Search Results (355)

The charged-lepton masses are free Yukawa-sector parameters in the Standard Model, whereas their measured pole-mass ratios display a highly structured hierarchy and satisfy the Koide relation to notable accuracy. This paper develops a conditional mathematical-physics proposal in which these dimensionless regularities arise from a charge-neutral parent carrier-defect architecture before effective Higgs–Yukawa read-out. The assumptions of the construction are stated explicitly as structural postulates and are separated from their derived consequences. The central rule assigns equal primitive weight to admissible internal sectors that are indistinguishable at the level where they first become exposed; protected sectors are removed before counting, and later refinements are conditional on previously selected sectors. Under this rule, the Koide relation follows as an equal-power theorem between the democratic parent component and the orthogonal branch-splitting component of the charged-lepton root-amplitude state. A minimal endpoint construction then yields a rapidly stabilizing charged tower for the electron–muon ratio. Because deeper charged terms are too small to remove the remaining residual, the framework assigns that residual to the continuation-dual neutral branch. The resulting neutral overlap gives a leading solar-angle target of 33.21 degrees and closes the electron–muon ratio at the present experimental precision; the Koide relation then fixes the corresponding tau ratios. The construction does not replace the Standard Model but is proposed as a selection rule for the boundary values of effective charged-lepton Yukawa parameters, with pole masses used because the claimed invariant is attached to completed asymptotic particle read-out. Running parameters, the absolute mass scale, and the full Pontecorvo–Maki–Nakagawa–Sakata (PMNS) matrix remain outside the present derivation. The proposal has explicit failure conditions: improved measurements can exclude the predicted tau ratios or solar-angle target, and the claimed conditional uniqueness fails if a different counting scheme satisfies the same postulates while producing different endpoint weights. Full article

The self-lubricating MoS₂ coating is highly susceptible to degradation in marine environments due to oxidative corrosion. To expand its application in high-humidity and high-salt-fog conditions, this study mixed W with MoS₂ and prepared W-MoS₂ self-lubricating coatings on the surface of CrNi3MoVA steel by electrospark deposition technology. The electrochemical corrosion behaviors of these coatings, with varying W/MoS₂ mass ratios, were examined using an electrochemical workstation in a 3.5 wt.% NaCl solution. The findings indicated that as the MoS₂ content increased, the low-frequency impedance modulus (LIMs) of the W-MoS₂ coating initially rose and then declined. At a MoS₂ content of 20 wt.%, the coating exhibited the highest LIM and the greatest corrosion resistance. In comparison to the CrNi3MoVA steel substrate, the corrosion current density was reduced by 67.4%, a result attributed to the coating’s dense microstructure and improved charge transfer resistance, thereby demonstrating its optimal protective performance. These results provide a laboratory electrochemical basis for designing corrosion-resistant self-lubricating ESD coatings for steel components exposed to chloride-containing environments; however, long-term immersion, cyclic salt-spray, field-exposure, and quantitative adhesion tests are still required before direct long-term marine-service durability can be confirmed. Full article

Efficient interfacial charge transfer is crucial for improving the photocatalytic performance of semiconductor heterojunctions under visible-light irradiation. In this study, Bi₂WO₆/P25 heterojunction photocatalysts modified with 7,7,8,8-tetracyanoquinodimethane (TCNQ) were prepared to enhance visible-light photocatalytic activity. The optimized sample with a TCNQ mass ratio of 0.3% exhibited the highest activity for rhodamine B degradation, achieving a degradation rate approximately 6.0 times higher than that of pure Bi₂WO₆ and 1.7 times higher than that of the pristine Bi₂WO₆/P25 heterojunction. The degradation rates of phenol were 6.5 times and 2.3 times higher for Bi₂WO₆ and BP-5, respectively. The enhanced photocatalytic performance was mainly attributed to the modification of TCNQ, which enhanced the electron transfer from P25 to Bi₂WO₆, establishing a multi-stage electron transfer mechanism involving P25 → Bi₂WO₆ → TCNQ. This molecular surface modification strategy provides new insights for the rational design of high-performance photocatalytic materials. Full article

