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Keywords = air-coupled ultrasound

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10 pages, 1904 KB  
Article
Resonant Ultrasound Spectroscopy Detection Using a Non-Contact Ultrasound Microphone
by Jake Pretula, Nolan Shaw, Ayden Chen, Kyle G. Scheuer and Ray G. DeCorby
Sensors 2025, 25(19), 6154; https://doi.org/10.3390/s25196154 - 4 Oct 2025
Viewed by 874
Abstract
We observed vibrational eigenmodes for a variety of millimeter-scale objects, including glass and sapphire lenses, by placing them on a piezoelectric ‘shaker’ driven by a broadband noise or frequency sweep signal, and using an optomechanical microphone to pick up their vibrational signatures emitted [...] Read more.
We observed vibrational eigenmodes for a variety of millimeter-scale objects, including glass and sapphire lenses, by placing them on a piezoelectric ‘shaker’ driven by a broadband noise or frequency sweep signal, and using an optomechanical microphone to pick up their vibrational signatures emitted into the surrounding air. High-quality vibrational modes were detected over the ~0–8 MHz range for a typical object–microphone spacing of 1–10 mm. The observed eigenfrequencies are shown to be in excellent agreement with numerical predictions. Non-contact detection of resonant vibrational eigenmodes in the MHz ultrasound range could find application in the quality control of numerous industrial parts, such as ball bearings and lenses. Full article
(This article belongs to the Special Issue The Evolving Landscape of Ultrasonic Sensing and Testing)
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22 pages, 30478 KB  
Article
Influence of Multiaxial Loading and Temperature on the Fatigue Behaviour of 2D Braided Thick-Walled Composite Structures
by Tim Luplow, Jonas Drummer, Richard Protz, Linus Littner, Eckart Kunze, Sebastian Heimbs, Bodo Fiedler, Maik Gude and Marc Kreutzbruck
J. Compos. Sci. 2025, 9(9), 481; https://doi.org/10.3390/jcs9090481 - 4 Sep 2025
Viewed by 1210
Abstract
While size effects in composite structures have been widely studied under quasi-static uniaxial loading, their influence under fatigue conditions, particularly in the presence of multiaxial stress states and elevated temperatures, remains insufficiently understood. This study investigates the fatigue behaviour of thick-walled [...] Read more.
While size effects in composite structures have been widely studied under quasi-static uniaxial loading, their influence under fatigue conditions, particularly in the presence of multiaxial stress states and elevated temperatures, remains insufficiently understood. This study investigates the fatigue behaviour of thick-walled ±45 braided glass fibre-reinforced polyurethane composite box structures under varying temperature and loading conditions. A combined experimental approach is adopted, coupling quasi-static and fatigue tests on large-scale structures with reference data from standardised coupon specimens. The influence of temperature (23–80 °C) and multiaxial shear–compression loading is systematically evaluated. The results demonstrate a significant temperature-dependent decrease in compressive strength and fatigue life, with a linear degradation trend that aligns closely between the box structure and coupon data. Under moderate multiaxial conditions, the fatigue life of box structures is not significantly impaired compared to uniaxial test coupon specimens. Complementary non-destructive testing using air-coupled ultrasound confirms these trends, demonstrating that guided-wave phase-velocity measurements capture the evolution of anisotropic damage and are therefore suitable for in situ structural health monitoring applications. Furthermore, these findings highlight that (i) the temperature-dependent fatigue behaviour of thick-walled composites can be predicted using small-scale coupon data and (ii) small shear components have a limited impact on fatigue life within the studied loading regime. Full article
(This article belongs to the Section Fiber Composites)
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13 pages, 7320 KB  
Article
Determination of Main Bearing Dynamic Clearance in a Shield Tunneling Machine Through a Broadband PMUT Array with a Decreased Blind Area and High Accuracy
by Guoxi Luo, Haoyu Zhang, Delai Liu, Wenyan Li, Min Li, Zhikang Li, Lin Sun, Ping Yang, Ryutaro Maeda and Libo Zhao
Sensors 2025, 25(13), 4182; https://doi.org/10.3390/s25134182 - 4 Jul 2025
Cited by 1 | Viewed by 833
Abstract
Traditional PMUT ultrasonic ranging systems usually possess a large measurement blind area under the integrated transmit–receive mode, dramatically limiting its distance measurement in confined spaces, such as when determining the clearance of large bearing components. Here, a broadband PMUT rangefinder was designed by [...] Read more.
