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18 pages, 3916 KiB  
Article
Bond Behavior Between Fabric-Reinforced Cementitious Matrix (FRCM) Composites and Different Substrates: An Experimental Investigation
by Pengfei Ma, Shangke Yuan and Shuming Jia
J. Compos. Sci. 2025, 9(8), 407; https://doi.org/10.3390/jcs9080407 (registering DOI) - 1 Aug 2025
Abstract
This study investigates the bond behavior of fabric-reinforced cementitious matrix (FRCM) composites with three common masonry substrates—solid clay bricks (SBs), perforated bricks (PBs), and concrete hollow blocks (HBs)—using knitted polyester grille (KPG) fabric. Through uniaxial tensile tests of the KPG fabric and FRCM [...] Read more.
This study investigates the bond behavior of fabric-reinforced cementitious matrix (FRCM) composites with three common masonry substrates—solid clay bricks (SBs), perforated bricks (PBs), and concrete hollow blocks (HBs)—using knitted polyester grille (KPG) fabric. Through uniaxial tensile tests of the KPG fabric and FRCM system, along with single-lap and double-lap shear tests, the interfacial debonding modes, load-slip responses, and composite utilization ratio were evaluated. Key findings reveal that (i) SB and HB substrates predominantly exhibited fabric slippage (FS) or matrix–fabric (MF) debonding, while PB substrates consistently failed at the matrix–substrate (MS) interface, due to their smooth surface texture. (ii) Prism specimens with mortar joints showed enhanced interfacial friction, leading to higher load fluctuations compared to brick units. PB substrates demonstrated the lowest peak stress (69.64–74.33 MPa), while SB and HB achieved comparable peak stresses (133.91–155.95 MPa). (iii) The FRCM system only achieved a utilization rate of 12–30% in fabric and reinforcement systems. The debonding failure at the matrix–substrate interface is one of the reasons that cannot be ignored, and exploring methods to improve the bonding performance between the matrix–substrate interface is the next research direction. HB bricks have excellent bonding properties, and it is recommended to prioritize their use in retrofit applications, followed by SB bricks. These findings provide insights into optimizing the application of FRCM reinforcement systems in masonry structures. Full article
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14 pages, 2138 KiB  
Article
Comparison Between Bond Strengths of a Resin Cement on Traditional Prosthetic Substrates and a 3D-Printed Resin for Permanent Restorations
by Alessandro Vichi, Hanan Al-Johani, Dario Balestra and Chris Louca
Coatings 2025, 15(8), 896; https://doi.org/10.3390/coatings15080896 (registering DOI) - 1 Aug 2025
Abstract
Recently, 3D-printed resins have been introduced as materials for definitive indirect restorations. Herein, a comparative assessment of the bond strengths of 3D-printed resins to a resin cement was performed. Methods: four definitive restorative materials were selected, i.e., a Feldspar ceramic (VITA Mark II, [...] Read more.
