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Keywords = coal rock heterogeneity

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29 pages, 5505 KiB  
Article
Triaxial Response and Elastoplastic Constitutive Model for Artificially Cemented Granular Materials
by Xiaochun Yu, Yuchen Ye, Anyu Yang and Jie Yang
Buildings 2025, 15(15), 2721; https://doi.org/10.3390/buildings15152721 - 1 Aug 2025
Viewed by 135
Abstract
Because artificially cemented granular (ACG) materials employ diverse combinations of aggregates and binders—including cemented soil, low-cement-content cemented sand and gravel (LCSG), and concrete—their stress–strain responses vary widely. In LCSG, the binder dosage is typically limited to 40–80 kg/m3 and the sand–gravel skeleton [...] Read more.
Because artificially cemented granular (ACG) materials employ diverse combinations of aggregates and binders—including cemented soil, low-cement-content cemented sand and gravel (LCSG), and concrete—their stress–strain responses vary widely. In LCSG, the binder dosage is typically limited to 40–80 kg/m3 and the sand–gravel skeleton is often obtained directly from on-site or nearby excavation spoil, endowing the material with a markedly lower embodied carbon footprint and strong alignment with current low-carbon, green-construction objectives. Yet, such heterogeneity makes a single material-specific constitutive model inadequate for predicting the mechanical behavior of other ACG variants, thereby constraining broader applications in dam construction and foundation reinforcement. This study systematically summarizes and analyzes the stress–strain and volumetric strain–axial strain characteristics of ACG materials under conventional triaxial conditions. Generalized hyperbolic and parabolic equations are employed to describe these two families of curves, and closed-form expressions are proposed for key mechanical indices—peak strength, elastic modulus, and shear dilation behavior. Building on generalized plasticity theory, we derive the plastic flow direction vector, loading direction vector, and plastic modulus, and develop a concise, transferable elastoplastic model suitable for the full spectrum of ACG materials. Validation against triaxial data for rock-fill materials, LCSG, and cemented coal–gangue backfill shows that the model reproduces the stress and deformation paths of each material class with high accuracy. Quantitative evaluation of the peak values indicates that the proposed constitutive model predicts peak deviatoric stress with an error of 1.36% and peak volumetric strain with an error of 3.78%. The corresponding coefficients of determination R2 between the predicted and measured values are 0.997 for peak stress and 0.987 for peak volumetric strain, demonstrating the excellent engineering accuracy of the proposed model. The results provide a unified theoretical basis for deploying ACG—particularly its low-cement, locally sourced variants—in low-carbon dam construction, foundation rehabilitation, and other sustainable civil engineering projects. Full article
(This article belongs to the Special Issue Low Carbon and Green Materials in Construction—3rd Edition)
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29 pages, 4280 KiB  
Article
Pore Structure and Fractal Characteristics of Coal Rocks Under Variable Moisture Content Increment Cycles Using LF-NMR Techniques
by Hongxin Xie, Yanpeng Zhao, Daoxia Qin, Hui Liu, Yaxin Xing, Zhiguo Cao, Yong Zhang, Liqiang Yu and Zetian Zhang
Water 2025, 17(13), 1884; https://doi.org/10.3390/w17131884 - 25 Jun 2025
Viewed by 631
Abstract
The spatiotemporal heterogeneity of moisture distribution causes the coal pillar dams in underground water reservoirs to undergo long-term dry–wet cycles (DWCs) under varying moisture content increments (MCIs). Accurately measuring the pore damage and fractal dimensions (Df) of coal rock by [...] Read more.