Traditional PMUT ultrasonic ranging systems usually possess a large measurement blind area under the integrated transmit–receive mode, dramatically limiting its distance measurement in confined spaces, such as when determining the clearance of large bearing components. Here, a broadband PMUT rangefinder was designed by integrating six types of different cells with adjacent resonant frequencies into an array. Through overlapping and coupling of the bandwidths from the different cells, the proposed PMUTs showed a wide –6 dB fractional bandwidth of 108% in silicon oil. Due to the broadening of bandwidth, the device could obtain the maximum steady state with less excitation (5 cycles versus 14 cycles) and reduce its residual ring-down (ca. 6 μs versus 15 μs) compared with the traditional PMUT array with the same cells, resulting in a small blind area. The pulse–echo ranging experiments demonstrated that the blind area was effectively reduced to 4.4 mm in air or 12.8 mm in silicon oil, and the error was controlled within ±0.3 mm for distance measurements up to 250 mm. In addition, a specific ultrasound signal processing circuit with functions of transmitting, receiving, and processing ultrasonic waves was developed. Combining the processing circuit and PMUT device, the system was applied to determine the axial clearance of the main bearing in a tunneling machine. This work develops broadband PMUTs with a small blind area and high resolution for distance measurement in narrow and confined spaces, opening up a new path for ultrasonic ranging technology. Full article
(This article belongs to the Section Industrial Sensors)
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20 pages, 4396 KB  
Article
Defect Detection in Wood Using Air-Coupled Ultrasonic Technique Based on Golay Code
by Jun Wang, Tianyou Xu and Hongyan Zou
Sensors 2025, 25(10), 3168; https://doi.org/10.3390/s25103168 - 17 May 2025
Viewed by 1778
Abstract
Air-coupled ultrasound overcomes the limitations of traditional contact-based ultrasonic methods that rely on liquid couplants. Still, it faces challenges due to the acoustic impedance mismatch between air and wood, causing significant signal scattering and attenuation. This results in weak transmission signals contaminated by [...] Read more.
Air-coupled ultrasound overcomes the limitations of traditional contact-based ultrasonic methods that rely on liquid couplants. Still, it faces challenges due to the acoustic impedance mismatch between air and wood, causing significant signal scattering and attenuation. This results in weak transmission signals contaminated by clutter and noise, compromising measurement accuracy. This study proposes a coded pulse air-coupled ultrasonic method for detecting defects in wood. The method utilizes Golay code complementary sequences (GCCSs) to generate excitation signals, with its feasibility validated through mathematical analysis and simulations. A-scan imaging was performed to analyze the differences in signal characteristics between defective and non-defective areas, while C-scan imaging facilitated a quantitative assessment of defects. Experimental results demonstrated that GCCS-enhanced signals improved the ultrasonic penetration and axial resolution compared to conventional multi-pulse excitation. The method effectively identified defects such as knots and pits, achieving a coincidence area of 85% and significantly enhancing the detection accuracy. Full article
(This article belongs to the Special Issue Novel Sensors for Structural Health Monitoring: 2nd Edition)
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14 pages, 3273 KB  
Article
Improved Autogenous Healing of Concrete with Superabsorbent Polymers Evaluated Through Coupled and Air-Coupled Ultrasound
by Gerlinde Lefever
Buildings 2025, 15(10), 1691; https://doi.org/10.3390/buildings15101691 - 17 May 2025
Cited by 1 | Viewed by 802
Abstract
Superabsorbent polymers have been introduced into cementitious materials to solve issues related to early-age cracking, caused by shrinkage, and manual repair. A general improvement of autogenous healing is noticed, while the extent and effectiveness depend on the type of hydrogel and the amount [...] Read more.
