Search Results (615)

New bulk chalcogenides from the system (GeTe₆)_1−xCu_x, where x = 5, 10, 15 and 20 mol%, have been synthesized. The structure and composition of the materials were studied using X-ray powder diffraction (XRD) and energy-dispersive spectroscopy (EDS). Scanning electron microscopy (SEM) was applied to analyze the surface morphology of the samples. Some thermal characteristics such as the glass transition, crystallization and melting temperature and some physico-chemical properties such as the density, compactness and molar and free volumes were also determined. The XRD patterns show sharp diffraction peaks, indicating that the synthesized new bulk materials are crystalline. The following four crystal phases were determined: Te, Cu, CuTe and Cu₂GeTe₃. The results from the EDS confirmed the presence of Ge, Te and Cu in the bulk samples in concentrations in good correspondence with those theoretically determined. A layered thin-film material based on Ge₁₄Te₈₁Cu₅, which exhibits lower network compactness compared to the other synthesized new chalcogenides, and the azo polymer PAZO was fabricated, and the kinetics of the photoinduced birefringence at 444 nm was measured. The results indicated an increase in the maximal induced birefringence for the layered structure in comparison to the non-doped azo polymer film. Full article

Stable generation and propagation of single-polarization single-mode (SPSM) beams in hollow-core fiber (HCF) has become an important research direction. However, their routine use is yet to become a reality, a major obstacle is to maintain the polarization state of light at a sufficiently long transmission distance in a wide spectral range. In the paper, a hollow-core anti-resonant fiber (HC-ARF) that can support SPSM beam transmission with an average loss of 15 dB/km in wavelengths beyond 1000 nm is proposed. SPSM guidance is achieved by setting the cladding tubes in the orthogonal direction to have different structures and material properties. Different cladding tube structures break the degeneracy of polarization modes, and different cladding tube materials make the polarization modes experience enough loss difference. In the range of more than 600 nm, the y-polarization loss ≈ 9.3 dB/km, while the x-polarization is > 500 dB/km, and the birefringence is > 1.7 × 10⁻⁵. In addition, the SPSM optimization process and bending losses in different directions are also discussed in detail. Full article

The temperature-dependent polarization performance of super-twisted nematic liquid crystals (STN-LCs) when used as polarizers has garnered considerable scholarly attention. In this study, the transmittance of an STN-LC cell was measured under incident light wavelengths of 650 nm, 532 nm, and 405 nm over the temperature range of 30 °C to 100 °C. The STN-LC cell was employed both as the sample under test and as an analyzer in a rotational measurement setup to investigate how its polarization properties vary with temperature. The results indicate that the LC cell exhibits the characteristics of a linear polarizer under red light (650 nm) and violet laser (405 nm) across the full temperature range. However, under green laser (532 nm), when the temperature exceeds 60 °C, its extinction ratio is poor, suggesting its unsuitability for polarization applications under such conditions. A birefringence inversion formula was derived using the transmittance difference method, which effectively eliminates the influence of the glass substrates on the measured transmittance of the LC layer. Utilizing this method, a simple optical setup consisting of a polarizer and photodetector was constructed to accurately extract the birefringence of the LC. The birefringence of super-twisted nematic liquid crystal can be obtained by the transmittance difference method, which is low-cost, has a simple optical path, and is convenient for temperature-controlled experimental measurements of the liquid crystal cell. The findings of this study provide methodological support for the precise determination of birefringence in LCs exhibiting linear polarization characteristics. Full article

Polarized light imaging (PLI) has been effective in visualizing and quantifying collagen content. Collagen-specific data are often overlaid over the tissue image for visualization. However, such contextual tissue images are typically in grayscale and lack important color information, limiting the usefulness of PLI in imaging the stained histology slides and for surgical guidance. The objective of this study was to develop a robust and easy-to-implement PLI technique to capture both true color and birefringent collagen data, and we call it ColorPOL. ColorPOL uses only one polarization-sensitive camera to capture information at 75 frames per second. The true color images were synthesized from individual RGB images, and collagen-specific information (fiber orientation and retardance) was derived from the green channel image. We implemented ColorPOL in transmission mode on an upright microscope and in reflection mode for wide-field thick tissue imaging. The color images in both implementations provided valuable color tissue context that facilitated the identification and localization of collagen content. Additionally, we demonstrated that in reflection mode, the high imaging speed enabled us to record and visualize continuous deformations of the collagenous tissues (tendons, sciatic nerves, and blood vessels) overlaid on the processed collagen-specific information. Robust performance and flexible configuration will make ColorPOL a valuable tool in basic research and translational applications. Full article

