Search Results (1,904)

Corrosion in steel pipelines can cause critical failures in industrial systems, while conventional inspection methods such as radiography and ultrasonic testing are costly and require specialized personnel. This study presents a mobile computer vision system for automated corrosion detection inside steel pipes using deep learning-based visual analysis. The proposed system consists of a Raspberry Pi 4-based mobile robot equipped with a high-resolution camera for internal inspection. Acquired images were processed using color-space transformations (RGB–HSV), filtering, and segmentation. Convolutional neural networks and semantic segmentation models, including YOLOv8-seg (Instance segmentation) and DeepLabV3 (Semantic segmentation), were trained on a custom corrosion image dataset to identify corroded regions. Real-time visualization was implemented via Flask-based video streaming. Experimental results demonstrated high detection accuracy for uniform corrosion, achieving a mean Intersection over Union (mIoU) above 0.98 and a precision of 0.99 with the YOLOv8-seg model. These results indicate that the proposed system enables reliable and automated corrosion inspection, with the potential to reduce inspection costs and improve operational efficiency. Future work will focus on enhancing real-time performance through hardware optimization. Full article

This study reports the synthesis of a high-entropy AlFeCuTiNi alloy via high-energy ball milling. The study investigates the effects of mechanical alloying time and sintering temperature on the microstructure, mechanical properties, wear, and corrosion behavior of the high-entropy AlFeCuTiNi alloy. XRD, SEM, and EDX analyses revealed that the mechanical alloying time and sintering temperature significantly affected the alloy’s homogeneity, phase structure, and oxide film stability. As the mechanical alloying time increases, the corrosion resistance of alloys sintered at 550 °C initially increases and then stabilizes. In samples sintered at 650 °C, corrosion resistance is generally higher. The highest corrosion resistance was achieved after 15 h of mechanical alloying and sintering at 650 °C. The study reveals that the best corrosion, wear, hardness, and wear density performance was observed in samples obtained at medium conditions, achieved after 20 h of mechanical alloying and sintering at 650 °C. These findings may contribute to optimizing production processes for sustainable material design. Moreover, this research highlights that high-entropy alloys and powder-metallurgy-based production methods enable industrial applications for energy-efficient, sustainable material design and contribute to sustainable production and circular-economy principles. Full article

Developing stable alumina-based scales is critical for alumina-forming austenitic (AFA) alloys exposed to highly basic molten carbonates. However, the inherently sluggish diffusion of Al in austenite often limits the establishment of continuous protective layers. Herein, a thermomechanical treatment (TMT) strategy is proposed to enhance short-circuit diffusion pathways and promote selective Al oxidation in a Li–Na–K carbonate melt at 700 °C. After 90% cold rolling, annealing at 800 °C and 1000 °C generated two distinct microstructural states characterized by different grain boundary types, dislocation densities, and NiAl precipitate populations. The 800 °C-annealed alloy exhibits a significantly lower steady-state corrosion rate (~62 μm/yr) compared with the coarse-grained 1000 °C counterpart. EBSD and TEM analyses reveal that ultrafine grains, abundant low-angle boundaries, and finely dispersed NiAl precipitates provide efficient fast-diffusion channels and local Al reservoirs, enabling rapid formation of a continuous LiAlO₂/Al₂O₃ inner layer. In contrast, insufficient Al flux in the 1000 °C microstructure results in extensive internal oxidation and growth of a thick, non-protective LiFeO₂/NiO scale. These findings demonstrate that controlling the defect and grain-boundary structure via TMT is an effective route to overcome Al diffusion limitations and improve the molten-carbonate corrosion resistance of AFA alloys. Full article

