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Keywords = critical pitting temperature

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24 pages, 13038 KiB  
Article
Simulation and Analysis of Electric Thermal Coupling for Corrosion Damage of Metro Traction Motor Bearings
by Haisheng Yang, Zhanwang Shi, Xuelan Wang, Jiahang Zhang, Run Zhang and Hengdi Wang
Machines 2025, 13(8), 680; https://doi.org/10.3390/machines13080680 - 1 Aug 2025
Viewed by 161
Abstract
With the electrification of generator sets, electric locomotives, new energy vehicles, and other industries, AC motors subject bearings to an electric field environment, leading to galvanic corrosion due to the use of variable frequency power supply drives. The phenomenon of bearing discharge breakdown [...] Read more.
With the electrification of generator sets, electric locomotives, new energy vehicles, and other industries, AC motors subject bearings to an electric field environment, leading to galvanic corrosion due to the use of variable frequency power supply drives. The phenomenon of bearing discharge breakdown in subway traction motors is a critical issue in understanding the relationship between shaft current strength and the extent of bearing damage. This paper analyzes the mechanism of impulse discharge that leads to galvanic corrosion damage in bearings at a microscopic level and conducts electric thermal coupling simulations of the traction motor bearing discharge breakdown process. It examines the temperature rise associated with lubricant film discharge breakdown during the dynamic operation of the bearing and investigates how breakdown channel parameters and operational conditions affect the temperature rise in the micro-region of bearing lubrication. Ultimately, the results of the electric thermal coupling simulation are validated through experimental tests. This study revealed that in an electric field environment, the load-bearing area of the outer ring experiences significantly more severe corrosion damage than the inner ring, whereas non-bearing areas remain unaffected by electrolytic corrosion. When the inner ring reaches a speed of 4500_rpm, the maximum widths of electrolytic corrosion pits for the outer and inner rings are measured at 89 um and 51 um, respectively. Additionally, the highest recorded temperatures for the breakdown channels in the outer and inner rings are 932 °C and 802 °C, respectively. Furthermore, as the inner ring speed increases, both the width of the electrolytic corrosion pits and the temperature of the breakdown channels rise. Specifically, at inner ring speeds of 2500_rpm, 3500_rpm, and 4500_rpm, the widths of the electrolytic pits in the outer ring raceway load zone were measured at 34 um, 56 um, and 89 um, respectively. The highest temperatures of the lubrication film breakdown channels were recorded as 612 °C, 788 °C, and 932 °C, respectively. This study provides a theoretical basis and data support for the protective and maintenance practices of traction motor bearings. Full article
(This article belongs to the Section Electrical Machines and Drives)
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22 pages, 9767 KiB  
Article
Freeze–Thaw-Induced Degradation Mechanisms and Slope Stability of Filled Fractured Rock Masses in Cold Region Open-Pit Mines
by Jun Hou, Penghai Zhang, Ning Gao, Wanni Yan and Qinglei Yu
Appl. Sci. 2025, 15(13), 7429; https://doi.org/10.3390/app15137429 - 2 Jul 2025
Viewed by 245
Abstract
In cold regions, the rock mass of open-pit mine slopes is continuously exposed to freeze–thaw (FT) environments, during which the fracture structures and their infilling materials undergo significant degradation, severely affecting slope stability and the assessment of service life. Conventional laboratory [...] Read more.
