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22 pages, 6888 KB  
Article
Research on the Disaster-Causing Factors of Water and Sand Inrush and the Evolution of Surface Collapse Funnel
by Rongqiang Wang, Binghan Lv, Qirui Yang and Guibin Zhang
Water 2025, 17(22), 3218; https://doi.org/10.3390/w17223218 - 11 Nov 2025
Abstract
Water and sand inrush is frequently accompanied by surface subsidence, which severely constrains the sustainable development of coordinated coal mining and ecological environment. This study investigated four key influencing factors based on a water and sand inrush test system: fracture width, aquifer thickness, [...] Read more.
Water and sand inrush is frequently accompanied by surface subsidence, which severely constrains the sustainable development of coordinated coal mining and ecological environment. This study investigated four key influencing factors based on a water and sand inrush test system: fracture width, aquifer thickness, sand particle size composition and stratigraphic sedimentary structure. It obtained the morphological evolution characteristics of collapse funnels and revealed the evolution mechanism of collapse funnels induced by water and sand inrush. The results indicate that fracture width and aquifer thickness mainly affect the range of collapse funnel, and both show a positive correlation with the radius of collapse funnels. Sandy particle size composition plays a dominant role in the morphology of collapse funnels induced by disasters: as the size of the soil skeleton particles increases, the morphology of collapse funnels changes sequentially from a bowl shape to an inverted cone shape and then to a funnel shape with a sunken center and raised slopes. The stratigraphic sedimentary structure has a significant impact on the morphology and damage induced by disasters in collapse funnels. The upper clay layer of the underlying aquifer inhibits the water and sand inrush processes to some extent. An increase in the thickness and number of clay layers effectively prevents the water and sand mixture from flowing into the fracture channel from the lateral direction. This reduces the damage range of collapse funnels and decreases the rate of water and sand inrush. This study clarifies the formation mechanism of surface collapse funnels under the influence of the disaster-causing factors of water and sand inrush, and provides theoretical guidance for the prevention and control of such disasters. Full article
(This article belongs to the Section Water Erosion and Sediment Transport)
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17 pages, 413 KB  
Article
Axial Length to Corneal Radius of Curvature Ratio (AL/CR) and Refractive Errors in a Single Center Romanian Population
by Maria-Cristina Marinescu, Dana-Margareta-Cornelia Dascalescu, Dan Stanila, Sanda Jurja, Mihaela-Monica Constantin, Valeria Coviltir, Cristina Alexandrescu, Radu-Constantin Ciuluvica and Miruna-Gabriela Burcel
Biomedicines 2025, 13(11), 2742; https://doi.org/10.3390/biomedicines13112742 - 10 Nov 2025
Viewed by 39
Abstract
Background: Refractive errors are a common ophthalmological complaint, with a significant potential on the quality of life of our patients—myopia in particular has a growing incidence worldwide. Recent research focused on the ratio between the axial length of the eye (AL) and [...] Read more.
