Search Results (33)

The SPICAV IR spectrometer aboard the Venus Express orbiter measured spectra of the 1.1 and 1.18 μm atmospheric transparency windows at the Venus night side in 2006–2014. The long-term measurements encompassed the major part of the Venus globe, including polar latitudes. For the first time, the H₂O volume mixing ratio in the deep Venus atmosphere at about 10–16 km has been retrieved for the entire SPICAV IR dataset using a radiative transfer model with multiple scattering. The retrieved H₂O volume mixing ratio is found to be sensitive to different approximations of the H₂O and CO₂ absorption lines’ far wings and assumed surface emissivity. The global average of the H₂O abundance retrieved for different parameters ranges from 23.6 ± 1.0 ppmv to 27.7 ± 1.2 ppmv. The obtained values are consistent with recent studies of water vapor below the cloud layer, showing the H₂O mixing ratio below 30 ppmv. Within the considered dataset, the zonal mean of the H₂O mixing ratio does not vary significantly from 60° S to 75° N, except for a 2 ppmv decrease noted at high latitudes. The H₂O local time distribution is also uniform. The 8-year observation period revealed no significant long-term trends or periodicities. Full article

The thick cloud layer enshrouding Venus influences its thermal balance and climate evolution. However, our knowledge of total optical depth, spatial and temporal variations in the clouds is limited. We present the first complete study of the SPICAV IR spectrometer observations in the 1.28- and 1.31-µm atmospheric transparency windows during the Venus Express mission in 2006–2014. The nadir spectra were analyzed with one-dimensional multiple scattering radiative transfer model to obtain the variability of total cloud opacity on the Venus night side. The optical depth recomputed to 1 µm averages 36.7 with a standard deviation of 6.1. Cloud opacity depends on latitude, with a minimum at 50–55° N. In the Southern Hemisphere, this latitude dependence is less pronounced due to the reduced spatial resolution of the experiment, determined by the eccentricity of the spacecraft’s orbit. Cloud opacity exhibits strong variability at short time scales, mostly in the range of 25–50. The variability is more pronounced in the equatorial region. The lack of imaging capability limits the quantitative characterization of the periodicity. No persistent longitude or local time trends were detected. Full article

Cesium tungsten bronzes (Cs_xWO₃), as functional materials with excellent near-infrared shielding properties, demonstrate significant potential for applications in smart windows. However, traditional synthesis methods, such as solid-state reactions and solvothermal/hydrothermal approaches, typically require harsh conditions, including high temperatures (above 200 °C), high pressure, inert atmospheres, or prolonged reaction times. In this study, we propose an optimized microwave-assisted solvothermal synthesis strategy that significantly reduces the severity of reaction conditions through precise parameter control. When benzyl alcohol was employed as the solvent, Cs_xWO₃ nanoparticles could be rapidly synthesized within a relatively short duration of 15 min at 180 °C, or alternatively obtained through 2 h at a low temperature of 140 °C. However, when anhydrous ethanol, which is cost-effective and environmentally friendly, was substituted for benzyl alcohol, successful synthesis was also achieved at 140 °C in 2 h. This method overcomes the limitations of traditional high-pressure reaction systems, achieving efficient crystallization under low-temperature and ambient-pressure conditions while eliminating safety hazards and significantly improving energy efficiency. The resulting materials retain excellent near-infrared shielding performance and visible-light transparency, providing an innovative solution for the safe, rapid, and controllable synthesis of functional nanomaterials. Full article

Daytime radiative cooling, based on selective infrared emissions through atmospheric transparency windows to outer space and the reflection of solar irradiance, is a zero-energy and environmentally friendly cooling technology. Poly(ethylene oxide) (PEO) electrospun membranes have both selective mid-infrared emissions and effective sunlight reflection, inducing excellent daytime radiative cooling performance. However, PEO is highly water soluble, which makes electrospun PEO membranes unable to cope with rainy conditions when used for outdoor daytime radiative cooling. Herein, we report an in situ UV-crosslinking strategy for preparing PEO electrospun membranes with water resistance for the application of daytime radiative cooling. Acrylate-terminated PEO was synthesized and mixed together with cross-linking agents and photoinitiators to prepare the electrospinning solution. During electrospinning, the nanofibers were irradiated with UV light to initiate the cross-linking. For a membrane with a thickness of 200 μm, the average solar reflectance was 89.6%, and the infrared emissivity (8–13 μm) was 96.3%. Although slight swelling happens to the cross-linked membrane once it comes into contact with water, the fibrous morphology shows no obvious change when prolonging the water soaking time, indicating excellent water resistance. The outdoor cooling performance test results showed that compared to the average temperature of the air in the test box, the average temperature drop in the membrane before and after water soaking was 13.8 °C and 11.5 °C, respectively. Crosslinked PEO-based electrospun membranes with both water resistance and radiative cooling performance may have real applications for outdoor daytime radiative cooling. Full article