Cellulose and chitosan are biopolymers widely used to prepare composites due to their complementary charges and intrinsic biocompatibility. While they are mainly of interest for medical applications, they are also suitable for water remediation. In their native states both biopolymers are non-porous; however, after dissolution and subsequent regeneration they can form porous structures that are better suited for such applications. In this work, cellulose pulp and chitosan were dissolved in an ionic liquid and regenerated in water at different mass ratios to produce hydrogels and their corresponding aerogels. The materials were structurally characterized and evaluated for dye adsorption and antimicrobial performance. Methylene blue and Congo red were selected as cationic and anionic dyes, respectively. The concentrations went from 5 to 80 mg/L in 24 h batch adsorption experiments. Chitosan-rich and intermediate cellulose–chitosan hydrogels preferentially removed Congo red, reaching 27 ± 1 mg/g and 24 ± 1 mg/g at 80 mg/L, respectively; the fully cellulose hydrogel maximized methylene blue uptake, achieving 23 ± 1 mg/g under the same conditions. SEM and XRD analyses revealed a hybrid architecture in which chitosan coats cellulose fibers and becomes more amorphous, while cellulose preserves crystalline domains that act as a rigid, highly porous backbone. Aerogels derived from freeze-dried hydrogels exhibited high porosity and water uptake, together with broad-spectrum antimicrobial activity, achieving bactericidal levels (≥99.9% inhibition) against Staphylococcus aureus for all compositions and against Escherichia coli for selected cellulose–chitosan ratios. These results demonstrate that cellulose–chitosan hydrogels and aerogels function as multifunctional bio-based materials whose supramolecular organization, surface charge distribution, and porosity can be tuned to balance adsorption selectivity and antimicrobial performance for advanced environmental applications. Full article

A biological/synthetic hybrid graft copolymer was obtained by grafting poly(acrylic acid) (PAA, synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization) to amylopectin (AMP). The novel graft copolymer presents amphiphilic properties due to the inherent insolubility of AMP in water and was further utilized as a mediator for the synthesis of gold nanoparticles (AuNPs) following an environmentally friendly in situ procedure. The AMP-g-PAA copolymer formation by the interaction of the PAA end groups with the C(6)-OH groups on an AMP backbone was confirmed by Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) and 1D (proton (¹H NMR) and carbon (¹³C NMR) nuclear magnetic resonance, and Distortionless Enhancement by Polarization Transfer (DEPT)) and 2D (correlation (COSY) and heteronuclear single quantum coherence (HSQC)) spectroscopies. The calculated degree of substitution of 1.17 suggests that the grafting was done at one OH from the three in an anhydroglycosidic unit (AGU) (preferably at that in C6 position), with a mean grafting efficiency of 76%. Additional information obtained using thermogravimetric analysis shows that the thermal decomposition of AMP-g-PAA occurs in two steps, with a residual mass of ~16 wt% at 700 °C, higher than AMP or PAA, indicating increased thermal stability of the copolymer. Dynamic and electrophoretic light scattering (DLS and ELS) measurements were used to determine the hydrodynamic size and ionic charge of the AMP-g-PAA self-assemblies in aqueous solution as well as their stability. The AMP-g-PAA was subsequently tested as a reducing agent in the environmentally friendly synthesis of AuNPs in aqueous solution, at different incubation temperatures, reaction duration, and inorganic/polymer weight ratios. The development of the surface plasmon resonance band of AuNPs, observed in UV–vis spectra, was consistently monitored over the reaction time. DLS analysis indicated time-dependent changes in the AuNPs’ particle size distributions, while scanning transmission electron microscopy confirmed that the AuNPs formed at the inorganic/polymer weight ratio of 0.36 and at 60 °C were predominantly well-dispersed, spherical-shaped nanoparticles. The AuNPs synthesized in situ within the copolymer matrix did not introduce additional cytotoxicity compared to the parent copolymer alone, with the composites representing a promising safety baseline for further investigation in biomedical applications. Full article

Vapor compression refrigeration systems account for a substantial share of global electricity consumption in residential and commercial applications, with environmental impacts arising from both energy use and refrigerant leakage. Refrigerant charge optimization offers an economical means of improving system performance without hardware modifications. Oil-free linear compressors mitigate lubricant-induced degradation of heat transfer, yet the combined influence of charge amount on the coefficient of performance (COP) and total equivalent warming impact (TEWI) has not been thoroughly quantified. An experimental investigation was conducted on a vapor compression refrigeration system equipped with an oil-free linear compressor using R134a. The experiments covered refrigerant charges of 220–330 g, piston strokes of 9–12 mm, and pressure ratios of 2.0–3.5. Component-level refrigerant distribution and system performance characteristics were analyzed systematically. The condenser holds 74.7% of the total refrigerant charge at the optimal charge of 280 g. Rising charge reduces superheat and increases subcooling, both of which serve as practical indicators of the charge level. The mass flow rate, cooling capacity, and COP all exhibit characteristic non-monotonic trends. The maximum COP of 4.67 and the maximum cooling capacity of 472.7 W are both achieved at 280 g, which is identified as the optimal operating condition. The oil-free design eliminates lubricant interference and yields a clearly condenser-dominated refrigerant distribution. The TEWI increases by only 3.6% when the charge is raised to 330 g, and this slight environmental drawback is offset by the gain in energy efficiency. A distinct COP reduction is observed at a charge of 220 g. The charge of 280 g achieves the best balance between energy efficiency and lifecycle CO₂ emissions. This work provides quantitative guidance for charge selection in oil-free linear compressor refrigeration systems. Full article