Thermal energy storage (TES) systems are widely employed in concentrated solar power (CSP) applications as a means of storing and dispatching energy. Typical thermal fluids used in TES systems include molten salts, such as solar salt (a KNO₃–NaNO₃ eutectic), as well as other inorganic salts currently under consideration. While these molten nitrate, chloride, sulfate, and carbonate salts offer favourable thermal properties, they can induce significant corrosion of metallic containment materials, leading to reduced system efficiency and component lifetime. Despite extensive post-exposure studies, in situ electrochemical understanding of corrosion mechanisms in molten solar salt remains limited, particularly for emerging alloys such as FeCrAl. In this study, the in situ corrosion behaviour of structural alloys in molten solar salt was investigated using electrochemical impedance spectroscopy (EIS). Complementary post-exposure characterization was performed using destructive techniques, including scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX), to assess microstructural and chemical changes. The materials evaluated were stainless steel SS316 and comparatively underexplored Kanthal FeCrAl alloys, exposed to molten solar salt (40 wt% KNO₃–60 wt% NaNO₃) at 545 °C. The electrochemical and microstructural analyses indicate that FeCrAl exhibits superior corrosion resistance associated with the formation of a more stable and protective oxide scale, compared to SS316 under the investigated conditions. This study provides new electrochemical evidence supporting the suitability of FeCrAl alloys for TES applications, while also indicating that SS316 may develop improved corrosion resistance over extended exposure durations, highlighting the importance of long-term performance assessment. Full article

This article provides an overview of modern surface engineering technologies used in the manufacturing of dental components, with a particular focus on dental implants, abutments, and crowns. The main objective of the study is to critically evaluate selected surface treatment and coating deposition methods applied to materials such as titanium, zirconia, hydroxyapatite, and NiTi alloys, and to discuss their relevance in terms of functionality, biocompatibility, and sustainability. The analyzed technologies include anodic oxidation, alkaline oxidation, electrochemical coating deposition, and other surface modification approaches aimed at improving osseointegration, corrosion resistance, and antibacterial performance. This literature review was conducted as a narrative review supported by the PRISMA framework, using the Scopus and Web of Science databases for the period 2016–2025. The findings highlight the increasing importance of surface treatments as a key factor influencing the durability and clinical success of dental implant systems. At the same time, the results indicate that the environmental aspects and energy efficiency of manufacturing and surface treatment processes are still addressed only marginally or qualitatively in the available literature. The identified research gaps include the lack of quantitative data on the energy demand of individual technologies, the absence of standardized indicators for environmental impact assessment, and the limited number of comparative studies evaluating different surface modification techniques in the context of dental manufacturing. Overall, the results emphasize the need for a more systematic sustainability assessment of surface engineering as an integral part of modern dental manufacturing practice. Full article

The compliant discharge of landfill leachate constitutes a pivotal factor for the effective implementation of integrated water resource management. Aged landfill leachate exhibits complex composition and an imbalanced carbon-to-nitrogen ratio. Electrocatalytic oxidation technology, as an efficient advanced oxidation process, demonstrates promising application potential. This study employed Ti/RuO₂–IrO₂ Anodes for the electrocatalytic oxidation treatment of aged landfill leachate. The removal efficiencies and variation patterns of chemical oxygen demand (COD), ammonia nitrogen, and total nitrogen at different current densities and reaction times were systematically investigated, along with an analysis of energy consumption and current efficiency. The degradation and transformation processes of organic matter were elucidated using Three-dimensional Excitation–Emission Matrix (EEM) Spectra. Fresh anodes and those used for 1000 h were characterized by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) to elucidate their failure mechanisms. The results demonstrate that electrocatalytic oxidation achieves efficient pollutant removal. At a current density of 1000 A/m² and a reaction time of 30 min, the effluent concentrations of ammonia nitrogen and total nitrogen satisfied the discharge standards, while COD complied with emission requirements after 60 min. The pollutant removal efficiencies were positively correlated with current density and reaction time. EEM analysis revealed that the electrocatalytic process effectively disrupts the structure of macromolecular organic matter, degrading it into smaller molecules and eventually achieving complete mineralization. Electrode characterization identified titanium substrate corrosion due to coating cracks and coating detachment as the primary causes of electrode failure. This study confirms the effectiveness of electrocatalytic oxidation technology for treating aged landfill leachate, and provides a theoretical foundation and technical support for its practical engineering application. The technology exhibits considerable theoretical significance and promising application potential in the treatment of landfill leachate. Full article