This study investigates the effects of microwave post-treatment and fatty acid type on the physicochemical properties of starch–lipid complexes derived from water caltrop (Trapa taiwanensis Nakai) starch. Complexes were prepared using stearic acid (C_18:0) or oleic acid (C_18:1), followed by microwave post-treatment at varying durations. Morphological analysis revealed that the starch–stearic acid complex exhibited more plate-like structures and birefringent spots compared to the starch–oleic acid complex. The complexing index increased with extended microwave exposure, indicating enhanced complex formation. Fourier-transform infrared spectroscopy showed no significant variation in the 1047/1022 cm⁻¹ absorption ratio, suggesting that the short-range molecular order remained unaffected. However, X-ray diffraction analysis indicated increased relative crystallinity, particularly in the stearic acid complex (10.4%) compared to the oleic acid complex (4.8%), likely due to the higher linearity and saturation of stearic acid. Differential scanning calorimetry confirmed the presence of both type I and type II crystallization in all samples. The starch–stearic acid complex exhibited greater thermal stability, promoted type II crystallization, and enhanced the ordered structure of type I crystallization. In contrast, microwave treatment had limited influence on the thermal properties of the starch–oleic acid complex. These findings demonstrate that microwave post-treatment facilitates starch–lipid complex formation and improves structural organization, particularly when saturated fatty acids are employed. Full article

The poor magnetic and magneto-optical properties of BiFeO₃, along with its significant lattice mismatch with silicon, have limited its application in silicon-based integrated magneto-optical devices. In this study, co-doping with Sr²⁺ and Ti⁴⁺ ions effectively transformed the trigonal structure of BiFeO₃ into a cubic phase, thereby reducing the lattice mismatch with silicon to 2.8%. High-quality, highly oriented, silicon-based cubic Sr,Ti:BiFeO₃ thin films were successfully fabricated using radio frequency magnetron sputtering. Due to the induced lattice distortion, the characteristic periodic spiral spin antiferromagnetic structure of BiFeO₃ was suppressed, resulting in a significant enhancement of the saturation magnetization of cubic Bi_0.5Sr_0.5Fe_0.5Ti_0.5O₃ (48.0 emu/cm³), compared to that of pristine BiFeO₃ (5.0 emu/cm³). Furthermore, the incorporation of Sr²⁺ and Ti⁴⁺ ions eliminated the birefringence effect inherent in trigonal BiFeO₃, thereby inducing a pronounced magneto-optical effect in the cubic Sr,Ti:BiFeO₃ thin film. The magnetic circular dichroic ellipticity (ψ_F) of Bi_0.5Sr_0.5Fe_0.5Ti_0.5O₃ reached an impressive 2300 degrees/cm. Full article

A laser diode (LD) end-pumped continuous-wave (CW) tunable Nd³⁺:LiYF₄ (Nd:YLF) laser operating on the ⁴F_3/2→⁴I_13/2 transition was performed. Four single-wavelength (SW) lasing at 1321, 1314, 1371, and 1364 nm in the π-polarized direction and three SW lasing at 1314, 1326, and 1371 nm in the σ-polarized direction were achieved using a tuning prism. At 20 W pump power, the σ-polarized 1314 nm emission generated 7.3 W power output with 39.4% slope efficiency. Further, the three-pair of switchable π-polarized dual-wavelengths (DWs) at 1321/1314 nm, 1371/1364 nm, and 1321/1364 nm and the two-pair of switchable σ-polarized DWs at 1314/1326 nm and 1314/1371 nm were also realized by rotating an intracavity birefringence filter (BF). In addition, by employing dual intracavity BFs, the balanced DW output power was attained, achieving 6.4 W total maximum output at 1314/1321 nm in the π-polarized direction. Full article

The rapid advancements in optical communication and sensing technologies have significantly increased the demand for advanced tunable spectral systems. This study presents a dual-band terahertz transmission and manipulation approach by leveraging the topologically protected properties of valley-topological photonic crystal edge states. The designed structure facilitates the excitation of the K valley within the range of 0.851–0.934 THz and the K′ valley from 1.604 to 1.686 THz, while also demonstrating anomalous refraction and birefringence. The calculated emission angles, derived through momentum matching, enable transitions between single-wave and dual-wave emissions and allow for precise angle control. The introduction of the liquid crystal material NJU-LDn-4 enables continuous tuning of the dual-band spectral range under a varying electric field, broadening the operating frequency bands to the ranges of 0.757–0.996 THz and 1.426–1.798 THz, respectively. These findings suggest promising applications in tunable filter design, optical communication, photonic computing, optical sensing, and high-resolution imaging, particularly in novel optical devices requiring precise control over spectral characteristics and light propagation. Full article

