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Search Results (931)

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Keywords = carbon-water coupling

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22 pages, 6347 KB  
Article
Identifying Spatial Heterogeneity in LCZ Impacts on SUHII and Corresponding Planning Strategies Using Coupled Spatial Autocorrelation and GWR Models: A Case Study of Berlin
by Changkun Xie, Mengling Yan, Afshin Afshari, Yuheng Cao, Yifeng Qin and Shengquan Che
Remote Sens. 2026, 18(12), 1989; https://doi.org/10.3390/rs18121989 (registering DOI) - 15 Jun 2026
Abstract
The urban heat island (UHI) effect has become a global environmental challenge, and quantifying the spatial heterogeneity of its driving mechanisms while developing differentiated regulation strategies remains a critical research gap. This study takes Berlin, Germany as a case study, integrating spatial autocorrelation [...] Read more.
The urban heat island (UHI) effect has become a global environmental challenge, and quantifying the spatial heterogeneity of its driving mechanisms while developing differentiated regulation strategies remains a critical research gap. This study takes Berlin, Germany as a case study, integrating spatial autocorrelation analysis with a coupled geographically weighted regression (GWR) model to systematically investigate the spatial heterogeneity of the driving mechanisms of Local Climate Zones (LCZs) on surface urban heat island intensity (SUHII), and proposes refined regulation strategies. First, the WUDAPT method was employed to generate a LCZ map, and global and local Moran’s I were used to identify SUHII spatial clustering characteristics, dividing the study area into High–High (HH), Low–Low (LL), and Not Significant (NS) clustering zones. Second, Ordinary Least Squares (OLS) and GWR coupled models were constructed to analyze the global and local relationships between LCZ composition and SUHII. The results indicate: (1) Berlin’s SUHII exhibits significant spatial clustering characteristics (Moran’s I = 0.984), with clear differentiation between the HH zone (25.8%, mean 2.67 °C) and the LL zone (26.4%, mean −0.16 °C); (2) the GWR model (R2 = 0.921, AICc = 1279.538) significantly outperforms the OLS model (R2 = 0.822, AICc = 2871.608), confirming strong spatial heterogeneity in the LCZ-SUHII relationship, with more pronounced advantages of GWR in urban–rural fringe areas; (3) LCZ 5 (low-density mid-rise buildings) and LCZ 2 (high-density mid-rise buildings) are key warming factors across the entire study area, but their warming effects are stronger in suburban areas than in central urban areas; LCZ A (dense trees) and LCZ G (water bodies) are key cooling factors across the entire area, but their cooling effects are stronger in central urban areas than in the suburbs. Based on these findings, this study establishes a differentiated strategy framework of “Zoning—Identifying Heterogeneity—Regulating”, proposing that HH zones should implement “carbon sink enhancement and source reduction”, NS zones should balance “ecological expansion with growth management”, and LL zones should adopt “strict protection and development restriction”. This framework provides a quantifiable scientific basis and practical guidance for refined urban thermal environment management. Full article
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22 pages, 5350 KB  
Article
Research on a Dynamic–Static Integration Method for Flooded Layer Identification in Cased Holes
by Changsheng Wang, Guishan Li, Xinyue Fu, Jinhai Zhang, Hui Xi, Hongqiang Guo, Juntao Liu, Haoyu Zhang and Fujun Long
Appl. Sci. 2026, 16(12), 6039; https://doi.org/10.3390/app16126039 (registering DOI) - 15 Jun 2026
Abstract
Accurate identification of flooded layers by cased-hole logging is a critical challenge for fine-scale development and enhanced oil recovery in water-flooded oil fields at medium to high water-cut stages. Conventional methods based on single-series logging or two-dimensional crossplot techniques are inadequate for the [...] Read more.
Accurate identification of flooded layers by cased-hole logging is a critical challenge for fine-scale development and enhanced oil recovery in water-flooded oil fields at medium to high water-cut stages. Conventional methods based on single-series logging or two-dimensional crossplot techniques are inadequate for the fine-scale interpretation of complex low-permeability reservoirs. This paper proposes a novel flooded layer identification method through the deep integration of dynamic and static data. The proposed approach organically couples static open-hole logging data (porosity, resistivity, etc.) with dynamic cased-hole logging data (pulsed neutron macroscopic capture cross-section Σ and carbon–oxygen ratio, C/O) within a three-dimensional (3D) crossplot framework. A multidimensional feature parameter space is constructed, and a spatial distance-ratio model is established to quantitatively calculate the flooding index Fw for continuous evaluation of flood level (non-flooded, weakly flooded, moderately flooded, and strongly flooded). Field application in Well X of a low-permeability oil field successfully identified two ambiguous apparent water layers as weakly flooded layers, previously indistinguishable using traditional 2D methods, with interpretation results highly consistent with subsequent production tests. The identification accuracy reached over 90.7%, providing a scalable technical framework for cased-hole flooded layer evaluation in medium-to-low-permeability complex reservoirs. Full article
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15 pages, 2283 KB  
Article
Removal of Azo Dyes Using a Coupled Adsorption and Electrochemical Oxidation Process—The Impact of Effluent Conditions
by Rosamonde Venn, Katrina Cullen, Nigel Brown, Stephen Boult, David A. Polya, Roy A. Wogelius and Bart E. van Dongen
Water 2026, 18(12), 1468; https://doi.org/10.3390/w18121468 (registering DOI) - 14 Jun 2026
Abstract
Azo dyes are a major cause of environmental pollution, but under lab-based conditions can be removed using a coupled adsorption and electrochemical oxidation process; the Nyex Rosalox™ (NR) process. However, wastewater effluents are more complex than tap water, indicating that there is a [...] Read more.
