Search Results (87)

The production of a stable and uniform spray is a primary concern in fuel atomization applications, such as in fluid catalytic cracking reactors, directly affecting the process quality and gas emissions. However, depending on nozzle geometry and operating conditions, undesired pulsed spray behavior may occur. This phenomenon originates from the internal multiphase flow interaction in Y-jet nozzles and leads to unstable sprays. Understanding the formation of spray pulsations is challenging due to limited internal flow visualization in the nozzle and the fast dynamics involved. Accordingly, this work elucidates the mechanisms of the pulsed spray formation through 3D transient numerical multiphase simulations inside a mixing chamber. The model is validated against internal pressure measurements and applied to investigate the internal mixing behavior across several operating conditions. Results show that the liquid-to-gas momentum flux ratio governs the internal flow regimes. A higher liquid momentum flux obstructs the gas flow, leading to periodic spray bursts when the gas overcomes the liquid back pressure. The simulations also reveal self-sustained oscillatory flow patterns and cyclic transitions between gas penetration and liquid accumulation, which produce periodic pressure fluctuations and nozzle discharge pulsations. The findings offer valuable guidance for optimizing nozzle operation and geometry to suppress pulsation and improve atomization performance. Full article

Metal Injection Molding (MIM) is an established, high-precision manufacturing route for small, geometrically complex metallic components, integrating polymer injection molding with powder metallurgy. State-of-the-art feedstock systems, such as Catamold (polyacetal-based), enable catalytic debinding performed in furnaces operating under ultra-high-purity nitric acid atmospheres (>99.999%). The subsequent thermal stages pre-sintering and sintering are carried out in continuous controlled-atmosphere furnaces or vacuum systems, typically employing inert (N₂) or reducing (H₂) atmospheres to meet the specific thermodynamic requirements of each alloy. However, incomplete decomposition or secondary volatilization of binder residues can lead to progressive hydrocarbon accumulation within the sinering chamber. These contaminants promote undesirable carburizing atmospheres, which, under austenitizing or intercritical conditions, increase carbon diffusion and generate uncontrolled surface carbon gradients. Such effects alter the microstructural evolution, hardness, wear behavior, and mechanical integrity of MIM steels. Conversely, inadequate dew point control may shift the atmosphere toward oxidizing regimes, resulting in surface decarburization and oxide formation effects that are particularly detrimental in stainless steels, tool steels, and martensitic alloys, where surface chemistry is critical for performance. This review synthesizes current knowledge on atmosphere-induced surface deviations in MIM steels, examining the underlying thermodynamic and kinetic mechanisms governing carbon transport, oxidation, and phase evolution. Strategies for atmosphere monitoring, contamination mitigation, and corrective thermal or thermochemical treatments are evaluated. Recommendations are provided to optimize surface substrate interactions and maximize the functional performance and reliability of MIM-processed steel components in demanding engineering applications. Full article

This work presents a catalysis-based electrochemical biosensor to evaluate the peroxidase-like activity of methemoglobin (Hb-PLA) after exposure to cigarette smoke (CS) at different time intervals. The system consists of a microelectrode array coupled with a PDMS chamber containing a methemoglobin solution (biorecognition element). Hydrogen peroxide (H₂O₂) acts as the substrate, while 3,3′,5,5′-tetramethylbenzidine (TMB) functions as the chromogenic substrate for the Hb-PLA through its oxidation reaction. A spectrophotometric technique is used as a reference method to assess the catalytic activity of methemoglobin. Positive control samples exhibited higher absorbance, indicating strong catalytic activity, whereas CS-exposed samples showed a marked reduction, which was confirmed by the negative control. Cyclic voltammetry revealed significant alterations in the oxidation and reduction peaks of the CS-exposed samples. Therefore, chronoamperometry was employed to quantify the charge transfer as the electrochemical response associated with Hb-PLA, yielding a sensitivity of 0.86 ± 0.06 (%Hb-PLA/mC) and a limit of detection (LOD) of 0.23 (mC). The results demonstrate that cigarette smoke impairs the Hb-PLA in a time-dependent manner, with longer exposure reducing the activity by up to 25%. The proposed biosensor provides a rapid, sensitive, and straightforward strategy for detecting functional alterations in solutions of methemoglobin induced by environmental pollutants such as cigarette smoke. Full article