Superabsorbent polymers have been introduced into cementitious materials to solve issues related to early-age cracking, caused by shrinkage, and manual repair. A general improvement of autogenous healing is noticed, while the extent and effectiveness depend on the type of hydrogel and the amount included. To evaluate the self-healing effectiveness, the regain of mechanical performance needs to be assessed. However, such evaluation requires destructive testing, meaning that the healing progress cannot be followed over time. As a solution, air-coupled ultrasonic testing was used within this study, adopting a novel laser interferometer as a receiver, to estimate the regained properties of cementitious mixtures with and without superabsorbent polymers. The sensitivity of ultrasonic waves to the elastic properties of the material under study allows us to monitor the crack healing progress, while the semi-contactless nature of the procedure enables an easy and reliable measurement. Up to 80% recovery in ultrasonic velocity was achieved with reference concrete, while SAP concrete demonstrated up to 100% recovery after wet–dry curing. Following microscopic analysis, up to 19% visual crack closure was obtained for reference concrete, compared to a maximum of 50% for SAP mixtures, for average crack widths between 250 µm and 450 µm. Full article
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14 pages, 5479 KB  
Article
Spectral Content Effects Study in Non-Contact Resonance Ultrasound Spectroscopy
by Muhammad Tayyib and Linas Svilainis
Sensors 2025, 25(1), 265; https://doi.org/10.3390/s25010265 - 5 Jan 2025
Viewed by 3589
Abstract
The application of spread-spectrum signals (arbitrary pulse width and position (APWP) sequences) in air-coupled resonant ultrasound spectroscopy is studied. It was hypothesized that spread-spectrum signal optimization should be based on te signal to noise ratio (SNR). Six APWP signal optimization criteria were proposed [...] Read more.
The application of spread-spectrum signals (arbitrary pulse width and position (APWP) sequences) in air-coupled resonant ultrasound spectroscopy is studied. It was hypothesized that spread-spectrum signal optimization should be based on te signal to noise ratio (SNR). Six APWP signal optimization criteria were proposed for this purpose. Experimental measurements were conducted using a thin polycarbonate sample using two standard spread-spectrum signals, linear and nonlinear frequency modulation, together with six optimized APWP signals. It was found that the performance of APWP signals derived from linear frequency modulation was better. The two best performing optimization criteria are SNR improvement on a linear scale with the SNR as an additional weight and energy improvement on a dB scale. The influence of spectral coverage on measurement errors was evaluated. It was found that it is sufficient to cover the sample resonance peak and the valley. The lowest error rates for density, 3%, and for thickness, 3.5%, were achieved when the upper valley was covered. For velocity, the best result, 5%, was achieved when the lower valley was covered. The lowest error rate for attenuation, 3.8%, was achieved in the case when both valleys were covered. Yet no significant performance degradation was noted when a whole −30 dB passband was covered. Full article
(This article belongs to the Section Sensors Development)
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16 pages, 4946 KB  
Article
A Composite Pulse Excitation Technique for Air-Coupled Ultrasonic Detection of Defects in Wood
by Jun Wang, Changsen Zhang, Maocheng Zhao, Hongyan Zou, Liang Qi and Zheng Wang
Sensors 2024, 24(23), 7550; https://doi.org/10.3390/s24237550 - 26 Nov 2024
Cited by 3 | Viewed by 1756
Abstract
To overcome the problems of the low signal-to-noise ratio and poor performance of wood ultrasonic images caused by ring-down vibrations during the ultrasonic quality detection of wood, a composite pulse excitation technique using a wood air-coupled ultrasonic detection system is proposed. Through a [...] Read more.