Azo dyes are a major cause of environmental pollution, but under lab-based conditions can be removed using a coupled adsorption and electrochemical oxidation process; the Nyex Rosalox™ (NR) process. However, wastewater effluents are more complex than tap water, indicating that there is a need to assess how altered effluent conditions affect the adsorption of azo dyes onto the adsorbent used (Nyex™ 2000) and overall removal efficiency of the NR process. Analysis indicates that higher temperatures, the addition of minor amounts of sodium chloride, or acidification increased adsorption, while the presence of dissolved organic carbon (DOC) only showed a minor impact if compared to baseline tap water conditions and appears to be dye-specific. Analyses further indicated that effluent conditions could have a major impact on the overall dye removal efficiency using the NR process, with up to 48% more being removed during acidic or saline conditions and, to a lesser extent, when DOC was present. Increased temperature or alkalinity had minimal impact, with inconsistent results across the dyes assessed. Combined, this highlights that effluent-specific conditions can have a major impact on the removal efficiency and should be considered during the planning stage of the azo dye treatment process. Full article
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34 pages, 7618 KB  
Article
Characteristics of Lower Cretaceous Calcite Veins and Their Relationship with Hydrocarbon Dissipation and Uranium Mineralization in the Qianjiadian Uranium Mining Area, Songliao Basin
by Bailin Wu, Mengdi Yang, Xiaorui Zhang, Songlin Yang, Yu Sun, Liangliang Zhang, Yaxin Ma, Yu Hou, Guoquan Sun, Siyuan Wang, Yeerzati Dawulietbieke and Quan Liu
Minerals 2026, 16(6), 631; https://doi.org/10.3390/min16060631 (registering DOI) - 12 Jun 2026
Viewed by 163
Abstract
Current research suggests that the uranium enrichment in the Qianjiadian deposit, southwestern Songliao Basin (China), is closely related to hydrocarbon dissipation and deep thermal fluids. However, previous investigations have not carried out systematic in-depth research on the abundant calcite veins hosted in diabase [...] Read more.
Current research suggests that the uranium enrichment in the Qianjiadian deposit, southwestern Songliao Basin (China), is closely related to hydrocarbon dissipation and deep thermal fluids. However, previous investigations have not carried out systematic in-depth research on the abundant calcite veins hosted in diabase within the ore district, especially regarding their types, genetic mechanisms, formation ages, and genetic links to uranium enrichment. In particular, whether their genesis is associated with the two critical ore-controlling factors (hydrocarbon dissipation and thermal fluid activities) remains poorly constrained and to be elucidated. Through analyses of major and trace element geochemistry, scanning electron microscopy, and fluid inclusion microthermometry on calcite veins within fractures of Lower Cretaceous diabase, this study confirms that the veins are products of epigenetic fluid infill with a medium-to-low temperature hydrothermal nature (115–215 °C). The direction of fluid migration was from north to south, consistent with the trend of hydrocarbon dissipation. In situ U-Pb dating yields Eocene (~42.9 Ma) and Pleistocene (1.57–2.82 Ma) ages for the calcite veins, which are highly consistent with the timing of diabase intrusion (early Eocene) and the main episodes of uranium mineralization (Eocene–Oligocene and Pleistocene). Carbon and oxygen isotope compositions and inclusion components indicate that the carbon source was mainly derived from dissipated hydrocarbons, rather than from sedimentary diagenesis or direct source rock generation. The C-O isotopic signatures reflect further carbon isotope fractionation following the interaction between dissipated hydrocarbons and groundwater, and the inclusion fluids, composed mainly of hydrocarbon gases and water, suggest that the carbon source for calcite vein formation was provided by dissipated hydrocarbons. The temporal coupling of hydrocarbon dissipation, calcite vein formation, uranium mineralization, and thermal input from diabase intrusion reflects the dynamic processes of basin evolution and tectonic reworking. The key dynamic backgrounds for this series of diagenetic and metallogenic events