Recently, 3D-printed resins have been introduced as materials for definitive indirect restorations. Herein, a comparative assessment of the bond strengths of 3D-printed resins to a resin cement was performed. Methods: four definitive restorative materials were selected, i.e., a Feldspar ceramic (VITA Mark II, VM), a polymer-infiltrated ceramic network (VITA Enamic, VE), a nanohybrid resin composite (Grandio Bloc, GB), and one 3D-printed resin (Crown Permanent, CP). VM and VE were etched and silanized, GB was sandblasted, and CP was glass bead blasted; for one further experimental group, this was followed by sandblasting (CPs). A resin cement (RelyX Unicem) was then used for bonding, and then a notched shear bond strength test (nSBS) was performed. Failure modes were observed and classified as adhesive, cohesive, or mixed, and SEM representative images were taken. Data were statistically analyzed with one-way ANOVA, Tukey, and Chi-square tests. Significant differences were detected in nSBS among materials (p < 0.001). The highest nSBS was found in VM (30.3 ± 1.8 MPa) a, followed by CPb, GBbc, CPbc, and VEc. Failure modes were significantly different (p < 0.001), and with different prevalent failure modes. The bond strength for 3D-printed permanent resin materials was shown to be lower than that of the felspathic ceramic but comparable to that of the resin block and PICN substrates. Full article
(This article belongs to the Special Issue Advanced Polymer Coatings: Materials, Methods, and Applications)
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18 pages, 1290 KiB  
Article
The Impact of Substituting Chalk with Fly Ash in Formulating a Two-Component Polyurethane Adhesive on Its Physicochemical and Mechanical Properties
by Edyta Pęczek, Renata Pamuła, Żaneta Ciastowicz, Paweł Telega, Łukasz Bobak and Andrzej Białowiec
Materials 2025, 18(15), 3591; https://doi.org/10.3390/ma18153591 - 30 Jul 2025
Abstract
This study aimed to evaluate the effect of replacing chalk with fly ash in a two-component polyurethane (2C PU) adhesive on its physicochemical, mechanical, and environmental properties, as a practical application of circular economy principles. Six adhesive formulations were prepared, each containing a [...] Read more.
This study aimed to evaluate the effect of replacing chalk with fly ash in a two-component polyurethane (2C PU) adhesive on its physicochemical, mechanical, and environmental properties, as a practical application of circular economy principles. Six adhesive formulations were prepared, each containing a chalk-to-fly ash ratio as a filler. The study evaluated rheological, mechanical, thermal, and environmental parameters. Mechanical tests confirmed cohesive failure within the bonded material, indicating that the bond strength at the adhesive–substrate interface exceeded the internal strength of the substrate. The highest contaminant elution levels recorded were 0.62 mg/kg for molybdenum and 0.20 mg/kg for selenium, which represent only 6.2% and 40% of the regulatory limits, respectively. Dissolved organic carbon (DOC) and total dissolved solids (TDS) did not exceed 340 mg/kg and 4260 mg/kg, respectively. GC-MS analysis did not reveal the presence of prominent volatile organic compound emissions. Initial screening suggests possible compatibility with low-emission certification schemes (e.g., A+, AgBB, EMICODE®), though confirmation requires further quantitative testing. The results demonstrate that fly ash can be an effective substitute for chalk in polyurethane adhesives, ensuring environmental compliance and maintaining functional performance while supporting the principles of the circular economy. Full article
(This article belongs to the Section Mechanics of Materials)
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17 pages, 5178 KiB  
Article
Improvement of Unconfined Compressive Strength in Granite Residual Soil by Indigenous Microorganisms
by Ya Wang, Meiqi Li, Hao Peng, Jiaxin Kang, Hong Guo, Yasheng Luo and Mingjiang Tao
Sustainability 2025, 17(15), 6895; https://doi.org/10.3390/su17156895 - 29 Jul 2025
Viewed by 164
Abstract
In order to study how indigenous microorganisms can enhance the strength properties of granite residual soil in the Hanzhong area, two Bacillus species that produce urease were isolated from the local soil. The two Bacillus species are Bacillus subtilis and Bacillus tequilensis, [...] Read more.
