkaline environments. To withstand 3.5 MPa hydrostatic pressure, a 6-mm-thick sleeve necessitates a 10 mm operational air gap, challenging magnetic circuit efficiency. To address this limitation, an improved 3D magnetic equivalent circuit (MEC) model was developed that explicitly accounts for flux leakage and axial end-effects, enabling the accurate characterization of large air gap fields. Leveraging this model, a Taguchi method-based optimization framework was implemented by balancing key parameters to maximize the torque density. This co-design strategy achieved a 21% increase in torque density, enabling higher torque transfer per unit volume. Experimental validation demonstrated a maximum torque of 920 Nm, with stable performance under simulated deep-sea conditions. This design establishes a new paradigm for high-power leak-free transmission in corrosive, high-pressure marine environments, advancing applications from deep-sea propulsion to offshore energy systems. Full article
(This article belongs to the Section Ocean Engineering)
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16 pages, 4461 KiB  
Article
Study on the Influence of Inducer Structure Change on Pump Cavitation Characteristics
by Zhengwei Wang, Wei Song, Xuanyi Lin, Yun Zhao and Yonggang Lu
Energies 2025, 18(15), 4059; https://doi.org/10.3390/en18154059 (registering DOI) - 31 Jul 2025
Abstract
Given that cryogenic pumps on liquefied natural gas (LNG) carriers are prone to cavitation under complex operating conditions, this paper examines the inducer of an LNG centrifugal pump to uncover how the inducer geometry affects both the cavitation behavior and internal flow-induced excitation [...] Read more.
Given that cryogenic pumps on liquefied natural gas (LNG) carriers are prone to cavitation under complex operating conditions, this paper examines the inducer of an LNG centrifugal pump to uncover how the inducer geometry affects both the cavitation behavior and internal flow-induced excitation at −163 °C. Through detailed numerical simulations, we evaluate the cavitation performance and flow excitation characteristics across a range of inducer designs, systematically varying the blade count, inlet and outlet angles, and blade wrap angle. Our results show that reducing the number of blades, together with properly optimized inlet/outlet and wrap angles, significantly enhances the cavitation resistance. These findings provide a solid theoretical basis and practical guidance for the engineering optimization of LNG ship pumps. Full article
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19 pages, 2616 KiB  
Article
Structural Analysis of Joints Made of Titanium Alloy TI-6AL-4V and Stainless Steel AISI 321 with Developed Conical Contact Surfaces Obtained by Diffusion Welding
by Olena Karpovych, Ivan Karpovych, Oleksii Fedosov, Denys Zhumar, Yevhen Karakash, Miroslav Rimar, Jan Kizek and Marcel Fedak
Materials 2025, 18(15), 3596; https://doi.org/10.3390/ma18153596 (registering DOI) - 31 Jul 2025
Abstract
The object of this study is welded joints of AISI 321 and Ti-6Al-4V, obtained by diffusion welding on developed conical surfaces. The problem of creating bimetallic joints of AISI 321 and Ti-6Al-4V with developed conical contact surfaces, using diffusion welding through an intermediate [...] Read more.