Formaldehyde (HCHO), a prevalent indoor air pollutant released from furniture and building materials, poses significant health risks due to its carcinogenic nature. In this study, a binary cuprous oxide–titanium dioxide (Cu₂O–TiO₂) composite photocatalyst was synthesized via a hydrothermal method to enable efficient visible-light-driven degradation of gaseous formaldehyde at ambient temperature. The structural, morphological, and optical properties of the as-prepared catalysts were characterized using XRD, SEM, TEM, EDX, and UV-Vis spectroscopy. While pristine Cu₂O exhibited a formaldehyde degradation efficiency of approximately 68% under white light illumination, the incorporation of TiO₂ markedly enhanced the photocatalytic performance. Among the different mass ratios tested, the Cu₂O–TiO₂ (1:1) composite demonstrated the highest activity, achieving 83% degradation of formaldehyde within 240 min under white light. Enhanced performance is attributed to the formation of a heterojunction that reduces the effective bandgap, promotes charge separation, and suppresses electron–hole recombination. Additionally, the generation of carbon dioxide and water as end products confirmed complete mineralization. The catalyst also showed good reusability, retaining over 81% efficiency after five cycles. This work presents a cost-effective, stable, and visible-light-active Cu₂O–TiO₂ heterojunction photocatalyst with strong potential for indoor air purification applications. Full article

CO₂ methanation with renewable hydrogen is a promising strategy for carbon valorization and synthetic natural gas (SNG) production. However, the molecular mechanisms behind catalyst-dependent adsorption and mass transport in zeolite-confined spaces are still not fully elucidated. Herein, we performed comparative molecular simulations on HZSM-5, Ni/ZSM-5 and Ru/ZSM-5 by combining density functional theory (DFT), grand canonical Monte Carlo (GCMC) and molecular dynamics (MD) methods, aiming to clarify the thermodynamic and mass transport mechanisms of reactant enrichment and product desorption in CO₂ methanation. The electronic structures of the three systems were systematically evaluated via Mulliken charge analysis, differential charge density mapping, and frontier molecular orbital calculations. We further quantified the adsorption thermodynamics and diffusion kinetics of reactants and products, focusing specifically on the effects of temperature and framework Si/Al ratio for Ni/ZSM-5. The results show that Ni doping greatly modulates the local electronic environment of the ZSM-5 framework, enhancing the adsorption of CO₂ (−121.9 kJ·mol⁻¹) and H₂ (−81.6 kJ·mol⁻¹) and weakening the adsorption of CH₄ and H₂O. A higher Si/Al ratio reduces CO₂ adsorption capacity, while elevated temperatures inhibit reactant adsorption and lower the diffusion selectivity of CH₄. This demonstrates that moderately low temperatures and moderate Si/Al ratios can optimize the adsorption and diffusion behaviors of reactants and products. This work provides molecular-level insights into the adsorption and diffusion behaviors of Ni/ZSM-5 and offers theoretical references for the rational development of high-performance CO₂ methanation catalysts. Full article

Film optimization using high power impulse magnetron sputtering (HiPIMS) currently faces challenges in process control, primarily due to its reliance on empirical trial-and-error adjustment of the macroscopic parameters as well as the insufficient understanding of the underlying mechanisms. To address these issues, this study adopts concentration ratios of monovalent ions over divalent ions of the same metallic element (i.e., Me⁺/Me²⁺) in plasma as a function of key controlled discharge parameters. A mass spectrometer was employed for the in situ diagnostics of ionic species in HiPIMS discharges of Cr, Ti, and Al targets. The influence of discharge parameters on Me⁺/Me²⁺ ratios was systematically investigated. Combined with film characterization, the correlations of discharge parameters, ion concentrations, microstructure evolution, and mechanical properties were established. Results demonstrated that Me⁺/Me²⁺ ratios could be tuned significantly by varying discharge parameters. Decreasing the Me⁺/Me²⁺ ratio suppressed growth of columnar grains and promoted film densification due to enhanced high-energy bombardment. This study reveals the dominant role of the charge state distribution of metallic ions in HiPIMS on the microstructure and properties of nitride films, thereby providing a novel approach to deposition-process optimization, which can also be used as guidance for studies on ternary as well as high-entropy nitride films. Full article

