Search Results (8)

Soil and water contamination with high nutrient concentrations from swine farms poses a risk to human and animal health. This study investigated the effects of biochar derived from young aromatic coconut husk (CH), coconut shell (CS), and their mixture (CHCS) on nutrient retention in biochar-amended soil columns for variable synthetic swine wastewater (SW) loading based on water use for piglets and fattening stalls. A 0.9 L leaching test column contained 3 g of each biochar type mixed with 300 g of soil. It was loaded daily with synthetic SW for 42 days at loading rates of 30 mL/day (piglet SW) and 60 mL/day (fattening SW). CH-amended soil was then selected to investigate the effect of rainfall rates at 0 (R0), 25 (R25), 70 (R70) and 140 (R140) mL/4 days on soil nutrient retention. Leachate was collected every 7 days to analyze nitrogen and phosphorus concentrations. The results showed that CH-amended soil had the highest retention of total nitrogen (TN) and phosphate among all treatments. For piglet SW, TN retention in CH-amended soil was 1.4–1.6 times higher than with CS and CHCS treatments, probably due to enhanced ammonium retention on exchangeable sites associated with the high cation exchange capacity of CH. High phosphate retention in CH-amended soil was linked to Ca²⁺ release from CH, facilitating phosphate precipitation. Moreover, CH-amended soil at R25 showed the highest ammonium retention but inhibited seed germination. Overall, CH-amended soil effectively retained nutrients and was suitable as a seedling growth medium, except under the R25 rainfall condition. Full article

Soil heavy metal pollution is becoming increasingly severe, while traditional remediation methods are inefficient and lack long-term stability. This study innovatively combines electrokinetic remediation (EK), microbial-induced calcium carbonate precipitation (MICP), and biochar for synergistic stabilization of contaminated soil. It evaluates the combined technology by comparing it with individual EK and MICP treatments through chemical speciation analysis and the Toxicity Characteristic Leaching Procedure (TCLP). The concentration of 1 mol/L urea–CaCl₂ was identified as optimal for microbial activity, achieving a microbial cell density (OD₆₀₀) of 1.0, a urease activity of 12 U/g, and a soil pH maintained within the range of 7.8–8.2. Corn stover biochar significantly enhanced urease activity—being 49.4% higher than that in the coconut shell biochar group and 25% higher than that in the bamboo biochar group—and increased the microbial survival rate by 25.4%. Group D1, which adopted the sequence of “EK treatment first, followed by biochar-synergized MICP treatment,” exhibited the best performance. It achieved stabilization efficiency of 51.90%, 73.40%, and 36.26% for bioavailable Cu, Cd, and Pb, respectively—all higher than those of individual EK and MICP treatments. Additionally, the residual fractions of heavy metals increased significantly, the leaching concentration of Cd in the anode region was below 1 mg/L, and energy consumption was 12.16% lower than that of the EK group. Microstructural analysis confirmed that the combined method promoted the formation of stable calcite, thereby improving soil aggregation and alleviating soil compaction. These findings collectively validate the proposed technology as a highly effective and sustainable strategy for stabilizing heavy metal-contaminated soil. Full article

The water adsorption property was shown to be the critical process limiting the thermal output in the adsorption heat storage driven by the air humidity process, which was different for the physical adsorbent and the physical/chemical adsorbent. In this study, coconut shell-based activated carbon (CAC), a hierarchically porous material that is both low-cost and mass-producible, was utilized as a physical adsorbent and as a matrix for loading calcium chloride (CAC/Ca). The incorporation of calcium chloride in CAC, with a 24% content, resulted in a 4~102% increase in water uptake capacity. The water uptake dynamics of high-thickness adsorbents are inhibited, especially for CAC/Ca. In the context of the adsorption test conducted within a fixed-bed reactor, an increase in air velocity was observed to facilitate water vapor supply, thereby culminating in higher output temperatures for both CAC and CAC/Ca, indicating a higher hydration conversion. The maximum discharge powers of CAC/Ca increased from 2 kW/m³ to 20 kW/m³, with the air velocity increasing from 0.5 m/s to 2.5 m/s. The heat-release densities of CAC and CAC/Ca at the air velocity of 2.5 m/s were 156 kJ/kg and 547 kJ/kg, respectively. Full article

This research examines the fresh properties, strength performance, and morphological analysis of self-compacting coconut shell concrete (SCCSC) blended with crushed coconut shell and manufactured sand (M-sand). Crushed coconut shell (CS) was used as a coarse aggregate (CA), and M-sand replaced river sand (R-sand) at 25%, 50%, 75%, and 100%. The study focused on the workability characteristics, mechanical behavior, and microstructural analysis of SCCSC. Experiments were performed on fresh and mechanical characteristics, including slump flow diameter, T₅₀₀ slump flow time, L-Box blocking ratio, V-funnel and a wet sieving stability test. Mechanical characteristics include compressive, split tensile, flexural, impact resistance and bond strength. Utilizing M-sand develops the mechanical performance of SCCSC. The morphological characteristics, using scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), Fourier transform infrared (FTIR) and the X-ray diffraction (XRD) technique, were studied in this research work. The findings show that the addition of M-sand increases the concrete strength. The microstructural analysis demonstrates that adding different amounts of M-sand to SCCSC reduced the porosity and anhydrous cement percentage, although it increased calcium hydroxide and hydration products. The substitution of 100% M-sand at 28 days increased compressive strength by 3.79% relative to the reference SCCSC. Based on the findings, the mechanical strength of SCCSC containing M-sand significantly improved compared to the concrete with river sand. Full article