The object of this study is welded joints of AISI 321 and Ti-6Al-4V, obtained by diffusion welding on developed conical surfaces. The problem of creating bimetallic joints of AISI 321 and Ti-6Al-4V with developed conical contact surfaces, using diffusion welding through an intermediate Electrolytic Tough Pitch Copper (Cu-ETP) copper layer, was solved. The joints were studied using micro-X-ray spectral analysis, microstructural analysis, and mechanical tests. High mutual diffusion of copper and titanium, along with increased concentrations of Cr and V in copper, was detected. The shear strength of the obtained welded joints is 250 MPa and 235 MPa at 30 min and 15 min, respectively, which is higher than the copper layer’s strength (180 MPa). The obtained results are explained by the dislocation diffusion mechanism in the volume of grains and beyond, due to thermal deformations during welding. Under operating conditions of internal pressure and cryogenic temperatures, the strength of the connection is ensured by the entire two-layer structure, and tightness is ensured by a vacuum-tight diffusion connection. The obtained strength of the connection (250 MPa) is sufficient under the specified operating conditions. Analysis of existing solutions in the literature review indicates that industrial application of technology for manufacturing bimetallic adapters from AISI 321 stainless steel and Ti-6Al-4V titanium alloy is limited to butt joints with small geometric dimensions. Studies of the transition zone structure and diffusion processes in bimetallic joints with developed conical contact surfaces enabled determination of factors affecting joint structure and diffusion coefficients. The obtained bimetallic adapters, made of Ti-6Al-4V titanium alloy and AISI 321 stainless steel, can be used to connect titanium high-pressure vessels with stainless steel pipelines. Full article
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15 pages, 5275 KiB  
Article
Effect of Copper in Gas-Shielded Solid Wire on Microstructural Evolution and Cryogenic Toughness of X80 Pipeline Steel Welds
by Leng Peng, Rui Hong, Qi-Lin Ma, Neng-Sheng Liu, Shu-Biao Yin and Shu-Jun Jia
Materials 2025, 18(15), 3519; https://doi.org/10.3390/ma18153519 - 27 Jul 2025
Viewed by 270
Abstract
This study systematically evaluates the influence of copper (Cu) addition in gas-shielded solid wires on the microstructure and cryogenic toughness of X80 pipeline steel welds. Welds were fabricated using solid wires with varying Cu contents (0.13–0.34 wt.%) under identical gas metal arc welding [...] Read more.
This study systematically evaluates the influence of copper (Cu) addition in gas-shielded solid wires on the microstructure and cryogenic toughness of X80 pipeline steel welds. Welds were fabricated using solid wires with varying Cu contents (0.13–0.34 wt.%) under identical gas metal arc welding (GMAW) parameters. The mechanical capacities were assessed via tensile testing, Charpy V-notch impact tests at −20 °C and Vickers hardness measurements. Microstructural evolution was characterized through optical microscopy (OM), scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). Key findings reveal that increasing the Cu content from 0.13 wt.% to 0.34 wt.% reduces the volume percentage of acicular ferrite (AF) in the weld metal by approximately 20%, accompanied by a significant decline in cryogenic toughness, with the average impact energy decreasing from 221.08 J to 151.59 J. Mechanistic analysis demonstrates that the trace increase in the Cu element. The phase transition temperature and inclusions is not significant but can refine the prior austenite grain size of the weld, so that the total surface area of the grain boundary increases, and the surface area of the inclusions within the grain is relatively small, resulting in the nucleation of acicular ferrite within the grain being weak. This microstructural transition lowers the critical crack size and diminishes the density for high-angle grain boundaries (HAGBs > 45°), which weakens crack deflection capability. Consequently, the crack propagation angle decreases from 54.73° to 45°, substantially reducing the energy required for stable crack growth and deteriorating low-temperature toughness. Full article
(This article belongs to the Section Metals and Alloys)
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31 pages, 5261 KiB  
Review
Wear- and Corrosion-Resistant Coatings for Extreme Environments: Advances, Challenges, and Future Perspectives
by Subin Antony Jose, Zachary Lapierre, Tyler Williams, Colton Hope, Tryon Jardin, Roberto Rodriguez and Pradeep L. Menezes
Coatings 2025, 15(8), 878; https://doi.org/10.3390/coatings15080878 - 26 Jul 2025
Viewed by 559
Abstract
Tribological processes in extreme environments pose serious material challenges, requiring coatings that resist both wear and corrosion. This review summarizes recent advances in protective coatings engineered for extreme environments such as high temperatures, chemically aggressive media, and high-pressure and abrasive domains, as well [...] Read more.