In order to study how indigenous microorganisms can enhance the strength properties of granite residual soil in the Hanzhong area, two Bacillus species that produce urease were isolated from the local soil. The two Bacillus species are Bacillus subtilis and Bacillus tequilensis, and they were used for the solidification and improvement of the granite residual soil. Unconfined compressive strength tests, scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses were systematically used to analyze the influence and mechanism of different cementation solution concentrations on the improvement effect. It has been found that with the growth of cementing fluid concentration, the unconfined compressive strength of improved soil specimens shows an increasing tendency, reaching its highest value when the cementing solution concentration is 2.0 mol/L. Among different bacterial species, curing results vary; Bacillus tequilensis demonstrates better performance across various cementing solution concentrations. The examination of failure strain in improved soil samples indicates that brittleness has been successfully alleviated, with optimal outcomes obtained at a cementing solution concentration of 1.0 mol/L. SEM and XRD analyses show that calcium carbonate precipitates (CaCO3) are formed in soil samples treated by both strains. These precipitates effectively bond soil particles, verifying improvement effects on a microscopic level. The present study proposes an environmentally friendly and economical method for enhancing engineering applications of granite residual soil in Hanzhong area, which holds significant importance for projects such as artificial slope filling, subgrade filling, and foundation pit backfilling. Full article
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36 pages, 4967 KiB  
Review
Mechanical Behavior of Adhesively Bonded Joints Under Tensile Loading: A Synthetic Review of Configurations, Modeling, and Design Considerations
by Leila Monajati, Aurelian Vadean and Rachid Boukhili
Materials 2025, 18(15), 3557; https://doi.org/10.3390/ma18153557 - 29 Jul 2025
Viewed by 272
Abstract
This review presents a comprehensive synthesis of recent advances in the tensile performance of adhesively bonded joints, focusing on applied aspects and modeling developments rather than providing a full theoretical analysis. Although many studies have addressed individual joint types or modeling techniques, an [...] Read more.
This review presents a comprehensive synthesis of recent advances in the tensile performance of adhesively bonded joints, focusing on applied aspects and modeling developments rather than providing a full theoretical analysis. Although many studies have addressed individual joint types or modeling techniques, an integrated review that compares joint configurations, modeling strategies, and performance optimization methods under tensile loading remains lacking. This work addresses that gap by examining the mechanical behavior of key joint types, namely, single-lap, single-strap, and double-strap joints, and highlighting their differences in stress distribution, failure mechanisms, and structural efficiency. Modeling and simulation approaches, including cohesive zone modeling, extended finite element methods, and virtual crack closure techniques, are assessed for their predictive accuracy and applicability to various joint geometries. This review also covers material and geometric enhancements, such as adherend tapering, fillets, notching, bi-adhesives, functionally graded bondlines, and nano-enhanced adhesives. These strategies are evaluated in terms of their ability to reduce stress concentrations and improve damage tolerance. Failure modes, adhesive and adherend defects, and delamination risks are also discussed. Finally, comparative insights into different joint configurations illustrate how geometry and adhesive selection influence strength, energy absorption, and weight efficiency. This review provides design-oriented guidance for optimizing bonded joints in aerospace, automotive, and structural engineering applications. Full article
(This article belongs to the Special Issue Advanced Materials and Processing Technologies)
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28 pages, 14358 KiB  
Article
Three-Dimensional Mesoscopic DEM Modeling and Compressive Behavior of Macroporous Recycled Concrete
by Yupeng Xu, Fei Geng, Haoxiang Luan, Jun Chen, Hangli Yang and Peiwei Gao
Buildings 2025, 15(15), 2655; https://doi.org/10.3390/buildings15152655 - 27 Jul 2025
Viewed by 284
Abstract
The mesoscopic-scale discrete element method (DEM) modeling approach demonstrated high compatibility with macroporous recycled concrete (MRC). However, existing DEM models failed to adequately balance modeling accuracy and computational efficiency for recycled aggregate (RA), replicate the three distinct interfacial transition zone (ITZ) types and [...] Read more.