include Late Cretaceous tectonic inversion, Eocene–Oligocene tectonic uplift and erosion, and Pleistocene differential uplift and subsidence. The thermal effects from hydrocarbon dissipation and diabase intrusion were the primary factors driving the anomalous uranium enrichment that formed this super-large deposit. The formation of the calcite veins, along with their characteristics indicative of medium-to-low temperature hydrothermal activity and hydrocarbon dissipation, provides a critical window for understanding these processes and offers robust scientific evidence for this genetic model. This study, for the first time, systematically reveals that the calcite veins within the diabase of the Qianjiadian uranium mining area are of medium-to-low temperature hydrocarbon-bearing hydrothermal origin, and constrains their formation ages to the Eocene (~42.9 Ma) and Pleistocene (1.57–2.82 Ma), which are highly coupled with diabase intrusion and two episodes of uranium mineralization events. C-O isotopic and fluid inclusion evidence indicates that the formation of calcite veins directly records the process of hydrocarbon dissipation–groundwater mixing, providing a new mineralogical and geochronological evidence chain for thermal–hydrocarbon–uranium-coupled mineralization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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27 pages, 7360 KB  
Article
From Strong Fluoride Binding to Reversible Electrodesorption: S, N-Regulated La-MOF-Derived Carbon Electrodes for Capacitive Deionization Defluoridation
by Xue Yang, Shirong Yang, Dongbao Song, Hongtao Zhang, Junfeng Li and Pu Wang
Materials 2026, 19(12), 2556; https://doi.org/10.3390/ma19122556 (registering DOI) - 12 Jun 2026
Viewed by 156
Abstract
La-MOFs exhibit strong affinity toward anions such as F and phosphate. However, conventional La-MOFs show limited regeneration performance when used as CDI electrodes, posing a major challenge for practical applications. In this study, a high-performance sulfur and nitrogen co-doped La-BDC-140-derived carbon electrode [...] Read more.
La-MOFs exhibit strong affinity toward anions such as F and phosphate. However, conventional La-MOFs show limited regeneration performance when used as CDI electrodes, posing a major challenge for practical applications. In this study, a high-performance sulfur and nitrogen co-doped La-BDC-140-derived carbon electrode (La-CNS3) was fabricated via a coupled carbonization and doping strategy. The optimized La-CNS3 electrode possessed abundant defects, a mesoporous structure, favorable hydrophilicity, and rapid charge-transfer capability, which collectively enhanced fluoride electrosorption. At 1.4 V, La-CNS3 achieved a fluoride removal capacity of 31.86 mg·g−1 for 10 mg·L−1 F solution and up to 195 mg·g−1 at an initial F concentration of 100 mg·L−1. More importantly, partial fluoride desorption was realized solely under reverse voltage, and the electrode maintained favorable defluoridation performance over 50 adsorption–desorption cycles. In actual groundwater treatment, the effluent fluoride concentration decreased to below 1.0 mg·L−1 after 120 min. XPS analysis and DFT calculations revealed that fluoride removal was mainly governed by La-F coordination, surface hydroxyl/water ligand exchange, and interfacial charge redistribution. The La2O2S/g-C3N4 structure provided a favorable balance between fluoride adsorption strength and desorption reversibility. This work offers a promising strategy for designing efficient, selective, and electrically regenerable rare-earth-based CDI electrodes for fluoride-contaminated water treatment. Full article
(This article belongs to the Section Carbon Materials)
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24 pages, 2416 KB  
Article
Data Centre Waste Heat for Building Heating: A Comparative Energy Analysis in Italy
by Luca Socci, Lorenzo Leoncini, Andrea Zini, Serena Mazzoni and Andrea Rocchetti
Sustainability 2026, 18(12), 6061; https://doi.org/10.3390/su18126061 (registering DOI) - 12 Jun 2026
Viewed by 91
Abstract
The decarbonisation of the building sector represents a key challenge for the European energy transition, particularly in the heating segment, which is still largely dependent on fossil fuels. In this context, data centres (DCs) offer a promising opportunity as local sources of recoverable [...] Read more.