In cold regions, the rock mass of open-pit mine slopes is continuously exposed to freeze–thaw (FT) environments, during which the fracture structures and their infilling materials undergo significant degradation, severely affecting slope stability and the assessment of service life. Conventional laboratory FT tests are typically based on uniform temperature settings, which fail to reflect the actual thermal variations at different burial depths, thereby limiting the accuracy of mechanical parameter acquisition. Taking the Wushan open-pit mine as the engineering background, this study establishes a temperature–depth relationship, defines multiple thermal intervals, and conducts direct shear tests on structural plane filling materials under various FT conditions to characterize the evolution of cohesion and internal friction angle. Results from rock mass testing and numerical simulation demonstrate that shear strength parameters exhibit an exponential decline with increasing FT cycles and decreasing burial depth, with the filling material playing a dominant role in the initial stage of degradation. Furthermore, a two-dimensional fracture network model of the rock mass was constructed, and the representative elementary volume (REV) was determined through the evolution of equivalent plastic strain. Based on this, spatial assignment of slope strength was performed, followed by stability analysis. Based on regression fitting using 0–25 FT cycles, regression model predictions indicate that when the number of FT cycles exceeds 42, the slope safety factor drops below 1.0, entering a critical instability state. This research successfully establishes a spatial field of mechanical parameters and evaluates slope stability, providing a theoretical foundation and parameter support for the long-term service evaluation and stability assessment of cold-region open-pit mine slopes. Full article
(This article belongs to the Special Issue Rock Mechanics and Mining Engineering)
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24 pages, 14794 KiB  
Article
Development of Laser AM Process to Repair Damaged Super Duplex Stainless Steel Components
by Abdul Ahmad, Paul Xirouchakis, Alastair Pearson, Frazer Brownlie and Yevgen Gorash
Sustainability 2025, 17(12), 5438; https://doi.org/10.3390/su17125438 - 12 Jun 2025
Viewed by 580
Abstract
The escalating demands of industrial applications, particularly those involving severe wear, temperature, and corrosive environments, present significant challenges for the long-term strength of critical components, often fabricated from high-value materials such as super duplex stainless steel alloys. Super duplex can withstand the corrosive [...] Read more.
The escalating demands of industrial applications, particularly those involving severe wear, temperature, and corrosive environments, present significant challenges for the long-term strength of critical components, often fabricated from high-value materials such as super duplex stainless steel alloys. Super duplex can withstand the corrosive environment (in particular, crevice corrosion and pitting damage) and maintain mechanical integrity sufficient for high-pressure pumping applications such as seawater injection and crude oil. Conventional repair methodologies frequently result in component rejection due to process-induced distortions or detrimental phase transformations, contributing to substantial material waste and hindering the adoption of circular economy principles. This research addresses this issue by developing and validating a novel repair process utilizing laser metal deposition (LMD) additive manufacturing. The research focuses on establishing optimized process parameters to ensure the salvaging and restoration of damaged super duplex components while preserving their requisite mechanical integrity and corrosion resistance, in accordance with industry standards. Comprehensive characterization, including microstructural analysis, chemical composition verification, hardness profiling, and mechanical fatigue testing, confirms the efficacy of the LMD repair process. This work demonstrates the potential for extending the service life of critical components, thereby promoting resource efficiency and contributing to a more sustainable and resilient industrial paradigm. Full article
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18 pages, 22803 KiB  
Article
Strength Deterioration Pattern and Stability Evaluation of Open−Pit Mine Slopes in Cold Regions Under Freeze–Thaw Cycles
by Penghai Zhang, Ning Gao, Wanni Yan, Jun Hou and Honglei Liu
Appl. Sci. 2025, 15(9), 4853; https://doi.org/10.3390/app15094853 - 27 Apr 2025
Cited by 3 | Viewed by 453
Abstract
With the gradual depletion of mineral resources in temperate regions, cold regions have become primary areas for mineral extraction. However, the freeze–thaw phenomena induced by temperature fluctuations pose significant threats to the stability of rock masses on open−pit mine slopes, further affecting normal [...] Read more.