GH3536 superalloy is widely used in the high-temperature components of aerospace applications for its excellent high-temperature strength and corrosion resistance. However, under such a harsh environment, surface defects can make the superalloy prone to corrosion and fatigue fractures. Therefore, it is important to eliminate surface defects through polishing. However, the existing polishing methods usually suffer from some issues such as surface integrity damage, low efficiency, and poor environmental sustainability. More importantly, these methods fail to account for the requirement of surface roughness below 0.05 μm in some high-precision aerospace components. Herein, the plasma electrolytic polishing (PEP) of GH3536 superalloy is systematically investigated and optimized through single-factor experiments and response surface methodology (RSM). A minimum surface roughness Ra of 0.044 μm with a mirror-like surface was achieved at a voltage of 303.8 V, electrolyte temperature of 66.2 °C, polishing time of 5 min, and submersion depth of 7.5 cm. At the same optimized condition, the material removal rate was 59.12 mg·min⁻¹. After polishing, the surface composition of GH3536 superalloy varied negligibly, while its corrosion resistance improved markedly, with a 53.72% increase in polarization resistance and a 43.46% decrease in corrosion current density. Meanwhile, the microhardness slightly decreased due to the removal of the work-hardened layer and the compressive residual stress exhibited a more uniform distribution across the surface, contributing to improved near-surface mechanical stability. This study establishes an optimized PEP parameter for improving the surface quality of GH3536 superalloy, offering a practical method for the precision finishing of aerospace-grade superalloy components. Full article

Slippery lubricant-infused surfaces (SLIPS) suffer from rapid lubricant depletion, severely limiting their durability in practical applications. To overcome this, we propose a laser-engineered hierarchical architecture that physically locks a solid paraffin lubricant, creating a multifunctional coating with thermally switchable slipperiness. Using femtosecond laser ablation, a hierarchical porous structure (HPS) was fabricated on an aluminum alloy, followed by silanization to achieve superhydrophobicity (contact angle ≈ 154.7°) for enhanced paraffin wetting. The resulting HPS-P coating exhibits thermally switchable adhesion: water droplets pin on the solid surface (sliding angle > 90°) but slide readily (<10°) upon heating above the paraffin’s melting point. The coating demonstrates rapid self-healing, repairing severe scratches within 100 s via molten paraffin flow. The HPS-P coating provides excellent corrosion protection, with its corrosion current density reduced by six orders of magnitude compared to bare aluminum and an inhibition efficiency approaching 100%. This work provides a durable, thermally responsive coating strategy with integrated anti-corrosion and self-healing functions for extreme environments. Full article

Zinc-ion batteries have garnered significant research interest owing to their inherent safety, low cost, and environmental compatibility. Nevertheless, their widespread adoption is impeded by critical challenges including uncontrollable dendrite growth, parasitic side reactions stemming from active water molecules, and the corrosion of the zinc anode in conventional aqueous electrolytes. Herein, a hydrated deep eutectic solvent (HDES) electrolyte based on ZnSO₄, MnSO₄, and ethylene is proposed for high-performance zinc-ion batteries. This electrolyte demonstrates excellent stability and simultaneously enables the formation of a protective coating on the Zn anode surface. Spectroscopic analyses and theoretical simulations reveal that this electrolyte reconfigures the primary Zn²⁺ solvation shell by replacing water molecules with HDES components. This tailored solvation structure facilitates interfacial desolvation, elevates nucleation overpotential, and promotes uniform, dendrite-free zinc deposition. Simultaneously, a robust hydrogen bond network effectively sequesters free water, significantly suppressing the hydrogen evolution reaction and anode corrosion. Benefiting from these features, the HDES-based full cell delivers exceptional long-term stability, achieving over 2000 cycles at 3 mA cm⁻² with a capacity retention exceeding 95% and a Coulombic efficiency surpassing 85%. In sharp contrast, the traditional aqueous counterpart fails within only 200 cycles. This tenfold lifespan enhancement, coupled with cost-effectiveness and non-flammability, presents a promising strategy for advanced, grid-scale zinc-based energy storage. Full article

Phytic acid (myo-inositol hexakisphosphate) and its salts, including iron, aluminum, sodium, and lanthanum phytate, are perhaps the most recent discovery in the field of bio-sourced flame retardants. Phytic acid can be extracted from sustainable resources, such as beans, cereals, and oilseeds. Its high phosphorus content (28 wt.% based on molecular weight) organized into six phosphate groups justifies the growing interest this biomolecule has attracted over the last decade in various sectors (as a corrosion inhibitor, antioxidant, and anticancer additive, among others). In addition, when exposed to a flame or an irradiative heat flux, phytic acid is a highly efficient dehydrating and char-forming agent. It also contributes to excellent flame-retardant properties when combined with other carbon sources, such as chitosan, or nitrogen-containing additives, including melamine, urea, and polyethyleneimine. This paper reviews the most recent advances in using phytic acid and its derivatives to design effective flame-retardant systems for textiles, bulk polymers, and foams. It also provides perspectives on possible future developments and implementations. Full article