The decarbonisation of the building sector represents a key challenge for the European energy transition, particularly in the heating segment, which is still largely dependent on fossil fuels. In this context, data centres (DCs) offer a promising opportunity as local sources of recoverable waste heat. This study investigates the use of data centre waste heat for building heating through a comparative annual energy analysis applied to two building typologies in a Mediterranean climate (Italy): a residential building and a school. Three scenarios are considered: non-integrated scenario S0 (data centre with its own cooling system and buildings with gas-fired boilers), non-integrated scenario S1 (data centre with its own cooling system and buildings with air-to-water heat pumps), and integrated scenario S2 (data centre cooling system coupled with the buildings through waste heat recovery and heat pump technology). A theoretical 300 kW data centre was considered as the waste heat source. The integrated scenario significantly improves system performance. In the residential case, the seasonal COP increases from 2.15 to 4.50, reducing electricity consumption from 289.5 MWh to 128.9 MWh. In the school case, the COP increases from 2.51 to 8.00, with electricity consumption decreasing from 161.3 MWh to 49.1 MWh. These improvements lead to reductions in non-renewable primary energy demand of up to 63% and 79% for the residential and school buildings, respectively, compared to the baseline scenario. The results demonstrate that data centres can act as decentralised thermal sources, supporting the transition towards low-carbon and Nearly Zero-Energy Buildings. Full article
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25 pages, 1643 KB  
Review
Carbon/Inorganic Hybrid Multifunctional Composites: Interface Engineering, Coupled Functions and Application-Ready Design
by Stefano Bellucci
Inorganics 2026, 14(6), 160; https://doi.org/10.3390/inorganics14060160 - 12 Jun 2026
Viewed by 228
Abstract
Carbon/inorganic hybrid composites have evolved from filler-reinforced materials into design platforms for coupled electromagnetic, thermal, sensing, environmental, protective and energy-related functions. Their distinctive value lies in the possibility of combining a conductive, polarizable or porous carbon phase with an inorganic phase that contributes [...] Read more.
Carbon/inorganic hybrid composites have evolved from filler-reinforced materials into design platforms for coupled electromagnetic, thermal, sensing, environmental, protective and energy-related functions. Their distinctive value lies in the possibility of combining a conductive, polarizable or porous carbon phase with an inorganic phase that contributes dielectric, magnetic, catalytic, ionic, thermally conductive or barrier behavior. This review examines carbon/inorganic hybrid multifunctional composites from the viewpoint of structure–property relationships, with emphasis on interfacial design, percolation, anisotropy, hierarchical architecture, processing and metrology. Selected graphitic composite studies are discussed as case studies for broadband dielectric spectroscopy, microwave shielding, high-frequency contact metrology, thermal diffusivity analysis and impedance-monitored graphene filters; these case studies are integrated with the broader international literature on CNT and graphene polymer composites, MXene films and foams, graphene/metal oxide photocatalysts, boron nitride/carbon thermal networks, biochar–graphene adsorbents, smart coatings, sensors, supercapacitors and water remediation systems. The central argument is that credible multifunctionality requires more than measuring several properties on the same material. It requires simultaneous or service-relevant co-optimization under constraints of thickness, density, processability, aging, humidity, corrosive media, regeneration, toxicity, economic feasibility and scalable fabrication. The review concludes with design rules and reporting recommendations intended to help move the field from impressive property demonstrations toward application-ready hybrid material systems. Full article
(This article belongs to the Special Issue Multifunctional Composites and Hybrid Materials)
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27 pages, 16622 KB  
Article
The Water-Energy Nexus in Deep Excavation Dewatering: A MODFLOW–Improved Genetic Algorithm Coupled Model for Energy Efficiency Optimization and Engineering Safety Control
by Weiwei Li, Wenbing Zhang, Xin Xiong, Lipei Zhou, Yanrong Zhao, Haonan Wang and Xiaosong Dong
Water 2026, 18(12), 1445; https://doi.org/10.3390/w18121445 - 11 Jun 2026
Viewed by 209
Abstract
Deep excavation dewatering is an energy-intensive groundwater control process in underground engineering, especially under strong recharge and heterogeneous hydrogeological conditions. Conventional dewatering designs often rely on conservative pumping schemes to ensure the required drawdown, which may generate redundant groundwater extraction, unnecessary electricity consumption, [...] Read more.