The mesoscopic-scale discrete element method (DEM) modeling approach demonstrated high compatibility with macroporous recycled concrete (MRC). However, existing DEM models failed to adequately balance modeling accuracy and computational efficiency for recycled aggregate (RA), replicate the three distinct interfacial transition zone (ITZ) types and pore structure of MRC, or establish a systematic calibration methodology. In this study, PFC 3D was employed to establish a randomly polyhedral RA composite model and an MRC model. A systematic methodology for parameter testing and calibration was proposed, and compressive test simulations were conducted on the MRC model. The model incorporated all components of MRC, including three types of ITZs, achieving an aggregate volume fraction of 57.7%. Errors in simulating compressive strength and elastic modulus were 3.8% and 18.2%, respectively. Compared to conventional concrete, MRC exhibits larger strain and a steeper post-peak descending portion in stress–strain curves. At peak stress, stress is concentrated in the central region and the surrounding arc-shaped zones. After peak stress, significant localized residual stress persists within specimens; both toughness and toughness retention capacity increase with rising porosity and declining compressive strength. Failure of MRC is dominated by tension rather than shear, with critical bonds determining strength accounting for only 1.4% of the total. The influence ranking of components on compressive strength is as follows: ITZ (new paste–old paste) > ITZ (new paste–natural aggregates) > new paste > old paste > ITZ (old paste–natural aggregates). The Poisson’s ratio of MRC (0.12–0.17) demonstrates a negative correlation with porosity. Predictive formulas for peak strain and elastic modulus of MRC were established, with errors of 2.6% and 3.9%, respectively. Full article
(This article belongs to the Special Issue Advances in Modeling and Characterization of Cementitious Composites)
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26 pages, 10667 KiB  
Article
Influence of Nitrogen and Hydrogen Addition on Composition, Morphology, Adhesion, and Wear Resistance of Amorphous Carbon Coatings Produced by RFCVD Method on Surface-Hardened Ultra-Fine Grained Bainitic 30HGSNA Steel
by Karol Wunsch, Tomasz Borowski, Emilia Skołek, Agata Roguska, Rafał Chodun, Michał Urbańczyk, Krzysztof Kulikowski, Maciej Spychalski, Andrzej Wieczorek and Jerzy Robert Sobiecki
Coatings 2025, 15(8), 877; https://doi.org/10.3390/coatings15080877 - 26 Jul 2025
Viewed by 262
Abstract
Ultra-fine-grained bainitic (UFGB) steels offer excellent mechanical properties, which can be further improved by applying diamond-like carbon (DLC) coatings. However, poor adhesion between the coating and substrate remains a key limitation. Since the steel’s microstructure degrades at high temperatures, enhancing adhesion without heating [...] Read more.
Ultra-fine-grained bainitic (UFGB) steels offer excellent mechanical properties, which can be further improved by applying diamond-like carbon (DLC) coatings. However, poor adhesion between the coating and substrate remains a key limitation. Since the steel’s microstructure degrades at high temperatures, enhancing adhesion without heating the substrate is essential. This study investigates surface hardening combined with simultaneous nitrogen and hydrogen doping during the Radio Frequency Chemical Vapor Deposition (RFCVD) process to improve coating performance. Varying gas compositions were tested to assess their effects on coating properties. Nitrogen incorporation decreased hardness from 12 GPa to 9 GPa but improved adhesion, while hydrogen limited damage after coating failure. Optimizing the gas mixture led to enhanced adhesion and wear resistance. Raman and X-ray photoelectron spectroscopy (XPS) analyses confirmed that the optimized coatings had the highest sp3 bond content and elevated nitrogen levels. While both hardness and adhesion contributed to wear resistance, no direct link to coating thickness was found. Overall, co-doping with nitrogen and hydrogen is an effective approach to improve adhesion and wear resistance without requiring high processing temperatures or complex equipment. Full article
(This article belongs to the Special Issue Recent Advances in Surface Functionalisation, 2nd Edition)
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25 pages, 6014 KiB  
Article
Research on Synergistic Enhancement of UHPC Cold Region Repair Performance by Steel Fibers and Early-Strength Agent
by Ming Xie, Zhangdong Wang, Li’e Yin and Hao Li
Buildings 2025, 15(15), 2630; https://doi.org/10.3390/buildings15152630 - 25 Jul 2025
Viewed by 207
Abstract
This study looked at the performance requirements of repair materials for concrete structures in cold regions, systematically analyzing the effects of steel fiber dosage (0.7–2.1%), early-strength agent PRIORITY dosage (6–10%), and their coupling effects on the workability, interfacial bond strength, and freeze–thaw resistance [...] Read more.