Newly brewed Baijiu often contains harmful substances such as mercaptan and methanol, which are spicy and harmful to health. At present, this is mainly solved by long-term cellaring, but this is faced with some problems such as a long cycle, high cost, high fire hazards and so on. Therefore, based on the principle of liquid jet cavitation explosion catalyzing the heterogeneous association of Baijiu molecules, this paper first developed the physical aging process and equipment without radiation and additives. Then, based on the traditional computational fluid dynamics (CFD) model of high-speed jet simulation, an N-CFD model which can accurately simulate the cavitation explosion catalytic process of high-speed jet of Baijiu was established by optimizing the three sub models of conservation, turbulence and VOF. Finally, the N-CFD model was used to optimize the distance between the nozzle and the reaction chamber wall of the new aging equipment. Through the 15 min aging experiment on 100 L Baijiu, the methanol concentration of Baijiu decreased by 68.14 ± 2.25%, and the concentration of ethyl acetate, ethyl lactate and ethyl palmitate increased from 6.105 ± 0.014, 3.498 ± 0.015 mg/L and 0.621 ± 0.010 mg/L to 6.332 ± 0.016, 4.868 ± 0.012 mg/L and 0.681 ± 0.008 mg/L. The results show that the aging technology equipment can adjust the self-coupling characteristics and dynamic characteristics of various molecules in Baijiu through high-speed jet, and catalyze the alternating phase transition and association of various molecules. Finally, the goal of high-efficiency and healthy aging Baijiu without additives was achieved, which helps the rapid and healthy development of the Baijiu brewing industry. Full article

Nanothermites are widely applied as specific power sources for microscale initiators and pyrotechnics. Increasing the charge density enhances energy storage within a confined combustion chamber, but it also alters the reaction kinetics. To systemically explore this phenomenon, the combustion and pressurization characteristics of electrosprayed nanothermite-based hybrid energetic materials (THEMs) with different metallic oxides (Fe₂O₃, CuO, and Bi₂O₃) and various energetic additives (nitrocellulose (NC), octogen (HMX), ammonium perchlorate (AP), and hexanitrohexaazaisowurtzitane (CL-20)) across various loading densities were tested. The results showed that increasing the loading density decreased the porosity of the loaded nanothermites and then rapidly decreased the convective heat transfer efficiency during the combustion propagation process. When the loading density exceeded a critical value, a dramatic decrease in the peak pressure, several orders-of-magnitude decrease in the pressurization rate, and an order-of-magnitude increase in the combustion duration occurred. Due to the dual effects of the porous microstructure on heat and mass transfer, the critical density of both the electrosprayed Al/CuO/NC/CL-20 composites and their physically mixed counterparts is between 37.9 and 43.9% theoretical maximum density (TMD). Because of the different synergistic catalytic effects, the fast reactivity at the high-loading-density maintaining capacity of the applied additives was AP > HMX ≈ CL-20 > NC. Owing to their intrinsic properties of low ignition temperature and high gas yield, the Bi₂O₃-THEMs could maintain high-speed reactivity even at 59.7% TMD. These results provide valuable insights into the rational design and tailoring of the reactivity of nanothermites for specific applications. Full article

In the present investigation, carbon dioxide (CO₂), carbon monoxide (CO), hydrocarbons (HC), nitric oxides (NO_X), particulate matter (PM), and fuel consumption were measured in a compression ignition internal combustion engine on a road route cycle in Quito, Ecuador. We used premium diesel and a mixture of diesel and cerium oxide at a concentration of 250 ppm. This research aimed to investigate the impact of cerium oxide on fossil fuels in terms of CO₂, CO, HC, NOx, PM, and fuel consumption. Five repetitions were performed for each fuel, and the results obtained were statistically analyzed using control charts. The experimental results showed a 27.1% reduction in PM, a 24.9% increase in NOx, and a 24.2% increase in HC, along with a 1% decrease in fuel consumption compared to the premium diesel case. We observed that the reduction in PM was due to the catalytic action of CeO₂, which enhances carbon oxidation. On the other hand, the increase in NOx was related to the higher temperature in the combustion chamber resulting from the improved thermal efficiency of the engine. This study provides guidelines for controlling air pollutants originating from vehicle emissions in high-altitude (over 2000 masl) road operations using cerium oxide as an additive. Full article

