Search Results (2,873)

This study explores the direct synthesis of carbon nanostructures on AISI 1018 low-carbon steel via spray pyrolysis, using α-pinene—a turpentine-derived terpene—as a sustainable carbon source. Two synthesis routes were evaluated: a catalyst-aided approach using ferrocene and a catalyst-free approach. Both methods yielded homogeneous coatings; however, the addition of ferrocene produced carbon nanotube (CNT) films (~70 μm), while the catalyst-free method resulted in carbon nanofiber (CNF) films (~50 μm). Tribological testing revealed that CNF coatings maintained a consistently low friction coefficient of ~0.12. In contrast, CNT coatings exhibited higher friction, increasing from 0.15 to 0.35 under loads of 2–5 N. SEM and Raman spectroscopy of the wear tracks suggest that CNFs retain their crystalline structure during friction, whereas CNTs become increasingly defective, leading to higher friction levels. Full article

A charge-balanced aqueous hybrid supercapacitor was constructed by coupling Co-modified MnWO₄ nanorods with H₂O₂-treated carbon nanotubes (OH-CNTs) in 1 M KOH. The samples were designated by the nominal Co/(Mn + Co) precursor molar fraction; ICP-OES measured bulk Co fractions of 0.09 ± 0.01, 0.47 ± 0.03, and 0.75 ± 0.04 mol% for the nominal 0.1, 0.5, and 0.8 mol% samples, respectively. Rietveld refinement confirmed retention of the monoclinic P2/c MnWO₄ phase with only small composition-dependent lattice changes. At an active-material loading of 2.00 ± 0.05 mg cm⁻², the optimized nominal 0.5 mol% sample delivered 429.5 ± 11.0 C g⁻¹ (119.3 ± 3.1 mAh g⁻¹) at 1 A g⁻¹ and retained 280.5 ± 8.5 C g⁻¹ (77.9 ± 2.4 mAh g⁻¹) at 15 A g⁻¹. Because the positive electrode exhibits battery-type behavior, specific charge and specific capacity are used as the primary performance descriptors. Over −0.9–0 V vs. SCE, pristine CNT and OH-CNT electrodes delivered of 189.0 ± 7.2 and 246.6 ± 8.1 C g⁻¹, corresponding to electrode-level apparent specific capacitances of 215 ± 8 and 280 ± 9 F g⁻¹ at 1 A g⁻¹ after correction for the measured IR drop. These values apply to the stated 90:5:5 CNT (or OH-CNT)/acetylene-black/PVDF formulation and CNT-active-mass normalization and should not be interpreted as intrinsic capacitances of isolated commercial MWCNT powders. Charge matching based on the measured gave m⁺/m⁻ = 0.574; integration at the actual device loadings yielded q⁺ = 0.861 ± 0.015 C and q⁻ = 0.854 ± 0.015 C (q⁺/q⁻ = 1.008). The device operated over 0–1.6 V and delivered 97.9 ± 3.1 F g⁻¹ at 0.51 A g⁻¹, corresponding to 34.8 Wh kg⁻¹ at 408 W kg⁻¹ when normalized to the combined active mass of both electrodes. Three independently assembled devices retained 96.0 ± 0.7% of the initial capacitance and showed a coulombic efficiency of 98.8 ± 0.1% at the 10,000th cycle at 5.13 A g⁻¹. Device metrics are normalized to the combined active mass of both electrodes and exclude current collectors, separator, electrolyte, and packaging. Full article

Thermally sprayed metallic coatings on carbon fiber-reinforced polymer (CFRP) substrates often contain pores and microstructural defects that can reduce adhesion, durability, and protective performance. In this study, a hybrid graphene nanoplatelet (GNP)-fullerene C60 reinforced epoxy coating was applied to HVOF-metallized CFRP, while a carbon nanotube (CNT)-based surface treatment was used to modify surface wettability. Micro-CT and SEM analyses indicated morphological changes consistent with partial coverage of accessible surface-connected defects and modification of the metallized layer surface. Pull-off adhesion strength increased from 320 psi to 650 psi, accompanied by a shift from adhesive to cohesive failure. The optimal nanofiller formulation improved tensile strength from approximately 25 MPa to 56 MPa (124%) and Young’s modulus by approximately 47% compared with neat epoxy. Abrasion testing showed more than 50% reduction in mass loss, and electrochemical impedance spectroscopy indicated improved barrier performance after 200 h of salt spray exposure. CNT surface modification transformed the coating from hydrophilic to superhydrophobic behavior, achieving water contact angles above 155°, delaying ice formation, and reducing ice accumulation. These results indicate that combining hybrid nanocomposite coatings with CNT functionalization can improve mechanical, protective, and surface-functional performance of HVOF-metallized CFRP systems under the laboratory conditions investigated. Full article