The development of highly efficient, stable, and cost-effective non-precious metal electrocatalysts to replace conventional platinum-based materials holds profound significance for accelerating the commercialization of advanced energy conversion devices, such as zinc–air batteries (ZABs). Herein, we propose a facile and highly efficient strategy to prepare a defect-rich, highly active nitrogen-doped porous carbon-based electrocatalyst (denoted U-Fe-N-C, urea-assisted iron–nitrogen–carbon material), via high-temperature co-pyrolysis of heme with urea. Our results demonstrate that urea not only serves as an excellent nitrogen source during pyrolysis, introducing abundant topological defects and heteroatom doping sites, but also induces the carbon substrate to form a hierarchical sponge-like porous structure with a high specific surface area. This unique microenvironment effectively prevents the agglomeration of iron species at high temperatures, achieving enhanced dispersion of iron species stabilized within the nitrogen-rich carbon matrix. Electrochemical evaluations reveal that under the optimal synthesis conditions (a precursor mass ratio of 1:3, calcination at 900 °C), U-Fe-N-C exhibits excellent oxygen reduction reaction (ORR) catalytic performance, delivering a half-wave potential of 0.731 V vs. RHE, and shows long-term operational durability that significantly surpasses that of commercial Pt/C. Furthermore, liquid rechargeable zinc–air batteries assembled with U-Fe-N-C as the air cathode deliver remarkable cycling stability, operating for up to 270 h of charge–discharge cycling without noticeable performance degradation. This study not only provides useful insights into the mechanisms of pore formation and assistance but also offers a practical perspective for the rational design and scalable synthesis of high-performance metal–nitrogen–carbon (M-N-C) electrocatalysts. Full article

In this study, we investigated the existence and properties of solitons in an unmagnetized plasma composed of positive ions, negative ions, negatively charged dust grains, non-thermal electrons and non-extensive positrons. We have conducted our study on this complex plasma model because it moves away from simplistic and idealized plasma models. Also, a study of solitons has not previously been conducted on this complex plasma model. Through the Sagdeev potential method, we have derived the energy integral and investigated the variation in the Sagdeev potential for different values of the parameters that are involved in our plasma model. We have found that the non-thermal parameter (β) and the non-extensive parameter (q) significantly influence the features of the solitons. The features of the solitons are also found to be influenced by the Mach number (M), the negative-ion-to-positive-ion mass ratio ($\mathsf{\Omega }$), the positron-to-positive-ion density ratio (δ_p), the electron-to-positron temperature ratio (σ_p), the dust charge density ratio (δ_d) and the negative-ion-to-positive-ion density ratio (δ_). The results from our study can be useful in investigating plasma in astrophysical environments, such as cometary tails and interstellar clouds. Full article

We derive the charged-lepton mass chain from the Recognition Composition Law (RCL) together with normalization, curvature normalization, and standard regularity. Through the theorem chain Tr1–Tr8, these postulates fix the golden ratio $\phi = \left(1+\sqrt{5}\right)/2$, the minimal period T_min = 8, the selected dimension D = 3, and the cube integers entering the master mass law. The charged-lepton formula is then assembled from the coherence scale, the lepton-sector baseline, the charge correction, and the derived generation steps. All parameters are discrete structural inputs, integers from cube geometry, named symmetry factors, and one external mathematical constant, rather than continuously adjustable dials. The construction is a structural constraint on the effective charged-lepton flavor pattern, not a replacement for the electroweak Higgs mechanism or for the full Standard Model quantum field theory. At the conversion stage to the International System of Units (SI), the electron fixes the single calibration anchor ${\tau }_0$, while the fine-structure constant $\alpha$ enters only as a fixed external dimensionless constant in the refinement layer. The phrase “zero continuously adjustable parameters” refers to the dimensionless content of the framework: the anchor ${\tau }_0$ is a unit-scale calibration fixed by the measured electron mass and cancels identically from every charged-lepton mass ratio. With that one anchor set, the remaining charged leptons become forward predictions: $m_{\mu }\in \left(\mathrm{105.5,105.9}\right) \mathrm{M}\mathrm{e}\mathrm{V}$ and $m_{\tau }\in \left(\mathrm{1774,1779}\right) \mathrm{M}\mathrm{e}\mathrm{V}$, with relative errors below $0.3\%$ and $0.2\%$, respectively. Floating-point evaluation gives $m_{\mu }\approx 105.658 \mathrm{M}\mathrm{e}\mathrm{V}$ and $m_{\tau }\approx 1776.71 \mathrm{M}\mathrm{e}\mathrm{V}$. Full article