Cost-effective procedures usually cannot achieve complete removal of priority contaminants present in water at very low concentrations (as pesticides or pharmaceuticals). Advanced oxidation processes (AOPs) represent promising technologies for removing priority contaminants from water at trace concentrations, yet practical implementation remains limited due to technical and economic constraints. This study presents an innovative flow-through photodegradation device designed to overcome current limitations while achieving efficient contaminant removal at industrial scale. The device integrates a UVC 254 nm lamp-equipped flow chamber with automated dosing pumps for hydrogen peroxide and/or solid catalyst suspensions, coupled with a 30 nm porous membrane filtration system for catalyst recirculation. This configuration optimizes light–catalyst–pollutant contact while enabling combined catalytic processes. Performance evaluation using acesulfame (ACE) and iohexol (IHX) as model contaminants demonstrated rapid and effective removal. IHX degradation with UVC and 75 μM H₂O₂ achieved complete removal with t₉₅% = 7.23 ± 1.21 min (pseudo-order 0.25, t₁/₂ = 3.27 ± 0.39 min), while ACE photolysis (with UVC only) required t₉₅% = 14.88 ± 2.02 min (pseudo-order 1.27, t₁/₂ = 2.35 ± 0.84 min). The introduction of t₉₅% as a performance metric provides practical insights for near-complete contaminant removal requirements. Real-world efficacy was confirmed using tertiary wastewater treatment plant effluents containing 14 μg/L IHX, achieving complete removal within 8 min. However, carbamazepine degradation proved slower (t₉₅% > 74 h), highlighting the need for combined catalytic approaches for recalcitrant compounds. Spiking experiments (1000 μg/L) revealed concentration-dependent kinetics and synergistic effects between co-present contaminants. Analysis identified degradation byproducts consistent with previous studies, including tri-deiodinated iohexol (474.17 Da) intermediates. This scalable system, constructed from commercially available components, demonstrates potential for cost-effective industrial implementation. The modular design allows adaptation to various contaminants through adjustable AOP combinations (UV/H₂O₂, photocatalysts, ozone), representing a practical advancement toward addressing the gap between laboratory-scale photocatalytic research and full-scale water treatment applications. Full article

The growing need for developing safer and more effective methods for obtaining enantiomers of chiral compounds, particularly those with pharmacological activity, highlights the potential of biocatalysis as an appropriate pharmaceutical research direction. However, low catalytic activity and stability of free enzymes are often among the substantial limitations to the wide application of biocatalysis. Therefore, to overcome these obstacles, new technological procedures are being designed. In this study, we present optimized protocols for the immobilization of Candida antarctica lipase B (CALB) on an octyl- agarose support, ensuring high enantioselectivity in an organic reaction medium. The immobilization procedures (with drying step), including buffers with different pH values and concentrations, as well as the study of the influence of temperature and immobilization time, were presented. It was found that the optimal conditions were provided by citrate buffer with a pH of 4 and a concentration of 300 mM. The immobilized CALB on the octyl-agarose support exhibited high catalytic activity in the kinetic resolution of (R,S)-1-phenylethanol via enantioselective transesterification with isopropenyl acetate in 1,2-dichloropropane (DCP), as a model reaction for lipase activity monitoring on an analytical scale. HPLC analysis demonstrated that the (R)-1-phenylethyl acetate was obtained in an enantiomeric excess of ee_p > 99% at a conversion of approximately 40%, and the enantiomeric ratio was E > 200. Thermal and storage stability studies performed on the immobilized CALB octyl-agarose support confirmed its excellent stability. After 7 days of thermal stability testing at 65 °C in a climatic chamber, the (R)-1-phenylethyl acetate was characterized by enantiomeric excess of ee_p > 99% at a conversion of around 40% (similar values of catalytic parameters to those achieved using a non-stored lipase). The documented high catalytic activity and stability of the developed CALB-octyl-agarose support allow us to consider it as a useful tool for enantioselective transesterification in organic medium. Full article

