Search Results (302)

Diabetes has become a global health challenge, driving the demand for innovative, non-invasive diagnostic technologies to improve glucose monitoring. Urinary glucose concentration, a reliable indicator of metabolic changes, provides a practical alternative for frequent monitoring without the discomfort of invasive methods. In this simulation-based study, we propose a novel asymmetric photonic structure that integrates Tamm plasmon polariton (TPP) modes and a cavity mode for high-precision refractive index sensing, with a conceptual focus on the potential detection of urinary glucose. The structure supports three distinct resonance modes, each with unique field localization. Both the TPP modes, confined at the metallic–dielectric interfaces, serve as stable references whose wavelengths are unaffected by refractive-index variations in human urine, whereas the cavity mode exhibits a redshift with increasing refractive index, enabling high responsiveness to analyte changes. The evaluation of sensing performance employs a sensitivity formulation that leverages either TPP mode as a reference and the cavity mode as a probe, thereby achieving dependable measurement and spectral stability. The optimized design achieves a sensitivity of 693 nm·RIU⁻¹ and a maximum figure of merit of 935 RIU⁻¹, indicating high detection resolution and spectral sharpness. The device allows both reflectance and transmittance measurements to ensure enhanced versatility. Moreover, the coupling between TPP and cavity modes demonstrates hybrid resonance, empowering applications such as polarization-sensitive or angle-dependent filtering. The figure of merit is analyzed further, considering resonance wavelength shifts and spectral sharpness, thus manifesting the structure’s robustness. Although this study does not provide experimental data such as calibration curves, recovery rates, or specificity validation, the proposed structure offers a promising conceptual framework for refractive index-based biosensing in human urine. The findings position the structure as a versatile platform for advanced photonic systems, offering precision, tunability, and multifunctionality beyond the demonstrated optical sensing capabilities. Full article

This paper comprehensively reports experimental proof of parity violation in the ground and photoexcited states of three mirror-symmetric Si–Si bond polymers in homogeneous solutions of achiral molecules under non-stirring conditions by analyzing 370 chiroptical datasets relating to multiple second-order helix–helix transitions in the circular dichroism (CD) of poly(di-i-butylsilane) (iBS), poly(di-i-pentylsilane) (iPS), and poly(di-i-hexylsilane) (iHS) in achiral alkanols and p-dioxane-h₈/-d₈. Particularly large (–)-CD of g_abs = −3.1 × 10⁻² at 290 nm was found for iBS in i-pentanol at 25 °C. Notably, iPS in n-propanol at −5 °C generated (–)-CD with g_abs = −0.48 × 10⁻² at 300 nm, but (+)-circularly polarized luminescence (CPL) with g_lum = +0.84 × 10⁻² at 326 nm. In contrast, iHS in n-octanol at 0 °C showed only very weak (–)-CD of g_abs ~−0.03 × 10⁻² at 310 nm. The H/D isotopes of p-dioxane-h₈/-d₈ weakly affected the helix–helix transition characteristics of iBS. (–)-Sign vibrational CD signals assigned to the handed symmetric and asymmetric bending modes of the CH₃ and CH₂ groups of the solvents and other achiral molecules were observed. We assumed (i) three ¹H nuclear-spin-1/2 induced handed motions of CH₃ rotors at i-alkyl side chains and achiral alkanols, and (ii) helical main-chain Si atoms (δ⁺) coordinated by handed lone pairs at oxygen (δ⁻) in gauche-containing n- and i-alkanols induced by the CH₃ rotors. A possible origin of biomolecular handedness is proposed based on the first observation of far-UV CD and UV spectra of zwitterionic glycine bearing H₃N⁺ rotor in neutral H₂O. Full article