With the gradual depletion of mineral resources in temperate regions, cold regions have become primary areas for mineral extraction. However, the freeze–thaw phenomena induced by temperature fluctuations pose significant threats to the stability of rock masses on open−pit mine slopes, further affecting normal mining operations. To investigate the strength degradation and stability evolution patterns of freeze–thaw slope rock masses, this study takes the Wushan Open−Pit Mine as its engineering context. We analyzed the relationship between rock temperature and burial depth, conducted freeze–thaw cyclic tests under realistic temperature ranges, and developed a mechanical parameter characterization model for freeze–thaw rock masses by integrating the generalized Hoek–Brown strength criterion. Slope safety factors and potential landslide mechanisms were determined through numerical simulations and the strength reduction method. Key findings include the following: (1) Shallow rock temperatures exhibit high synchronization with atmospheric temperature, characterized by large fluctuations and rapid variation rates, whereas deep rock demonstrates opposite trends. (2) As freeze–thaw cycles increase and burial depth decreases, the internal friction angle and cohesion of slope rock masses follow negative exponential decay functions. After 20 freeze–thaw cycles, the internal friction angle and cohesion of rock at a 5.27 m depth decreased by 18.36% and 33.92%, respectively. In contrast, rock at a 0.10 m depth showed more severe reductions of 31.81% and 50.14%. (3) Increasing freeze–thaw cycles progressively lower the safety factors of slope benches, with potential slip surfaces displaying reduced average depths and curvature, alongside elevated dip angles. These findings provide critical insights for preventing freeze–thaw−induced landslide hazards in cold−region open−pit mine slopes. Full article
(This article belongs to the Special Issue Rock Mechanics and Mining Engineering)
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17 pages, 18517 KiB  
Article
Investigation on High-Temperature Wear Resistance of Co-Based Superalloys Modified by Chromium–Aluminizing Coatings
by Yang Zhang, Ji Liu, Xuehui Zhang and Jibin Pu
Materials 2025, 18(6), 1229; https://doi.org/10.3390/ma18061229 - 10 Mar 2025
Viewed by 853
Abstract
This study systematically explores and expands upon the research questions, revealing the scientific principles and engineering value of chromium–aluminum (Cr-Al) co-diffusion coatings in enhancing high-temperature friction performance. This study addresses the critical need for wear resistance in GH5188 cobalt-based alloy stator bushings operating [...] Read more.
This study systematically explores and expands upon the research questions, revealing the scientific principles and engineering value of chromium–aluminum (Cr-Al) co-diffusion coatings in enhancing high-temperature friction performance. This study addresses the critical need for wear resistance in GH5188 cobalt-based alloy stator bushings operating in high-temperature environments. The high-temperature wear resistance mechanism of aluminized coatings modified with Cr elements on the GH5188 alloy, based on thermal diffusion technology, was investigated. The experimental results indicate that the high-temperature wear resistance of the samples was directly related to the type and content of oxides in the wear scars and debris. After friction at 700 °C, the aluminized coating on the GH5188 alloy showed the lowest oxide content in the wear scars, primarily composed of CoAl2O4. The oxides in the wear scars of the GH5188 alloy and Al-Cr co-aluminized coatings were mainly CoCr2O4 and Cr2O3, with the Al-Cr co-aluminized coating showing the highest amount of wear debris. The Cr-rich oxide debris not only has high thermodynamic stability but also exhibits relatively low high-temperature growth stress, making it difficult to spall. Additionally, the higher diffusion coefficient of Cr3+ accelerates the reoxidation of wear debris pits, resulting in excellent high-temperature wear resistance. The wear rate of the Al-Cr co-aluminized coating was reduced by 30% compared with the GH5188 substrate and by 69% compared with the aluminized coating. In summary, the key findings are not only applicable to cobalt-based alloys but can also be extended to a broader range of material systems and engineering applications. This provides new perspectives and methodologies for the design of high-temperature coatings, the development of materials for extreme conditions, and interdisciplinary applications. Full article
(This article belongs to the Special Issue Smart Coatings for the Corrosion Protection of Alloys)
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18 pages, 6744 KiB  
Article
A Spatiotemporal-Adaptive-Network-Based Method for Predicting Axial Forces in Assembly Steel Struts with Servo System of Foundation Pits
by Weiwei Liu, Jianchao Sheng, Jian Zhou, Jinbo Fu, Wangjing Yao, Kuan Chang and Zhe Wang
Appl. Sci. 2025, 15(5), 2343; https://doi.org/10.3390/app15052343 - 22 Feb 2025
Viewed by 448
Abstract
The axial force in assembly steel struts with servo systems is a critical indicator of stability in foundation pit support systems. Due to its high sensitivity to temperature variations and direct influence on the lateral deformation of the foundation pit enclosure structure, accurate [...] Read more.