Tribological processes in extreme environments pose serious material challenges, requiring coatings that resist both wear and corrosion. This review summarizes recent advances in protective coatings engineered for extreme environments such as high temperatures, chemically aggressive media, and high-pressure and abrasive domains, as well as cryogenic and space applications. A comprehensive overview of promising coating materials is provided, including ceramic-based coatings, metallic and alloy coatings, and polymer and composite systems, as well as nanostructured and multilayered architectures. These materials are deployed using advanced coating technologies such as thermal spraying (plasma spray, high-velocity oxygen fuel (HVOF), and cold spray), chemical and physical vapor deposition (CVD and PVD), electrochemical methods (electrodeposition), additive manufacturing, and in situ coating approaches. Key degradation mechanisms such as adhesive and abrasive wear, oxidation, hot corrosion, stress corrosion cracking, and tribocorrosion are examined with coating performance. The review also explores application-specific needs in aerospace, marine, energy, biomedical, and mining sectors operating in aggressive physiological environments. Emerging trends in the field are highlighted, including self-healing and smart coatings, environmentally friendly coating technologies, functionally graded and nanostructured coatings, and the integration of machine learning in coating design and optimization. Finally, the review addresses broader considerations such as scalability, cost-effectiveness, long-term durability, maintenance requirements, and environmental regulations. This comprehensive analysis aims to synthesize current knowledge while identifying future directions for innovation in protective coatings for extreme environments. Full article
(This article belongs to the Special Issue Advanced Tribological Coatings: Fabrication and Application)
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14 pages, 1682 KiB  
Article
Recording of Cardiac Excitation Using a Novel Magnetocardiography System with Magnetoresistive Sensors Outside a Magnetic Shielded Room
by Leo Yaga, Miki Amemiya, Yu Natsume, Tomohiko Shibuya and Tetsuo Sasano
Sensors 2025, 25(15), 4642; https://doi.org/10.3390/s25154642 - 26 Jul 2025
Viewed by 277
Abstract
Magnetocardiography (MCG) provides a non-invasive, contactless technique for evaluating the magnetic fields generated by cardiac electrical activity, offering unique spatial insights into cardiac electrophysiology. However, conventional MCG systems depend on superconducting quantum interference devices that require cryogenic cooling and magnetic shielded environments, posing [...] Read more.
Magnetocardiography (MCG) provides a non-invasive, contactless technique for evaluating the magnetic fields generated by cardiac electrical activity, offering unique spatial insights into cardiac electrophysiology. However, conventional MCG systems depend on superconducting quantum interference devices that require cryogenic cooling and magnetic shielded environments, posing considerable impediments to widespread clinical adoption. In this study, we present a novel MCG system utilizing a high-sensitivity, wide-dynamic-range magnetoresistive sensor array operating at room temperature. To mitigate environmental interference, identical sensors were deployed as reference channels, enabling adaptive noise cancellation (ANC) without the need for traditional magnetic shielding. MCG recordings were obtained from 40 healthy participants, with signals processed using ANC, R-peak-synchronized averaging, and Bayesian spatial signal separation. This approach enabled the reliable detection of key cardiac components, including P, QRS, and T waves, from the unshielded MCG recordings. Our findings underscore the feasibility of a cost-effective, portable MCG system suitable for clinical settings, presenting new opportunities for noninvasive cardiac diagnostics and monitoring. Full article
(This article belongs to the Special Issue Novel Optical Sensors for Biomedical Applications—2nd Edition)
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41 pages, 16361 KiB  
Review
Progress on Sustainable Cryogenic Machining of Hard-to-Cut Material and Greener Processing Techniques: A Combined Machinability and Sustainability Perspective
by Shafahat Ali, Said Abdallah, Salman Pervaiz and Ibrahim Deiab
Lubricants 2025, 13(8), 322; https://doi.org/10.3390/lubricants13080322 - 23 Jul 2025
Viewed by 228
Abstract
The current research trends of production engineering are based on optimizing the machining process concerning human and environmental factors. High-performance materials, such as hardened steels, nickel-based alloys, fiber-reinforced polymer (FRP) composites, and titanium alloys, are classified as hard-to-cut due to their ability to [...] Read more.