Hydroxychloroquine (HCQ), a cornerstone therapeutic agent for autoimmune diseases, requires precise serum concentration monitoring due to its narrow therapeutic window. Current HCQ monitoring methods such as HPLC and LC-MS/MS are sensitive but costly and complex. While electrochemical sensors offer rapid, cost-effective detection, their large chambers and high sample consumption hinder point-of-care use. To address these challenges, we developed a microfluidic electrochemical sensing platform based on a screen-printed carbon electrode (SPCE) modified with a hierarchical nanocomposite of gold nanoparticles (AuNPs), copper-based metal–organic frameworks (Cu-MOFs), and multi-walled carbon nanotubes (MWCNTs). The Cu-MOF provided high porosity and analyte enrichment, MWCNTs established a 3D conductive network to enhance electron transfer, and AuNPs further optimized catalytic activity through localized plasmonic effects. Structural characterization (SEM, XRD, FT-IR) confirmed the successful integration of these components via π-π stacking and metal–carboxylate coordination. Electrochemical analyses (CV, EIS, DPV) revealed exceptional performance, with a wide linear range (0.05–50 μM), a low detection limit (19 nM, S/N = 3), and a rapid response time (<5 min). The sensor exhibited outstanding selectivity against common interferents, high reproducibility (RSD = 3.15%), and long-term stability (98% signal retention after 15 days). By integrating the nanocomposite-modified SPCE into a microfluidic chip, we achieved accurate HCQ detection in 50 μL of serum, with recovery rates of 95.0–103.0%, meeting FDA validation criteria. This portable platform combines the synergistic advantages of nanomaterials with microfluidic miniaturization, offering a robust and practical tool for real-time therapeutic drug monitoring in clinical settings. Full article

This study investigates the X-ray emissions from Hydrogen Rydberg Matter (HRM) using a state of-the-art Timepix3 detector with a Cadmium Telluride (CdTe) sensor, which offers imaging operation. The experimental setup featured an ultra-high vacuum (UHV) chamber containing potassium-doped iron oxide catalytic source, exposed to hydrogen or deuterium gas flowing through the source. A 1064 nm pulsed YAG laser was used to stimulate the HRM. The Timepix detector was calibrated with Cs-137 662 keV and 21 keV source. Results show a prominent emission peak in the 25–50 keV range, with significant contributions at 406 keV identified through aluminum foil attenuation experiments. These findings advance our understanding of radiation phenomena in hydrogen-loaded systems and suggest new avenues for exploring the unique emissions from HRM, potentially impacting material science and catalysis. Full article

This study explores the computational analysis of catalytic combustion in cylindrical reactors using the Finite Volume Method (FVM) within Ansys Fluent. Through the incorporation of a combustion channel to facilitate diesel combustion, Ansys Fluent is utilized to predict the fluid dynamics during catalytic combustion. An extensive reaction mechanism file containing all related reactions is added into Ansys Fluent to model the catalytic combustion of methane. In this study, the catalyzed combustion of a methane, hydrogen, and air mixture is simulated on a heated platinum wall within a cylindrical channel using a 2D axisymmetric solver. Two mechanism files are employed: one defining gaseous species and the other including surface species definitions and surface reactions. Volumetric reactions are excluded from this analysis. The cylindrical channel comprises three sections: inlet, catalytic, and outlet, with the catalyzed reactions occurring on the wall surface of the catalytic section. The simulation results exhibit a gradual decrease in the mass fraction of reactants as catalytic combustion proceeds within the chamber, accompanied by a simultaneous increase in product formation. In particular, the presence of a catalytic channel within the combustion chamber catalyzes the combustion reaction, resulting in a higher chamber temperature. This study also presents predicted mass fraction profiles for both reactants and combustion products, highlighting the efficiency of Computational Fluid Dynamics (CFD) simulations in predicting chemical processes, particularly catalytic combustion. This research contributes to the understanding of complex phenomena such as catalytic combustion and underscores the potential of CFD simulations in explaining complicated chemical processes. Full article

Although various studies on nitrous oxide as a prospective green propellant have been recently explored, a polyethylene nitrous oxide catalytic decomposition hybrid thruster was barely demonstrated due to an inordinately high catalyst preheating time of a heater, which led to the destruction of components. Therefore, hydrogen peroxide was used as a preheatant, a substance to preheat, with a dual-catalyst bed. The thruster with polyethylene (PE) as a fuel, N₂O as an oxidizer, H₂O₂ as the preheatant, Ru/Al₂O₃ as a catalyst for the oxidizer, and Pt/Al₂O₃ as a catalyst for the preheatant was arranged. A preheatant supply time of 10 s with a maximum catalyst bed temperature of more than 500 °C and without combustion and an oxidizer supply time of 20 s with a burning time of approximately 15 s were decided. Because the catalyst bed upstream part for decomposing the preheatant was far from the post-combustion chamber, the post-combustion chamber pressure increased and the preheatant mass flow rate decreased after a hard start during the preheatant supply time. Moreover, because the catalyst bed upstream part primarily contributed to preheating, the maximum catalyst bed temperature was less than the decomposition temperature of the preheatant during the preheatant supply time. Additionally, because the catalyst bed downstream part for decomposing the oxidizer was far from the post-combustion chamber, the post-combustion chamber pressure decreased and then increased during a transient state in the oxidizer supply time. Full article