Passive daytime radiative cooling (PDRC) has emerged as a promising, electricity-free cooling approach that reflects sunlight while radiating heat through the atmospheric transparent window. However, the design and optimization of PDRC materials remain challenging, requiring significant time and resources for experimental and numerical modeling efforts. In this work, we developed a machine learning (ML)-driven approach to predict scattering efficiency in the wavelength of 0.3–2.5 μm, with the aim of eventually optimizing the microstructural design of PDRC materials. By employing ML models such as linear regression, neural networks, and random forests, we aimed to predict and optimize the scattering efficiency across different pore sizes and mixed-pore-size configurations. As a result, the random forest model demonstrated superior prediction performance with minimal error, effectively capturing complex, non-linear interactions between material features. We also leveraged data transformation techniques such as one-hot encoding for generative predictions in mixed-pore-size configurations. The presented ML-driven platform serves as a valuable open resource for PDRC researchers, facilitating the rapid and cost-effective optimization of PDRC materials and accelerating the development of sustainable cooling technologies. Full article

Germanium (Ge) is a system-forming material of IR photonics for the atmospheric transparency window of 8–14 µm. For optics of the 3–5 µm range, more widespread silicon (Si), which has phonon absorption bands in the long-wave region, is predominantly used. A technology for growing Ge single crystals has been developed, allowing the production of precision optical parts up to 500 mm in diameter. Ge is used primarily for the production of transparent optical parts for thermal imaging devices in the 8–14 µm range. In addition, germanium components are widely used in a large number of optical devices where such properties as mechanical strength, good thermal properties, and climatic resistance are required. A very important area of application of germanium is nonlinear optics, primarily acousto-optics. The influence of doping impurities and temperature on the absorption of IR radiation in germanium is considered in detail. The properties of germanium photodetectors are reported, primarily on the effect of photon drag of holes. Optical properties in the THz range are considered. The features of optical properties for all five stable isotopes of germanium are studied. The isotopic shift of absorption bands in the IR region, caused by phonon phenomena, which was discovered by the authors for the first time, is considered. Full article

Due to climate change, population increase, and the urban heat island effect (UHI), the demand for cooling energy, especially in urban areas, has increased and will further increase in the future. Technologies such as radiative cooling offer a sustainable and energy-free solution by using the wavelength ranges of the atmosphere that are transparent to electromagnetic radiation, the so-called atmospheric window (8–13 µm), to emit thermal radiation into the colder (3 K) outer space. Previous publications in the field of textile building cooling have focused on specific fiber structures and textile substrate materials as well as complex multi-layer constructions, which restrict the use for highly scaled outdoor applications. This paper describes the development of a novel substrate-independent coating with spectrally selective radiative properties. By adapting the coating parameters and combining low-emitting and solar-reflective particles, along with a matrix material emitting strongly in the mid-infrared range (MIR), substrate-independent cooling below ambient temperature is achieved. Moreover, the coating is designed to be easily applicable, with a low thickness, to ensure high flexibility and scalability, making it suitable for various applications such as membrane architecture, textile roofs, or tent construction. The results show a median daytime temperature reduction (7 a.m.–7 p.m.) of 2 °C below ambient temperature on a hot summer day. Full article