This study looked at the performance requirements of repair materials for concrete structures in cold regions, systematically analyzing the effects of steel fiber dosage (0.7–2.1%), early-strength agent PRIORITY dosage (6–10%), and their coupling effects on the workability, interfacial bond strength, and freeze–thaw resistance of rapid-hardening ultra-high-performance concrete (UHPC). Through fluidity testing, bond interface failure analysis, freeze–thaw cycle testing, and pore analysis, the mechanism of steel fibers and early-strength agent on the multi-dimensional performance of fast-hardening UHPC was revealed. The results showed that when the steel fiber dosage exceeded 1.4%, the flowability was significantly reduced, while a PRIORITY dosage of 8% improved the flowability by 20.5% by enhancing the paste lubricity. Single addition of steel fibers decreased the interfacial bond strength, but compound addition of 8% PRIORITY offset the negative impact by optimizing the filling effect of hydration products. Under freeze–thaw cycles, excessive steel fibers (2.1%) exacerbated the mass loss (1.67%), whereas a PRIORITY dosage of 8% increased the retention rate of relative dynamic elastic modulus by 10–15%. Pore analysis shows that the synergistic effect of 1.4% steel fiber and 8% PRIORITY can reduce the number of pores, optimize the pore distribution, and make the structure denser. The study determined that the optimal compound mixing ratio was 1.4% steel fibers and 8% PRIORITY. This combination ensures construction fluidity while significantly improving the interfacial bond durability and freeze–thaw resistance, providing a theoretical basis for the design of concrete repair materials in cold regions. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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18 pages, 7058 KiB  
Article
Failure Analysis and Optimized Simulation Design of Silicon Micromechanical Resonant Accelerometers
by Jingchen Wang, Heng Liu and Zhi Li
Sensors 2025, 25(15), 4583; https://doi.org/10.3390/s25154583 - 24 Jul 2025
Viewed by 163
Abstract
To develop solutions to the frequency instability and failure of silicon micromechanical resonant accelerometers, the state characteristics of micromechanical resonant accelerometers are investigated under temperature and vibration stresses. Through theoretical analysis and finite element simulation, the following is found: the Young’s modulus of [...] Read more.
To develop solutions to the frequency instability and failure of silicon micromechanical resonant accelerometers, the state characteristics of micromechanical resonant accelerometers are investigated under temperature and vibration stresses. Through theoretical analysis and finite element simulation, the following is found: the Young’s modulus of silicon varies with temperature, causing a resonance frequency shift of −1.364 Hz/°C; the residual stress of temperature change affects the resonance frequency shift of the microstructure, causing it to be 5.43 Hz/MPa (tensile stress) and −5.25 Hz/MPa (compressive stress); thermal expansion triggers the failure of the bonding wire, and, in the range of 10 °C to 150 °C, the peak stress of the electrode/lead bond area increases from 83.2/85.6 MPa to 1.08/1.28 GPa. The failure mode under vibration stress is resonance structure fracture and interlayer peeling. An isolation frame design is proposed for the sensitive part of the microstructure, which reduces the frequency effects by 34% (tensile stress) and 15% (compressive stress) under temperature-variable residual stresses and the maximum value of the structural root mean square stresses by 69.7% (X-direction), 63.6% (Y-direction), and 71.3% (Z-direction) under vibrational stresses. Full article
(This article belongs to the Section Physical Sensors)
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17 pages, 8715 KiB  
Article
Experimental Investigation of Failure Behaviors of CFRP–Al Lap Joints with Various Configurations Under High- and Low-Temperature Conditions
by Mingzhen Wang, Qiaosheng Huang, Qingfeng Duan, Wentao Yang, Yue Cui and Hongqiang Lyu
Materials 2025, 18(15), 3467; https://doi.org/10.3390/ma18153467 - 24 Jul 2025
Viewed by 286
Abstract
The failure behaviors of CFR–aluminum lap joints with diverse configurations through quasi-static tensile tests were conducted at −40 °C, 25 °C, and 80 °C. Four specimen types were examined: CFRP–aluminum alloy two-bolt single-lap joints (TBSL), two-bolt double-lap joints (TBDL), two-bolt bonded–bolted hybrid single-lap [...] Read more.