The spatiotemporal heterogeneity of moisture distribution causes the coal pillar dams in underground water reservoirs to undergo long-term dry–wet cycles (DWCs) under varying moisture content increments (MCIs). Accurately measuring the pore damage and fractal dimensions (Df) of coal rock by different MCIs under DWCs is a prerequisite for in-depth disclosure of the strength deterioration mechanism of underground reservoir coal pillar dams. This study employed low-field nuclear magnetic resonance (LF-NMR) to quantitatively characterize the pore structural evolution and fractal dimension with different MCI variations (Δw = 4%, 6%, 8%) after one to five DWCs. The results indicate that increasing MCIs at constant DWC numbers (NDWC) induces significant increases in pore spectrum area, adsorption pore area, and seepage pore area. MRI visualization demonstrates a progressive migration of NMR signals from sample peripheries to internal regions, reflecting enhanced moisture infiltration with higher MCIs. Total porosity increases monotonically with MCIs across all tested cycles. Permeability, T2 cutoff (T2C), and Df of free pores exhibit distinct response patterns. A porosity-based damage model further reveals that the promoting effect of cycle numbers on pore development and expansion outweighs that of MCIs at NDWC = 5. This pore-scale analysis provides essential insights into the strength degradation mechanisms of coal pillar dams under hydro-mechanical coupling conditions. Full article
(This article belongs to the Topic Hydraulic Engineering and Modelling)
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26 pages, 7179 KiB  
Article
Quantitative Identification of Emission Sources and Emission Dynamics of Pressure-Relieved Methane Under Variable Mining Intensities
by Xuexi Chen, Xingyu Chen, Jiaying Hu, Jian Xiao, Jihong Sun and Zhilong Yan
Processes 2025, 13(3), 704; https://doi.org/10.3390/pr13030704 - 28 Feb 2025
Cited by 1 | Viewed by 565
Abstract
This study addresses the abnormal emission of pressure-relieved methane under high-intensity mining conditions by integrating geostatistical inversion, FLAC3D-COMSOL coupled numerical simulations, and stable carbon–hydrogen isotopic tracing. Focusing on the 12023 working face at Wangxingzhuang Coal Mine, we established a heterogeneous methane [...] Read more.
This study addresses the abnormal emission of pressure-relieved methane under high-intensity mining conditions by integrating geostatistical inversion, FLAC3D-COMSOL coupled numerical simulations, and stable carbon–hydrogen isotopic tracing. Focusing on the 12023 working face at Wangxingzhuang Coal Mine, we established a heterogeneous methane reservoir model to analyze the mechanical responses of surrounding rock, permeability evolution, and gas migration patterns under mining intensities of 2–6 m/d. Key findings include the following: (1) When the working face advanced 180 m, vertical stress in concentration zones increased significantly with mining intensity, peaking at 12.89% higher under 6 m/d compared to 2 m/d. (2) Higher mining intensities exacerbated plastic failure in floor strata, with a maximum depth of 47.9 m at 6 m/d, enhancing permeability to 223 times the original coal seam. (3) Isotopic fingerprinting and multi-method validation identified adjacent seams as the dominant gas source, contributing 77.88% of total emissions. (4) Implementing targeted long directional drainage boreholes in floor strata achieved pressure-relief gas extraction efficiencies of 34.80–40.95%, reducing ventilation air methane by ≥61.79% and maintaining return airflow methane concentration below 0.45%. This research provides theoretical and technical foundations for adaptive gas control in rapidly advancing faces through stress–permeability coupling optimization, enabling the efficient interception and resource utilization of pressure-relieved methane. The outcomes support safe, sustainable coal mining practices and advance China’s Carbon Peak and Neutrality goals. Full article
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20 pages, 5784 KiB  
Article
Pore Structure Evolution of Coal After Supercritical CO2–Water–Rock Treatment: A Multifractal Analysis
by Sijian Zheng, Yanzhi Liu, Fansheng Huang, Shiqi Liu, Shuxun Sang, Xuguang Dai and Meng Wang
Fractal Fract. 2025, 9(3), 144; https://doi.org/10.3390/fractalfract9030144 - 25 Feb 2025
Cited by 2 | Viewed by 562
Abstract
The evolution of coal’s pore structure is crucial to the efficient capture of carbon dioxide (CO2) within coalbeds, as it provides both adsorption sites and seepage space for the adsorbed- and free-phase CO2, respectively. However, the conventional single fractal [...] Read more.