Background: Refractive errors are a common ophthalmological complaint, with a significant potential on the quality of life of our patients—myopia in particular has a growing incidence worldwide. Recent research focused on the ratio between the axial length of the eye (AL) and the corneal radius of curvature (CR), as it had proven valuable in refractive error diagnosis, and risk of progression and of complications. The objective of the study is to compare young emmetropic, hyperopic, and myopic eyes in terms of corneal biomechanics and ocular biometry, focusing on the AL/CR ratio. Methods: This cross-sectional study included 144 myopic eyes, 92 emmetropic eyes, and 47 hyperopic eyes. Measurements included cycloplegic autorefractometry (SE—spherical equivalent), Ocular Response Analyzer (CH—corneal hysteresis, CRF—corneal resistance factor), Aladdin biometry (AL, CR, ACD—anterior chamber depth, CCT—central corneal thickness, AL/CR ratio). Results: ACD, AL, and AL/CR were significantly higher and CCT, SE, CH, and CRF were lower in myopia. The AL/CR ratio correlated positively with AL and ACD and negatively with SE and CR in myopes and hyperopes, and correlated positively with AL and negatively with SE, CH, CRF, and CCT in emmetropes. Conclusions: The AL/CR ratio is significantly higher in myopes and significantly lower in hyperopes, compared to emmetropes, with differences also being in biomechanical properties (CH, CRF) and morphological ones (AL, CCT, ACD). This suggests the AL/CR ratio as a future potential biomarker for refractive errors, particularly for their risk of progression and complications. Full article
(This article belongs to the Special Issue Molecular Research in Ocular Pathology)
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14 pages, 1504 KB  
Article
Intelligent Reflecting-Surface-Aided Orbital Angular Momentum Divergence-Alleviated Wireless Communication Mechanism
by Qiuli Wu, Yufei Zhao, Shicheng Li, Yiqi Li, Deyu Lin and Xuefeng Jiang
Network 2025, 5(4), 48; https://doi.org/10.3390/network5040048 - 30 Oct 2025
Viewed by 224
Abstract
Orbital angular momentum (OAM) beams exhibit divergence during transmission, which constrains the capacity of communication system channels. To address these challenges, intelligent reflecting surfaces (IRSs), which can independently manipulate incident electromagnetic waves by adjustment of their amplitude and phase, are employed to construct [...] Read more.
Orbital angular momentum (OAM) beams exhibit divergence during transmission, which constrains the capacity of communication system channels. To address these challenges, intelligent reflecting surfaces (IRSs), which can independently manipulate incident electromagnetic waves by adjustment of their amplitude and phase, are employed to construct IRS-assisted OAM communication systems. By introducing additional information pathways, IRSs enhance diversity gain. We studied the simulations of two placement methods for an IRS: arbitrary placement and standard placement. In the case of arbitrary placement, the beam reflected by the IRS can be decomposed into different OAM modes, producing various reception powers corresponding to each OAM mode component. This improves the signal-to-noise ratio (SNR) at the receiver, thereby enhancing channel capacity. In particular, when the IRS is symmetrically and uniformly positioned at the center of the main transmission axis, its elements can be approximated as a uniform circular array (UCA). This configuration not only achieves optimal reception along the direction of the maximum gain of the orbital angular momentum beam but also reduces the antenna radius required at the receiver to half or even less. Full article
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12 pages, 368 KB  
Article
Formation of Multispheres and Myelin Based on Multiple Solutions of Membrane Shape Equation
by Tao Xu and Zhong-Can Ou-Yang
Membranes 2025, 15(10), 319; https://doi.org/10.3390/membranes15100319 - 16 Oct 2025
Viewed by 557
Abstract
In this work, we construct a multiple solutions theory based on a membrane shape equation. The membrane shape of a vesicle or a red blood cell is determined using the Zhongcan–Helfrich shape equation. These spherical solutions, which have an identical radius rs [...] Read more.
In this work, we construct a multiple solutions theory based on a membrane shape equation. The membrane shape of a vesicle or a red blood cell is determined using the Zhongcan–Helfrich shape equation. These spherical solutions, which have an identical radius rs but different center positions, can be described by the same equation: ϕρ/rs=0. A degeneracy for the spherical solutions exists, leading to multisphere solutions with the same radius. Therefore, there can be multiple solutions for the sphere equilibrium shape equation, and these need to satisfy a quadratic equation. The quadratic equation has a maximum of two roots. We also find that the multiple solutions should be in a line to undergo rotational symmetry. We use the quadratic equation to compute the sphere radius, together with a membrane surface constraint condition, to obtain the number of small spheres. We ensure matching with the energy constraint condition to determine the stability of the full solutions. The method is then extended into the myelin formation of red blood cells. Our numerical calculations show excellent agreement with the experimental results and enable the comprehensive investigation of cell fission and fusion phenomena. Additionally, we have predicted the existence of the bifurcation phenomenon in membrane growth and proposed a control strategy. Full article
(This article belongs to the Special Issue Composition and Biophysical Properties of Lipid Membranes)
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17 pages, 4058 KB  
Article
Medical Imaging-Based Kinematic Modeling for Biomimetic Finger Joints and Hand Exoskeleton Validation
by Xiaochan Wang, Cheolhee Cho, Peng Zhang, Shuyuan Ge and Jiadi Chen
Biomimetics 2025, 10(10), 652; https://doi.org/10.3390/biomimetics10100652 - 1 Oct 2025
Viewed by 435
Abstract
Hand rehabilitation exoskeletons play a critical role in restoring motor function in patients with stroke or hand injuries. However, most existing designs rely on fixed-axis assumptions, neglecting the rolling–sliding coupling of finger joints that causes instantaneous center of rotation (ICOR) drift, leading to [...] Read more.