In this work, three biochars were synthesized from a mixture of an abundant agricultural waste (date palm fronds) and an animal biomass (chicken manure) at pyrolysis temperatures of 700 °C (B-700), 800 °C (B-800), and 900 °C (B-900), respectively. These biochars were characterized and used as electrode materials in a capacitive deionization (CDI) process to remove salts from saline water. The CDI results show that the B-700 electrode displayed the highest desalination efficiency of 10.2% with 100 ppm NaCl. Further mixing the B-700 with 10% and 20% of multi-walled carbon nanotubes (CNT) revealed an enhanced desalination performance. For instance, a biochar-20%CNT electrode achieved a salt adsorption capacity (SAC) of 11.32 mg/g at 200 ppm NaCl, which is 7.6 times higher than that of B-700 alone. The performance enhancement is attributed to carbon nanotubes acting as conductive channels between biochar particles, thereby improving electrical conductivity and electrochemical properties of the CDI electrode. Additionally, the presence of well-known hydrophilic functional groups on CNT surfaces enhances hydrophilicity, providing a highly porous surface area. The results suggest that the CDI method with biochar–CNT electrodes offers opportunities for energy-efficient, low-cost freshwater production, with significant scaling up potential for the treatment of brackish and wastewater. Full article

In this paper, the nonlinear vibration (NV) response of carbon nanotube-reinforced composite (CNTRC) marine panels (MPs) fitted with symmetric multi-vibration absorbers (MVAs) subjected to steady, velocity-dependent hydrodynamic loads is investigated. To model actual marine conditions more realistically, the lift and drag forces varying with flow velocity were taken into account using experimentally supported Matveev-based formulations for a specific ship. Within the shell, three carbon nanotube (CNT) distribution schemes are considered: one uniformly distributed (UD) CNT configuration and two functionally graded (FG) CNT patterns, namely FG-V and FG-X. The analytical framework is further constructed using classical shell theory (CST) by incorporating geometric nonlinear terms, and the Galerkin technique is employed to obtain a reduced-order model. Thereafter, the NV response of the CNTRC-MPs is predicted through the P-T method, which relies on the joint application of the piecewise constant argument and Taylor series expansion. The results indicate that symmetric MVAs can effectively suppress NV behavior and significantly decrease the maximum NV amplitude of the panel. Moreover, the effectiveness of the proposed configuration is shown to depend on both the absorber characteristics and the reinforcement pattern of CNTs. The study demonstrates that the use of symmetric absorber systems offers a practical and efficient passive vibration-control solution for advanced marine composite panels. Full article

To address the persistent challenge of membrane wetting during oil-gas separation in transformer condition monitoring, an omniphobic composite membrane was developed to facilitate the reliable online detection of dissolved gases. An F-CNTs/Teflon AF/PVDF composite membrane, featuring a loofah-like hierarchical structure and omniphobic properties, was fabricated via spraying-deposition strategy on the polyvinylidene fluoride (PVDF) substrate. The morphology, surface chemical composition, wettability and stability of the F-CNTs/Teflon AF/PVDF composite membrane were systematically characterized. Subsequently, the oil-gas separation performance of the composite membrane was evaluated using standard transformer oil containing dissolved gases as the feed solution. The results indicated that fluorinated carbon nanotubes (F-CNTs) were successfully modified onto the membrane surface, creating a re-entrant morphology composed of an intersecting nanotube network that mimics the hierarchical architecture of a loofah. The F-CNTs/Teflon AF/PVDF composite membrane exhibited exceptional omniphobicity, achieving contact angles of 168.2 ± 1.5° and 127.5 ± 1.0° towards DI water and mineral insulating oil, respectively. Additionally, the loofah-inspired composite membrane demonstrated robust thermal and ultrasonic stability. In oil-gas separation tests, the omniphobic membrane displayed a rapid response and high efficiency for dissolved gas extraction, achieving dynamic equilibrium within 64 min. Furthermore, the modification improved permeation efficiency by 25.6%. These results suggest that the developed omniphobic membrane is a promising alternative for oil-gas separation in the condition monitoring of oil-filled electrical equipment. Full article