The evolution of coal’s pore structure is crucial to the efficient capture of carbon dioxide (CO2) within coalbeds, as it provides both adsorption sites and seepage space for the adsorbed- and free-phase CO2, respectively. However, the conventional single fractal method for characterizing pore structure fails to depict the intricacies and variations in coal pores. This study innovatively applies the low-temperature N2/CO2 sorption measurement and multifractal theory to investigate the evolution of the microporous structure of coals (e.g., from the Huainan coalfield) during the supercritical CO2(ScCO2)–water–rock interaction process. Firstly, we observed that the ScCO2–water–rock interaction does not significantly alter the coal’s pore morphology. Notably, taking the ZJ-8# sample as an example, low-temperature N2 sorption testing displayed a stable pore volume following the reaction, accompanied by an increase in specific surface area. Within the CO2 sorption testing range, the ZJ-8# sample’s pore volume remained unchanged, while the specific surface and pore width performed displayed a slight decrease. Secondly, by introducing key parameters from multifractal theory (such as Dq, α(q), τ(q), and f(α)), we assessed the heterogeneity characteristics of the coal’s pore structure before and after the ScCO2–water–rock reaction. The N2 sorption analysis reveals an increase in pore heterogeneity for the ZJ-8# sample and a decrease for the GQ-13# sample within the sorption testing range. In the context of low-temperature CO2 sorption analysis, the pore distribution complexity and heterogeneity of the GQ-11# and GQ-13# samples’ pores were escalated after ScCO2–water–rock interaction. The experimental and analysis results elucidated the dual roles of precipitation and dissolution exerted by the ScCO2–water–rock interaction on the micropores of coal reservoirs, underscoring the heterogeneous nature of the reaction’s influence on pore structures. The application of fractal theory offers a novel perspective compared to traditional pore characterization methods, significantly improving the precision and comprehensiveness of pore structure change descriptions. Full article
(This article belongs to the Special Issue Multiscale Fractal Analysis in Unconventional Reservoirs)
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25 pages, 18430 KiB  
Article
Pore Structure and Heterogeneity Characteristics of Deep Coal Reservoirs: A Case Study of the Daning–Jixian Block on the Southeastern Margin of the Ordos Basin
by Bo Li, Yanqin Guo, Xiao Hu, Tao Wang, Rong Wang, Xiaoming Chen, Wentian Fan and Ze Deng
Minerals 2025, 15(2), 116; https://doi.org/10.3390/min15020116 - 24 Jan 2025
Cited by 2 | Viewed by 820
Abstract
To clarify the micropore structure and fractal characteristics of the Danning–Jixian block on the eastern margin of the Ordos Basin, this study focuses on the deep coal rock of the Benxi Formation in that area. On the basis of an analysis of coal [...] Read more.
To clarify the micropore structure and fractal characteristics of the Danning–Jixian block on the eastern margin of the Ordos Basin, this study focuses on the deep coal rock of the Benxi Formation in that area. On the basis of an analysis of coal quality and physical properties, qualitative and quantitative studies of pore structures with different pore diameters were conducted via techniques such as field emission scanning electron microscopy (FE-SEM), low-pressure CO2 adsorption (LP-CO2A), low-temperature N2 adsorption (LT-N2A), and high-pressure mercury intrusion (HPMI). By applying fractal theory and integrating the results from the LP-CO2A, LT-N2A, and HPMI experiments, the fractal dimensions of pores with different diameters were obtained to characterize the complexity and heterogeneity of the pore structures of the coal samples. The results indicate that the deep coal reservoirs in the Danning–Jixian block have abundant nanometer-scale organic matter gas pores, tissue pores, and a small number of intergranular pores, showing strong heterogeneity influenced by the microscopic components and forms of distribution of organic matter. The pore structure of the Benxi Formation exhibits significant cross-scale effects and strong heterogeneity and is predominantly composed of micropores that account for more than 90% of the total pore volume; the pore structure is affected mainly by the degree of coalification, the vitrinite group, and the ash yield. Fractal analysis reveals that the heterogeneity of macropores is greater than that of mesopores and micropores. This may be attributed to the smaller pore sizes and concentrated distributions of micropores, which are less influenced by diagenesis, resulting in simpler pore structures with lower fractal dimensions. In contrast, mesopores and macropores, with larger diameters and broader distributions, exhibit diverse origins and are more affected by diagenesis, reflecting strong heterogeneity. The abundant storage space and strong self-similarity of micropores in deep coal facilitate the occurrence, flow, and extraction of deep coalbed methane. Full article
(This article belongs to the Special Issue Characterization of Geological Material at Nano- and Micro-scales)
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24 pages, 5031 KiB  
Article
Effect of the Heterogeneity of Coal on Its Seepage Anisotropy: A Micro Conceptual Model
by Xiuling Chen, Guanglei Cui, Jiaming Luo, Chunguang Wang and Jian Zhang
Energies 2024, 17(24), 6484; https://doi.org/10.3390/en17246484 - 23 Dec 2024
Viewed by 721
Abstract
Coal is a typical dual-porosity structural material. The injection of CO2 into coal seams has been shown to be an effective method for storing greenhouse gasses and extracting coal bed methane. In light of the theory of dual-porosity media, we investigate the [...] Read more.