Deep excavation dewatering is an energy-intensive groundwater control process in underground engineering, especially under strong recharge and heterogeneous hydrogeological conditions. Conventional dewatering designs often rely on conservative pumping schemes to ensure the required drawdown, which may generate redundant groundwater extraction, unnecessary electricity consumption, additional carbon emissions, and excessive drawdown-induced settlement. To address this problem, this study develops a coupled improved genetic algorithm and MODFLOW optimization model, termed IGA-M, for dewatering well-group operation under engineering safety constraints. The purpose of the proposed model is not to reduce pumping arbitrarily, but to identify and eliminate redundant pumping while satisfying prescribed requirements for target water levels, settlement control, and hydraulic-gradient safety. Through the FloPy interface, the Improved Genetic Algorithm is dynamically linked with MODFLOW to establish a closed-loop simulation-optimization framework. In each optimization iteration, candidate well operation schemes are automatically transferred to MODFLOW, and the simulated hydraulic heads and settlement responses are returned to evaluate the objective function and safety constraints. In this framework, groundwater extraction, electricity consumption, carbon emissions, and land subsidence are treated as physically linked performance indicators of the optimized dewatering scheme. Validation using an idealized case shows that, under the same safety requirements, the IGA-M model reduces redundant hydraulic loading compared with the traditional uniformly distributed pumping method. By removing redundant pumping beyond the safety requirement, the optimized scheme reduced groundwater extraction by 62.7%, which was accompanied by a 44.9% decrease in both carbon emissions and comprehensive costs, as well as a 57.7% reduction in settlement at observation points. In a practical high-permeability deep excavation adjacent to the Yellow River, the model achieved well-group flow regulation under strong recharge conditions. Compared with the traditional scheme, it eliminated approximately 661,000 m3 of redundant groundwater extraction, corresponding to a 17.7% decrease, and consequently saved 26,800 kWh of electricity and reduced CO2 emissions by nearly 16,000 kg during the dewatering period. These results demonstrate that the proposed IGA-M framework can transform MODFLOW from a post-design verification tool into an active optimization engine for dewatering design. It provides a physically based decision-support method for reducing redundant pumping and improving energy efficiency while maintaining engineering safety. Full article
(This article belongs to the Section Water-Energy Nexus)
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34 pages, 4454 KB  
Article
Thermochemical Activation of Lightweight Slag–Perlite Alkali-Activated Slag (AAS): Overcoming Aggregate Brittleness and Sulfate Degradation
by Hasan Eker and Demet Demir Şahin
Sustainability 2026, 18(12), 5981; https://doi.org/10.3390/su18125981 - 11 Jun 2026
Viewed by 142
Abstract
The successful realization of a circular economy in the cement industry, coupled with a substantial reduction in carbon emissions, relies on the development of sustainable alternative binder systems. This study investigated the physicomechanical performance and sulfate resistance of composites produced by alkali activation [...] Read more.
The successful realization of a circular economy in the cement industry, coupled with a substantial reduction in carbon emissions, relies on the development of sustainable alternative binder systems. This study investigated the physicomechanical performance and sulfate resistance of composites produced by alkali activation of natural perlite and blast furnace slag. The aim of the research was to improve mechanical properties under low- and medium-alkalinity conditions (5–10 M NaOH). The samples were cured at an ambient temperature of 20 °C and then treated with heat at 60 °C. These samples were then mechanically processed and subjected to five soak–dry cycles in 5% and 10% Na2SO4 solutions. The results showed that heat treatment resulted in the formation of a dense C-A-S-H gel, increasing compressive strength approximately eightfold, from 11.64 MPa to 92 MPa. However, perlite’s porous and brittle structure limits its flexural strength to 0.27 MPa; this value is insufficient for structural applications. Under severe sulfate attack (10% Na2SO4), samples cured at ambient temperature showed a 12% mass increase in the first cycle due to solution infiltration into capillary voids. As a consequence of extensive ettringite and gypsum formation, the specimens experienced severe deterioration, resulting in a complete loss of mechanical integrity and a residual compressive strength of 0 MPa. In contrast, heat-treated samples showed limited ion diffusion due to a denser matrix and an improved aggregate interface transition zone, resulting in a 2.6% mass increase and a residual compressive strength of 5.17 MPa. Consequently, the obtained findings indicate that thermally treated alkali-activated slag–perlite composites exhibit high resistance against sodium sulfate attack and may have potential for use in specific industrial environments with high sulfate concentrations. However, the performance of these materials under more complex aggressive conditions, such as mining environments involving magnesium sulfate exposure and acidic drainage waters, should be further validated through future studies. Full article
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23 pages, 1475 KB  
Perspective
Toward Rational Design of PFAS-Extracting Deep Eutectic Solvents: Bifunctional Architectures, Leaching Constraints, and Scalability Targets
by Santiago Aparicio
Molecules 2026, 31(12), 2019; https://doi.org/10.3390/molecules31122019 - 9 Jun 2026
Viewed by 207
Abstract
Per- and polyfluoroalkyl substances (PFASs) constitute a chemically diverse family of persistent contaminants, the regulation of which is tightening rapidly in Europe and the United States. Granular activated carbon, selective ion exchange, and pressure-driven membranes remove many long-chain PFASs, but their performance is [...] Read more.