The current research trends of production engineering are based on optimizing the machining process concerning human and environmental factors. High-performance materials, such as hardened steels, nickel-based alloys, fiber-reinforced polymer (FRP) composites, and titanium alloys, are classified as hard-to-cut due to their ability to maintain strength at high operating temperatures. Due to these characteristics, such materials are employed in applications such as aerospace, marine, energy generation, and structural. The purpose of this article is to investigate the machinability of these alloys under various cutting conditions. The purpose of this article is to compare cryogenic cooling and cryogenic processing from the perspective of machinability and sustainability in the manufacturing process. Compared to conventional machining, hybrid techniques, which mix cryogenic and minimal quantity lubricant, led to significantly reduced cutting forces of 40–50%, cutting temperatures and surface finishes by approximately 20–30% and more than 40%, respectively. A carbon footprint is determined by several factors including power consumption, energy requirements, and carbon dioxide emissions. As a result of the cryogenic technology, the energy consumption, power consumption, and CO2 emissions were reduced by 40%, 28%, and 35%. Full article
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9 pages, 2281 KiB  
Communication
Characterization of Small Extracellular Vesicles Isolated from Aurelia aurita
by Aldona Dobrzycka-Krahel, Aleksandra Steć, Grzegorz S. Czyrski, Andrea Heinz and Szymon Dziomba
Biology 2025, 14(8), 922; https://doi.org/10.3390/biology14080922 - 23 Jul 2025
Viewed by 237
Abstract
A moon jellyfish (Aurelia aurita) is a representative of the phylum Cnidaria, commonly found in the northern seas of the globe. The regenerative abilities of cnidarians have recently been associated with extracellular vesicles (EVs) secreted by these organisms. In this study, [...] Read more.
A moon jellyfish (Aurelia aurita) is a representative of the phylum Cnidaria, commonly found in the northern seas of the globe. The regenerative abilities of cnidarians have recently been associated with extracellular vesicles (EVs) secreted by these organisms. In this study, a method for the isolation of EVs from the oral arms of A. aurita is presented. The methodology includes differential centrifugation, size-exclusion chromatography, and ultrafiltration. The isolates were characterized with tunable resistive pulse sensing, cryogenic transmission electron microscopy, capillary electrophoresis (CE), and electrophoretic light scattering (ELS). Small (<150 nm in diameter) EVs were abundant in the isolates. The EVs were found to carry nucleic acids, indicating their role in signaling. Additionally, the difference in zeta potential values measured with ELS and CE indicates high glycation in the vesicles analyzed. Although the method developed was effective in isolating EVs from small sample volumes (0.5 mL), the EV yield was insufficient for omics analysis. Thus, the scaling up of the isolation process is required for comprehensive biochemical analysis and biological activity assessment in A. aurita-derived EVs. Full article
(This article belongs to the Section Marine Biology)
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19 pages, 5702 KiB  
Article
Experimental Investigation on Microstructure and Mechanical Properties of Deep Cryogenically Treated Vanadium Alloy Steels
by Dilşad Akgümüş Gök and Rasim İpek
Metals 2025, 15(8), 822; https://doi.org/10.3390/met15080822 - 23 Jul 2025
Viewed by 198
Abstract
In this study, deep cryogenic treatment (DCT) was applied to cold work tool steels with different vanadium weights (Vanadis 4 and Vanadis 10) for 12, 24 and 36 h, and the changes in their mechanical properties and microstructures were examined. Compression, tensile, hardness, [...] Read more.