The axial force in assembly steel struts with servo systems is a critical indicator of stability in foundation pit support systems. Due to its high sensitivity to temperature variations and direct influence on the lateral deformation of the foundation pit enclosure structure, accurate prediction is essential for safety monitoring and early warning. This study proposes a novel method for predicting the axial force in assembly steel struts with servo systems based on a spatiotemporal adaptive network. The method begins by feeding historical axial force data from multiple steel struts into an LSTM network to extract temporal sequence features. A self-attention mechanism is then employed to capture the global dependencies within the axial force data, enhancing the feature representation. Concurrently, a convolutional neural network (CNN) is utilized to extract local spatial features. Additionally, excavation depth and excavated soil stratification data are processed through convolutional operations to derive stratification-related features. Subsequently, the temporal and spatial features of axial force are fused with stratification-related features derived from excavation data and further refined through a CNN, enabling more accurate predictions. Validation using deep foundation pit data from a metro station in Zhejiang Province demonstrated the method’s reliability and improved performance across multiple metrics compared to the existing approaches. Full article
(This article belongs to the Special Issue Applications of Machine Learning in Geotechnical Engineering)
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19 pages, 14726 KiB  
Article
Heat Treatment Effect on the Corrosion Resistance of 316L Stainless Steel Produced by Laser Powder Bed Fusion
by Kevin Sangoi, Mahdi Nadimi, Jie Song and Yao Fu
Metals 2025, 15(1), 41; https://doi.org/10.3390/met15010041 - 4 Jan 2025
Cited by 2 | Viewed by 2099
Abstract
This study explores the effect of heat treatment on the microstructural characteristics and corrosion resistance of 316L stainless steels (SSs) produced via laser powder bed fusion (L-PBF), focusing on anisotropic corrosion behavior—a relatively less explored phenomenon in LPBF 316L SSs. By systematically analyzing [...] Read more.
This study explores the effect of heat treatment on the microstructural characteristics and corrosion resistance of 316L stainless steels (SSs) produced via laser powder bed fusion (L-PBF), focusing on anisotropic corrosion behavior—a relatively less explored phenomenon in LPBF 316L SSs. By systematically analyzing the effects of varying heat treatment temperatures (500 °C, 750 °C, and 1000 °C), this work uncovers critical correlations between microstructural evolution and corrosion properties. The findings include the identification of anisotropic corrosion resistance between horizontal (XY) and vertical (XZ) planes, with the vertical plane demonstrating higher pitting and repassivation potentials but greater post-repassivation current densities. Furthermore, this study highlights reductions in grain size, dislocation density, and melt pool boundaries with increasing heat treatment temperatures, which collectively diminishes corrosion resistance. These insights advance the understanding of processing–structure–property relationships in additively manufactured metals, providing practical guidelines for optimizing thermal post-processing to enhance material performance in corrosive environments. Full article
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21 pages, 6306 KiB  
Article
Enrichment of Trace Elements in the Early Carboniferous Coals from the Machala Mine in Eastern Qiangtang Basin, Eastern Tibet, SW China
by Junwei Qiao, Duo Wang, Fangpeng Du, Xinru Fu, Hafiz Zameer ul Hassan, Hui Zhang, Cheng Yang, Yi Jiang and Lingchen Li
Minerals 2025, 15(1), 34; https://doi.org/10.3390/min15010034 - 30 Dec 2024
Viewed by 931
Abstract
The Machala Mine, which is located in the Eastern Tibetan Plateau, was one of the highest coal mines in the world, with an elevation of 5200 m. The Machala coals are rich in a variety of critical and harmful elements. However, the occurrence [...] Read more.