Coal is a typical dual-porosity structural material. The injection of CO2 into coal seams has been shown to be an effective method for storing greenhouse gasses and extracting coal bed methane. In light of the theory of dual-porosity media, we investigate the impact of non-homogeneity on seepage anisotropy and examine the influence of CO2 gas injection on the anisotropy of coal and the permeability of fractures. The results demonstrate that under constant pressure conditions, coal rock has the greatest permeability variation in the direction of face cleats and the smallest changes in the direction of vertical bedding. The more pronounced the heterogeneity, the more evident the change in permeability and the less pronounced the decreasing stage of permeability. Additionally, the larger the diffusion coefficient is, the less pronounced the permeability change. The change in permeability is inversely proportional to the size of the adsorption constant and directly proportional to the size of the fracture. As the matrix block size increases, the permeability also increases, whereas the decrease in permeability becomes less pronounced. The findings of this study offer a theoretical basis for further research into methods for enhancing the CO2 sequestration rate. Full article
(This article belongs to the Special Issue Advances in the Development of Geoenergy: 2nd Edition)
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11 pages, 3932 KiB  
Article
Influence of Complex Lithology Distribution on Fracture Propagation Morphology in Coalbed Methane Reservoir
by Weiping Ouyang, Luoyi Huang, Jinghua Liu, Mian Zhang and Guanglong Sheng
Appl. Sci. 2024, 14(24), 11681; https://doi.org/10.3390/app142411681 - 14 Dec 2024
Cited by 1 | Viewed by 728
Abstract
The mineral composition in coalbed methane (CBM) reservoirs significantly influences fracture morphology, making the description of reservoir heterogeneity challenging. This study develops a fracture propagation model for CBM reservoirs that incorporates the varying mineral properties within the reservoir’s lithology. Dynamic logging data are [...] Read more.
The mineral composition in coalbed methane (CBM) reservoirs significantly influences fracture morphology, making the description of reservoir heterogeneity challenging. This study develops a fracture propagation model for CBM reservoirs that incorporates the varying mineral properties within the reservoir’s lithology. Dynamic logging data are considered to characterize rock mechanical properties, which form the basis for in situ stress estimation. Using an adjusted critical circumferential stress calculation for coal rock, the model considers the impact of complex lithology on fracture propagation. A comprehensive fractal index is introduced to capture the influence of different minerals on fracture morphology and propagation randomness. Models representing clay, quartz, and pyrite with varied compositions were constructed to explore the effects of each mineral on fracture characteristics. In single-component models, clay-rich reservoirs exhibited the highest induced fracture density, with quartz and pyrite showing approximately 65% and 20% of the fracture density observed in clay, respectively. Fractures primarily propagated toward quartz-rich regions, while pyrite significantly inhibited fracture growth. In mixed-mineral models, increasing the quartz proportion by 40% resulted in a 20 m increase in fracture length and a 30% reduction in fracture density. Fractures predominantly propagated around pyrite boundaries, demonstrating pyrite’s resistance to fracture penetration. Clay and quartz promote fracture development, whereas pyrite hinders fracture formation. The fracture inversion model presented here effectively captures the influence of complex mineral distributions on fracture morphology, offering valuable insights for optimizing fracturing production strategies. Full article
(This article belongs to the Special Issue Artificial Intelligence (AI) in Enhanced Oil Recovery)
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16 pages, 6896 KiB  
Article
Numerical Simulation Study on Optimal CO2 Injection Well Placement for Sequestration in Old Gob: A Case Study of the Huainan Mining Area
by Yongchun Chen, Yanfei Xu, Yuchen Tian, Helong Zhang, Bo Xue, Shiheng Chen, Yinghai Liu, Yanzhi Liu, Shiqi Liu, Shuxun Sang and Sijian Zheng
Processes 2024, 12(10), 2167; https://doi.org/10.3390/pr12102167 - 4 Oct 2024
Viewed by 1134
Abstract
The old gob, as a potential CO2 geological storage reservoir, has huge storage potential. To clarify the distribution characteristics and storage capacity of CO2 in the old gob after different well deployment schemes, this study, based on the actual geological conditions [...] Read more.
