Search Results (120)

As consumer preferences tend toward safer, chemical residue-free, and nutritionally rich fruits, preharvest bagging has gained attention as a sustainable method for improving fruit quality and protecting produce from environmental and biological stressors and pesticide residues. This study assessed the impact of preharvest bagging using paper bags with inner aluminum coating on the physicochemical traits, storability, and browning susceptibility after cutting or bruising of ‘Afrata Volou’ quince (Cydonia oblonga Mill.) fruit grown in central Greece. Fruits were either bagged or left unbagged approximately 60 days before harvest, and evaluations were conducted at harvest and after three months of cold storage, plus two days of shelf-life. Fruit bagging reduced the quince’s flesh temperature on the tree crown. Bagging had minor effects on fruit and nutritional quality, except for more yellow skin and higher titratable acidity (TA). Also, at harvest, bagging did not significantly affect fruit flesh browning after cutting or bruising. After three months of storage, unbagged and bagged quince fruit developed more yellow skin color, without significant alterations in most quality characteristics and nutritional value, but increased total tannin content (TTC). After three months of storage, the quince flesh color determined immediately after cutting or bruising was brighter and more yellowish compared to that at harvest, due to continuation of fruit ripening, but it darkened faster with time after cutting or skin removal. Therefore, fruit bagging appears to be a sustainable practice for improving the aesthetic and some chemical quality characteristics of quince, particularly after storage, without negative impacts on other characteristics such as texture and phenolic content. Full article

The construction sector presently consumes about 40% of global energy and generates 36% of CO₂ emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article

Orthopedic implants are essential for treating severe fractures and incomplete bone regeneration. However, metal-based implants often suffer from corrosion and biocompatibility issues. This study developed 3D-printed Polylactic Acid Plus (PLA+) bone screws coated with molybdenum and zirconia (ZrO₂) nanocomposites using the dip-coating method. The Taguchi method optimized five coating parameters: molybdenum weight, zirconia weight, ethanol volume, incubation time, and coating duration. The Taguchi method and Response Surface Methodology (RSM) were used for data analysis, while NSGA-II and TOPSIS determined the optimal parameters. Molybdenum weight significantly increased compressive strength (35.45%), while coating time had the greatest effect on density (25.88%). Optimization improved compressive strength/Ec (Modulus of elasticity) to 315.808 MPa and density to 1.141 g/cm³. Compressive strength was significantly improved through optimized coating parameters; however, the achieved value of 315.808 MPa requires validation due to its relatively high magnitude compared to typical PLA materials reported in the literature. The study concludes that combining the Taguchi and NSGA-II methods effectively enhances the mechanical performance and biocompatibility of biodegradable bone screws. The optimal dip-coating parameters were 0.101 g molybdenum, 0.100 g zirconia, 59.523 mL ethanol, 6.025 h of incubation, and 7.907 min of coating time. However, the study is limited to in vitro mechanical testing, and further in vivo evaluations are necessary to confirm long-term biocompatibility and performance. Full article

This study examines the impact of PVD coatings on cutting tool wear during the milling of 316L stainless steel under air cooling conditions. In the experiment, a carbide milling cutter coated with a nanocomposite nACo3 (AlTiSiN) coating was used. The coating was deposited using a next-generation device, the PLATIT π411PLUS, which features one central and three lateral rotating cathodes. The nanocomposite nACo3 coating obtained with this method exhibits exceptionally high structural density and excellent mechanical properties. The new generation of the nACo3 coating demonstrates improved surface properties and a lower friction coefficient compared to previous generations. The findings indicate that PVD nACo3 coatings significantly enhance wear resistance, extending tool life while maintaining acceptable surface quality. The optimal cutting time was determined to be approximately 90 min, after which a sharp increase in surface roughness and tool wear was observed. After 120 min of machining, substantial deterioration of surface quality parameters was recorded, suggesting increasing cutting forces and cutting edge degradation. SEM and EDS analyses revealed the presence of adhered material on the tool and sulfide inclusions in the microstructure of 316L stainless steel, which influenced the machining process. The nACo3 coating demonstrated high thermal and wear resistance, making it an effective solution for machining difficult-to-cut materials. This study suggests that selecting appropriate cutting parameters, tool geometry, protective coatings, and cooling strategies can significantly affect tool longevity and machining quality. The novelty of this research lies in the application of innovative nanocomposite PVD coatings during the milling of 316L stainless steel under air cooling conditions. These studies indicate potential future research directions, such as the use of minimum quantity lubrication (MQL) or cryogenic cooling as methods to reduce tool wear and improve post-machining surface quality. Full article