The Machala Mine, which is located in the Eastern Tibetan Plateau, was one of the highest coal mines in the world, with an elevation of 5200 m. The Machala coals are rich in a variety of critical and harmful elements. However, the occurrence and enrichment mechanisms of these elements are not well understood, which hinders the assessment of their environmental impacts and recycling potential. Furthermore, the enrichment mechanism identified in the Machala coals is expected to extend our understanding of the simultaneous enrichment of multiple elements in coal. A total of 18 coal samples were collected from 14 coal (or carbonaceous mudstone) seams at the Machala open-pit mine for systematic analyses, including macerals, coal quality, minerals, trace, and major elements of coals. The results suggested that the coal seams in the Machala Mine were dominated by low-sulfur (mainly less than 1%), medium-to-low-ash (average: 18.15%), low-volatile (average: 16.01%), and medium-high-to-high-calorific (average: 27.23 MJ/kg) coals. The coal macerals were predominantly vitrinite, with the collodetrinite being the most abundant, followed by collotelinite and vitroderinite, while telinite was present in low amounts. The mineral compositions were mainly quartz and kaolinite, with average contents of 37.8% and 48.2%, respectively, which were followed by illite and smectite-mixed layers, with average contents of 4.7% and 3.3%, respectively. Other minerals, including plagioclase, pyrite, siderite, chlorite, and potassium feldspar, were present in low quantities. However, C3 coal seam was an exception, with a high pyrite content of 23.2% (low-temperature ash sample). The Machala coal seams were characterized by varying degrees of enrichment in Li, As, Pb, Hg, and Sn. Correlation analyses and energy spectrum analyses indicated that clays were their major host minerals. The enrichment of Li in the Machala Coal Mine was mainly attributed to volcanic ash during the sedimentation period, while As, Pb, Hg, and Sn were primarily sourced from hydrothermal fluids in the late stages. Full article
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16 pages, 5953 KiB  
Article
Microstructural and Electrochemical Analysis of the Physically Simulated Heat-Affected Zone of Super-Duplex Stainless Steel UNS S32750
by Francisco Magalhães dos Santos, Leonardo Oliveira Passos da Silva, Ygor Tadeu Bispo dos Santos, Bruna Callegari, Tiago Nunes Lima and Rodrigo Santiago Coelho
Metals 2025, 15(1), 2; https://doi.org/10.3390/met15010002 - 24 Dec 2024
Viewed by 1106
Abstract
Super-duplex stainless steels (SDSSs) were introduced in the oil and gas industry due to their high resistance to pitting corrosion, promoted by the high content of alloying elements. The welding process can cause an unbalanced ferrite/austenite microstructure and, consequently, the possibility of deleterious [...] Read more.