The failure behaviors of CFR–aluminum lap joints with diverse configurations through quasi-static tensile tests were conducted at −40 °C, 25 °C, and 80 °C. Four specimen types were examined: CFRP–aluminum alloy two-bolt single-lap joints (TBSL), two-bolt double-lap joints (TBDL), two-bolt bonded–bolted hybrid single-lap joints (BBSL), and two-bolt bonded–bolted hybrid double-lap joints (BBDL). The analysis reveals that double-lap joints possess a markedly higher strength than single-lap joints. The ultimate loads of the TBSL (single-lap joints) at temperatures of −40 °C and 25 °C are 29.5% and 26.20% lower, respectively, than those of the TBDL (double-lap joints). Similarly, the ultimate loads of the BBSL (hybrid single-lap joints) at −40 °C, 25 °C, and 80 °C are 19.8%, 31.66%, and 40.05% lower, respectively, compared to the corresponding data of the TBDL. In bolted–bonded hybrid connections, the adhesive layer enhances the joint’s overall stiffness but exhibits significant temperature dependence. At room and low temperatures, the ultimate loads of the BBDL are 46.97 kN at −40 °C and 50.30 kN at 25 °C, which are significantly higher than those of the TBDL (42.24 kN and 44.63 kN, respectively). However, at high temperatures, the load–displacement curves of the BBDL and TBDL are nearly identical. This suggests that the adhesive layers are unable to provide a sufficient shear-bearing capacity due to their low modulus at elevated temperatures. This research provides valuable insights for designing composite–metal connections in aircraft structures, highlighting the impacts of different joint configurations and temperature conditions on failure modes and load-bearing capacities. Full article
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15 pages, 1307 KiB  
Article
Shear Bond Strength and Finite Element Stress Analysis of Composite Repair Using Various Adhesive Strategies With and Without Silane Application
by Elif Ercan Devrimci, Hande Kemaloglu, Cem Peskersoy, Tijen Pamir and Murat Turkun
Appl. Sci. 2025, 15(15), 8159; https://doi.org/10.3390/app15158159 - 22 Jul 2025
Viewed by 192
Abstract
This study evaluated the effect of various adhesive systems, particularly silane application, on the repair bond strength of a nanofill resin composite and associated stress distribution using finite element analysis (FEA). A total of 105 composite specimens (4 × 6 mm) were aged [...] Read more.
This study evaluated the effect of various adhesive systems, particularly silane application, on the repair bond strength of a nanofill resin composite and associated stress distribution using finite element analysis (FEA). A total of 105 composite specimens (4 × 6 mm) were aged by thermal cycling (10,000 cycles), roughened, etched with phosphoric acid, and assigned to seven groups (n = 15): G1. control—no adhesive; G2. Single Bond Universal Adhesive; G3. composite primer; G4. PQ1; G5. Silane + PQ1; G6. Clearfil Universal Bond; G7. All-Bond Universal. Shear bond strength was measured using a universal testing machine (1 mm/min), and failure modes were microscopically classified. FEA was conducted under static and fatigue conditions using 3D models built in Fusion-360. Mechanical properties were obtained from technical data and the literature. A 300 N load was applied and contact detection (0.05 mm) and constraint zones were defined. Statistical analysis was performed using one-way ANOVA and Tukey’s HSD (p = 0.05). Pearson’s correlation was used to assess the relationship between bond strength and von Mises stress. The highest bond strength was found in G2 (21.54 MPa) while G1 showed the lowest (8.86 MPa). Silane-treated groups exhibited favorable stress distribution and a strong correlation between experimental and simulated outcomes. Silane applications significantly enhance composite repair performance. Full article
(This article belongs to the Special Issue Dental Materials: Latest Advances and Prospects, Third Edition)
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22 pages, 3746 KiB  
Article
Shear Performance of UHPC-NC Composite Structure Interface Treated with Retarder: Quantification by Fractal Dimension and Optimization of Process Parameters
by Runcai Weng, Zhaoxiang He, Jiajie Liu, Bin Lei, Linhai Huang, Jiajing Xu, Lingfei Liu and Jie Xiao
Buildings 2025, 15(15), 2591; https://doi.org/10.3390/buildings15152591 - 22 Jul 2025
Viewed by 278
Abstract
Prefabricated Ultra-High-Performance Concrete (UHPC) and cast-in-place Normal Concrete (NC) composite members are increasingly used in bridge engineering because they combine high performance with cost-effectiveness. The bond at the UHPC-NC interface is critical as it directly impacts the composite structure’s safety. This study employed [...] Read more.