This study aims to assess the thermal dynamics of supporting structures during laser-assisted debonding of bonded yttrium-stabilized zirconia (YSZ) ceramic. We tested the hypothesis that the heat transfer to dentin analog material and composite resin resembles that of dentin. Thirty sintered YSZ (ZirCAD, Ivoclar, Schann, Liechtenstein) slabs (4 mm diameter, 1 mm thickness) were air particle abraded, followed by two coats of Monobond Plus (Ivoclar). The slabs were bonded to exposed occlusal dentin, NEMA G10 dentin analog, or composite resin cylinders using Multilink Automix (Ivoclar) dual-cured cement. The bonded YSZ specimens (n = 10/group) subjected to irradiation with an Er,Cr:YSGG laser (Waterlase MD, Biolase, Foothill Ranch, CA, USA) at 7.5 W, 25 Hz, with 50% water and air for 15 s. Heat transfer during laser irradiation was monitored with an infrared camera (Optris PI 640, Optris GmbH, Berlin, Germany) at 0.1-s intervals. Data were analyzed using one-way ANOVA, which showed no significant differences in mean temperature between zirconia and cement layers across the substrates (composite resin, G10, dentin) (p = 0.0794). These results suggest flexibility in substrate choice for future thermal dynamics studies under laser irradiation. Full article

This in vitro study evaluated the sealing ability and microleakage of calcium silicate-based sealers compared to an epoxy resin-based sealer. One hundred twenty-five roots from anterior teeth were chemo-mechanically prepared and divided into four groups: AH Plus (AH), ProRoot MTA (PR), Medcem MTA (MC), and Total Fill BC Sealer/BC-coated gutta-percha (TF); n = 30. Confocal laser scanning microscopy was used to measure sealer penetration at three horizontal levels in 10 roots per group, while glucose leakage over 30 days was assessed in 20 roots. A lateral compaction technique was used for most groups, except for TF, which employed a single-cone method. Data were analyzed using Python with a Kruskal–Wallis test and Dunn’s post hoc test. TF showed significantly greater penetration in the coronal and middle sections, while PR had the least penetration in the apical section. PR exhibited the highest canal circumference penetration, especially compared to MC and TF. Glucose leakage increased over time in all groups, with TF showing the highest permeability after 30 days. Overall, calcium silicate-based sealers PR, MC, and TF performed similarly to the epoxy resin standard AH, with all groups exhibiting decreasing penetration from coronal to apical and increased leakage over time. Full article

Seedling establishment is often a critical bottleneck in the revegetation of mine tailings and similar substrates. Biochar and deactivated yeast are potential sustainable materials that could be used in this context as seed coatings to aid in seedling establishment. We conducted a greenhouse study on biochar and deactivated yeast use as seed coatings, assessing germination, establishment, and early growth of white clover (Trifolium repens) and purple prairie clover (Dalea purpurea). Coated seeds were applied to a mine tailing, a coarse granitic sand, and potting soil mix substrates; seedling establishment and growth were monitored over 75 days. Biochar coatings enhanced the seedling establishment of Trifolium, with biochar and biochar plus yeast coatings giving the best results. In some cases, these effects persisted throughout the experiment: biochar coatings resulted in a ~fivefold increase in Trifolium biomass at harvest for plants in the potting soil mix but had neutral effects on sand or tailings. Biochar seed coatings also enhanced Dalea germination in some cases, but the benefits did not persist. Our results indicate that biochar-based seed coatings can have lasting effects on plant growth well beyond germination but also emphasize highly species-specific responses that highlight the need for further study. Full article

Fullerene is a cosmic material with a buckyball-like structure comprising 60 carbon atoms. It has attracted significant interest because of its outstanding antioxidant, antiviral, and antibacterial properties. Natural fullerene (NC60) in shungite meets the demand of biomedical fields to scavenge reactive oxygen species in many diseases. However, its hydrophobicity and poor solubility in water hinder its use as an antioxidant. In this study, highly water-dispersed and stable Pluronic-coated natural fullerene nanoaggregates (NC60/Plu) were prepared from various Pluronic polymers. The water dispersity and stability of NC60 were compared and optimized based on the characteristics of Pluronic polymers including F68, F127, L35, P123, and L81. In particular, NC60 coated with Pluronic F127 at a weight ratio of 1 to 5 showed excellent antioxidant effects both in situ and in vitro. This suggests that the high solubilization of NC60 in Pluronic polymers increases its chance of interacting with reactive oxygen radicals and improves radical scavenging activity. Thus, the optimized NC60/PF127 may be a novel biocompatible antioxidant for treating various diseases associated with oxidative stress. Full article