Hand rehabilitation exoskeletons play a critical role in restoring motor function in patients with stroke or hand injuries. However, most existing designs rely on fixed-axis assumptions, neglecting the rolling–sliding coupling of finger joints that causes instantaneous center of rotation (ICOR) drift, leading to kinematic misalignment and localized pressure concentrations. This study proposes the Instant Radius Method (IRM) based on medical imaging to continuously model ICOR trajectories of the MCP, PIP, and DIP joints, followed by the construction of an equivalent ICOR through curve fitting. Crossing-type biomimetic kinematic pairs were designed according to the equivalent ICOR and integrated into a three-loop ten-linkage exoskeleton capable of dual DOFs per finger (flexion–extension and abduction–adduction, 10 DOFs in total). Kinematic validation was performed using IMU sensors (Delsys) to capture joint angles, and interface pressure distribution at MCP and PIP was measured using thin-film pressure sensors. Experimental results demonstrated that with biomimetic kinematic pairs, the exoskeleton’s fingertip trajectories matched physiological trajectories more closely, with significantly reduced RMSE. Pressure measurements showed a reduction of approximately 15–25% in mean pressure and 20–30% in peak pressure at MCP and PIP, with more uniform distributions. The integrated framework of IRM-based modeling–equivalent ICOR–biomimetic kinematic pairs–multi-DOF exoskeleton design effectively enhanced kinematic alignment and human–machine compatibility. This work highlights the importance and feasibility of ICOR alignment in rehabilitation robotics and provides a promising pathway toward personalized rehabilitation and clinical translation. Full article
(This article belongs to the Special Issue Bionic Wearable Robotics and Intelligent Assistive Technologies)
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19 pages, 4151 KB  
Article
Three-Dimensional Heterogeneity of Salinity Extremes Modulated by Mesoscale Eddies Around the Hawaiian Islands
by Shiyan Li, Zhenhui Yi, Qiwei Sun, Hanshi Wang, Xiang Gao, Wenjing Zhang, Jian Shi, Hailong Guo, Jingxing Chen and Jie Wu
Remote Sens. 2025, 17(18), 3167; https://doi.org/10.3390/rs17183167 - 12 Sep 2025
Viewed by 500
Abstract
Salinity extremes (SEs) play a crucial role in marine ecosystems, ocean circulation, and climate variability. Understanding their distribution and drivers is essential for predicting changes in ocean salinity under climate change, particularly in dynamic regions such as the Hawaiian Islands, where mesoscale eddies [...] Read more.