The telescope Mini-EUSO has been observing, since 2019, the Earth in the ultraviolet band (290–430 nm) through a nadir-facing UV-transparent window in the Russian Zvezda module of the International Space Station. The instrument has a square field of view of 44°, a spatial resolution on the Earth surface of 6.3 km and a temporal sampling rate of 2.5 microseconds. The optics is composed of two 25 cm diameter Fresnel lenses and a focal surface consisting of 36 multi-anode photomultiplier tubes, 64 pixels each, for a total of 2304 channels. In addition to the main camera, Mini-EUSO also contains two cameras in the near infrared and visible ranges, a series of silicon photomultiplier sensors and UV sensors to manage night-day transitions. Its triggering and on-board processing allow the telescope to detect UV emissions of cosmic, atmospheric and terrestrial origin on different time scales, from a few microseconds up to tens of milliseconds. This makes it possible to investigate a wide variety of events: the study of atmospheric phenomena (lightning, transient luminous events (TLEs) such as ELVES and sprites), meteors and meteoroids; the search for nuclearites and strange quark matter; and the observation of artificial satellites and space debris. Mini-EUSO is also potentially capable of observing extensive air showers generated by ultra-high-energy cosmic rays with an energy above 10²¹ eV and can detect artificial flashing events and showers generated with lasers from the ground. The instrument was integrated and qualified in 2019 in Rome, with additional tests in Moscow and final, pre-launch tests in Baikonur. Operations involve periodic installation in the Zvezda module of the station with observations during the crew night time, with periodic downlink of data samples, and the full dataset being sent to the ground via pouches containing the data disks. In this work, the mission status and the main scientific results obtained so far are presented, in light of future observations with similar instruments. Full article

This article presents the results of evaluating the possibility of conducting radio astronomy studies in the windows of atmospheric transparency ~100, ~230, and ~350 GHz using the optical Big Telescope Alt-Azimuthal (BTA) of the Special Astrophysical Observatory of the Russian Academy of Sciences (SAO RAS). A list of some promising astronomical tasks is proposed. The astroclimat conditions at the BTA site and possible optical, cryogenic, and mechanical interfaces for mounting a superconducting radio receiver at the focus of the optical telescope are considered. As a receiving system, arrays of detectors cooled to ~0.3 K based on the superconductor–insulator–normal metal–insulator–superconductor (SINIS) structure are proposed. The implementation of the project will make it possible to use the BTA site of the SAO RAS not only to solve some astronomical problems (it is possible to consider the implementation of a single observatory, the VLBI (very-long-baseline interferometry) mode in the Suffa, EHT (Event Horizon Telescope), and Millimetron projects), but it will also be used to test various cryogenic detectors in a real observatory. Full article

Accurate thermal infrared (TIR) fast-forward models are critical for weather forecasting via numerical weather prediction (NWP) satellite radiance assimilation and operational environmental data record (EDR) retrieval algorithms. The thermodynamic and compositional data about the surface and lower troposphere are derived from semi-transparent TIR window bands (i.e., surface-sensitive channels) that can span into the far-infrared (FIR) region under dry polar conditions. To model the satellite observed radiance within these bands, an accurate a priori emissivity is necessary for the surface in question, usually provided in the form of a physical or empirical model. To address the needs of hyperspectral TIR satellite radiance assimilation, this paper discusses the research, development, and preliminary validation of a physically based snow/ice emissivity model designed for practical implementation within operational fast-forward models such as the U.S. National Oceanic and Atmospheric Administration (NOAA) Community Radiative Transfer Model (CRTM). To accommodate the range of snow grain sizes, a hybrid modeling approach is adopted, combining a layer scattering model based on the Mie theory (viz., the Wiscombe–Warren 1980 snow albedo model, its complete derivation provided in the Appendices) with a specular facet model. The Mie-scattering model is valid for the smallest snow grain sizes typical of fresh snow and frost, whereas the specular facet model is better suited for the larger sizes and welded snow surfaces typical of aged snow. Comparisons of the model against the previously published spectral emissivity measurements show reasonable agreement across zenith observing angles and snow grain sizes, and preliminary observing system experiments (OSEs) have revealed notable improvements in snow/ice surface window channel calculations versus hyperspectral TIR satellite observations within the NOAA NWP radiance assimilation system. Full article

Radio astronomical observations at millimeter and submillimeter wavelengths are a very important tool for astrophysical research. However, there is a huge area in northeastern Eurasia, including the whole Russian territory, which lacks sufficiently large radio telescopes effectively operating at these wavelengths. In this review, we describe our long-term efforts to find suitable sites for such radio telescopes in this area, that is, sites with good atmospheric transparency at millimeter and submillimeter waves. We describe methods and instruments used for measurements and evaluations of the atmospheric opacity. They include special radiometric systems, which are used for estimations of the atmospheric opacity in the transparency windows from the sky brightness measurements. Evaluation of the precipitable water vapor from such measurements by the artificial neural network is discussed. Other approaches use water vapor radiometers, global atmospheric models and signals of the Global Navigation Satellite Systems. To date, long-term radiometric monitoring has been performed at several candidate sites, and atmospheric conditions for many sites have been evaluated using global atmospheric models. Several sites with the best atmospheric transparency at millimeter and submillimeter wavelengths have been selected. They can be effectively used for astronomical observations, at least in the major atmospheric transparency windows at 1.3 mm and 0.85 mm. In general, the results show that northeastern Eurasia is a promising area for submillimeter astronomy. These results can also be used for space communications and radar systems. Full article