The aim of this study was to investigate whether PolyJet technology, which uses rubber-like materials for printing and is known for its high resolution and performance, could be suitable for producing flexographic printing plates. In our research, we designed test plates that were printed using PolyJet technology with TangoBlackPlus FLX9870-DM resin. These 3D-printed plates were evaluated for their resistance to various flexographic inks and solvents, and their contact angles were measured. Subsequently, the prints were made on a Flexiproof device using water-based ink with both the test plates and traditional photopolymer plates across six different substrates. The print quality was assessed using densitometry and spectrophotometry. Our findings indicate that the 3D-printed plates are suitable for printing solid areas and lines with water-based inks. However, the print quality of the 3D-printed plates is slightly lower than that of the photopolymer plates, with the optical density values for the high-quality prints on coated papers being approximately 10% lower. Additionally, the plates printed with TangoBlack Plus resin appear to be suitable for UV inks due to their high resistance, but they are not resistant to the solvents used in solvent-based inks. Full article

The shielded pair resonator method is a useful tool in the measurement of accelerator components, such as the beam screens used in the Large Hadron Collider (LHC), the High-Luminosity (HL) LHC, or future accelerators. It can measure the resistive losses at several frequency points by separating the resistive losses on the sample from other sources of losses. We built a new resonator to be inserted into a superconducting dipole magnet (peak magnetic field of 9.5 T) and to measure the surface resistance of beam screens, such as LHC beam screens coated with amorphous carbon (a-C). The device can measure surface resistance at any temperature between 4.2 K and 300 K, in the frequency range of 400 MHz to 1600 MHz. We conducted the first surface resistance measurements of two a-C coated beam screens at 4.2 K and showed that the 200 nm to 400 nm titanium underlayer plus 50 nm a-C only has a limited effect on the surface resistance. This first result supports the choice of this coating as baseline for the HL-LHC triplets magnets upgrade. The resonator will have an important role in the characterization of next-generation beam screens, such as a beam screen with laser-engineered surface structure (LESS). Further measurements of the LHC beam screen in the presence of magnetic fields up to 9.5 T and throughout the full temperature range are going to be reported separately. Full article

This experimental study was performed to assess whether applying a metal primer containing 10-MDP multiple times affected the repair shear bonding ability of base metal alloys to resin composites. Ten base metal alloys were randomly assigned to each group in the manner described, following multiple applications of a metal primer (Clearfil Ceramic Primer Plus), namely one to five applications, and no primer application as a negative control. On the specimens’ prepared surfaces, the resin composite was pushed into the mold and then light-activated for 40 s. The bonded samples were kept for 24 h at 37 °C in distilled water in an incubator. The shear bond strength was determined using a universal testing device. A stereomicroscope was used to determine the debonded surface. The one-way ANOVA and Tukey’s test were implemented to statistically analyze. The lowest shear bond strength was found in group 6 (6.14 ± 1.12 MPa), demonstrating a significant difference (p = 0.000) when compared to groups 1 to 5. The shear bond strength of group 3 was highest at 21.49 ± 1.33 MPa; there was no significant difference between group 3 and groups 4 and 5 (20.21 ± 2.08 MPa and 20.98 ± 2.69 MPa, respectively) (p = 0.773, p = 1.000, respectively). All fractured specimens in groups 1, 2, and 6 were identified as adhesive failure. Groups 3 and 4 exhibited the highest percentage of mixed failures. To achieve the repair shear bonding ability of base metal alloys to resin composites, the sandblasted base metal alloys should be coated with three applications of a metal primer before applying the adhesive agent. Full article

Coatings play a crucial role in the functionality of vacuum chambers in particle accelerators, serving a dual goal by efficiently facilitating pumping and mitigating electron cloud effects. However, their impact on the surface impedance of the chamber walls raises concerns, potentially affecting the machine performance and imposing limitations on achievable energies and currents. Therefore, an electromagnetic characterization is essential for a comprehensive study of accelerator structures, particularly in the context of the next-generation machines where the demand for extremely short particle bunches accentuates the importance of evaluating material responses in the very-high-frequency region. We present a technique for probing the sub-THz response of coating materials by measuring pulsed signals passing through a specifically designed waveguide, in which is placed a slab with the deposited material under test. The proposed methodology allows for a comprehensive exploration of the electromagnetic properties of the most used technical surfaces (substrate plus coatings) in accelerators under realistic conditions, providing valuable insights into their behavior in the sub-THz frequency range. The experimental data of three different Non-Evaporable Getter coating samples, prepared on a copper substrate at the CERN deposition facilities under different sputtering conditions, are discussed. The findings contribute to a deeper understanding of the complex interactions between coatings and accelerator structures, with the aim of optimizing performance and efficiency in the evolving landscape of particle acceleration technologies. The limitations and advantages of the technique are also reported. Full article