Super-duplex stainless steels (SDSSs) were introduced in the oil and gas industry due to their high resistance to pitting corrosion, promoted by the high content of alloying elements. The welding process can cause an unbalanced ferrite/austenite microstructure and, consequently, the possibility of deleterious phases, increasing the risk of failure. The aim of this work is to investigate the behavior of the heat-affected zone (HAZ) of SDSS UNS S32750 steel produced with different thermal inputs simulated in a Gleeble® welding simulator and correlate these findings with its corrosion properties. The pitting resistance was investigated by electrochemical techniques in sodium chloride solution, and the critical pitting temperature (CPT) was calculated for each evaluated microstructure. The material as received presents 46.19 vol% ferrite and a high corrosion resistance, with a CPT of 71.54 °C. HAZ-simulated cycles resulted in similar ferrite percentages, between 54.09 vol% and 57.25 vol%. A relationship was found between heat input, ferrite content, and CPT: increasing the heat input results in greater ferrite content and lowers the CPT, which may favor the pitting corrosion process. Therefore, it is concluded that the ferrite content directly influences the pitting behavior of the material. Full article
(This article belongs to the Special Issue Welding and Joining of Advanced High-Strength Steels (2nd Edition))
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12 pages, 4591 KiB  
Article
Assessing the Corrosive Effects of Unmelted Particles in Additively Manufactured Ti6Al4V: A Study in Simulated Body Fluid
by Surinder Pal, Xavier Velay and Waqas Saleem
Alloys 2024, 3(4), 257-268; https://doi.org/10.3390/alloys3040015 - 9 Oct 2024
Cited by 3 | Viewed by 1908
Abstract
This study investigates the corrosion behavior of Grade 23 Ti6Al4V alloys produced through laser powder bed fusion (L-PBF) when exposed to simulated body fluid at room temperature, focusing on the role of unmelted particles. This research aims to understand how these microstructural features, [...] Read more.
This study investigates the corrosion behavior of Grade 23 Ti6Al4V alloys produced through laser powder bed fusion (L-PBF) when exposed to simulated body fluid at room temperature, focusing on the role of unmelted particles. This research aims to understand how these microstructural features, resulting from the additive manufacturing process, influence the corrosion resistance of the alloys. It was observed that unmelted particles serve as critical sites for initiating localized corrosion, including pitting, which significantly compromises the material’s overall durability. Electrochemical testing and detailed surface analysis revealed that these particles, alongside other defects such as voids, exacerbate the susceptibility to corrosion in biomedical environments where high material reliability is paramount. Weight loss measurements conducted over exposure periods of 48 h, 96 h, and 144 h demonstrated a progressive increase in corrosion, correlating with the presence of unmelted particles. These findings underscore the importance of optimizing L-PBF processing parameters to minimize the formation of unmelted particles, thereby enhancing corrosion resistance and extending the operational lifespan of Ti6Al4V implants in biomedical applications. Full article
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16 pages, 7810 KiB  
Article
Study of Effects of Post-Weld Heat Treatment Time on Corrosion Behavior and Manufacturing Processes of Super Duplex Stainless SAF 2507 for Advanced Li-Ion Battery Cases
by Yoon-Seok Lee, Jinyong Park, Jung-Woo Ok, Seongjun Kim, Byung-Hyun Shin and Jang-Hee Yoon
Materials 2024, 17(16), 4107; https://doi.org/10.3390/ma17164107 - 19 Aug 2024
Cited by 3 | Viewed by 1330
Abstract
Lithium-ion batteries are superior energy storage devices that are widely utilized in various fields, from electric cars to small portable electric devices. However, their susceptibility to thermal runaway necessitates improvements in battery case materials to improve their safety. This study used electrochemical analyses, [...] Read more.
Lithium-ion batteries are superior energy storage devices that are widely utilized in various fields, from electric cars to small portable electric devices. However, their susceptibility to thermal runaway necessitates improvements in battery case materials to improve their safety. This study used electrochemical analyses, including open-circuit potential (OCP), potentiodynamic polarization, and critical pitting temperature (CPT) analyses, to investigate the corrosion resistance of super duplex stainless steel (SAF 2507) applied to battery cases in relation to post-weld heat treatment (PWHT) time. The microstructure during the manufacture, laser welding, and PWHT was analyzed using field-emission scanning electron microscopy, X-ray diffraction, and electron backscatter diffraction, and the chemical composition was analyzed using dispersive X-ray spectroscopy and electron probe micro-analysis. The PWHT increased the volume fraction of austenite from 5% to 50% over 3 min at 1200 °C; this increased the OCP from −0.21 V to +0.03 V, and increased the CPT from 56 °C to 73 °C. The PWHT effectively improved the corrosion resistance, laying the groundwork for utilizing SAF 2507 in battery case materials. But the alloy segregation and heterogeneous grain morphology after PWHT needs improvement. Full article
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17 pages, 7204 KiB  
Article
Behavior and Activity Patterns of the Critically Endangered Mangshan Pit Viper (Protobothrops mangshanensis) Determined Using Remote Monitoring
by Zeshuai Deng, Xiangyun Ding, Bing Zhang, Linhai Li, Dejia Hou, Yue Cao, Jun Chen and Daode Yang
Animals 2024, 14(15), 2247; https://doi.org/10.3390/ani14152247 - 2 Aug 2024
Viewed by 1796
Abstract
This study focuses on understanding the behavior and activity patterns of the critically endangered Protobothrops mangshanensis in China in order to better provide scientific data for upcoming artificial breeding and propagation efforts. We conducted a long-term observation of 15 Mangshan pit vipers at [...] Read more.