In this study, first-principles calculations were employed to systematically investigate the adsorption of Cl⁻ on Al₂Cu(110) surfaces, clean Al(111)/Al₂Cu(110) interfaces, and Fe/Si-doped interfaces, as well as the influence of strain on interfacial electronic structure and corrosion activity. When Cl⁻ is adsorbed on Al sites, the bonding between Cl and Al exhibits strong ionic characteristics with localized charge transfer, while adsorption on Cu sites is characterized by more delocalized, covalent interactions. This competition dictates the site-dependent stability of adsorption. Through geometric–electronic synergy, the interface functions as both a “Cl⁻ enrichment zone” and an “activity source,” significantly favoring Cl⁻ adsorption at high-activity anodic sites such as Al-hole and Al-bridge. Conversely, Cu-top sites maintain a high work function and an inert cathodic nature, facilitating the formation of efficient micro-galvanic couples across the interface. Moreover, Fe/Si doping further modulates the interfacial electronic landscape: Si serves as an effective strengthening element due to its low substitution energy and high stability, while Fe primarily forms a solid solution on the Al side, potentially introducing galvanic corrosion risks. Stress analysis indicates that tensile strain systematically enhances surface activity by lowering the work function, while compressive strain non-monotonically influences corrosion through a three-stage mechanism involving the “densification–cracking–plastic relaxation” of the passive film. These findings elucidate the atomistic origins of corrosion initiation at Cu–Al composite interfaces and provide a theoretical foundation for enhancing corrosion resistance through alloy design and strain engineering. Full article

The integration of sustainable and natural waste-derived materials into lightweight metals presents a promising strategy with both environmental and performance-related benefits. In this study, a biobased magnesium composite reinforced with dried leaf powder (DLP) derived from fallen waste leaves was synthesized using a controlled powder metallurgy method incorporating energy efficient hybrid microwave sintering, followed by hot extrusion at varying temperatures (350 °C, 250 °C, 150 °C). Microstructural analysis revealed that the addition of DLP had minimal effect on the overall grain morphology, while lower extrusion temperatures promoted finer grains due to restricted grain growth. Mg–5DLP composites consistently exhibited higher porosity than pure Mg, primarily due to the evaporation of organic constituents during sintering. The damping performance of the biomass-containing materials was improved (54.5% increase), particularly at lower extrusion temperatures (250 °C), though mechanical performance showed a trade-off with reduced hardness and compressive strength. A slight increase in yield strength at lower extrusion temperatures was attributed to retained dislocation density and grain refinement. Thermal stability remained largely unaffected, while corrosion behavior was strongly dependent on both DLP addition and extrusion temperature, with Mg–5DLP samples corroding faster than pure Mg when extruded at higher temperatures; interestingly, however, at the lowest extrusion temperature (150 °C), improved corrosion resistance to pure Mg (1.3 mm/year for Mg-5DLP vs. 2.0 mm/year for pure Mg) was observed. Overall, this work demonstrates that extrusion temperature is a critical factor in controlling the microstructure, thermal response, damping response, mechanical behavior and corrosion of biobased composites. The study not only highlights the potential of using direct biomass reinforcement of magnesium to synthesize lightweight, ecofriendly materials, but also lays a strong foundation for future investigations into biobased composite design, processing optimization, and property tailoring. Full article

To address force uniformity and corrosion issues in slope reinforcement, this paper presents a field implementation of pressure-uniformly-dispersed Carbon-Fiber-Reinforced Polymer (CFRP) anchor cables integrated with Fiber Bragg Grating (FBG) sensing technology. A tensioning trial was conducted on a dangerous rock project on Guangyang Island, Chongqing, utilizing a distributed FBG array (0.5 m spacing) for full-length strain monitoring. The results confirm that, under the specific conditions of this project, the anchorage segment exhibits the characteristic two-stage behavior of “delayed activation–uniform bearing” previously documented in bonded anchor systems, with a critical transition observed at approximately 120 kN. Beyond this threshold, the anchorage efficiency reached approximately 85%, validating the three-stage uniformly dispersed design for this specific geological context. While the load transfer mechanism aligns with established bonded anchor mechanics, this study demonstrates the practical feasibility of high-resolution distributed sensing in CFRP anchor systems, providing benchmark data for construction quality control and long-term health monitoring of similar slope reinforcement projects. Full article