To overcome the problems of the low signal-to-noise ratio and poor performance of wood ultrasonic images caused by ring-down vibrations during the ultrasonic quality detection of wood, a composite pulse excitation technique using a wood air-coupled ultrasonic detection system is proposed. Through a mathematical analysis of the output of the ultrasonic transducer, the conditions necessary for implementing composite pulse excitation were analyzed and established, and its feasibility was verified through COMSOL simulations. Firstly, wood samples with knot and pit defects were used as experimental samples. We refined the parameters for the composite pulse excitation technique by conducting A-scan measurements on both defective and non-defective areas of the samples. Moreover, two stepper motors were employed to control the path for C-scan imaging to detect wood defects. The experiment results showed that the composite pulse excitation technique significantly enhanced the precision of nondestructive ultrasonic testing for wood defects compared to the traditional single-pulse excitation method. This technique successfully achieved precise detection and location of pit defects, with a detection accuracy rate of 90% for knot defects. Full article
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16 pages, 5316 KB  
Article
Intelligent Optimization Design of a Phononic Crystal Air-Coupled Ultrasound Transducer
by Jianghai Wang, Huawei Ji, Anqi Qi, Yu Liu, Liming Lin, Xin Wu and Jing Ni
Materials 2023, 16(17), 5812; https://doi.org/10.3390/ma16175812 - 24 Aug 2023
Cited by 6 | Viewed by 2105
Abstract
To further improve the operational performance of a phononic crystal air-coupled ultrasonic transducer while reducing the number of simulations, an intelligent optimization design strategy is proposed by combining finite element simulation analysis and artificial intelligence (AI) methods. In the proposed strategy, the structural [...] Read more.
To further improve the operational performance of a phononic crystal air-coupled ultrasonic transducer while reducing the number of simulations, an intelligent optimization design strategy is proposed by combining finite element simulation analysis and artificial intelligence (AI) methods. In the proposed strategy, the structural design parameters of 1–3 piezoelectric composites and acoustic impedance gradient matching layer are sampled using the optimal Latin hypercube sampling (OLHS) method. Moreover, the COMSOL software is utilized to calculate the performance parameters of the transducer. Based on the simulation data, a radial basis function neural network (RBFNN) model is trained to establish the relationship between the design parameters and the performance parameters. The accuracy of the approximation model is verified through linear regression plots and statistical methods. Finally, the NSGA-II algorithm is used to determine the design parameters of the transducer. After optimization, the band gap widths of the piezoelectric composites and acoustic impedance gradient matching layer are increased by 16 kHz and 13.5 kHz, respectively. Additionally, the −6 dB bandwidth of the transducer is expanded by 11.5%. The simulation results and experimental results are consistent with the design objectives, which confirms the effectiveness of the design strategy. This work provides a feasible strategy for the design of high-performance air-coupled ultrasonic transducers, which is of great significance for the development of non-destructive testing technology. Full article
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97 pages, 144318 KB  
Article
A Review on Acoustics of Wood as a Tool for Quality Assessment
by Voichita Bucur
Forests 2023, 14(8), 1545; https://doi.org/10.3390/f14081545 - 28 Jul 2023
Cited by 27 | Viewed by 6871
Abstract
Acoustics is a field with significant application in wood science and technology for the classification and grading, through non-destructive tests, of a large variety of products from standing trees to building structural elements and musical instruments. In this review article the following aspects [...] Read more.