Per- and polyfluoroalkyl substances (PFASs) constitute a chemically diverse family of persistent contaminants, the regulation of which is tightening rapidly in Europe and the United States. Granular activated carbon, selective ion exchange, and pressure-driven membranes remove many long-chain PFASs, but their performance is less robust for short-chain and ultrashort species, and all generate concentrated secondary waste streams. Hydrophobic deep eutectic solvents (DESs), including natural deep eutectic solvents (NADESs), have emerged as tunable liquid extractants able to concentrate PFASs into small solvent volumes that can be regenerated or coupled to destruction. This perspective differs from existing DES-PFAS reviews by converting qualitative solvent-selection arguments into a decision framework with explicit acceptance gates: broad PFAS affinity, a component-resolved non-migration specification for treated water, viscosity and mass-transfer limits, regenerability targets, and techno-economic/life-cycle benchmarking against incumbent processes. We refine the bifunctional DES design hypothesis by separating validated regimes from unresolved cases, identifying the reliability limits of COSMO-RS, molecular dynamics, and machine-learning screening, and defining tiered reporting requirements for early-stage studies. The central message is that PFAS-extracting DES should no longer be evaluated only by single-compound removal percentages; they must be judged as integrated, closed-loop treatment materials with solvent losses, regeneration stability, destruction compatibility, cost, and environmental impacts that are quantified from the outset. Full article
(This article belongs to the Section Molecular Liquids)
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33 pages, 15794 KB  
Review
Advances in Electrofusion Welding Technology for Polymeric Pipelines: From Process Optimization to Mechanism-Driven Control
by Bingyuan Hong, Zhongjian Sun, Zenan Wu, Yu Meng, Zhiwei Chen, Xianlei Chen, Weiqiang Wang and Daiwei Liu
Polymers 2026, 18(11), 1402; https://doi.org/10.3390/polym18111402 - 5 Jun 2026
Viewed by 390
Abstract
With the rapid development of clean and low-carbon energy systems, non-metallic pipelines have become increasingly important in urban gas distribution, water supply, and emerging energy-transport applications, including hydrogen service. As a critical joining technology that governs system integrity and long-term operational safety, electrofusion [...] Read more.
With the rapid development of clean and low-carbon energy systems, non-metallic pipelines have become increasingly important in urban gas distribution, water supply, and emerging energy-transport applications, including hydrogen service. As a critical joining technology that governs system integrity and long-term operational safety, electrofusion welding requires a comprehensive and mechanism-oriented understanding beyond empirical process control. In this study, a review is conducted on research published over the past decade in the field of electrofusion welding of non-metallic pipelines, with emphasis on fundamental technical issues including the formation and evolution of temperature fields, characteristics of the molten fusion zone and defect development, and thermo-mechanical coupling with residual stress generation. Based on a synthesis of the literature, the review clarifies the global research landscape, core research communities, and underlying knowledge structure. The results indicate a clear transition of the field from empirically driven parameter optimization toward a mechanism-based and process-controllable paradigm centered on temperature field evolution, fusion zone development, and thermo-mechanical behavior. Current research hotspots converge on HDPE material adaptability, welding process regulation, and the long-term reliability of welded joints. Building on these insights, future research directions are discussed, including mechanism-driven process design, intelligent defect identification based on multi-source data, and full-life reliability assessment under service conditions. This review provides a theoretical framework to support process optimization and engineering application of electrofusion welding in non-metallic pipeline systems. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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32 pages, 4036 KB  
Review
Landscape Structural Patterns and Soil–Water Loss in the Karst Critical Zone in Southwest China: Coupling Mechanisms, Regional Specificity, and Research Challenges
by Chenyi Zhu, Xiaoxi Lyu, Dongnan Wang, Jinglin Mo, Yunyu Huang and Mingyue Ma
Land 2026, 15(6), 986; https://doi.org/10.3390/land15060986 - 4 Jun 2026
Viewed by 301
Abstract
Karst critical zones in Southwest China are highly vulnerable to soil–water loss because thin soils, exposed carbonate bedrock, well-developed epikarst, and strong surface–subsurface connectivity promote both surface erosion and subsurface leakage. Although soil erosion, subsurface leakage, karst rocky desertification, and ecological restoration have [...] Read more.