The N,N′-Bis(salicylidene)-1,3-propanediamine Schiff base (Salpn) was synthesized, characterized, and assessed as a corrosion inhibitor for low-carbon steel (LCS) in a 0.5 mol L⁻¹ HCl solution. The study included chemical, electrochemical, and quantum mechanical methods to provide a comprehensive assessment. Experimental results revealed that the inhibition efficiency (IE) of Salpn increased with concentration, reaching a maximum of 69.1% at 300 ppm and 298 K, while a slight decrease to 64.3% was observed as the temperature increased. Tafel plot identified Salpn as a mixed-type inhibitor, while electrochemical impedance spectroscopy (EIS) revealed that the double layer capacitance decreased while the charge-transfer resistance increased as the concentration of Salpn increased. The thermodynamic study revealed that the adsorption of Salpn on the LCS surface follows the Langmuir isotherm model. The calculated standard free energy of adsorption (ΔG^°_ads) values ranged from −27.53 to −30.17 kJ mol⁻¹, confirming that the inhibition process occurs via a mixed mechanism involving both physisorption and chemisorption. The presence of a protective film on the LCS surface was suggested by SEM observations, while EDX analysis showed an increase in C, O, and N signals, providing further indication of the inhibitor’s integration into the surface layer. Density functional tight-binding (DFTB+) calculations supported the high inhibitory performance by showing a low hardness value (0.091 eV). The compound’s high global softness (σ = 10.989 eV⁻¹) suggested that it is an effective corrosion inhibitor. The Monte Carlo (MC) simulations demonstrated a strong interaction with a highly negative adsorption energy of −654.145 kJ mol⁻¹. These findings collectively validate Salpn as an effective and strongly adsorbing corrosion inhibitor. Full article

This study investigates the protective performance of a triazole-based Mannich base corrosion inhibitor, 4-((1,2,4-triazolyl)methyl) dibutylamine (TZMBA), on P110 carbon steel in dissolved oxygen environments. TZMBA was synthesized via a Mannich reaction, and its molecular structure was confirmed by Fourier transform infrared spectroscopy (FT-IR). The corrosion inhibition behavior and underlying mechanisms were systematically explored through weight loss measurements, surface characterization, and multiscale molecular simulations. Weight loss results indicated that TZMBA significantly mitigates the corrosion of P110 steel, with inhibition efficiency reaching 81.5% at 1.67 mmol/L and 82.0% at 2.14 mmol/L. Adsorption thermodynamic analysis revealed that the process follows the Langmuir isotherm model. The calculated standard Gibbs free energy ${∆G}_{ads}^0$ of −38.69 kJ/mol suggests a spontaneous, mixed-type adsorption mechanism involving both physisorption and chemisorption. Scanning electron microscopy (SEM) observations confirmed a marked reduction in surface degradation, characterized by suppressed corrosion products and minimized localized attack. X-ray photoelectron spectroscopy (XPS) further verified that TZMBA anchors to the metal surface through chemical coordination, forming a robust organic-inorganic composite film. From a theoretical perspective, frontier molecular orbital (FMO) analysis showed that TZMBA’s high E_HOMO and narrow energy gap facilitate efficient electron transfer. Combined Fukui function and molecular electrostatic potential (MEP) maps identified the nitrogen atoms in the triazole ring and amine group as the primary active sites. Furthermore, molecular dynamics (MD) simulations demonstrated that TZMBA molecules adopt a nearly parallel configuration on the Fe surface. The high negative interaction energy obtained from MD simulations confirms a strong binding affinity and a potent inherent driving force for the formation of a stable protective layer. Overall, the integration of experimental data and theoretical calculations establishes TZMBA as an effective inhibitor that provides superior protection by forming a stable, compact adsorption film on P110 carbon steel. Full article