The old gob, as a potential CO2 geological storage reservoir, has huge storage potential. To clarify the distribution characteristics and storage capacity of CO2 in the old gob after different well deployment schemes, this study, based on the actual geological conditions of the old gob in the Huainan mining area, uses the COMSOL software to numerically simulate CO2 injection into the old gob, considering the heterogeneity of permeability and the difference in coal-rock adsorption capacity within the old gob. The research indicates that the distribution characteristics of CO2 are significantly influenced by the deployment scheme. Specifically, different deployment schemes result in varying CO2 concentrations and distribution patterns. Particularly, when the injection well is deployed at a depth of 65 m, the distribution of CO2 in the low-permeability upper part of the old gob will significantly increase and the horizontal distribution range will significantly decrease. Under different well deployment modes, the CO2 storage capacity varies significantly. When the injection well is deployed at a depth of 65 m, it is more conducive to the storage of CO2 than at other deeper depths and the total storage capacity is larger. In addition, increasing the number of monitoring wells helps the migration and diffusion of CO2 in the old gob. Reasonably increasing the number of monitoring wells and adopting a symmetric deployment mode can significantly improve the CO2 storage capacity in the old gob. Through a reasonable deployment scheme, the CO2 storage capacity in the old gob can be more than 1.8 times that of the single monitoring well deployment scheme. Overall, based on the analysis of the distribution characteristics and storage capacity, the vertical positioning of the injection wells and the deployment mode of the monitoring wells that are conducive to improving the CO2 storage capacity in the old gob are obtained, which can provide an important reference for the well deployment scheme of CO2 storage in the old gob. Full article
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15 pages, 7611 KiB  
Article
Experimental Study on the Impact of High-Frequency Vibration Excitation on Coal Fracturing
by Lei Zhang, Xufeng Wang and Zhijun Niu
Fractal Fract. 2024, 8(9), 546; https://doi.org/10.3390/fractalfract8090546 - 19 Sep 2024
Viewed by 1084
Abstract
The ultrasonic vibration rock-breaking method has been successfully applied to hard rock due to its high efficiency and controllable energy, providing a novel approach for the development of a more efficient, intelligent, safe, and environmentally friendly reconstruction method for coal and rock reservoirs. [...] Read more.
The ultrasonic vibration rock-breaking method has been successfully applied to hard rock due to its high efficiency and controllable energy, providing a novel approach for the development of a more efficient, intelligent, safe, and environmentally friendly reconstruction method for coal and rock reservoirs. By subjecting the rock to ultra-high frequency (>15 kHz) vibration load, rapid fatigue damage can be induced within a short period of time, thereby enhancing the extent of cracking in hard rock. In order to investigate the impact of high-frequency vibration excitation on coal cracking, this study conducted exploratory tests using an independently designed ultrasonic vibration excitation system. These tests were combined with nuclear magnetic resonance (NMR) and permeability measurements to compare and analyze the pore fracture structure and permeability changes in coal samples under resonant and non-resonant conditions. Additionally, multifractal characteristics of the coal samples were investigated. The results demonstrate that high-frequency vibration excitation leads to significant expansion of micropores and mesopores in coal samples. Moreover, there is a strong exponential relationship between coal porosity/permeability and excitation time. After 40 s of stimulation, both porosity and permeability increase by 32.4% and over 8400%, respectively; these increases are five times higher for resonance-state compared to non-resonance-state conditions. Furthermore, water-saturated coal samples exhibit multifractal characteristics in their NMR T2 spectrum distribution, and multifractal parameters ΔD(q)and Δα show positive correlations with the proportion of mesoporous/macropores but negative correlations with the proportion of micropores; conversely, Δf shows an opposite trend relative to pore proportions. The pore structure of coal exhibits intricate multi-scale characteristics, and the heterogeneity at various scales is quantified through multifractal analysis. This study confirms the feasibility of utilizing high-frequency vibration excitation for cracking coal rocks while also providing valuable insights for further expanding its application. Full article
(This article belongs to the Special Issue Applications of Fractal Analysis in Underground Engineering)
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20 pages, 42171 KiB  
Article
Fractal Characteristics and Energy Evolution Analysis of Rocks under True Triaxial Unloading Conditions
by Cheng Pan, Chongyan Liu, Guangming Zhao, Wei Yuan, Xiao Wang and Xiangrui Meng
Fractal Fract. 2024, 8(7), 387; https://doi.org/10.3390/fractalfract8070387 - 28 Jun 2024
Cited by 10 | Viewed by 1385
Abstract
To investigate the mechanical properties and energy evolution laws of rocks under true triaxial unloading conditions, a study was conducted using a true triaxial rock testing system on three different types of rocks: coal, sandy mudstone, and siltstone. The study examined the mechanical [...] Read more.