Karst critical zones in Southwest China are highly vulnerable to soil–water loss because thin soils, exposed carbonate bedrock, well-developed epikarst, and strong surface–subsurface connectivity promote both surface erosion and subsurface leakage. Although soil erosion, subsurface leakage, karst rocky desertification, and ecological restoration have been widely studied, the coupling between landscape structural patterns and soil–water loss remains insufficiently synthesized. This semi-systematic critical review synthesizes evidence from karst hydrology, soil erosion, karst rocky desertification, landscape structure, and critical zone studies, with a primary focus on Southwest China. The reviewed evidence indicates that geomorphic setting, land use vegetation structure, bare-rock exposure, and epikarst development jointly regulate runoff generation, infiltration, sediment detachment, subsurface leakage, and sediment connectivity. Peak–cluster depressions commonly favor internal sediment storage and vertical leakage, whereas valley and canyon systems tend to enhance surface runoff connectivity and channelized sediment export. However, pathway dominance varies with rainfall intensity, soil moisture, soil thickness, land use, karst rocky desertification degree, and fracture–conduit connectivity. Long-term soil–water loss may further reshape landscape structure through soil thinning, vegetation degradation, bedrock exposure, and karst rocky desertification feedbacks. Current research is limited by insufficient quantification of subsurface soil loss, weak integration between landscape metrics and hydrological models, and scarce long-term monitoring data. Future studies should integrate field monitoring, tracers, remote sensing, landscape metrics, and coupled surface–subsurface models to support geomorphic-setting-specific karst rocky desertification control. Full article
(This article belongs to the Section Land, Soil and Water)
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20 pages, 41743 KB  
Article
Hydrochemical Tracing for Solute Sources and Enrichment Mechanisms in Inland Lake Waters of the Qiangtang Plateau, Northern Tibet, China
by Yuanqing Liu, Dongguang Wen, Le Zhou, Lin Lv, Xuejun Ma, Jianhua Feng, Yanwei Guo, Jian Cao and Tao Lv
Minerals 2026, 16(6), 599; https://doi.org/10.3390/min16060599 - 3 Jun 2026
Viewed by 157
Abstract
To elucidate the solute sources, migration and enrichment mechanisms of water bodies in the endorheic lake region of the Qiangtang Plateau on the Tibetan Plateau and clarify the hydrogeochemical cycling patterns in alpine arid environments, this study focuses on two core scientific objectives: [...] Read more.
To elucidate the solute sources, migration and enrichment mechanisms of water bodies in the endorheic lake region of the Qiangtang Plateau on the Tibetan Plateau and clarify the hydrogeochemical cycling patterns in alpine arid environments, this study focuses on two core scientific objectives: quantitative identification of the multi-source contributions of aquatic solutes, and revelation of the key processes governing the enrichment of strategic elements including lithium (Li) and boron (B). To achieve these goals, we conducted systematic hydrogeological field investigations and collected 28 multi-type water samples, covering springs, rivers, thermal springs, freshwater lakes, salt lake brines, atmospheric precipitation, and glacial meltwater. The physicochemical properties, major ions, and trace elements of all samples were comprehensively analyzed. On this basis, the hydrogeochemical characteristics, evolutionary processes, and solute origins of regional waters were systematically explored. Combined with PHREEQC numerical simulation, principal component analysis (PCA), and Pearson correlation analysis, the dominant controlling factors of water geochemistry were quantified, and a conceptual hydrogeochemical evolution model was established. The results reveal a clear hydrogeochemical evolutionary gradient across the study area: water bodies evolve from low-salinity HCO3-Ca recharge end-members and transitional HCO3·SO4-Ca(Mg) type water to highly mineralized Cl-Na (SO4·Cl-Na) salt lake brines, accompanied by synchronous enrichment of Li, B, arsenic (As), and other characteristic elements. Solute accumulation in regional waters is governed by the ternary coupling effects of evaporative concentration, rock weathering and leaching, and deep geothermal fluid input, while cation exchange and mineral dissolution–precipitation reactions further modulate ionic composition and ratios. Elements including As, Li, B, and chloride (Cl) exhibit conservative migration behaviors in non-hydrothermal waters, whereas thermal springs possess unique geochemical signatures driven by deep fluid recharge. PCA results indicate that evaporative concentration serves as the primary controlling factor with a contribution rate of 55.39%; rock weathering provides the basic solute load (17.09%); and the coupled processes of deep fluid mixing and carbonate precipitation regulate elemental fractionation (14.21%). These findings systematically clarify the hydrogeochemical evolution laws and multi-source coupling mechanisms of inland lake waters in the Qiangtang Plateau. Furthermore, this study establishes a conceptual framework of “multi-source recharge–water–rock interaction–evaporative concentration”, advances the understanding of alpine hydrological cycling under climate change, and provides a solid scientific foundation for hydrological cycle research and green exploration of strategic mineral resources in endorheic salt lake regions. Full article
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28 pages, 8769 KB  
Article
Integrated Cryogenic Separation and Energy Valorization of Flue Gas: Thermodynamic Analysis of a Process Line for CO2 and N2 Liquefaction with CO2-Based Power Recovery
by Orlando Corigliano and Angelo Algieri
Thermo 2026, 6(2), 42; https://doi.org/10.3390/thermo6020042 - 2 Jun 2026
Viewed by 219
Abstract
This work presents the thermodynamic design and performance assessment of an integrated process line for the separation, liquefaction, storage, and valorization of carbon dioxide (CO2) and nitrogen (N2) from flue gas streams. The proposed system aims to combine carbon [...] Read more.