Prefabricated Ultra-High-Performance Concrete (UHPC) and cast-in-place Normal Concrete (NC) composite members are increasingly used in bridge engineering because they combine high performance with cost-effectiveness. The bond at the UHPC-NC interface is critical as it directly impacts the composite structure’s safety. This study employed 3D laser scanning acquired the UHPC substrate geometry, utilized fractal dimension analysis to quantify the interface roughness, and adopted the slant shear test to evaluate the effects of retarder application mass and hydration delay duration on roughness and bond strength. The research results indicate that the failure modes of UHPC-NC specimens can be categorized into interface shear failure and NC splitting tensile failure. With the extension of hydration delay duration, both the interface roughness and bond strength show a decreasing trend. The influence of retarder dosage on interface roughness and bond strength exhibits a threshold effect. This study also confirms the effectiveness of fractal dimension as a quantitative tool for characterizing the macroscopic roughness features of the bonding interface. The findings of this paper provide a solid theoretical basis and quantitative support for optimizing key process parameters such as retarder dosage and precisely controlling hydration delay duration, offering significant engineering guidance for enhancing the interface bonding performance of UHPC-NC composite structures. Full article
(This article belongs to the Special Issue Low Carbon and Green Materials in Construction—3rd Edition)
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11 pages, 1578 KiB  
Article
Impact of Hydrofluoric Acid, Ytterbium Fiber Lasers, and Hydroxyapatite Nanoparticles on Surface Roughness and Bonding Strength of Resin Cement with Different Viscosities to Lithium Disilicate Glass Ceramic: SEM and EDX Analysis
by Abdullah Aljamhan and Fahad Alkhudhairy
Crystals 2025, 15(7), 661; https://doi.org/10.3390/cryst15070661 - 20 Jul 2025
Viewed by 253
Abstract
This study looks at the effect of surface conditioners hydrofluoric acid (HFA), Ytterbium fibre laser (YFL), and Hydroxyapatite nanoparticles (HANPs) on the surface roughness (Ra) and shear bond strength (SBS) of different viscosity resin cements to lithium disilicate glass ceramic (LDC). A total [...] Read more.
This study looks at the effect of surface conditioners hydrofluoric acid (HFA), Ytterbium fibre laser (YFL), and Hydroxyapatite nanoparticles (HANPs) on the surface roughness (Ra) and shear bond strength (SBS) of different viscosity resin cements to lithium disilicate glass ceramic (LDC). A total of 78 IPS Emax discs were prepared and categorized into groups based on conditioning methods. Group 1 HFA–Silane (S), Group 2: YFL-S, and Group 3: HANPs-S. A scanning electron microscope (n = 1) and profilometer (n = 5) were used on each conditioned group for the assessment of surface topography and Ra. A total of 20 LDC discs for each conditioned group were subsequently categorized into two subgroups based on the application of high- and low-viscosity dual-cured resin cement. SBS and failure mode were assessed. ANOVA and post hoc Tukey tests were employed to identify significant differences in Ra and SBS among different groups. LDC conditioned with HFA-S, HANPs-S, and YFL-S demonstrated comparable Ra scores (p > 0.05). Also, irrespective of the type of conditioning regime, the use of low-viscosity cement improves bond values when bonded to the LDC. LDC treated with YFL-S and HANPs-S can serve as an effective substitute for HFA-S in enhancing the Ra and surface characteristics of LDC. The low-viscosity resin cement demonstrated superior performance by achieving greater bond strength. Full article
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27 pages, 15704 KiB  
Article
Study on Mechanical Properties of Composite Basalt Fiber 3D-Printed Concrete Based on 3D Meso-Structure
by Shengxuan Ding, Jiren Li and Mingqiang Wang
Materials 2025, 18(14), 3379; https://doi.org/10.3390/ma18143379 - 18 Jul 2025
Viewed by 372
Abstract
As 3D concrete printing emerges as a transformative construction method, its structural safety remains hindered by unresolved issues of mechanical anisotropy and interlayer defects. To address this, we systematically investigate the failure mechanisms and mechanical performance of basalt fiber-reinforced 3D-printed magnesite concrete. A [...] Read more.