Online aggression and abusive language on social media pose a growing threat to democratic discourse, as they contribute to polarization, delegitimization of political actors, and the erosion of civil debate. While much of the current research relies on computational methods to detect hate speech, fewer studies investigate how online aggression functions discursively in specific socio-political contexts. This study addresses this gap by analyzing patterns of verbal aggression on Facebook and Twitter during two key events in Poland in 2020: the presidential election and the Women’s Strike. Adopting a mixed-method approach (combining sentiment analysis, content analysis, and discourse analysis) and comparing two socio-political events that generated extensive online debate, this study investigates the patterns and communicative functions of hostile and aggressive language on Facebook and Twitter. The study reveals that neutral posts dominated both datasets, but negative and aggressive posts were significantly more frequent during the Women’s Strike, where verbal aggression was used not only to reinforce group identity but also to express moral outrage, trauma, and demands for change. In contrast, aggression during the election campaign was less frequent but more calculated. It functioned as a strategic tool to delegitimize political opponents and reinforce partisan divides. Users employed vitriolic language and profanity as rhetorical tools to undermine authority, reinforce group identity, and mobilize supporters. The study also reveals asymmetric patterns of aggression, with public figures and institutions, particularly the ruling party, Church, and police, being primary targets. The findings have significant implications for understanding the dynamics of online debates and aggression patterns in social media. Full article

Directed cell migration is crucial for numerous biological processes, including tissue regeneration and cancer metastasis. However, conventional symmetrical micropatterns typically result in bidirectional cell migration guidance instead of unidirectional guidance. In this study, polydimethylsiloxane (PDMS)-based platforms with asymmetrical arrowhead micropatterns, nanopillars, and selective fibronectin coating were developed to enhance unidirectional cell migration. The platforms were fabricated using nanoimprint lithography and PDMS replication techniques, allowing for precise control over surface topography and biochemical modification. The MC3T3 osteoblastic cells cultured on these platforms demonstrated significantly enhanced directional migration, characterized by increased displacement, and directional alignment with micropattern orientation compared to symmetrical patterns. Quantitative analyses revealed that asymmetrical arrowheads combined with nanopillars induced more focal adhesions and F-actin polarization at cell front regions, supporting the observed unidirectional cell migration enhancement. These results confirm that integrating micropattern asymmetry, nanoscale features, and biochemical functionalization synergistically promotes unidirectional cell migration. The developed platforms offer valuable insights and practical strategies for designing advanced biomaterials capable of precise spatial cell guidance that can be applied to the designs of organ-on-a-chip systems. Full article

The interfacial Dzyaloshinskii–Moriya interaction (DMI) plays a pivotal role in stabilising and controlling the motion of chiral spin textures, such as Néel-type bubble domains, in ultrathin magnetic films—an essential feature for next-generation spintronic devices. In this work, we investigate domain wall (DW) dynamics in magnetron-sputtered Ta(3 nm)/Pt(3 nm)/Co(1 nm)/RuO₂(1 nm) [Ru(1 nm)]/Pt(3 nm) multilayers, benchmarking their behaviour against control stacks. Vibrating sample magnetometry (VSM) was employed to determine saturation magnetisation and perpendicular magnetic anisotropy (PMA), while polar magneto-optical Kerr effect (P-MOKE) measurements provided coercivity data. Kerr microscopy visualised the expansion of bubble-shaped domains under combined perpendicular and in-plane magnetic fields, enabling the extraction of effective DMI fields. Brillouin light scattering (BLS) spectroscopy quantified the asymmetric propagation of spin waves, and micromagnetic simulations corroborated the experimental findings. The Pt/Co/RuO₂ system exhibits a Dzyaloshinskii–Moriya interaction (DMI) constant of ≈1.08 mJ/m², slightly higher than the Pt/Co/Ru system (≈1.03 mJ/m²) and much higher than the Pt/Co control (≈0.23 mJ/m²). Correspondingly, domain walls in the RuO₂-capped films show pronounced velocity asymmetry under in-plane fields, whereas the symmetric Pt/Co/Pt shows negligible asymmetry. Despite lower depinning fields in the Ru-capped sample, its domain walls move faster than those in the RuO₂-capped sample, indicating reduced pinning. Our results demonstrate that integrating RuO₂ significantly alters interfacial spin–orbit interactions. Full article