Plus, minus, and double-strand RNA viruses are all found in nature. We use computational models to study the relative success of these strategies. We consider translation, replication, and virion assembly inside one cell, and transmission of virions between cells. For viruses which do not incorporate a polymerase in the capsid, transmission of only plus strands is the default strategy because virions containing minus strands are not infectious. Packaging only plus strands has a significant advantage if the number of RNA strands produced per cell is larger than the number of capsids. In this case, by not packaging minus strands, the virus produces more plus-strand virions. Therefore, plus-strand viruses are selected at low multiplicity of infection. However, at high multiplicity of infection, it is preferable to package both strands because the additional minus virions produced are helpful when there are multiple infections per cell. The fact that plus-strand viruses are widespread while viruses that package both strands are not seen in nature suggests that RNA strands are indeed produced in excess over capsids, and that the multiplicity of infection is not sufficiently high to favor the production of both kinds of virions. For double-strand viruses, we show that it is advantageous to produce only plus strands from the double strand within the cell, as is observed in real viruses. The reason for the success of minus-strand viruses is more puzzling initially. For viruses that incorporate a polymerase in the virion, minus virions are infectious. However, this is not sufficient to explain the success of minus-strand viruses, because in this case, viruses that package both strands outcompete those that package only minus or only plus. Real minus-strand viruses make use of replicable strands that are coated by a nucleoprotein, and separate translatable plus strands that are uncoated. Here we show that when there are distinct replicable and translatable strands, minus-strand viruses are selected. Full article

The development of high-filled 3D printing resin necessitates a bonding protocol for dental indirect restorations to achieve optimal bond strength after cementation. This study evaluates shear bond strengths of high-filler 3D printed materials for permanent restorations with various surface treatments. Rodin Sculpture 1.0 (50% lithium disilicate fillers) and 2.0 Ceramic Nanohybrid (>60% zirconia and lithium disilicate fillers) were tested, with Aelite All-Purpose Body composite resin as control. Samples were prepared, post-cured, and sandblasted with alumina (25 µm). Surface roughness was analyzed using an optical profilometer. Two bonding protocols were compared. First, groups were treated with lithium disilicate silane (Porcelain Primer) or zirconia primer (Z-Prime Plus) or left untreated without a bonding agent. Beam-shaped resin cement (DuoLink Universal) specimens were bonded and stored in a 37 °C water bath. Second, additional sets of materials were coated with a bonding agent (All-Bond Universal), either followed by silane application or left untreated. These sets were then similarly stored alongside resin cement specimens. Shear bond tests were performed after 24 h. SEM images were taken after debonding. One-Way ANOVA and post hoc Duncan were performed for the statistical analysis. Rodin 1.0 exhibited increased adhesive failure with silane or zirconia primer coating, but significantly improved bond strengths with bonding agent application. Rodin 2.0 showed consistent bond strengths regardless of bonding agent application, but cohesive failure rates increased with bonding agent and filler coating. In all groups, except for Rodin 1.0 without bonding agent, silane coating increased cohesive failure rate. In conclusion, optimal shear bond strength for high-filler 3D printing materials can be achieved with silane coating and bonding agent application. Full article

This paper proposes a temperature-adaptive radiative cooling (TARC) coating with simple preparation, cost effectiveness, and large-scale application based on a thermochromic powder. To determine the energy efficiency of the proposed TARC coating, the heat transfer on the surface of the TARC coating was analyzed. Then, a typical two-story residential building with a roof area of 258.43 m² was modeled using EnergyPlus. Finally, the energy-saving potential and carbon emission reduction resulting from the application of the proposed TARC roof in buildings under different climates in China were discussed. The results showed that the average solar reflectivity under visible light wavelengths (0.38–0.78 μm) decreases from 0.71 to 0.37 when the TARC coating changes from cooling mode to heating mode. Furthermore, energy consumption can be reduced by approximately 17.8–43.0 MJ/m² and 2.0–32.6 MJ/m² for buildings with TARC roofs compared to those with asphalt shingle roofs and passive daytime radiative cooling (PDRC) roofs, respectively. This also leads to reductions in carbon emissions of 9.4–38.0 kgCO₂/m² and 1.0–28.9 kgCO₂/m² for the buildings located in the selected cities. To enhance building energy efficiency, TARC roofs and PDRC roofs are more suitable for use on buildings located in zones with high heating demands and high cooling demands, respectively. Full article