CO₂ adsorption is one of the promising CCS technologies, and activated coke is a solid adsorbent with excellent adsorption properties. In this study, activated coke was prepared by using bituminous coal and coconut shells activated with KOH or CaCl₂ in a physically activated atmosphere and modified with ammonia. The effect of the active agent impregnation ratio on the physicochemical properties of activated coke was investigated by N₂ adsorption isotherms, scanning electron microscopy (SEM) and Fourier transform infrared spectrometry (FTIR). The CO₂ adsorption performance of activated coke was tested, and the effect of nitrogen-containing functional groups on CO₂ adsorption was investigated by experiments and simulations. The results showed that the specific surface area of activated coke reached 629.81 m²/g at a KOH impregnation ratio of 0.5 and 610.66 m²/g at a CaCl₂ impregnation ratio of 1. The maximum CO₂ adsorption capacity of activated coke reached 71.70 mg/g and 90.99 mg/g for conventional power plant flue gas and oxy–fuel combustion flue gas, respectively. After ammonia modification, the CO₂ adsorption capacity of activated coke was further increased. Simulations showed that pyrrole and pyrrole functional groups changed the polarity of graphene and established weak interactions with CO₂. Full article

To minimize the energy consumption and adverse impact of excessive waste accumulation on the environment, coconut shell (CA) became a potential (partial) replacement agent for fine aggregates in structural concrete production. Thus, systematic experimental and theoretical studies are essential to determine the thermal and structural properties of such concrete containing optimum level of CA. In this view, an artificial neural network (ANN) model, gene expression programming (GEP) model, and response surface method (RS) were used to predict and optimize the desired engineering characteristics of some concrete mixes designed with various levels of CA inclusion. Furthermore, the proposed model’s performance was assessed in terms of different statistical parameters calculated using ANOVA. The results revealed that the proposed concrete mix made using 53% of CA as a partial replacement of fine aggregate achieved an optimum density of 2246 kg/m³ and thermal conductivity of 0.5952 W/mK, which was lower than the control specimen (0.79 W/mK). The p-value of the optimum concrete mix was less than 0.0001 and the F-value was over 147.47, indicating the significance of all models. It is asserted that ANN, GEP, and RSM are accurate and reliable, and can further be used to predict a strong structural–thermal correlation with minimal error. In brief, the specimen composed with 53% of CA as a replacement for fine aggregate may be beneficial to develop environmentally amiable green structural concrete. Full article

An environmentally friendly hydrogel based on gelatin has been investigated as a gel polymer electrolyte in a symmetric carbon-based supercapacitor. To guarantee the complete sustainability of the devices, biomaterials from renewable resources (such as chitosan, casein and carboxymethyl cellulose) and activated carbon (from coconut shells) have been used as a binder and filler within the electrode, respectively. The electrochemical properties of the devices have been compared by using cyclic voltammetry, galvanostatic charge/discharge curves and impedance spectroscopy. Compared to the liquid electrolyte, the hydrogel supercapacitors show similar energy performance with an enhancement of stability up to 12,000 cycles (e.g., chitosan as a binder). The most performant device can deliver ca. 5.2 Wh/kg of energy at a high power density of 1256 W/kg. A correlation between the electrochemical performances and charge storage mechanisms (involving faradaic and non-faradaic processes) at the interface electrode/hydrogel has been discussed. Full article

In-situ remediation of heavy-metal-contaminated soil in farmland using phytostabilization combined with soil amendments is a low-cost and effective technology for soil pollution remediation. In this study, coconut shell biochar (CB, 0.1% and 0.5%), organic fertilizer (OF, 3.0%), and Fe-Si-Ca material (IS, 3.0%) were used to enhance the phytostabilization effect of ramie (Boehmeria nivea L.) on Cd and Pb in highly polluted soils collected at Dabaoshan (DB) and Yangshuo (YS) mine sites. Results showed that simultaneous application of CB, OF, and IS amendments (0.1% CB + 3.0% OF + 3.0% IS and 0.5% CB + 3.0% OF + 3.0% IS, DB-T5 and DB-T6) could significantly increase soil pH, reduce the concentrations of CaCl₂-extractable Cd and Pb, and increase the contents of Ca, P, S, and Si in DB soil. Under these two treatments, the growth of ramie was significantly improved, its photosynthesis was enhanced, and its levels of Cd and Pb were reduced, in comparison with the control (DB-CK). After applying DB-T5 and DB-T6, the concentrations of Cd and Pb in roots were decreased by 97.7–100% and 64.6–77.9%, while in shoots they were decreased by up to 100% and 92.9–100%, respectively. In YS-T4 (0.5% CB + 3.0% OF), the concentrations of Cd and Pb in roots were decreased by 39.5% and 46.0%, and in shoots they were decreased by 44.7% and 88.3%. We posit that phytostabilization using ramie and amendments could reduce the Cd and Pb bioavailability in the soil mainly through rhizosphere immobilization and plant absorption. In summary, this study suggests that the use of tolerant plant ramie and simultaneous application of coconut shell biochar, organic fertilizer, and Fe-Si-Ca materials is an effective stabilization strategy that can reduce Cd and Pb availabilities in soil. Ultimately, this strategy may reduce the exposure risk of crops to heavy metal pollution in farmland. Full article