To investigate the mechanical properties and energy evolution laws of rocks under true triaxial unloading conditions, a study was conducted using a true triaxial rock testing system on three different types of rocks: coal, sandy mudstone, and siltstone. The study examined the mechanical behavior, failure patterns, and fractal dimensions of these rocks under true triaxial unloading conditions. The tests revealed significant variations in stress–strain curves and failure patterns among the different rock types. Observation indicated that rocks with lower peak strength exhibited higher fractal dimensions and increased fragmentation upon failure. Subsequently, based on the experimental data of siltstone, the impact of the unloading rate and particle size distribution on the energy evolution under true triaxial single-sided unloading paths was further investigated using the three-dimensional particle flow software PFC3D 6.0, revealing the micro-mechanisms of rock energy evolution. The study revealed that when the initial stress unloading level was low, the total energy and strain energy at the peak strength exhibited a strong linear relationship with the unloading rate. Before the stress peak, the dissipative energy was mainly composed of frictional energy. After the stress peak, the dissipative energy consisted of frictional energy, damping energy, and kinetic energy. The heterogeneity of rock significantly affected the distribution of dissipative energy, with an increase in rock heterogeneity leading to a decrease in frictional energy and an increase in kinetic energy. Full article
(This article belongs to the Special Issue Fractal Analysis and Its Applications in Rock Engineering)
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21 pages, 9618 KiB  
Article
Trace Elements Distribution in the k7 Seam of the Karaganda Coal Basin, Kazakhstan
by Aiman Kopobayeva, Irina Baidauletova, Altynay Amangeldikyzy and Nazym Askarova
Geosciences 2024, 14(6), 143; https://doi.org/10.3390/geosciences14060143 - 24 May 2024
Cited by 8 | Viewed by 2027
Abstract
We investigated the distribution patterns and evaluated the average contents of trace elements in the k7 seam of the Karaganda coal basin in Central Kazakhstan. This paper presents the results of studying the geochemistry of 34 elements in 85 samples of the [...] Read more.
We investigated the distribution patterns and evaluated the average contents of trace elements in the k7 seam of the Karaganda coal basin in Central Kazakhstan. This paper presents the results of studying the geochemistry of 34 elements in 85 samples of the k7 seam. The study employed a suite of advanced high-resolution analytical methods, including atomic emission spectrometry with inductively coupled plasma (ICP–OES) and mass spectrometry with inductively coupled plasma (ICP–MS), along with their processing and interpretation. It was determined that the concentrations of trace elements in the k7 seam are primarily associated with lithophile elements, revealing high concentrations of Li, V, Sc, Zr, Hf, and Ba. Additionally, increased concentrations of Nb, Ta, Se, Te, Ag, and Th were observed compared to the coal Clarke. Specific Nb(Ta)–Zr(Hf)–Li mineralization accompanied by a group of associated metals (Ba, V, Sc, etc.) was identified. The study revealed lateral and vertical heterogeneity of the rare elements’ distributions in coals, attributed to the formation dynamics of the coal basin. A correlation between Li and Al2O3 with a less positive relationship with K2O suggests the affinity of certain elements (Li, Ta, Nb, and Ba) to kaolinite. Clay layers showed increased radioactivity, with Th—13.2 ppm and U—2.6 ppm, indicating the possible presence of volcanogenic pyroclastic rocks characterized by radioactivity. Taken together, these data reveal the features of the rock composition of the source area, which is considered a mineralization source. According to geochemical data, it was found that the source area mainly consists of igneous felsic rocks, indicating that the formation occurred under conditions of a volcanic arc. This study’s novelty lies in estimating the average trace elements in the k7 seam, with elevated concentrations of certain elements that suggest promising prospects for industrial extraction from coals and coal wastes. These findings offer insights into considering coal as a potential source of raw material for rare metal production, guiding the industrial processing of key elements within coal. The potential extraction of metals from coal deposits, including from dumps, holds significance for industrial and commercial technologies, as processing critical coal elements can reduce disposal costs and mitigate their environmental impact. Full article
(This article belongs to the Topic Petroleum Geology and Geochemistry of Sedimentary Basins)
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19 pages, 4388 KiB  
Review
Review on Dust Control Technologies in Coal Mines of China
by Rongting Huang, Yichun Tao, Jianglin Chen, Shihang Li and Shiyuan Wang
Sustainability 2024, 16(10), 4038; https://doi.org/10.3390/su16104038 - 11 May 2024
Cited by 14 | Viewed by 3568
Abstract
China faces a challenge in the sustainable development of the coal industry due to pneumoconiosis problems. Dust control technologies are crucial for safe production and miners’ health, ensuring the industry’s longevity. This article reviews the development process of dust prevention and control in [...] Read more.