Salinity extremes (SEs) play a crucial role in marine ecosystems, ocean circulation, and climate variability. Understanding their distribution and drivers is essential for predicting changes in ocean salinity under climate change, particularly in dynamic regions such as the Hawaiian Islands, where mesoscale eddies significantly modulate water mass properties. This study investigates the three-dimensional characteristics of SEs and their responses to mesoscale eddies using mooring observations and sea surface salinity data. We find that high salinity extremes (HSEs) generally occur more frequently than low salinity extremes (LSEs) in the study region, though LSEs exhibit greater duration and intensity. Mesoscale eddies modulate SEs significantly—anticyclonic eddies (AEs) enhance LSEs, whereas cyclonic eddies (CEs) promote HSEs in the upper layer. This relationship reverses in the deeper layer, with AEs favoring HSEs and CEs enhancing LSEs. These opposing effects are driven by a vertical displacement of the subsurface salinity maximum layer, where CEs lift high-salinity subsurface water to the upper ocean via upwelling, creating HSEs in the upper layer and LSEs in the deeper layer, while AEs subduct high-salinity water downward, reducing upper-layer salinity (LSEs) but increasing deeper-layer salinity (HSEs) via downwelling. Spatially, CEs exhibit a single-core high-salinity anomaly, displaced westward by 0.3 times of the eddy radius from the eddy center, with HSEs peaking in frequency and intensity near the core. In contrast, AEs display a dipole salinity anomaly (low northwest/high southeast), aligning with LSE frequency distribution, while HSEs show an inverse pattern. Mooring data further reveal that AE-LSE co-occurrence is highest within 1.2 times of the eddy radius, whereas CE-HSE probability declines with eddy intensity. Notably, AE-HSE and CE-LSE probabilities, though initially weaker, surpass AE-LSE and CE-HSE at certain depths, underlining the complexity of depth-dependent eddy modulation. These findings may advance understanding of ocean salinity dynamics and provide insights into how mesoscale processes modulate extreme events, with implications for marine biogeochemistry and climate modeling. Full article
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10 pages, 208 KB  
Article
The Impact of Concomitant Upper Extremity Fractures on Outcomes in Geriatric Patients Following Hip Fracture Surgery
by Nadav Graif, Etay Elbaz, Yaniv Warschawski, Efi Kazum, Lior Shabtai, Nissan Amzallag and Shai Factor
J. Clin. Med. 2025, 14(18), 6380; https://doi.org/10.3390/jcm14186380 - 10 Sep 2025
Viewed by 469
Abstract
Background: Hip fractures in geriatric patients represent a major public health burden, with a clinically important subset presenting with concomitant upper extremity (UE) fractures. The independent impact of these dual injuries on clinical outcomes remains incompletely characterized. Methods: A retrospective study of patients [...] Read more.
Background: Hip fractures in geriatric patients represent a major public health burden, with a clinically important subset presenting with concomitant upper extremity (UE) fractures. The independent impact of these dual injuries on clinical outcomes remains incompletely characterized. Methods: A retrospective study of patients aged ≥65 years who underwent surgical treatment for hip fracture at tertiary medical center, between January 2010 and January 2024. Patients were stratified based on the presence of a UE fracture sustained at the same time as the hip fracture. Multivariable regression models were used to assess outcomes, adjusting for age, sex, hip fracture type, and comorbidity burden. Primary outcomes were hospital length of stay and mortality at 30 days and 1 year. Secondary outcomes included readmission rates, revision surgery, and infection complications. Results: Of 7488 patients, 251 (3.4%) had concomitant upper extremity (UE) fractures. These patients had a longer mean hospital stay compared with isolated hip fractures (20.2 vs. 17.5 days, p = 0.047), with no significant difference in 30-day mortality (p = 0.439) and a trend toward lower 1-year mortality (p = 0.058). In the concomitant UE fracture group, operative treatment was associated with longer hospitalization (26.2 vs. 19.2 days, p = 0.05) and higher revision surgery rates (14.0% vs. 3.1%, p = 0.01). Subgroup analyses by fracture type showed similar trends, with longer hospital stays observed in intracapsular fractures with concomitant injury (p = 0.05). Subgroup analysis by UE fracture location showed significantly longer stays for distal radius fractures compared with isolated hip fractures, whereas no significant differences were observed for proximal humerus or other UE fracture locations. Conclusions: Concomitant UE fractures in geriatric hip fracture patients are associated with prolonged hospitalization. Operative management of UE fractures results in longer hospital stays and an increased risk of revision surgery. These findings highlight the importance of tailored perioperative planning and resource allocation for this vulnerable patient group. Full article
(This article belongs to the Special Issue Trauma Surgery: Strategies, Challenges and Vision of the Future)
16 pages, 9817 KB  
Article
Synthesizing a Spatial Mechanism with a Hollow Core for Use in a Wrist Pronation and Supination Orthotic
by Tianze Xu, David H. Myszka, Clément Trotobas, Christine Azevedo and Andrew P. Murray
Machines 2025, 13(9), 833; https://doi.org/10.3390/machines13090833 - 9 Sep 2025
Viewed by 500
Abstract
Full use of the upper limb is necessary to carry out most tasks of daily life. Upper limb deficiencies, whether through complete or incomplete paralysis, inevitably lead to a loss of autonomy. Assistive orthoses are a potential method for restoring some autonomy. Pronation [...] Read more.