Low-temperature synthesis of Bi₂Se₃ thin film semiconductor thermoelectric materials is prepared by the plasma-enhanced chemical vapor deposition method. The Bi₂Se₃ film demonstrated excellent crystallinity due to the Se-rich environment. Experimental results show that the prepared Bi₂Se₃ film exhibited 90% higher transparency in the mid-IR region, demonstrating its potential as a functional material in the atmospheric window. Excellent mobility of 2094 cm²/V·s at room temperature is attributed to the n-type conductive properties of the film. Thermoelectrical properties indicate that with the increase in Se vapor, a slight decrease in conductivity of the film is observed at room temperature with an obvious increase in the Seebeck coefficient. In addition, Bi₂Se₃ thin film showed an enhanced power factor of as high as 3.41 μW/cmK². Therefore, plasma-enhanced chemical vapor deposition (PECVD)-grown Bi₂Se₃ films on Al₂O₃ (001) substrates demonstrated promising thermoelectric properties. Full article

Fiber laser sources operating near 2300 nm in the atmospheric transparency window are interesting for different applications, such as remote sensing, lidars, and others. The use of Tm-doped fiber lasers based on tellurite fibers is highly promising. We propose and theoretically study a highly efficient diode-pumped Tm-doped zinc-tellurite fiber laser operating at two cascade radiative transitions at 1960 nm and 2300 nm, with additional energy transfer between these laser waves due to the Raman interaction. We demonstrate numerically that a dramatic increase in the slope efficiency up to 57% for the laser wave at 2300 nm, exceeding the Stokes limit by 22% relative to the pump at 793 nm, can be obtained with optimized parameters thanks to Raman energy transfer from the laser wave at 1960 nm to the wave at 2300 nm. Full article

Negative group delay may be observed in dispersive media with anomalous dispersion in a certain frequency range. The fact that an outgoing wave packet precedes an incoming one does not violate the causality principle but is only a consequence of a waveform reshaping. This effect is observed in media such as photonic crystals, hyperbolic and epsilon-near-zero metamaterials, undersized waveguides, subwavelength apertures, side-by-side prisms, and resonant circuits at various frequencies. The current work is devoted to the design of a simple negative-group-delay medium with tunable properties in the THz frequency range. This medium consists of a bismuth-based frequency-selective surface on a dielectric substrate and may be tuned both statically and dynamically. While a geometry variation defines a main form of an effective permittivity dispersion and group delay/group velocity spectra, an external voltage allows one to adjust them with high precision. For the configuration proposed in this work, all frequency regions with noticeable change in group delay/group velocity lie within atmospheric transparency windows, which are to be used in 6G communications. This medium may be applied to THz photonics for a tunable phase-shift compensation, dispersion management in systems of THz signal modulation, and for encoding in next-generation wireless communication systems. Full article

Daytime passive radiative cooling (DPRC) has remained a challenge over the past decades due to the necessity of precisely defined materials with a significantly high emissivity of thermal radiation within the atmospheric transparent window wavelength range (8–13 μm) as well as high reflectivity in the solar spectrum (0.2–3 μm). Fortunately, recent advances and technological improvements in nanoscience and metamaterials are making it possible to create diverse metamaterials. This enables the production of DPRC in direct solar irradiation. The development of a material that is appropriate for effective DPRC is also a noteworthy development in this field of technology. This review gives a thorough introduction and discussion of the fundamental ideas, as well as the state-of-the-art and current trends in passive radiative cooling, and describes the cutting-edge materials and various photonic radiator structures that are useful in enhancing net cooling performance. This work also addresses a novel skylight window that offers passive cooling developed at the Åbo Akademi (ÅA) University, Finland. In conclusion, nanomaterials and nanoparticle-based coatings are preferred over all other approaches for commercialization in the future because of their low cost, the ability for large-scale production, simplicity in fabrication, and great potential for further increasing cooling performance. Full article