Acoustics is a field with significant application in wood science and technology for the classification and grading, through non-destructive tests, of a large variety of products from standing trees to building structural elements and musical instruments. In this review article the following aspects are treated: (1) The theoretical background related to acoustical characterization of wood as an orthotropic material. We refer to the wave propagation in anisotropic media, to the wood anatomic structure and propagation phenomena, to the velocity of ultrasonic waves and the elastic constants of an orthotropic solid. The acoustic methods for the determination of the elastic constants of wood range from the low frequency domain to the ultrasonic domain using direct contact techniques or ultrasonic spectroscopy. (2) The acoustic and ultrasonic methods for quality assessment of trees, logs, lumber and structural timber products. Scattering-based techniques and ultrasonic tomography are used for quality assessment of standing trees and green logs. The methods are based on scanning stress waves using dry-point-contact ultrasound or air-coupled ultrasound and are discussed for quality assessment of structural composite timber products and for delamination detection in wood-based composite boards. (3) The high-power ultrasound as a field with important potential for industrial applications such as wood drying and other applications. (4) The methods for the characterization of acoustical properties of the wood species used for musical instrument manufacturing, wood anisotropy, the quality of wood for musical instruments and the factors of influence related to the environmental conditions, the natural aging of wood and the effects of long-term loading by static or dynamic regimes on wood properties. Today, the acoustics of wood is a branch of wood science with huge applications in industry. Full article
(This article belongs to the Special Issue Reviews on Structure and Physical and Mechanical Properties of Wood)
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12 pages, 3074 KB  
Article
All-Optical, Air-Coupled Ultrasonic Detection of Low-Pressure Gas Leaks and Observation of Jet Tones in the MHz Range
by Kyle G. Scheuer and Ray G. DeCorby
Sensors 2023, 23(12), 5665; https://doi.org/10.3390/s23125665 - 17 Jun 2023
Cited by 8 | Viewed by 2905
Abstract
We used an ultrasensitive, broadband optomechanical ultrasound sensor to study the acoustic signals produced by pressurized nitrogen escaping from a variety of small syringes. Harmonically related jet tones extending into the MHz region were observed for a certain range of flow (i.e., Reynolds [...] Read more.
We used an ultrasensitive, broadband optomechanical ultrasound sensor to study the acoustic signals produced by pressurized nitrogen escaping from a variety of small syringes. Harmonically related jet tones extending into the MHz region were observed for a certain range of flow (i.e., Reynolds number), which is in qualitative agreement with historical studies on gas jets emitted from pipes and orifices of much larger dimensions. For higher turbulent flow rates, we observed broadband ultrasonic emission in the ~0–5 MHz range, which was likely limited on the upper end due to attenuation in air. These observations are made possible by the broadband, ultrasensitive response (for air-coupled ultrasound) of our optomechanical devices. Aside from being of theoretical interest, our results could have practical implications for the non-contact monitoring and detection of early-stage leaks in pressured fluid systems. Full article
(This article belongs to the Special Issue Acoustic Sensors and Their Applications)
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16 pages, 4162 KB  
Article
Polyimide-On-Silicon 2D Piezoelectric Micromachined Ultrasound Transducer (PMUT) Array
by Sanjog Vilas Joshi, Sina Sadeghpour and Michael Kraft
Sensors 2023, 23(10), 4826; https://doi.org/10.3390/s23104826 - 17 May 2023
Cited by 12 | Viewed by 4644
Abstract
This paper presents a fully addressable 8 × 8 two-dimensional (2D) rigid piezoelectric micromachined ultrasonic transducer (PMUT) array. The PMUTs were fabricated on a standard silicon wafer, resulting in a low-cost solution for ultrasound imaging. A polyimide layer is used as the passive [...] Read more.
This paper presents a fully addressable 8 × 8 two-dimensional (2D) rigid piezoelectric micromachined ultrasonic transducer (PMUT) array. The PMUTs were fabricated on a standard silicon wafer, resulting in a low-cost solution for ultrasound imaging. A polyimide layer is used as the passive layer in the PMUT membranes on top of the active piezoelectric layer. The PMUT membranes are realized by backside deep reactive ion etching (DRIE) with an oxide etch stop. The polyimide passive layer enables high resonance frequencies that can be easily tuned by controlling the thickness of the polyimide. The fabricated PMUT with 6 µm polyimide thickness showed a 3.2 MHz in-air frequency with a 3 nm/V sensitivity. The PMUT has shown an effective coupling coefficient of 14% as calculated from the impedance analysis. An approximately 1% interelement crosstalk between the PMUT elements in one array is observed, which is at least a five-fold reduction compared to the state of the art. A pressure response of 40 Pa/V at 5 mm was measured underwater using a hydrophone while exciting a single PMUT element. A single-pulse response captured using the hydrophone suggested a 70% −6 dB fractional bandwidth for the 1.7 MHz center frequency. The demonstrated results have the potential to enable imaging and sensing applications in shallow-depth regions, subject to some optimization. Full article
(This article belongs to the Special Issue Advanced Sensors in MEMS)
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13 pages, 4048 KB  
Article
Enhancing Hot Air Drying Efficiency through Electrostatic Field–Ultrasonic Coupling Pretreatment
by Ri-Fu Yang, Ying-Ying Peng and Yu-Rong Wang
Foods 2023, 12(8), 1727; https://doi.org/10.3390/foods12081727 - 21 Apr 2023
Cited by 4 | Viewed by 2025
Abstract
The drying of compact and biologically active materials presents significant challenges. In this study, we propose using electrostatic field–ultrasonic coupling pretreatment to enhance the drying efficiency of ginkgo fruits. We designed and constructed an experimental device to investigate the effects of ultrasonic power, [...] Read more.