This work presents the design evolution, fabrication, and characterisation of an additively manufactured ring-type thermal airflow sensor for in-pipe flow monitoring, developed employing exclusively Fused Deposition Modelling (FDM) additive manufacturing technology and a commercially available Carbon Nanotube (CNT)-enriched Biopolymer Polylactic Acid (PLA) composite filament. The design evolution proceeds through three progressive stages. In the first stage, a flat heater element is characterised through Constant-Current (CC) Joule heating experiments in order to derive the corresponding Temperature Coefficient of Resistance (TCR) and Thermal Resistance from the obtained experimental data. Consequently, a Finite Element Method (FEM) model implemented in COMSOL Multiphysics^® and calibrated with the extracted material parameters validates the experimental temperature–power relationship and predicts the convective cooling behaviour at various airflow velocities. In the second stage, the geometry is optimised by introducing a conductive trace with a reduced-cross-section central region; as a result, an equivalent thermal localisation is achieved at approximately 26% lower supplied power with respect to the initial heating element, enabled by the design freedom inherent in the FDM process. We should note that the specific sensing geometry can also be directly embedded into any 3D-printed structural component (e.g., a bracket or housing), enabling simultaneous local thermal heating and/or thermal monitoring together with structural functionality within a single printed part. In the third and final stage—the target device—a fully monolithic ring-type airflow sensor is directly integrated into a 3D-printed pipe segment during the printing process. Under constant-current excitation at 40 mA, the device exhibits a monotonically decreasing resistance with increasing airflow (ΔR ≈ 117 Ω over 0–4 m/s) due to convective cooling, while in a single flow-interruption cycle, approximately 79% of the flow-induced resistance change was recovered upon flow removal, with a residual offset of approximately 3% of the heated baseline. A coupled electrothermal FEM model of the device further supports the experimental response by comparing the simulated temperature rise with the values inferred from resistance measurements, while also clarifying the role of the effective internal convective cooling conditions imposed by the pipe geometry. Key features of the proposed device are low raw-consumables cost, fast on-site manufacturing employing a commercially available desktop 3D printer, monolithic construction free of wire-bonded interconnections, and simplicity, indicating its potential for flow monitoring and condition-based maintenance systems aboard vessels as well as in a wide range of industrial sectors. We should note that the present characterisation was performed under laboratory conditions employing a single prototype per design stage; the effects of humidity, salt exposure, vibration, temperature cycling, and material-batch variability remain to be assessed prior to shipboard deployment. Full article

With the increasing demand for tunnel construction under extreme geological conditions such as high geo-stress, rock bursts, and fault zones, the performance requirements for shotcrete in initial support systems have become more stringent. This study develops a cross-scale structured hybrid fiber-reinforced shotcrete by incorporating alkali-resistant glass fibers including HP and HD types with different lengths and carbon nanotubes (CNTs) into a conventional shotcrete matrix. An orthogonal experimental design at four factors and four levels was adopted to investigate the effects of fiber and CNT contents on the mechanical properties and microstructure of shotcrete. Uniaxial compressive strength, splitting tensile strength, slumping, rebound rate, and microscopic characteristics such as SEM were evaluated at 3, 7, and 28 days. Results show that the optimal mix proportion is 4% HP fiber (24 mm), 2% HD fiber (18 mm), 2% HD fiber (6 mm), and 0.2% CNT. Under this formulation, the 28-day compressive and splitting tensile strengths reached 43.53 MPa and 4.85 MPa, respectively, with a rebound rate as low as 3.85%. The enhanced performance is attributed to the multi-scale reinforcement mechanism. Long fibers suppress macroscopic cracks, short fibers bridge micro-cracks, and CNTs densify the interfacial transition zone. This study provides a parametric reference for the development of high-performance shotcrete and its engineering application in complex underground excavations. Full article

This study investigates the use of silica fume as a potential physical medium for carbon nanotube (CNT) incorporation in cementitious mortars, aiming to enhance mechanical performance and improve cement-use efficiency. Four mixtures were produced with a constant water-to-binder ratio of 0.50: a reference mortar (REF), a mortar incorporating 0.2 wt.% CNTs (REFCNT), a mortar with 10 wt.% cement replacement by silica fume (REFSIL), and a hybrid system containing both CNTs and silica fume (SILCNT). CNTs were introduced using a dry pre-mixing approach with silica fume, avoiding the use of surfactants, chemical functionalization, or ultrasonication. The incorporation of CNTs alone resulted in limited mechanical efficiency, leading to a reduction in flexural tensile strength at 7 days and marginal improvements at 28 days. In contrast, the hybrid SILCNT system exhibited the best overall performance, with increases of 6.2% in flexural tensile strength, 13.7% in axial compressive strength, and 16.0% in prismatic compressive strength at 28 days, indicating improved mechanical efficiency of the composite system. Regarding the environmental indicator (EPI), REFSIL and SILCNT showed a reduced value (0.68 kgCO₂/MPa, respectively) compared to REF and REFCNT (~0.86 kgCO₂/MPa). The results suggest that the combined use of silica fume and CNTs improves the mechanical efficiency of cementitious composites, leading to lower cement-based CO₂ emission indicators. The role of silica fume in potentially facilitating CNT distribution is proposed as a plausible hypothesis based on indirect evidence, including mechanical performance trends and microstructural observations. Full article