The internal growth patterns and surface micromorphology of diamonds provide a record of their multi-stage evolution, from initial formation within the mantle to their eventual ascent to the Earth’s surface via deeply derived kimberlite magmas. In this study, gemological microscopic examination, Diamond View^TM, Raman spectroscopy, and electron probe analysis were employed to analyze the surface features, internal patterns, and inclusions of the Tancheng alluvial diamonds in Shandong Province, China. The results show that surface features of octahedra with triangular and sharp edges, thick steps with irregular contours or rounded edges, and thin triangular or serrated layers are developed on diamonds during deep-mantle storage, as well as during the growth process of diamonds, when they are not subjected to intense dissolution. The rounding of octahedral and cubic diamond edges and their transformation into tetrahedral (THH) shapes are attributed to resorption in kimberlitic magma. These characteristics indicate that the Tancheng diamonds were commonly resorbed by carbonate–silicate melts during mantle storage. Abnormal birefringence phenomena, including irregular extinction patterns, petaloid and radial extinction patterns, and banded birefringence, were formed during the diamond growth stage. In contrast, fine grid extinction patterns and composite superimposed extinction patterns are related to later plastic deformation. The studied diamonds mainly contain P-type inclusions of olivine and graphite, with a minority of E-type inclusions, including coesite and omphacite. The pressure of entrapment of olivine inclusions within the Tancheng diamonds ranges from 4.3 to 5.9 GPa, which is consistent with that of coesite inclusions, which yield pressure ranging from 5.2 to 5.5 GPa, and a temperature range of 1083–1264 °C. Overall, the evidence suggests that Tancheng diamonds probably originated from hybrid mantle sources metasomatized by the subduction of ancient oceanic lithosphere. Full article

We present and demonstrate a highly birefringent fiber Bragg grating (Hi-Bi FBG) that was fabricated using a femtosecond laser to induce a sawtooth stress region near the FBG. The FBG is fabricated with a femtosecond laser point-by-point method, while the sawtooth stress region is generated in fiber cladding using the femtosecond laser along a sawtooth path. This sawtooth stressor can introduce an anisotropic and asymmetric refractive index profile in the cross-section of the fiber, resulting in additional birefringence up to 2.97 × 10⁻⁴ along the axial direction of the FBG. The central wavelengths of the Hi-Bi FBG at the fast and slow axes exhibit different sensitivities to temperature and strain, allowing simultaneous measurement of the strain and temperature by tracking the resonant wavelength shifts in the two axes. The experimental results show that the temperature sensitivities of the fast and slow axes are 10.32 pm/°C and 10.42 pm/°C, while the strain sensitivities are 0.91 pm/µε and 0.99 pm/µε. The accuracy of this proposed sensor in measuring strain and temperature is estimated to be 2.2 µε and 0.2 °C. This approach addresses the issue of cross-sensitivity between temperature and strain and offers some advantages of low cost, compact size, and significant potential for advancements in practical multi-parameter sensing applications. Full article

Silicon photonics is the leading platform in photonic integrated circuits (PICs), enabling dense integration and low-cost manufacturing for applications such as data communications, artificial intelligence, and quantum processing, to name a few. However, efficient and polarization-insensitive fiber-to-PIC coupling for multipoint wafer characterization remains a challenge due to the birefringence of silicon waveguides. Here, we address this issue by proposing polarization-insensitive grating couplers based on subwavelength dielectric metamaterials and metaheuristic optimization. Subwavelength periodic structures were engineered to act as uniaxial homogeneous linear (UHL) materials, enabling tailored anisotropy. On the other hand, particle swarm optimization (PSO) was employed to optimize the coupling efficiency, bandwidth, and polarization-dependent loss (PDL). Numerical simulations demonstrated that a pitch of 100 nm ensures UHL behavior while minimizing leaky waves. Optimized grating couplers achieved coupling efficiencies higher than −3 dB and a PDL of below 1 dB across the telecom C-band (1530–1565 nm). Three optimization strategies were explored, balancing efficiency, the bandwidth, and the PDL while considering the Pareto front. This work establishes a robust framework combining metamaterial engineering with computational optimization, paving the way for high-performance polarization-insensitive grating couplers with potential uses in advanced photonic applications. Full article