This study focuses on understanding the behavior and activity patterns of the critically endangered Protobothrops mangshanensis in China in order to better provide scientific data for upcoming artificial breeding and propagation efforts. We conducted a long-term observation of 15 Mangshan pit vipers at different sites in Hunan Province during the summer and autumn of 2021. Our methods involved analyzing the influence of environmental factors such as temperature, relative humidity, and light condition on the snakes’ day and night activity and behaviors. The results revealed that the wild behaviors of Protobothrops mangshanensis include resting, sunbathing, crawling, and exploring, with distinct rhythms in their diel behavior. The snakes’ diel activity exhibits three peak periods which may be related to food activity and sunbathing. This study also highlights the complex interplay of environmental factors on the activity of Protobothrops mangshanensis. Relative humidity was identified as a critical factor accounting for the difference in activity between observation groups. There was little inter-individual variation among the 15 Protobothrops mangshanensis, even though these snakes used terrestrial and arboreal habitats under different environmental conditions. These findings enhance our understanding of Protobothrops mangshanensis behavior and provide a basis for effective conservation measures for this rare and critically endangered species. Full article
(This article belongs to the Section Herpetology)
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15 pages, 3642 KiB  
Article
Effect of Annealing after Casting and Cold Rolling on Microstructure and Electrochemical Behavior of High-Entropy Alloy, Cantor
by Jinsurang Lim, Byung-Hyun Shin, Doo-In Kim, Jong-Seong Bae, Jung-Woo Ok, Seongjun Kim, Jinyong Park, Je In Lee and Jang-Hee Yoon
Metals 2024, 14(8), 846; https://doi.org/10.3390/met14080846 - 24 Jul 2024
Cited by 5 | Viewed by 2008
Abstract
High-entropy alloys (HEAs), a relatively new class of materials, have attracted significant attention in materials science owing to their unique properties and potential applications. High entropy stabilizes the phase of a solid solution over a wide range of chemical compositions, yielding unique properties [...] Read more.
High-entropy alloys (HEAs), a relatively new class of materials, have attracted significant attention in materials science owing to their unique properties and potential applications. High entropy stabilizes the phase of a solid solution over a wide range of chemical compositions, yielding unique properties superior to those of conventional alloys. Therefore, this study analyzed the microstructure and electrochemical behavior of HEAs (Cantor) to evaluate their corrosion resistance, according to their manufacturing process (casting, cold rolling, and annealing). The microstructural morphologies and sizes were analyzed using electron backscatter diffraction. The electrochemical behavior was examined using open circuit potential measurements, electrochemical impedance spectroscopy, potentiodynamic polarization tests, and critical pitting temperature measurements using a potentiostat. The casting process formed a nonuniform microstructure (average grain size = 19 μm). The cold rolling process caused the formation of fine grains (size = 4 μm). A uniform microstructure (grain size > 151 μm) was formed after heat treatment. The corrosion resistance of the HEAs was determined from the passivation layer formed by Cr oxidation. These microstructural differences resulted in variations in the electrochemical behavior. Microstructural and electrochemical analyses are crucial because HEAs have diverse potential applications. Therefore, this study contributes to future improvements in HEA manufacturing processes. Full article
(This article belongs to the Special Issue Casting Alloy Design and Characterization—2nd Edition)
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14 pages, 7682 KiB  
Article
Study of the Corrosion Behavior of Stainless Steel in Food Industry
by Stefano Rossi, Sergio Maria Leso and Massimo Calovi
Materials 2024, 17(7), 1617; https://doi.org/10.3390/ma17071617 - 1 Apr 2024
Cited by 9 | Viewed by 3259
Abstract
AISI 304L stainless steel is widely used in the processing equipment and food and beverage handling industries due to its corrosion resistance, hygienic properties, and cost-effectiveness. However, it is prone to pitting and crevice corrosion phenomena, the development of which can be influenced [...] Read more.