This work develops an Updated Lagrangian Smoothed Particle Hydrodynamics (ULSPH) framework to simulate high-speed icebreaking by a hemispherically capped cylinder (HCC). Using a self-programmed C++ code with Drucker–Prager damage criteria, this work systematically analyzes how impact velocity (100–200 m/s), ice thickness (10–40 cm), and impact angle (60–90°) govern structural loads and ice failure modes. The head of the HCC is always the stress concentration area, and the peak value of the impact force increases non-linearly with increasing the initial velocity from 100 m/s to 200 m/s. The increase in ice layer thickness from 10 cm to 40 cm raises the peak value of the impact force by 18.1%. The ice layer deformation shows three-stage characteristics: collision depression, penetration perforation, and through-spray. When the impact angle α is non-vertical, the strain of the ice layer is asymmetrically distributed, and the component of the peak impact force along the y direction increases significantly with the decrease in the impact angle, reaching 129.3 kN at α = 60°. Results reveal velocity-driven nonlinear force amplification, asymmetric strain distribution at oblique angles, and critical stress concentration at the HCC head, providing design insights for polar equipment. Full article

In this paper, a low loss and high polarization-maintaining single-mode hollow-core anti-resonant fiber (PM-HC-ARF) is designed. The elliptical core in the PM-HC-ARF is formed by strategically enlarging selected cladding air holes along the y-axis. Additionally, the variations in the wall thickness in both the x and y directions generate the distinct surface modes. By simultaneously employing an elliptical core and asymmetric core-wall thickness, we enhance the phase birefringence. Theoretical analysis results show that the proposed PM-HC-ARF achieves a transmission loss of 0.00082 dB/m at wavelength 1450 nm, along with a birefringence of 1.38 × 10⁻⁴; it demonstrates CL levels an order of magnitude below state-of-the-art polarization-maintaining HC-ARFs. Moreover, within the S+C+L+U communication bands, it achieves a bandwidth exceeding 380 nm (1420–1800 nm) while maintaining a birefringence of greater than 1.45 × 10⁻⁴. In particular, this PM-HC-ARF demonstrates a maximum higher-order mode extinction ratio of over 32,070; the single-mode transmission characteristics are excellent, along with exceptional bending resistance characteristics. When the bending radius exceeds 3 cm, the impacts on the loss and birefringence are negligible; this also demonstrates that the fiber structure shows good robustness when subjected to harsh environment interference. The proposed PM-HC-ARF is believed to have important applications in fiber optic gyroscopes, optical amplifiers, and hydrophones. Full article

Anti-resonant hollow-core fibers have exhibited excellent performance in applications such as high-power pulse transmission, network communication, space exploration, and precise sensing. Employing anti-resonant hollow-core fibers instead of light guiding arms for transmitting laser energy at the 2.79 μm band can significantly enhance the flexibility of medical laser handles, reduce system complexity, and increase laser transmission efficiency. Nevertheless, common anti-resonant hollow-core fibers do not have the ability to maintain the polarization state of light during laser transmission, which greatly affects their practical applications. In this paper, we propose a polarization-maintaining anti-resonant hollow-core fiber applicable for transmission at the mid-infrared 2.79 μm band. This fiber features a symmetrical geometric structure and an asymmetric refractive index cladding composed of quartz and a type of mid-infrared glass with a higher refractive index. Through optimizing the fiber structure at the wavelength scale, single-polarization transmission can be achieved at the 2.79 μm wavelength, with a polarization extinction ratio exceeding 1.01 × 10⁵, indicating its stable polarization-maintaining performance. Simultaneously, it possesses low-loss transmission characteristics, with the loss in the x-polarized fundamental mode being less than 9.8 × 10⁻³ dB/m at the 2.79 µm wavelength. This polarization-maintaining anti-resonant hollow-core fiber provides a more reliable option for the light guiding system of the 2.79 μm Er; Cr: YSGG laser therapy device. Full article