In this study, deep cryogenic treatment (DCT) was applied to cold work tool steels with different vanadium weights (Vanadis 4 and Vanadis 10) for 12, 24 and 36 h, and the changes in their mechanical properties and microstructures were examined. Compression, tensile, hardness, SEM–EDS, carbide size, XRD and Rietveld analyses were performed to examine the mechanical and microstructural properties of the cryogenically treated samples. In this study, increasing the cryogenic treatment time and vanadium weight ratio did not have a positive effect on the hardness, and it was determined that the most positive result in terms of tensile and compressive strength was obtained in the V4DCT-24 sample. The results of this study showed that the cryogenic treatment formed secondary carbides, vanadium carbide (VC) and chromium carbide (Cr7C3), in vanadium cold work tool steels and reduced the amount of retained austenite (γ-Fe), transformed into martensite (α’-Fe) structures. Additionally, cryogenically treated Vanadis steels are thought to be usable in the metal processing industry, especially for cutting tools and molds. Full article
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130 pages, 2839 KiB  
Review
Issues Relative to the Welding of Nickel and Its Alloys
by Adam Rylski and Krzysztof Siczek
Materials 2025, 18(15), 3433; https://doi.org/10.3390/ma18153433 - 22 Jul 2025
Viewed by 187
Abstract
Nickel is used in aerospace, military, energy, and chemical sectors. Commercially pure (CP) Ni, and its alloys, including solid-solution strengthened (SSS), precipitation strengthened (PS), and specialty alloys (SA), are widely utilized, typically at elevated temperatures, in corrosive settings and in cryogenic milieu. Ni [...] Read more.
Nickel is used in aerospace, military, energy, and chemical sectors. Commercially pure (CP) Ni, and its alloys, including solid-solution strengthened (SSS), precipitation strengthened (PS), and specialty alloys (SA), are widely utilized, typically at elevated temperatures, in corrosive settings and in cryogenic milieu. Ni or Ni-based alloys frequently require welding realized, inter alia, via methods using electric arc and beam power. Tungsten inert gas (TIG) and Electron-beam welding (EBW) have been utilized most often. Friction stir welding (FSW) is the most promising solid-state welding technique for connecting Ni and its alloys. The primary weldability issues related to Ni and its alloys are porosity, as well as hot and warm cracking. CP Ni exhibits superior weldability. It is vulnerable to porosity and cracking during the solidification of the weld metal. Typically, SSS alloys demonstrate superior weldability when compared to PS Ni alloys; however, both types may experience weld metal solidification cracking, liquation cracking in the partially melted and heat-affected zones, as well as ductility-dip cracking (DDC). Furthermore, PS alloys are prone to strain-age cracking (SAC). The weldability of specialty Ni alloys is limited, and brazing might provide a solution. Employing appropriate filler metal, welding settings, and minimal restraint can reduce or avert cracking. Full article
(This article belongs to the Section Metals and Alloys)
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24 pages, 15762 KiB  
Article
Performance of TiSiN/TiAlN-Coated Carbide Tools in Slot Milling of Hastelloy C276 with Various Cooling Strategies
by Ly Chanh Trung and Tran Thien Phuc
Lubricants 2025, 13(7), 316; https://doi.org/10.3390/lubricants13070316 - 19 Jul 2025
Viewed by 423
Abstract
Nickel-based superalloy Hastelloy C276 is widely used in high-performance industries due to its strength, corrosion resistance, and thermal stability. However, these same properties pose substantial challenges in machining, resulting in high tool wear, surface defects, and dimensional inaccuracies. This study investigates methods to [...] Read more.
Nickel-based superalloy Hastelloy C276 is widely used in high-performance industries due to its strength, corrosion resistance, and thermal stability. However, these same properties pose substantial challenges in machining, resulting in high tool wear, surface defects, and dimensional inaccuracies. This study investigates methods to enhance machining performance and surface quality by evaluating the tribological behavior of TiSiN/TiAlN-coated carbide inserts under six cooling and lubrication conditions: dry, MQL with coconut oil, Cryo-LN2, Cryo-LCO2, MQL–Cryo-LN2, and MQL–Cryo-LCO2. Open-slot finishing was performed at constant cutting parameters, and key indicators such as cutting zone temperature, tool wear, surface roughness, chip morphology, and microhardness were analyzed. The hybrid MQL–Cryo-LN2 approach significantly outperformed other methods, reducing cutting zone temperature, tool wear, and surface roughness by 116.4%, 94.34%, and 76.11%, respectively, compared to dry machining. SEM and EDS analyses confirmed abrasive, oxidative, and adhesive wear as the dominant mechanisms. The MQL–Cryo-LN2 strategy also lowered microhardness, in contrast to a 39.7% increase observed under dry conditions. These findings highlight the superior performance of hybrid MQL–Cryo-LN2 in improving machinability, offering a promising solution for precision-driven applications. Full article
(This article belongs to the Special Issue High Performance Machining and Surface Tribology)
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12 pages, 1442 KiB  
Article
Reversible Binding of Nitric Oxide in a Cu(II)-Containing Microporous Metal-Organic Framework
by Konstantin A. Bikov, Götz Schuck and Peter A. Georgiev
Molecules 2025, 30(14), 3007; https://doi.org/10.3390/molecules30143007 - 17 Jul 2025
Viewed by 231
Abstract
We studied the adsorption thermodynamics and mechanism behind the binding of nitric oxide (NO) in the interior surfaces and structural fragments of the high metal center density microporous Metal-Organic Framework (MOF) CPO-27-Cu, by gas sorption, at a series of temperatures. For the purpose [...] Read more.