The drying of compact and biologically active materials presents significant challenges. In this study, we propose using electrostatic field–ultrasonic coupling pretreatment to enhance the drying efficiency of ginkgo fruits. We designed and constructed an experimental device to investigate the effects of ultrasonic power, pretreatment time, hot air drying temperature, and electrostatic field voltage on the moisture content of the fruits. We used the response surface methodology to identify optimal process conditions and further explored the kinetic model for the moisture content of the fruits under the pretreatment. The results showed that the optimal process parameters for electrostatic–ultrasound pretreatment and the drying of ginkgo fruits were: an electrostatic field voltage of 11.252 kV, an ultrasound power of 590.074 W, a pretreatment time of 32.799 min, and a hot air drying temperature of 85 °C. Under the optimized process conditions, the correlation between the moisture content of ginkgo fruits and the two-term drying kinetics model was the highest. After electrostatic–ultrasound coupling pretreatment, the drying rate of ginkgo fruits was significantly improved during hot air drying. Full article
(This article belongs to the Section Food Engineering and Technology)
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9 pages, 1539 KB  
Article
Broadband Air-Coupled Ultrasound Emitter and Receiver Enable Simultaneous Measurement of Thickness and Speed of Sound in Solids
by Klaas Bente, Janez Rus, Hubert Mooshofer, Mate Gaal and Christian Ulrich Grosse
Sensors 2023, 23(3), 1379; https://doi.org/10.3390/s23031379 - 26 Jan 2023
Cited by 14 | Viewed by 4634
Abstract
Air-coupled ultrasound sensors have advantages over contact ultrasound sensors when a sample should not become contaminated or influenced by the couplant or the measurement has to be a fast and automated inline process. Thereby, air-coupled transducers must emit high-energy pulses due to the [...] Read more.
Air-coupled ultrasound sensors have advantages over contact ultrasound sensors when a sample should not become contaminated or influenced by the couplant or the measurement has to be a fast and automated inline process. Thereby, air-coupled transducers must emit high-energy pulses due to the low air-to-solid power transmission ratios (10−3 to 10−8). Currently used resonant transducers trade bandwidth—a prerequisite for material parameter analysis—against pulse energy. Here we show that a combination of a non-resonant ultrasound emitter and a non-resonant detector enables the generation and detection of pulses that are both high in amplitude (130 dB) and bandwidth (2 µs pulse width). We further show an initial application: the detection of reflections inside of a carbon fiber reinforced plastic plate with thicknesses between 1.7 mm and 10 mm. As the sensors work contact-free, the time of flight and the period of the in-plate reflections are independent parameters. Hence, a variation of ultrasound velocity is distinguishable from a variation of plate thickness and both properties are determined simultaneously. The sensor combination is likely to find numerous industrial applications necessitating high automation capacity and opens possibilities for air-coupled, single-side ultrasonic inspection. Full article
(This article belongs to the Special Issue Acoustic Sensors and Their Applications)
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10 pages, 2828 KB  
Communication
Multiple Damage Detection in PZT Sensor Using Dual Point Contact Method
by Sayantani Bhattacharya, Nitin Yadav, Azeem Ahmad, Frank Melandsø and Anowarul Habib
Sensors 2022, 22(23), 9161; https://doi.org/10.3390/s22239161 - 25 Nov 2022
Cited by 3 | Viewed by 2914
Abstract
Lead Zirconate Titanate (PZT) is used to make ultrasound transducers, sensors, and actuators due to its large piezoelectric coefficient. Several micro-defects develop in the PZT sensor due to delamination, corrosion, huge temperature fluctuation, etc., causing a decline in its performance. It is thus [...] Read more.