Environmental impacts of wastewater from textile and dyestuff industries are of growing concern due to limited freshwater availability and inadequate treatment facilities. Carbon nanotubes (CNTs) offer excellent adsorption potential because of their outstanding mechanical and chemical properties, however; their application in textile effluent treatment has not been widely studied. Moreover, laboratory-based studies are often costly and limited to a few variables, making it challenging to reveal the underlying relationships among several physicochemical parameters and CNT treatments. Multivariate statistical analysis (MVSA) offers an effective approach to overcome this challenge. To the best of our knowledge, no studies have integrated laboratory analysis of nanotube-based textile effluent treatment with an MVSA approach. This study aims to evaluate the physicochemical characterization of textile effluent, treat effluent with CNT, and explore the relationship between physicochemical parameters and CNT by integrating laboratory experiments with MVSA. For this purpose, single-walled CNT (SWCNT) and multi-walled CNT (MWCNT) were applied in batch mode adsorption experiments using various dosages and adsorption times. Scanning electron microscopy and Fourier transform infrared spectroscopy (FTIR), along with physicochemical analyses, were conducted to characterize the effluent and adsorption processes. The FTIR spectrum indicated that the absorption peaks of C=C, C=O, and the acidic f -OH group on CNTs enhance wettability and hydrophilic character, thereby increasing adsorption capacity. Experimental results demonstrated significant reductions in electrical conductivity (EC), total dissolved solids (TDS), turbidity, total organic carbon (TOC), and chemical oxygen demand (COD). CNT dosages of 1 to 5 g/100 mL and adsorption times of 2 to 5 h achieved removal efficiencies ranging from approximately 20% to 90% for SWCNT and MWCNT. MVSA indicated that MWCNT was more strongly associated with ionic and physical parameters (turbidity, TDS, EC, and pH), whereas SWCNT was more strongly related to organic load indicators, particularly COD and TOC. Overall, this study highlights the potential of CNT coupled with the MVSA technique as an effective and sustainable approach for textile wastewater treatment and offers valuable insights for researchers working in this field. Full article

Carbon nanotube (CNT)- and graphene flake (GF)-modified polyester (PET) nonwoven composites were prepared using a one-sided impregnation process with waterborne polyurethane (PU) as the binder. The objective of this work was to clarify how the geometry and loading of one-dimensional CNTs and two-dimensional GFs regulate conductive network formation, anisotropic mechanical behavior, and thermal response in PU/PET nonwoven composites. The novelty of the study lies in the direct comparison of CNT and GF fillers in the same nonwoven/PU matrix and in correlating filler morphology with mechanical reinforcement, electrical conductivity, and textile-related thermal management performance. The sample codes C5 and C6 represent CNT contents of 5 and 6 wt.%, respectively, while G4 and G6 represent GF contents of 4 and 6 wt.%, respectively. Scanning electron microscopy (SEM) showed that GF tended to form sheet-like coatings on fiber surfaces and to fill inter-fiber pores, whereas CNTs showed more local aggregation because of their high surface energy. The composites exhibited anisotropic tensile behavior, with higher tensile strength in the longitudinal direction than in the transverse direction. In the longitudinal tensile test, G4 reached a tensile strength of 13.01 MPa, while C5 reached 11.35 MPa. With increasing carbon material content, both the electrical and thermal conductivities of the composites increased. The electrical conductivity reached 0.02100 S/cm for C6 and 0.05893 S/cm for G6. The thermal conductivity of the CNT/PU/PET composites increased from 0.1163 to 0.1923 W/(m·K), whereas that of the GF/PU/PET composites increased from 0.1793 to 0.2537 W/(m·K). Infrared thermal imaging further indicated that carbon material addition produced faster heating and slower heat dissipation than the unmodified PU/PET sample. These results provide a useful reference for developing multifunctional nonwoven composites for smart textiles, special protective clothing, wearable thermal management layers, and flexible electronic textile substrates. Full article