Liquid crystals based on dispersions of two-dimensional (2D) materials have recently been developed for light modulation, exhibiting superior performances compared to conventional organic liquid crystals in a variety of prototypical applications, including coloration, solar-blind communications and blue-light fluoresce. Among the diverse family of 2D liquid crystals, vermiculite-based liquid crystals stand out with advantages in low cost, ease of mass production and environmental sustainability, owing to the high natural abundance of the material. Here, we demonstrated magnetic-field tunable optics with 2D vermiculite dispersions prepared through a facile ‘exchange and redispersion’ method. By exploiting the intrinsic ion-exchange capability of clay minerals, we observed a significantly enhanced magneto-birefringence of the vermiculite dispersion upon replacing the native cations with magnetic ions, manifesting in a doubled Cotton–Mouton coefficient, representing the highest value among previous reports. Magnetization measurements reveal that there is a remarkable magnetic anisotropy in Fe ion-exchanged vermiculite samples in contrast to the isotropic magnetism of pristine vermiculite, which accounts for the observed enhancement of magneto-birefringence. Our findings demonstrate that ion exchange can serve as a simple and effective strategy to modulate the physical and chemical properties of 2D materials’ dispersions, thereby opening avenues for broader and more diverse applications. Full article

Early-life nutrition is crucial for healthy infant development. This study explored the effects of high-temperature (30 min, 121 °C) and high-humidity treatments on the starch properties and digestibility of infant purees made from wheat, rice, and maize. Purees were prepared using whole grains (WGs), whole grain flours (WGFs), and flour suspensions (FSs) subjected to thermal treatment. Untreated whole grain samples from each cereal served as controls. Samples were analyzed for microstructure, thermal properties, viscosity, and starch digestibility. Microstructural analysis revealed partial to complete loss of amyloplast birefringence, particularly in FS. The thermal treatment reduced peak viscosity in WGs, WGFs, and FSs. Also, the flour suspensions showed lower thermal stability and a phytic acid content reduction of 30%. In vitro digestion revealed a significant reduction in total hydrolyzed starch (THS) in wheat- (27.8 g/100 g starch) and maize- (11.3 g/100 g starch) WG purees compared to controls. In contrast, WGF purees showed significant increases in THS: 29% (wheat), 70% (rice), and 92% (maize). FS purees also showed significant increases in THS (57.4, 39.3, and 45.4 g/100 g starch for wheat, rice, and maize, respectively), alongside a decrease in resistant starch. In conclusion, thermal treatment modulates starch digestibility and viscosity properties in a cereal-dependent manner, offering a potential approach to optimize infant nutrition. Full article

Optical differential operations can directly extract edge information from images and have significant application potential in fields such as image processing and object recognition. In this work, we propose an optical spatial differentiator based on the birefringence effect of uniaxial crystals. The system comprises two orthogonal polarizers and a uniaxial crystal, offering advantages of structural simplicity, operational stability, low cost, and seamless compatibility with conventional optical systems. Experimental results demonstrate that the proposed differentiator achieves clear edge imaging for both amplitude and phase objects, while also enabling dark-field differential imaging of transparent biological cells, thereby substantially enhancing imaging quality and contrast. This efficient and robust design provides a promising solution for advancing optical differentiation techniques in applications ranging from data processing to biomedical imaging. Full article

In the argillic alteration zone of the SinAbad area of the Urumieh–Dokhtar magmatic belt (Iran), Mg-rich, Fe-poor chlorites, which crystallised at temperatures between 160 °C and 260 °C, were affected by extensive alteration to smectite mixed-layering at the micro- and nano-scales during the retrograde evolution of the hydrothermal system. Chlorites retain their usual optical aspect and properties, except for the index of refraction perpendicular to the (001) layers, which becomes lower than those parallel to the layers, producing an increase in birefringence and change in the optic and elongation signs, in comparison to the ordinary ones for Mg chlorites. Scanning electron microscopy (SEM) maps and compositions, and electron microprobe (EMP) analyses indicate minor but ubiquitous Ca (and K) content. X-ray diffraction (XRD) of chloritic concentrates allowed the identification of chlorite and tosudite. High-resolution transmission electron microscopy (HRTEM) images show major 14 Å (chlorite), with the frequent presence of 24 Å (contracted tosudite) individual layers and small packets up to five layers thick. Lateral change from 14 Å to 24 Å individual layers has been visualised. High-resolution chemical maps obtained in high-angle annular dark-field (HAADF) mode confirm the existence of areas preferentially dominated by chlorite or tosudite. The overall chemical compositions obtained by SEM, EMP, and transmission electron microscopy (TEM) align from the chlorite to the tosudite end-members, whose pure compositions could be determined from extreme analytical electron microscopy (AEM) analyses. The described intergrowths and interlayers, under the optical resolution, could provide a clue to explain changes in the normal optic properties of chlorite, which are mentioned, but not explained, in the literature. Full article