Full use of the upper limb is necessary to carry out most tasks of daily life. Upper limb deficiencies, whether through complete or incomplete paralysis, inevitably lead to a loss of autonomy. Assistive orthoses are a potential method for restoring some autonomy. Pronation and supination, the turning of the wrist relative to the elbow, receives less focus than other joint movements in the arm. First, the utility of this degree-of-freedom in the arm is less obvious. Second, when compared to flexion and extension of the elbow, wrist prono-supination has no clear center of rotation due to the combined movement of the ulna and the radius bones as they cross and uncross in the forearm. This paper presents initial work in the design of a mechanism for a portable assistive orthosis that is expected to include powered prono-supination. The component proposed in this work is based on a spherical mechanism architecture. The capacity of these mechanisms to have a hollow center and to produce paths that follow arcs on spheres makes them worth consideration in this application. An optimization was carried out to perform path generation of a single spherical four-bar with the intent of replicating it three times to create the device proposed in this work. The mechanical design was modeled and a conceptual prototype was constructed to perform preliminary operational evaluations. Full article
(This article belongs to the Collection Machines, Mechanisms and Robots: Theory and Applications)
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24 pages, 1473 KB  
Article
The Black Hole with a Finite-Sized Core Structure
by Ting-Han Pei
Symmetry 2025, 17(9), 1431; https://doi.org/10.3390/sym17091431 - 2 Sep 2025
Viewed by 742
Abstract
To meet the supergravity requirements of a black hole without a singularity, we propose some possible finite-sized core structures to avoid the confusing singularity problem. This research first studies the Coulomb repulsion between electrons at a distance of 10−15 m, where the [...] Read more.
To meet the supergravity requirements of a black hole without a singularity, we propose some possible finite-sized core structures to avoid the confusing singularity problem. This research first studies the Coulomb repulsion between electrons at a distance of 10−15 m, where the inverse square of the distance is still workable, revealing that the energy of the entire observable universe is required to form a charged region with a radius of 50 m, including 1.4 × 1031 Coulomb electrons. Therefore, the existence of a singularity at the center of a black hole becomes physically unreasonable in this case. To avoid the singularity problem, we propose a finite-sized black hole core in which the inner core is composed of the vast majority of neutrons and a very small amount of 56Fe. Under the conditions of a total charge of 1.648824 × 1020 C and a total mass equivalent to the Sun, a finite-sized black hole is constructed through this finite-sized core model. We use this non-rotating but charged, compact, star-like structure, surrounded by counter-rotating and co-rotating electrons, to construct a Kerr–Newman black hole with a finite-sized core structure. Based on this model, we can obtain the same spacetime as that of a traditional Kerr–Newman black hole. Full article
(This article belongs to the Special Issue Gravitational Physics, Black Holes and Space–Time Symmetry)
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15 pages, 999 KB  
Article
Determination of the Radius of the Ring Current in the Earth’s Core According to the Data of the INTERMAGNET Network Observatories
by Ivan Vassilyev, Inna Fedulina, Zhassulan Mendakulov, Beibit Zhumabayev and Igor Kozin
Appl. Sci. 2025, 15(17), 9633; https://doi.org/10.3390/app15179633 - 1 Sep 2025
Viewed by 745
Abstract
The geomagnetic dynamo is currently considered the most likely source of the Earth’s main dipole field. However, the radius of the current ring located in the Earth’s core is not reliably known. There are methods for indirectly estimating the radius of this current. [...] Read more.