N-glycosylation, particularly terminal mannose exposure, is a critical quality attribute affecting macrophage targeting and the clinical efficacy of enzyme replacement therapy for Gaucher disease. This study developed a universal, sensitive, and quantitative method to compare the N-glycan profiles of three recombinant human glucocerebrosidase products from different expression systems: imiglucerase, velaglucerase alfa, and velaglucerase beta. Using 2-aminobenzamide labeling combined with HILIC-UPLC-FLD and high-resolution mass spectrometry, an N-glycan profiling platform was established. A multidimensional calibration system integrating retention time, glucose unit values, and mass-to-charge ratios was constructed, and collision-induced dissociation tandem MS was used to identify isomers and phosphorylated glycans. The method showed good specificity, linearity, precision, and accuracy. Glycan profiling revealed clear product-dependent differences: imiglucerase was enriched in core-fucosylated Man3 structures, velaglucerase alfa was dominated by Man9 and contained more phosphorylated and sialylated glycans, whereas velaglucerase beta showed a highly homogeneous Man5 profile. These findings demonstrate how distinct manufacturing strategies shape glycosylation patterns and provide a basis for biosimilar development and comparability assessment. Full article

Improving energy efficiency of electric arc furnace (EAF) steelmaking is a key pathway for the iron and steel industry to achieve carbon neutrality. Based on statistical data from 56 industrial EAFs, this study established and validated a comprehensive mass and energy balance model with a verification error of less than 5% and systematically quantified the effects of furnace type, furnace capacity, hot metal charging ratio, and scrap preheating on EAF energy efficiency through statistical analysis and scenario simulation. The results show that furnace type is the decisive factor for energy efficiency; Consteel and shaft furnace EAFs with scrap preheating are significantly more efficient than conventional EAFs, with the shaft furnace exhibiting the highest preheating efficiency and best stability. The scale effect of furnace capacity on energy efficiency is weak and fully overshadowed by furnace type. Each 10% increase in hot metal ratio reduces specific power consumption by about 50 kWh/t in conventional furnaces, and the optimal hot metal ratio is 40–50% to balance power consumption and total energy consumption. Scrap preheating saves electricity by recovering physical heat, with each 100 °C temperature increase reducing power consumption by 25 kWh/t; compared with the Consteel process, the shaft furnace process reduces total energy consumption by approximately 14% and increases energy efficiency by 9%. This study provides theoretical support and practical guidance for process optimization in the low-carbon transformation of EAF short-flow steelmaking. Full article

Photocatalytic water splitting for hydrogen (H₂) evolution is a critical sustainable energy strategy, and cadmium sulfide (CdS) is a promising visible-light photocatalyst due to its suitable band gap. However, the practical application of pure CdS is severely hindered by rapid charge-carrier recombination and significant photocorrosion. In this work, we constructed a CdS/vanadium carbide (VC) photocatalyst via a simple ultrasonic method. The structural, morphological, optical, and photoelectrochemical properties of the composites were systematically investigated. Under visible light (λ ≥ 420 nm) and with 0.35 M Na₂S-0.25 M Na₂SO₃ as the sacrificial agent, the optimized composite featuring a CdS:VC mass ratio of 10:1 (denoted CV-10) achieved a remarkable hydrogen evolution rate of 3485.6 μmol g⁻¹ h⁻¹. This rate represents a 60-fold enhancement over pure-phase CdS and significantly surpasses that of a conventional Pt/CdS catalyst. Furthermore, the CV-10 composite demonstrated excellent stability, showing no activity decay after 16 h of cycling. Spectroscopic and electrochemical analyses revealed that the metallic VC can function as an efficient cocatalyst, accelerating charge separation and transfer while suppressing electron–hole recombination. This work demonstrates that noble-metal-free VC is a highly effective and low-cost cocatalyst, providing a new pathway for designing efficient and stable CdS-based photocatalysts in solar hydrogen production. Full article