Lead Zirconate Titanate (PZT) is used to make ultrasound transducers, sensors, and actuators due to its large piezoelectric coefficient. Several micro-defects develop in the PZT sensor due to delamination, corrosion, huge temperature fluctuation, etc., causing a decline in its performance. It is thus necessary to identify, locate, and quantify the defects. Non-Destructive Structural Health Monitoring (SHM) is the most optimal and economical evaluation method. Traditional ultrasound SHM techniques have a huge impedance mismatch between air and solid material, and most of the popular signal processing methods define time series signals in only one domain, which provides sub-optimal results for non-stationary signals. Thus, to improve the accuracy of detection, the point contact excitation and detection method is implemented to determine the interaction of ultrasonic waves with micro-scale defects in the PZT. The signal generated from this method being non-stationary in nature, it requires signal processing with changeable resolutions at different times and frequencies. The Haar Discrete Wavelet Transformation (DWT) is applied to the time series data obtained from the coulomb coupling setup. Using the above process, defects up to 100 μm in diameter could be successfully distinguished. Full article
(This article belongs to the Special Issue Smart Materials for Structural Health Monitoring and Damage Detection)
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17 pages, 2639 KB  
Article
Ultrasound/Chlorine: A Novel Synergistic Sono-Hybrid Process for Allura Red AC Degradation
by Oualid Hamdaoui, Slimane Merouani, Hadjer C. Benmahmoud, Meriem Ait Idir, Hamza Ferkous and Abdulaziz Alghyamah
Catalysts 2022, 12(10), 1171; https://doi.org/10.3390/catal12101171 - 4 Oct 2022
Cited by 18 | Viewed by 2673
Abstract
Herein, we present an original report on chlorine activation by ultrasound (US: 600 kHz, 120 W) for intensifying the sonochemical treatment of hazardous organic materials. The coupling of US/chlorine produced synergy via the involvement of reactive chlorine species (RCSs: Cl, ClO [...] Read more.
Herein, we present an original report on chlorine activation by ultrasound (US: 600 kHz, 120 W) for intensifying the sonochemical treatment of hazardous organic materials. The coupling of US/chlorine produced synergy via the involvement of reactive chlorine species (RCSs: Cl, ClO and Cl2•−), resulting from the sono-activation of chlorine. The degradation of Allura Red AC (ARAC) textile dye, as a contaminant model, was drastically improved by the US/chlorine process as compared to the separated techniques. A synergy index of 1.74 was obtained by the US/chlorine process for the degradation of ARAC (C0 = 5 mg·L−1) at pH 5.5 and [chlorine]0 = 250 mM. The synergistic index increased by up to 2.2 when chlorine concentration was 300 µM. Additionally, the synergetic effect was only obtained at pH 4–6, where HOCl is the sole chlorine species. Additionally, the effect of combining US and chlorine for ARAC degradation was additive for the argon atmosphere, synergistic for air and negative for N2. An air atmosphere could provide the best synergy as it generates a relatively moderate concentration of reactive species as compared to argon, which marginalizes radical–radical reactions compared to radical–organic ones. Finally, the US/chlorine process was more synergistic for low pollutant concentrations (C0 ≤ 10 mg·L−1); the coupling effect was additive for moderate concentrations (C0~20–30 mg·L−1) and negative for higher C0 (>30 mg·L−1). Consequently, the US/chlorine process was efficiently operable under typical water treatment conditions, although complete by-product analysis and toxicity assessment may still be necessary to establish process viability. Full article
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