Carbon nanotubes (CNTs) serve as exceptional multifunctional supports for metal phthalocyanine (MPc)-based electrocatalysts, effectively addressing the inherent limitations of molecular catalysts such as poor conductivity and aggregation. This review systematically summarizes the recent advances in engineering the interface between MPcs and CNTs to optimize performance in sustainable energy conversion and environmental remediation. We categorize the engineering strategies into three synergistic dimensions: (1) dispersion and modification engineering, introducing the most direct physical anchoring dispersion strategy via non-covalent interactions and targeted modifications to yield highly active catalysts; (2) chemical bonding engineering, in which robust axial coordination or covalent grafting creates stable, well-defined active sites and prevents leaching; and (3) geometric and spatial engineering, which exploits CNTs’ unique curvature, atomic defects, inner cavities and one-dimensional architecture to induce strain, symmetry breaking, and nanoconfinement, thereby steering reaction pathways or to construct conductive nanocomposites. These strategies highlight that CNTs are not merely passive scaffolds but active regulators that geometrically and electronically modulate MPcs. By balancing molecular dispersion, charge transfer, and mass transport, CNT-supported MPcs exhibit superior activity, selectivity, and stability for critical electrochemical reactions, including the oxygen reduction reaction (ORR), CO₂ reduction reaction (CO₂RR), and nitrate reduction reaction (NO₃RR), demonstrating substantial potential for advancing sustainable energy technologies and environmental applications. Full article

An adsorptive stripping voltammetric method for the determination of ultra trace amounts of Mo(VI) using an electrode based on a mixture of carbon nanotubes and spherical glassy carbon (CNT/SGC) was developed. The electrode was modified by depositing a lead film in situ during each measurement cycle. In a supporting electrolyte containing 0.2 mol/L of acetic buffer pH = 5.3; 0.2 mmol/L of Pb(II); and 0.15 mmol/L of cupferron, the stripping response observed at −0.62 V was proportional to the Mo(VI) concentration within the range of 7 nmol/L to 0.6 µmol/L. The measurement protocol involved a 20 s electrode modification followed by a 30 s adsorption of Mo(VI)–cupferron complexes. The limit of detection was found to be 2.5 nmol/L with a correlation coefficient of 0.997. The method has been applied to the determination of Mo(VI) in mineral water samples. Full article

Carbon nanotube (CNT) networks are promising candidate channel materials for thin-film transistors (TFTs). However, the charge trapping characteristics underlying the gate hysteresis effect still remain unclear. Herein, high-performance CNT TFTs with good consistencies were fabricated to investigate the hysteresis-induced performance variations and the dynamic charge trapping/releasing behaviors at different gate biases. Both the subthreshold and suprathreshold characteristics of the TFTs are remarkably changed under different gate sweeping directions. The origin of gate hysteresis was illustrated by comparing the effects of gas desorption and selective re-adsorption, and the adsorbed O₂ and H₂O make different contributions related to specific charge trapping characteristics. We further demonstrate that the dynamic charge trapping/releasing processes are governed by the applied gate biases, revealing the equivalency between the positive charge trapping and negative charge releasing processes, and vice versa. The time-dependent degradation of the on-state current has been fitted to perform a statistical analysis based on the measurement results of eight devices. Three characteristic time constants have been determined, corresponding to a multi-step trapping process that may be dominated by dielectric surface trapping and trap-assisted tunneling into the bulk defects in the dielectric layer near the CNTs and those in depth, respectively. Full article

This paper delves into the free vibration analysis of a rotating non-uniform functionally graded carbon nanotube-reinforced composite (FG-CNTRC) beam with symmetric material distribution, taking into account boundary relaxation. Three common carbon nanotube (CNT) distributions, namely FG-X, UD, and FG-O, are considered. The governing equations of a rotating FG-CNTRC beam with variable cross-section and boundary relaxation are formulated via Hamilton’s principle. Some factors, including the centrifugal force induced by rotation, boundary relaxation, cross-section gradient, and others, substantially complicate the boundary conditions, making it challenging to directly obtain an analytical solution with variable coefficients. To address this, a novel power series solution based on the differential transformation method (DTM) is introduced to discretize the vibration equation and obtain the natural frequency of the rotating FG-CNTRC beam, which forms the core novelty of this study. Comprehensive numerical calculations are carried out, and the reliability of the DTM results is fully verified via comparisons with finite element (FEM) outputs and published reference data. Full article