The rational design of high-performance microwave absorbers with broadband coverage, superior attenuation, and environmental durability is critical for addressing challenges in both defense and civilian technologies. High-entropy alloys (HEAs) exhibit atomic-scale asymmetric arrangements, demonstrating exceptional potential for microwave absorption through their unique lattice distortion, high entropy, sluggish diffusion, and “cocktail effect”. This critical review article provides an overview of the progress made in the development and understanding of HEA-based microwave absorbing materials. Initially, the microwave dissipation mechanisms for HEAs were analyzed, where atomic-scale distortions enhance polarization loss and broaden resonance bandwidth. Subsequently, key synthesis techniques like mechanical alloying and carbothermal shock are discussed, highlighting non-equilibrium processing for phase engineering. Building on these foundations, the discussion then progresses to evaluate four principal material design approaches: (1) compositionally-tuned powders, (2) multifunctional core–shell structures, (3) phase-controlled architectures, and (4) two-dimensional/porous configurations, each demonstrating distinct performance advantages. Finally, the discussion concludes by addressing current challenges in quantitative property modeling and industrial scalability while outlining future directions, including machine learning-assisted design and flexible integration, providing comprehensive guidance for developing next-generation high-performance microwave absorbing materials. Full article

A square patch metasurface is designed, simulated, fabricated, and experimentally tested to investigate polarization characteristics quantitatively. The metasurface consists of one layer unit cell in the form of a square patch with one via and a lumped resistor, which is used for harvesting RF (radio frequency) energy. FR4 dielectric is used as a substrate supported by a metal ground plane. Polarization-dependent properties with specific surface current patterns and voltage dip are obtained when simulating under normal incidence of a plane wave. This characteristic results from changes in surface current conditions when the polarization angle is varied. A voltage dip appears at a specific polarization angle when the surface current pattern is symmetrical. This condition occurs when the position of the lumped resistor from the center of the patch is perpendicular to the linearly polarized incident electric field. A couple of 10 × 10 arrays with different resistor positions are fabricated and tested. The experimental results are in good agreement with the simulated results. The proposed design demonstrates a symmetric unit cell structure with one via and a resistor that exhibits polarization-dependent behavior for linear polarization. An asymmetric patch design is explored through both simulation and measurement to mitigate polarization dependence by suppressing the dip behavior, albeit at the expense of reduced absorption efficiency. This study provides a complete polarization analysis for both symmetric and asymmetric patch metasurfaces with a single via and a single lumped resistor, and introduces a predictive relation between the position of the resistor relative to the center of the patch and the resulting voltage dip behavior. Full article

Designing advanced electrode architectures with tailored morphology and redox synergy is essential for achieving high-performance supercapacitive energy storage. In this study, a PVP-assisted hydrothermal approach was employed to synthesize binder-free NiCo₂O₄ nanostructured electrodes directly on nickel foam substrates. By modulating the PVP concentration (0.5–2 wt%), hierarchical flower-like nanosheets were engineered, with the NiCo-P₁ sample (1 wt% PVP) exhibiting an optimized structure, superior electroactive surface area, and enhanced ion accessibility. Comprehensive electrochemical analysis revealed that NiCo-P₁ delivered an outstanding areal capacitance of 36.5 F/cm² at 10 mA/cm², along with excellent cycling stability over 15,000 cycles with 80.97% retention. Kinetic studies confirmed dominant diffusion-controlled redox behavior with high OH⁻ diffusion coefficients and minimal polarization. An asymmetric pouch-type supercapacitor device (NiCo-P₁//AC) exhibited a wide operating window of 1.5 V, achieving a remarkable areal capacitance of 187 mF/cm², energy density of 0.058 mWh/cm², and capacitive retention of 78.78% after 5000 cycles. The superior performance is attributed to the synergistic integration of mixed-valence Ni and Co species, engineered nanosheet morphology, and low interfacial resistance. This work underscores the significance of surfactant-directed design in advancing cost-effective, high-performance electrodes for next-generation flexible energy storage technologies. Full article