The geomagnetic dynamo is currently considered the most likely source of the Earth’s main dipole field. However, the radius of the current ring located in the Earth’s core is not reliably known. There are methods for indirectly estimating the radius of this current. Another method is proposed that allows one to indirectly estimate the radius of the current ring inside the Earth’s core based on measurements of the Earth’s magnetic field by observatories included in the INTERMAGNET network. The results of measurements taken on a day with low magnetic activity were compared using the least squares method with fields that could be created by ring currents of different diameters at the locations of magnetic observatories. The assumption was made that the ring current in the model used is located in the plane of the Earth’s equator with the center coinciding with the axis of rotation of the Earth. Estimates of the current radius in the range of 957–1595 km were obtained, which corresponds to the boundary between the solid and liquid cores of the Earth. These results can refine the model of the structure of the Earth’s core and Earth’s magnetism. Full article
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23 pages, 8824 KB  
Article
Investigating Green View Perception in Non-Street Areas by Combining Baidu Street View and Sentinel-2 Images
by Hongyan Wang, Xianghong Che and Xinru Yang
Sustainability 2025, 17(16), 7485; https://doi.org/10.3390/su17167485 - 19 Aug 2025
Viewed by 869
Abstract
Urban greening distribution critically impacts residents’ quality of life and environmental sustainability. While the Green View Index (GVI), derived from street view imagery, is widely adopted for urban green space assessment, its limitation lies in the inability to capture non-street-area vegetation. Remote sensing [...] Read more.
Urban greening distribution critically impacts residents’ quality of life and environmental sustainability. While the Green View Index (GVI), derived from street view imagery, is widely adopted for urban green space assessment, its limitation lies in the inability to capture non-street-area vegetation. Remote sensing imagery, conversely, provides full-coverage urban vegetation data. This study focuses on Beijing’s Third Ring Road area, employing DeepLabv3+ to calculate a street-view-based GVI as a predictor. Correlations between the GVI and Sentinel-2 spectral bands, along with two vegetation indices, such as the Normalized Difference Vegetation Index (NDVI) and Fractional Vegetation Cover (FVC), were analyzed under varying buffer radius. Regression and classification models were subsequently developed for GVI prediction. The optimal classifier was then applied to estimate green perception levels in non-street zones. The results demonstrated that (1) at a 25 m buffer radius, the near-infrared band, NDVI, and FVC exhibited the highest correlations with the GVI, reaching 0.553, 0.75, and 0.752, respectively. (2) Among the five machine learning regression models evaluated, the random forest algorithm demonstrated superior performance in GVI estimation, achieving a coefficient of determination (R2) of 0.787, with a root mean square error (RMSE) of 0.063 and a mean absolute error (MAE) of 0.045. (3) When evaluating categorical perception levels of urban greenery, the Extremely Randomized Trees classifier (Extra Trees) demonstrated superior performance in green vision perception level estimation, achieving an accuracy (ACC) score of 0.652. (4) The green perception level in non-road areas within Beijing’s Third Ring Road is 56.8%, which is considered relatively poor. Moreover, the green perception level within the Second Ring Road is even lower than that in the area between the Second and Third Ring roads. This study is expected to provide valuable insights and references for the adjustment and optimization of green perception distribution in Beijing, thereby supporting more informed urban planning and the development of sustainable, human-centered green spaces across the city. Full article
(This article belongs to the Special Issue Remote Sensing in Landscape Quality Assessment)
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31 pages, 6857 KB  
Article
Performance Analysis and Experimental Validation of Small-Radius Slope Steering for Mountainous Crawler Tractors
by Luojia Duan, Longhai Zhang, Kaibo Kang, Yuxuan Ji, Xiaodong Mu, Hansong Wang, Junrui Zhou, Zhijie Liu and Fuzeng Yang
Agronomy 2025, 15(8), 1956; https://doi.org/10.3390/agronomy15081956 - 13 Aug 2025
Viewed by 620
Abstract
This study investigates the dynamic performance of mountainous crawler tractors during small-radius slope steering, providing theoretical support for power machinery design in hilly and mountainous regions. Addressing the mechanization demands in complex terrains and existing research gaps, a steering dynamics model is established. [...] Read more.