In the H₂O₂/Kerosene bipropellant thruster, a liquid fuel jet is transversely injected into a crossflow of hot oxygen and water vapor, catalytically decomposed from a liquid oxidizer. Due to the high temperature and oxygen-rich environment, kerosene is auto-ignited without the need for an additional ignition source. Hence, fuel trajectory and breakup processes play a significant role in determining the performance of the rocket engine. However, little effort has been made to analyze these characteristics during actual rocket engine operation, mainly due to its harsh operating conditions of high temperature and pressure. In this study, an optically accessible combustion chamber was prepared to visualize the trajectory and breakup processes of the liquid jet during rocket engine operation. Physical and chemical processes inside the chamber were recorded using a high-speed camera utilizing a shadowgraph technique along with chemiluminescence suppression. Hot-fire tests were performed using 90 wt.% hydrogen peroxide and Jet A-1 in various jet-to-crossflow momentum flux ratios. Test cases with water injection replacing fuel were conducted with varying momentum flux ratios to identify the effect of the combustion process on the liquid jet. The study revealed that the existing correlations for the liquid jet trajectory commonly used for designing the H₂O₂/Kerosene bipropellant thruster in the past induced significant errors and suggested that the radiation heat transfer from the combustion flame downstream could affect the breakup processes upstream. A new correlation was suggested that accurately predicts the liquid fuel jet trajectory of the H₂O₂/Kerosene bipropellant thruster. Full article

This paper presents a mission concept for a Low Earth Orbit (LEO) satellite equipped with a payload for space experiments, designed to be recovered on Earth post-mission. The focus of this study is on developing a mission concept with fast de-orbit and accurate landing capability for a small satellite payload. Two re-entry configurations are analyzed: one employing a deployable aero-brake heat shield for aerodynamic descent and another integrating a propulsion system. Aerodynamic analysis of the capsule, including drag coefficient and stability at relevant altitudes, was conducted using the Direct Simulation Monte Carlo (DSMC) method. A trade-off analysis, accounting for uncertainties such as C_D, atmospheric density, and ignition timing, revealed significant differences in mission profiles. A propulsion system providing a ΔV of approximately 100 m/s reduces descent time from 54 days (aerodynamic-only re-entry) to under 1 h, without altering trajectory. Drag-related uncertainties contribute to a landing dispersion of ~100 km, while a ±1% error in total impulse increases dispersion to 400 km. A monopropellant rocket engine was preliminarily designed, meeting constraints such as catalytic chamber pressure and performance targets. The resulting thruster, weighing under 4 kg and contained within a 250 mm-high, 350 mm-diameter cylinder, supports three potential component layouts. Full article

This paper presents the results of a hot-fire test campaign aimed at characterizing a newly developed ignition system for nitromethane-based green monopropellants. Nitromethane-based propellants are a cost-effective replacement for hydrazine and energetic ionic liquid hydrazine alternatives such as LMP-103S and ASCENT. The developed system uses a glow plug as the ignition source. Additionally, gaseous oxygen is injected simultaneously into the combustion chamber at the beginning of a firing. After closing the oxygen valve, a pure monopropellant operation follows. Three test series were carried out using NMP-001, a previously characterized nitromethane-based monopropellant. During the first test series, the required ROF for ignition was identified to be above 0.3. In the second test series, the low-pressure combustion limit was shown to be 13.9 bar, which is significantly lower than the 30 bar limit of heritage nitromethane-based monopropellants. In the third test series, the oxygen injection timing was optimized to minimize the required amount of oxygen for successful ignition to 1.5 g per ignition in this test setup. This approach to ignition is more cost effective than the catalytic initiation used for other monopropellants because neither costly precious-metal catalytic materials nor lengthy preheating procedures are required. Full article