Symmetrical bearing raceway led to the axial sliding of rolling elements, which is a crucial factor in shortening the operational lifespan. This study addresses this limitation through three-step advancements: first, a parametric equation for logarithmic spiral raceways is developed by analyzing their asymmetric geometric features; second, based on the geometrical model, we systematically investigate the parameters of the logarithmic spiral that affects the bearing performance metrics; and finally, a novel fatigue life prediction framework that integrates static mechanical analysis with raceway parameters establishes the theoretical foundation for optimizing the raceway parameters. The results of the model analysis show that the error of the maximum contact stress verified by the finite element method is less than 8.3%, which verifies the model’s accuracy. Increasing the contact angle α of the outer ring from 82 to 85 can increase fatigue life by 15.6 times while increasing the initial polar radius O of the inner ring from 7.8 mm to 8.1 mm will cause fatigue life to drop by 86.9%. The orthogonal experiment shows that the contact angle α of the outer ring has the most significant influence on the service life, and the optimal parameter combination (clearance δ of 0.02 mm, inner race and outer race strike angles α of 85°, an inner race initial polar radius $r_o$ of 7.8 mm, and an outer race initial polar radius $r_o$ of 7.9 mm) achieves a 60.7% fatigue life increase. The findings provide theoretical support and parameter guidance for the optimal bearing design with logarithmic spiral raceways. Full article

The flight feather rachis is a lightweight, anisotropic structure that must withstand asymmetric aerodynamic loads generated during flapping flight—particularly under unidirectional compression during the wing downstroke. To accommodate this spatiotemporal loading regime, the rachis exhibits refined internal organization, especially along the dorsoventral axis. In this study, we used finite element modeling (FEM) to investigate how dorsoventral polarization in cortical keratin allocation modulates the mechanical performance of shaft-like structures under bending. All models were constructed with conserved second moments of area and identical material properties to isolate the effects of spatial material placement. We found that dorsal-biased reinforcement delays yield onset, enhances strain dispersion, and promotes elastic recovery, while ventral polarization leads to premature strain localization and plastic deformation. These outcomes align with the dorsally thickened rachises observed in flight-specialized birds and reflect their adaptation to asymmetric aerodynamic forces. In addition, we conducted a conceptual exploration of radial (cortex–medulla) redistribution, suggesting that even inner–outer asymmetry may contribute to directional stiffness tuning. Together, our findings highlight how the flight feather rachis integrates cortical material asymmetry to meet directional mechanical demands, offering a symmetry-informed framework for understanding biological shaft performance. Full article

We propose a tunable multi-functional metamaterial composed of two pairs of gold corner resonators interconnected with photosensitive silicon, operating in the terahertz range. This design achieves dual-band unidirectional reflectionlessness, polarization conversion, and asymmetric transmission for linearly polarized waves, regardless of whether the photosensitive silicon is in the insulating or conductivity state. When the photosensitive silicon transitions from the insulating state to the conductivity state, its conductivity increases significantly, resulting in a frequency shift phenomenon in the functional peak frequencies. Numerical simulations demonstrate the structure’s robust performance in dual-band unidirectional reflectionlessness and its significant asymmetric transmission, with minimal sensitivity to variations in the incident angle and photosensitive silicon sheet length. By integrating multiple functionalities and enabling frequency tunability through the control of photosensitive silicon conductivity, this design offers a reconfigurable solution for THz applications, such as switches, polarization converters, and modulators. Full article

This work presents a theoretical and numerical investigation of a switchable tri-functional terahertz metamaterial incorporating vanadium dioxide (VO₂) and photosensitive silicon. The selective absorption, broadband linear-to-linear polarization conversion, and dual-band asymmetric transmission (AT) can be realized by utilizing the phase transition characteristic of VO₂. When VO₂ behaves as a metal, the proposed metamaterial functions as a selective perfect absorber for x-polarized waves at 2.84 THz, while exhibiting near-zero absorption for y-polarized waves. When VO₂ is in its insulating state, the proposed metamaterial acts as a linear polarization converter, achieving a polarization conversion ratio exceeding 99% within the frequency range of 1.07 to 4.29 THz. Meanwhile, a dual-band AT effect can be simultaneously realized associated with the broadband near-perfect polarization conversion. Furthermore, the polarization conversion efficiency and AT can be actively modulated by adjusting the conductivity of the photosensitive silicon, offering a novel approach for realizing multifunctional terahertz devices. Full article