AISI 304L stainless steel is widely used in the processing equipment and food and beverage handling industries due to its corrosion resistance, hygienic properties, and cost-effectiveness. However, it is prone to pitting and crevice corrosion phenomena, the development of which can be influenced by factors such as chloride concentration, temperature, humidity, and bacterial presence. Surface treatments, including roughness levels and residual tensile stress, can significantly affect the corrosion behavior and resistance of the material. This study aims to evaluate the impact of three different surface treatments on the durability of AISI 304L steel. The correlation between surface roughness resulting from pre-treatment and pitting potential values will be examined. Additionally, the influence of different concentrations of biocide additives on surface durability will be assessed to determine the maximum effective concentration for preventing pitting phenomena. Passivation processes will also be evaluated as a potential solution for improving the pitting potential and overall durability of the components. By optimizing surface treatments and biocide concentrations, improved corrosion resistance and durability can be achieved, ensuring the long-term performance and reliability of AISI 304L steel components in critical applications such as food processing and beverage handling. Full article
(This article belongs to the Special Issue State of the Art of Materials Science and Engineering in Italy)
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14 pages, 23949 KiB  
Article
Investigation of Layered Structure Formation in MgB2 Wires Produced by the Internal Mg Coating Process under Low and High Isostatic Pressures
by Daniel Gajda, Michał Babij, Andrzej Zaleski, Doğan Avci, Fırat Karaboga, Hakan Yetis, Ibrahim Belenli and Tomasz Czujko
Materials 2024, 17(6), 1362; https://doi.org/10.3390/ma17061362 - 16 Mar 2024
Cited by 6 | Viewed by 1370
Abstract
Currently, MgB2 wires made by the powder-in-tube (PIT) method are most often used in the construction and design of superconducting devices. In this work, we investigated the impact of heat treatment under both low and high isostatic pressures on the formation of [...] Read more.
Currently, MgB2 wires made by the powder-in-tube (PIT) method are most often used in the construction and design of superconducting devices. In this work, we investigated the impact of heat treatment under both low and high isostatic pressures on the formation of a layered structure in PIT MgB2 wires manufactured using the Mg coating method. The microstructure, chemical composition, and density of the obtained superconductive wires were investigated using scanning electron microscopy (SEM) with an energy-dispersive X-ray spectroscopy (EDS) analyzer and optical microscopy with Kameram CMOS software (version 2.11.5.6). Transport measurements of critical parameters were made by using the Physical Property Measurement System (PPMS) for 100 mA and 19 Hz in a perpendicular magnetic field. We observed that the Mg coating method can significantly reduce the reactions of B with the Fe sheath. Moreover, the shape, uniformity, and continuity of the layered structure (cracks, gaps) depend on the homogeneity of the B layer before the synthesis reaction. Additionally, the formation of a layered structure depends on the annealing temperature (for Mg in the liquid or solid-state), isostatic pressure, type of boron, and density of layer B before the synthesis reaction. Full article
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