This work presents the thermodynamic design and performance assessment of an integrated process line for the separation, liquefaction, storage, and valorization of carbon dioxide (CO2) and nitrogen (N2) from flue gas streams. The proposed system aims to combine carbon capture with cryogenic energy storage by exploiting the thermophysical properties of the main flue gas constituents. A representative flue gas derived from complete methane combustion (9.5% CO2, 71.5% N2, and 19% H2O by volume) is considered as the feed stream. The process is developed and simulated in DWSIM v9.0.5, adopting a steady-state mass and energy balance framework coupled with rigorous thermodynamic modeling of phase equilibria and unit operations. The plant configuration is based on sequential cooling, compression, and expansion stages, enabling the selective condensation of H2O, CO2, and N2 at different temperature levels. The system integrates heat exchangers, compressors, pumps, turboexpanders, phase separators, and cryogenic storage tanks, while a portion of the liquefied CO2 is reused as an energy carrier through vaporization and expansion in a dedicated turbine. The results demonstrate that the process achieves a CO2 capture ratio of 81.7%, with a specific electric consumption (SEC) of 10.44 kWh/kgCO2 and 1.71 kWh/kgN2. The overall net electric demand is 1.29 kWh/kg of treated flue gas, while the round-trip efficiency (ηRT,CO2) is 18.6%. A significant amount of energy can further be recovered from the “waste” exhaust water stream (12.94 kgL-H2O/kgflue-gas, at 91 °C and 1.2 bar) up to 800 Wh/kgflue-gas, improving the performance of the entire process (SECCO2: 3.86 kWh/kgCO2, ηRT,CO2: 69.8%). The study confirms the thermodynamic feasibility of the proposed configuration and identifies nitrogen liquefaction as the dominant energy-intensive step. Future optimization efforts should therefore focus on reducing exergy destruction in the deep cryogenic section through improved heat integration, enhanced cold-energy recovery, optimized compression–expansion staging, and reduced pressure losses. Full article
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56 pages, 3538 KB  
Review
A Review of Non-Thermal Plasma Technology and Plasma–Artificial Intelligence Integration in Agriculture
by Liangtong Yao and Jianmin Gao
Agronomy 2026, 16(11), 1067; https://doi.org/10.3390/agronomy16111067 - 28 May 2026
Viewed by 316
Abstract
As agriculture moves towards green transformation and low-carbon production, the high energy consumption, environmental burden, and residue risks associated with conventional chemical fertilisers, pesticides, and disinfectants have become increasingly prominent. Non-thermal plasma (NTP) can generate reactive oxygen and nitrogen species (RONS) under near-ambient [...] Read more.
As agriculture moves towards green transformation and low-carbon production, the high energy consumption, environmental burden, and residue risks associated with conventional chemical fertilisers, pesticides, and disinfectants have become increasingly prominent. Non-thermal plasma (NTP) can generate reactive oxygen and nitrogen species (RONS) under near-ambient temperature and pressure conditions, while offering low chemical residue, high reactivity, and modular equipment design. It has therefore attracted growing attention in agricultural engineering and green agricultural input preparation. This review focuses primarily on studies published within the past five years, together with the selected foundational literature retrieved from Web of Science, Scopus, PubMed, MDPI, and ScienceDirect. It systematically examines the fundamental mechanisms, application modes, and representative agricultural scenarios of NTP, with particular emphasis on agricultural nitrogen fixation and fertilisation, seed treatment and seedling raising, crop growth regulation and protection, soil improvement and remediation, and postharvest preservation and safety treatment of agricultural products. Key technological advances are then summarised, including optimisation of discharge systems and reactor configurations, plasma–catalysis synergy, preparation of plasma-activated water (PAW) and plasma-activated mist (PAM), and the development and integration of specialised agricultural equipment. In addition, the current state-of-the-art (SOA) of artificial intelligence (AI) applications in plasma-process modelling, process-parameter optimisation, agricultural performance evaluation, and intelligent control is discussed. Existing evidence indicates that NTP is particularly relevant to controlled-environment agriculture, including greenhouse cultivation, hydroponics, and aeroponics, where discharge processes, water or nutrient solutions, and crop root-zone management can be coupled for in situ nitrogen supply, activated-medium preparation, and crop protection. However, reported effects remain strongly dependent on discharge type, energy input, reactive-species composition, treatment dose, crop species, cultivation system, and application route. Therefore, NTP-based agricultural technologies should be evaluated using consistent indicators, including energy consumption, product selectivity, reactive-species stability, treatment throughput, crop response, ecological safety, and system-level integration with AI and IoT. Future research should prioritise high-efficiency reactors, standardised evaluation frameworks, cross-scale mechanistic understanding, reliable datasets, and closed-loop intelligent control, thereby supporting the transition from laboratory studies to reproducible and application-oriented agricultural systems. Full article
(This article belongs to the Special Issue High-Voltage Plasma Applications in Agriculture)
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