China faces a challenge in the sustainable development of the coal industry due to pneumoconiosis problems. Dust control technologies are crucial for safe production and miners’ health, ensuring the industry’s longevity. This article reviews the development process of dust prevention and control in underground coal mines in China, summarizes various technologies, and divides them into dust suppression, open-space dust reduction, and mine dust collectors according to different stages and environments of use. In dust suppression technologies, coal-seam water injection can reduce total dust generation by 60%, wet rock drilling can reduce drilling dust in the presence of stable water sources and high-pressure bearing equipment, and water-seal blasting can reduce blasting dust by 50–70%. In open-space dust reduction technologies, spray dust suppression can remove total dust by 50–95% and the removal efficiencies of foam dedusting for total and respirable dust are reported to reach 95% and 85% under the right conditions, respectively. In dust collector technologies, dry collectors can remove 80–95% of total dust. Wet collectors achieve up to 90% efficiency, dependent on water supply and waste processing. This article also discusses vapor heterogeneous condensation technology as a promising method for improving respirable dust removal in humid mine environments. Full article
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19 pages, 4477 KiB  
Article
Three-Dimensional Heterogeneity of the Pore and Fracture Development and Acoustic Emission Response Characteristics of Coal Rocks in the Yunnan Laochang Block
by Xingzhi Liu, Songhang Zhang, Yongkang Xie and Tao Wang
Energies 2024, 17(5), 1207; https://doi.org/10.3390/en17051207 - 3 Mar 2024
Cited by 3 | Viewed by 1177
Abstract
Studying the heterogeneity of coal reservoirs is significant to coal bed methane (CBM) exploitation. To investigate the development of the pore–fracture and acoustic emission response characteristics of the coal rock in the Yunnan Laochang block, four cores were extracted from the same coal [...] Read more.
Studying the heterogeneity of coal reservoirs is significant to coal bed methane (CBM) exploitation. To investigate the development of the pore–fracture and acoustic emission response characteristics of the coal rock in the Yunnan Laochang block, four cores were extracted from the same coal rock in different directions. Through a comprehensive analysis using CT scanning and three-axis compression tests combined with synchronous acoustic emission experiments, a three-dimensional visualization of the pore–fracture structure and an analysis of the acoustic emission process during the elastic phase were conducted. Additionally, the impact of the heterogeneous development of pore–fractures on the acoustic emission characteristics was discussed. The results show that: there is strong heterogeneity in pore and fracture development within the coal rock, with the most significant development occurring along the direction of vertical stratification; the acoustic emission process in the elastic phase can be divided into three stages: strong–weak–strong; the development of pores and fractures affects the acoustic emission characteristics, with both counts and signal strength increasing as the percentage of voids rises; and the inferred in situ stress aligns with strike-slip faulting stress using acoustic emission. These results can provide a reference for the actual project. Full article
(This article belongs to the Section H: Geo-Energy)
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27 pages, 13900 KiB  
Article
Full-Scale Pore Structure Characterization and Its Impact on Methane Adsorption Capacity and Seepage Capability: Differences between Shallow and Deep Coal from the Tiefa Basin in Northeastern China
by Na Zhang, Shuaidong Wang, Jiaqi Wu, Zheng Li and Xinyue Wang
Fractal Fract. 2024, 8(1), 48; https://doi.org/10.3390/fractalfract8010048 - 12 Jan 2024
Cited by 9 | Viewed by 2213
Abstract
Deep low-rank coalbed methane (CBM) resources are numerous and widely distributed in China, although their exploration remains in its infancy. In this work, gas adsorption (N2/CO2), mercury intrusion porosimetry, and 3D CT reconstruction were performed on five coal samples [...] Read more.