This study investigates the dynamic performance of mountainous crawler tractors during small-radius slope steering, providing theoretical support for power machinery design in hilly and mountainous regions. Addressing the mechanization demands in complex terrains and existing research gaps, a steering dynamics model is established. The model incorporates an amplitude-varied multi-peak cosine ground pressure distribution, employs position vectors and rotation matrices to characterize 3D pose variations in the tractor’s center of mass, and integrates slope angle, soil parameters, vehicle geometry, center-of-mass shift, bulldozing resistance, and sinkage resistance via d’Alembert’s principle. Numerical simulations using Maple 2024 analyzed variations in longitudinal offset of the instantaneous steering center, bilateral track traction forces, and bulldozing resistance with slope, speed, and acceleration. Variable-gradient steering tests on the “Soil-Machine-Crop” Comprehensive Experimental Platform demonstrated model accuracy, with <8% mean error and <12% maximum relative error between predicted and measured track forces. This research establishes a theoretical foundation for predicting, evaluating, and controlling the steering performance/stability of crawler tractors in complex slope conditions. Full article
(This article belongs to the Special Issue Unmanned Farms in Smart Agriculture—2nd Edition)
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30 pages, 4370 KB  
Article
A Blur Feature-Guided Cascaded Calibration Method for Plenoptic Cameras
by Zhendong Liu, Hongliang Guan and Qingyang Ni
Sensors 2025, 25(16), 4940; https://doi.org/10.3390/s25164940 - 10 Aug 2025
Viewed by 700
Abstract
Accurate and robust calibration of multifocal plenoptic cameras is essential for high-precision 3D light field reconstruction. In this work, we propose a blur feature-guided cascaded calibration for the plenoptic camera. First, white images at different aperture values are used to estimate the high-confidence [...] Read more.
Accurate and robust calibration of multifocal plenoptic cameras is essential for high-precision 3D light field reconstruction. In this work, we propose a blur feature-guided cascaded calibration for the plenoptic camera. First, white images at different aperture values are used to estimate the high-confidence center point and radius of micro-images, and the defocus theory is used to estimate the initial values of the intrinsic parameters. Second, the gradient value is introduced to quantify the degree of blurring of the corner points, which are then divided into three types: clear, semi-clear, and blurred. Furthermore, a joint geometric constraint model of epipolar lines and virtual depth is constructed, and the coordinates of the semi-clear and blurred corner points are optimized in a step-by-step manner by using the clear corner point coordinates. The micro-image center ray projection equation is then devised to assist in the optimization of the microlens array core parameters and establish blur-adaptive credibility weights, thereby constructing a global nonlinear optimization. Finally, the proposed method is tested on both simulated and captured datasets, and the results exhibit superior performance when compared with the established methods described by Labussière, Nousias, and Liu. The proposed method excels in corner feature extraction, calibration accuracy of both internal and external parameters, and calibration sensitivity when applied to multifocal-length light field cameras, highlighting its advantages and robustness. Full article
(This article belongs to the Section Sensing and Imaging)
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21 pages, 2838 KB  
Article
Reactivity of Ammonia in 1,2-Addition to Group 13 Imine Analogues with G13–P–Ga Linkages: The Electronic Role of Group 13 Elements
by Zheng-Feng Zhang and Ming-Der Su
Molecules 2025, 30(15), 3222; https://doi.org/10.3390/molecules30153222 - 31 Jul 2025
Viewed by 453
Abstract
Using density functional theory (M06-2X-D3/def2-TZVP), we investigated the 1,2-addition reactions of NH3 with a series of heavy imine analogues, G13=P-Rea (where G13 denotes a Group 13 element; Rea = reactant), featuring a mixed G13–P–Ga backbone. Theoretical analyses revealed that the bonding nature [...] Read more.