As 3D concrete printing emerges as a transformative construction method, its structural safety remains hindered by unresolved issues of mechanical anisotropy and interlayer defects. To address this, we systematically investigate the failure mechanisms and mechanical performance of basalt fiber-reinforced 3D-printed magnesite concrete. A total of 30 cube specimens (50 mm × 50 mm × 50 mm)—comprising three types (Corner, Stripe, and R-a-p)—were fabricated and tested under compressive and splitting tensile loading along three orthogonal directions using a 2000 kN electro-hydraulic testing machine. The results indicate that 3D-printed concrete exhibits significantly lower strength than cast-in-place concrete, which is attributed to weak interfacial bonds and interlayer pores. Notably, the R-a-p specimen’s Z-direction compressive strength is 38.7% lower than its Y-direction counterpart. To complement the mechanical tests, DIC, CT scanning, and SEM analyses were conducted to explore crack development, internal defect morphology, and microstructure. A finite element model based on the experimental data successfully reproduced the observed failure processes. This study not only enhances our understanding of anisotropic behavior in 3D-printed concrete but also offers practical insights for print-path optimization and sustainable structural design. Full article
(This article belongs to the Special Issue 3D Printing Materials in Civil Engineering)
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33 pages, 4942 KiB  
Review
A Review of Crack Sealing Technologies for Asphalt Pavement: Materials, Failure Mechanisms, and Detection Methods
by Weihao Min, Peng Lu, Song Liu and Hongchang Wang
Coatings 2025, 15(7), 836; https://doi.org/10.3390/coatings15070836 - 17 Jul 2025
Viewed by 410
Abstract
Asphalt pavement cracking represents a prevalent form of deterioration that significantly compromises road performance and safety under the combined effects of environmental factors and traffic loading. Crack sealing has emerged as a widely adopted and cost-effective preventive maintenance strategy that restores the pavement’s [...] Read more.
Asphalt pavement cracking represents a prevalent form of deterioration that significantly compromises road performance and safety under the combined effects of environmental factors and traffic loading. Crack sealing has emerged as a widely adopted and cost-effective preventive maintenance strategy that restores the pavement’s structural integrity and extends service life. This paper presents a systematic review of the development of crack sealing technology, conducts a comparative analysis of conventional sealing materials (including emulsified asphalt, hot-applied asphalt, polymer-modified asphalt, and rubber-modified asphalt), and examines the existing performance evaluation methodologies. Critical failure mechanisms are thoroughly investigated, including interfacial bond failure resulting from construction defects, material aging and degradation, hydrodynamic scouring effects, and thermal cycling impacts. Additionally, this review examines advanced sensing methodologies for detecting premature sealant failure, encompassing both non-destructive testing techniques and active sensing technologies utilizing intelligent crack sealing materials with embedded monitoring capabilities. Based on current research gaps, this paper identifies future research directions to guide the development of intelligent and sustainable asphalt pavement crack repair technologies. The proposed research framework provides valuable insights for researchers and practitioners seeking to improve the long-term effectiveness of pavement maintenance strategies. Full article
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