Deep low-rank coalbed methane (CBM) resources are numerous and widely distributed in China, although their exploration remains in its infancy. In this work, gas adsorption (N2/CO2), mercury intrusion porosimetry, and 3D CT reconstruction were performed on five coal samples of deep and shallow low-rank coal from northeast China to analyze their pore structure. The impact of the features in the pore structure at full scale on the capacity for methane adsorption and seepage is discussed. The results indicate that there are significant differences between deep low-rank coal and shallow low-rank coal in terms of porosity, permeability, composition, and adsorption capacity. The full-scale pore distribution was dispersed over a broad range and exhibited a multi-peak distribution, with the majority of the peak concentrations occurring between 0.45–0.7 nm and 3–4 nm. Mesopores are prevalent in shallow coal rock, whereas micropores are the most numerous in deep coal rock. The primary contributors to the specific surface area of both deep and superficial coal rock are micropores. Three-dimensional CT reconstruction can characterize pores with pore size greater than 1 μm, while the dominating equivalent pore diameters (Deq) range from 1 to 10 μm. More mini-scale pores and fissures are observed in deep coal rock, while shallow coal rock processes greater total and connection porosity. Multifractal features are prevalent in the fractal qualities of all the numbered samples. An enhancement in pore structure heterogeneity occurs with increasing pore size. The pore structure of deep coal rock is more heterogeneous. Furthermore, methane adsorption capacity is favorably connected with D1 (0.4 nm < pore diameter ≤ 2 nm), D2 (2 nm < pore diameter ≤ 5 nm), micropore volume, and specific surface area and negatively correlated with D3 (5 nm < pore diameter ≤ 50 nm), showing that methane adsorption capability is primarily controlled by micropores and mesopores. Methane seepage capacity is favorably connected with the pore volume and connected porosity of macropores and negatively correlated with D4 (pore diameter > 50 nm), indicating that the macropores are the primary factor influencing methane seepage capacity. Full article
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33 pages, 104359 KiB  
Article
Origin of Zn-Pb Mineralization of the Vein Bt23C, Bytíz Deposit, Příbram Uranium and Base-Metal Ore District, Czech Republic: Constraints from Occurrence of Immiscible Aqueous–Carbonic Fluids
by Jana Ulmanová, Zdeněk Dolníček, Pavel Škácha and Jiří Sejkora
Minerals 2024, 14(1), 87; https://doi.org/10.3390/min14010087 - 11 Jan 2024
Cited by 4 | Viewed by 2297
Abstract
The mineralogical, fluid inclusion, and stable isotope (C, O) study was conducted on a Late Variscan Zn-Pb vein Bt23C, Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. The vein is hosted by folded Proterozoic clastic sediments in exo-contact of a Devonian-to-Lower-Carboniferous granitic [...] Read more.
The mineralogical, fluid inclusion, and stable isotope (C, O) study was conducted on a Late Variscan Zn-Pb vein Bt23C, Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. The vein is hosted by folded Proterozoic clastic sediments in exo-contact of a Devonian-to-Lower-Carboniferous granitic pluton. Siderite, dolomite-ankerite, calcite, quartz, baryte, galena, sphalerite, V-rich mica (roscoelite to an unnamed V-analogue of illite), and chlorite (chamosite) form the studied vein samples. The banded texture of the vein was modified by the episodic dissolution of earlier carbonates and/or sphalerite. Petrographic, microthermometric, and Raman studies of fluid inclusions proved a complicated fluid evolution, related to the activity of aqueous fluids and to an episode involving an aqueous–carbonic fluid mixture. Homogenization temperatures of aqueous inclusions decreased from ~210 to ~50 °C during the evolution of the vein, and salinity varied significantly from pure water up to 27 wt.% NaCl eq. The aqueous–carbonic fluid inclusions hosted by late quartz show highly variable phase compositions caused by the entrapment of accidental mixtures of a carbonic and an aqueous phase. Carbonic fluid is dominated by CO2 with minor CH4 and N2, and the associated aqueous solution has a medium salinity (6–14 wt.% NaCl eq.). The low calculated fluid δ18O values (−4.7 to +3.6‰ V-SMOW) suggest a predominance of surface waters during the crystallization of dolomite-ankerite and calcite, combined with a well-mixed source of carbon with δ13C values ranging between −8.2 and −10.5‰ V-PDB. The participation of three fluid endmembers is probable: (i) early high-temperature high-salinity Na>Ca-Cl fluids from an unspecified “deep” source; (ii) late low-salinity low-temperature waters, likely infiltrating from overlying Permian freshwater partly evaporated piedmont basins; (iii) late high-salinity chloridic solutions with both high and low Ca/Na ratios, which can represent externally derived marine brines, and/or local shield brines. The source of volatiles can be (i) in deep crust, (ii) from interactions of fluids with sedimentary wall rocks and/or (iii) in overlying Permian piedmont basins containing, in places, coal seams. The event dealing with heterogeneous CO2-bearing fluids yielded constraints on pressure conditions of ore formation (100–270 bar) as well as on the clarification of some additional genetic aspects of the Příbram’s ores, including the reasons for the widespread dissolution of older vein fill, the possible re-cycling of some ore-forming components, pH changes, and occasionally observed carbon isotope shift due to CO2 degassing. Full article
(This article belongs to the Special Issue Genesis and Evolution of Pb-Zn-Ag Polymetallic Deposits)
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