Using density functional theory (M06-2X-D3/def2-TZVP), we investigated the 1,2-addition reactions of NH3 with a series of heavy imine analogues, G13=P-Rea (where G13 denotes a Group 13 element; Rea = reactant), featuring a mixed G13–P–Ga backbone. Theoretical analyses revealed that the bonding nature of the G13=P moiety in G13=P-Rea molecules varies with the identity of the Group 13 center. For G13=B, Al, Ga, and In, the bonding is best described as a donor–acceptor (singlet–singlet) interaction, whereas for G13=Tl, it is characterized by an electron-sharing (triplet–triplet) interaction. According to our theoretical studies, all G13=P-Rea species—except the Tl=P analogue—undergo 1,2-addition with NH3 under favorable energetic conditions. Energy decomposition analysis combined with natural orbitals for chemical valence (EDA–NOCV), along with frontier molecular orbital (FMO) theory, reveals that the primary bonding interaction in these reactions originates from electron donation by the lone pair on the nitrogen atom of NH3 into the vacant p-π* orbital on the G13 center. In contrast, a secondary, weaker interaction involves electron donation from the phosphorus lone pair of the G13=P-Rea species into the empty σ* orbital of the N–H bond in NH3. The calculated activation barriers are primarily governed by the deformation energy of ammonia. Specifically, as the atomic weight of the G13 element increases, the atomic radius and G13–P bond length also increase, requiring a greater distortion of the H2N–H bond to reach the transition state. This leads to a higher geometrical deformation energy of NH3, thereby increasing the activation barrier for the 1,2-addition reaction involving these Lewis base-stabilized, heavy imine-like G13=P-Rea molecules and ammonia. Full article
(This article belongs to the Special Issue Exclusive Feature Papers in Inorganic Chemistry, 3rd Edition)
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28 pages, 6188 KB  
Article
Mechanical Behavior of Topology-Optimized Lattice Structures Fabricated by Additive Manufacturing
by Weidong Song, Litao Zhao, Junwei Liu, Shanshan Liu, Guoji Yu, Bin Qin and Lijun Xiao
Materials 2025, 18(15), 3614; https://doi.org/10.3390/ma18153614 - 31 Jul 2025
Cited by 1 | Viewed by 1238
Abstract
Lattice-based metamaterials have attracted much attention due to their excellent mechanical properties. Nevertheless, designing lattice materials with desired properties is still challenging, as their mesoscopic topology is extremely complex. Herein, the bidirectional evolutionary structural optimization (BESO) method is adopted to design lattice structures [...] Read more.
Lattice-based metamaterials have attracted much attention due to their excellent mechanical properties. Nevertheless, designing lattice materials with desired properties is still challenging, as their mesoscopic topology is extremely complex. Herein, the bidirectional evolutionary structural optimization (BESO) method is adopted to design lattice structures with maximum bulk modulus and elastic isotropy. Various lattice configurations are generated by controlling the filter radius during the optimization processes. Afterwards, the optimized lattices are fabricated using Stereo Lithography Appearance (SLA) printing technology. Experiments and numerical simulations are conducted to reveal the mechanical behavior of the topology-optimized lattices under quasi-static compression, which are compared with the traditional octet-truss (OT) and body-centered cubic (BCC) lattice structures. The results demonstrate that the topology-optimized lattices exhibited superior mechanical properties, including modulus, yield strength, and specific energy absorption, over traditional OT and BCC lattices. Moreover, apart from the elastic modulus, the yield stress and post-yield stress of the topology-optimized lattice structures with elastically isotropic constraints also present lower dependence on the loading direction. Accordingly, the topology optimization method can be employed for designing novel lattice structures with high performance. Full article
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