We studied the adsorption thermodynamics and mechanism behind the binding of nitric oxide (NO) in the interior surfaces and structural fragments of the high metal center density microporous Metal-Organic Framework (MOF) CPO-27-Cu, by gas sorption, at a series of temperatures. For the purpose of comparison, we also measured the corresponding CO2 adsorption isotherms, and as a result, the isosteric heats of adsorption for the two studied adsorptives were derived, being in the range of 12–15 kJ/mol for NO at loadings up to 0.5 NO molecules per formula unit (f.u.) of the bare compound (C4O3HCu), and 23–25 kJ/mol CO2 in the range 0–1 CO2 per f.u. Microscopically, the mode of NO binding near the square pyramid Cu(II) centers was directly accessed with the use of in situ NO gas adsorption X-ray Absorption Spectroscopy (XAS). Additionally, during the vacuum/temperature activation of the material and consequent NO adsorption, the electronic state of the Cu-species was monitored by observing the corresponding X-ray Near Edge Spectra (XANES). Contrary to the previously anticipated chemisorption mechanism for NO binding at Cu(II) species, we found that at slightly elevated temperatures, under ambient, but also cryogenic conditions, only relatively weak physisorption takes place, with no evidence for a particular adsorption preference to the coordinatively unsaturated Cu-centers of the material. Full article
(This article belongs to the Special Issue Functional Porous Frameworks: Synthesis, Properties, and Applications)
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15 pages, 1642 KiB  
Article
Cryogenic System for FTIR Analysis of Hydrocarbon Fuels at Low Temperature and Atmospheric Pressure
by Gulzhan Turlybekova, Alisher Kenbay, Abdurakhman Aldiyarov, Yevgeniy Korshikov, Aidos Lesbayev, Assel Nurmukan and Darkhan Yerezhep
Appl. Sci. 2025, 15(14), 7944; https://doi.org/10.3390/app15147944 - 17 Jul 2025
Viewed by 298
Abstract
This study presents a novel approach to FTIR spectroscopy at low temperatures under atmospheric pressure. The work aimed to confirm the efficiency of a fundamentally new cryogenic setup that enables material research under the specified conditions. The new technique combines a nitrogen-based cryogenic [...] Read more.
This study presents a novel approach to FTIR spectroscopy at low temperatures under atmospheric pressure. The work aimed to confirm the efficiency of a fundamentally new cryogenic setup that enables material research under the specified conditions. The new technique combines a nitrogen-based cryogenic capillary cooling system with precise temperature monitoring via a PID controller, along with DRIFT spectroscopy for hydrocarbon materials. New fundamental data were obtained on the properties and behavior of hydrocarbon compounds such as methanol, kerosene, and ethanol. The IR spectra of these samples contain key characteristic vibrations of hydrocarbon functional groups, which demonstrate the effective operability of the cryogenic device. A detailed description of the setup and measurement technique is provided, along with a thorough comparison of the results with data from other authors. The application scope of the cryogenic device, the relevance of the research, and potential future developments are also discussed. Full article
(This article belongs to the Special Issue Advanced Spectroscopy Technologies)
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