Search Results (43)

This study evaluated the sustainability of removing phenolic compounds from olive mill effluents using a nanobiochar synthesized from olive pomace. Catechol, tyrosol, hydroxytyrosol, and homovanillic alcohol were chosen as model pollutants due to their presence in agro-industrial wastewater. The surface morphology, elemental composition, crystallographic structure, functional groups, porosity, and thermal stability of the nanobiochar were investigated by SEM, EDX, XRD, FTIR, BET analysis, and TGA/DTA. The developed nanobiochar exhibited a predominantly amorphous carbon structure, enriched in carbon (85.6%), with localized graphitic domains. Its mesoporous architecture (S_BET = 15.478 m² g⁻¹; Dp = 2.14 nm) promotes accessibility to active sites, while its thermal stability confirmed its suitability for adsorption applications. In this batch adsorption study, the technological aspect considered is the influence of operating parameters on adsorption efficiency, using kinetic and equilibrium models. Pseudo-first-order and pseudo-second-order kinetic models, as well as Freundlich and Langmuir isotherms, were used to analyze the experimental data. The pseudo-second-order model proved to be the most suitable for describing adsorption, suggesting that the process is primarily dominated by chemisorption. Similarly, the Langmuir model gave the least satisfactory results regarding equilibrium data, indicating monolayer adsorption on homogeneous active sites. The adsorption capacity of phenolic compounds was variable. The highest adsorption capacities were observed for catechol (250 mg g⁻¹), tyrosol (19.23 mg g⁻¹), homovanillic alcohol (15.38 mg g⁻¹), and hydroxytyrosol (13.16 mg g⁻¹). The results of this research indicate that adsorption affinity depends on molecular structure and electronic properties. Furthermore, computer modeling based on molecular simulations and electronic descriptors was performed to explain the adsorption mechanism. Linear regression, principal component analysis, and elastic regression revealed strong correlations between adsorption parameters and molecular descriptors. These results demonstrate that olive pomace-based nanobiochar is an environmentally friendly adsorbent for the treatment of phenolic effluents, with adsorption primarily controlled by surface interactions. Full article

The generation of agro-industrial residues represents an environmental challenge and an opportunity for their valorization within a circular economy framework. In this study, Agave salmiana bagasse residues were evaluated as a reinforcing material for developing bioplastics made from maize starch (polymer matrix). Maguey bagasse was collected, ground and sieved to particle sizes below 200 μm and incorporated into bioplastic formulations at different content levels. Five bioplastic films (M1–M5) were obtained and characterized regarding their physical, chemical, mechanical, thermal, and morphological properties. The evaluated parameters included density, color (CIE Lab*), moisture content, water absorption, FTIR analysis, tensile properties, thermal behavior, and surface morphology via SEM. The results showed significant differences among the bioplastic formulations. The moisture content ranged from 7.15% to 10.57%, while water absorption after 24 h reached values of up to 65% for the formulation with the highest bagasse content. Mechanical and thermal analyses indicated that the incorporation of maguey bagasse influenced the structural performance of the bioplastics, while SEM observations revealed changes in surface morphology associated with fiber incorporation. These findings demonstrate the potential of A. salmiana bagasse as a reinforcing agent in starch-based bioplastics, contributing to the development of sustainable materials. The results support their potential as a biodegradable material with exploratory application in an agricultural system. Full article

Light regime and growth phase are significant determinants of agro-morphological traits and secondary metabolite accumulation in plants. This study evaluated the effects of two light conditions on agro-morphological and phytochemical traits of two Hypericum perforatum genotypes (Topas and Mariana). Natural daylight and an extended 19 h photoperiod with supplemental white fluorescent light were tested at two growth phases (vegetative versus reproductive (flowering)), based on leaf sampling at the respective phases. Analysis of variance showed significant effects of growth phase, light treatment, and genotype on most traits, with growth phase exerting the most decisive influence (p < 0.01). Significant genotype × growth phase interactions were observed for most traits, whereas genotype × light interactions mainly affected phytochemical parameters. Leaf area, gland number, and gland area increased during the reproductive phase, especially in Topas, and were further enhanced under the 19 h photoperiod. Leaf area increased markedly during the reproductive phase, reaching 118.81 mm² in Topas under the 19 h photoperiod compared with 68.40 mm² under natural light. Prolonged light exposure increased hypericin, pseudo-hypericin, hyperforin, flavonoids, and total phenolics. The highest sum of hypericins (4.67 mg g⁻¹ DW), flavonoids (143.09 mg QE g⁻¹ DW), and phenolics (242.74 mg GA g⁻¹ DW) was observed in the Topas in the reproductive phase under the 19 h photoperiod, whereas hyperforin content peaked in vegetative Mariana (55.65 mg g⁻¹ DW). In contrast, the lowest sum of hypericins (1.80 mg g⁻¹ DW) occurred in vegetative Mariana under natural light, while the minimum flavonoids (74.45 mg QE g⁻¹ DW) and phenolics (133.22 mg GA g⁻¹ DW) contents were recorded in the vegetative Topas under natural light regim, and the lowest hyperforin concentration (19.65 mg g⁻¹ DW) was found in the Mariana genotype under natural light regime and in the reproductive phase. Principal component analysis associated PC1 with agro-morphological traits and hypericin-related metabolites, and PC2 with hyperforin and white gland traits. Heatmap and correlation analyses supported these patterns. Overall, extended photoperiod and growth phase are critical drivers of medicinal compound accumulation in H. perforatum. Full article

The sustainable management and valorisation of agricultural and agro-industrial residues are essential to reduce environmental impacts, enhance resource efficiency, and support circular economy strategies. In Mediterranean regions, large quantities of residual biomass are annually produced from olive and citrus supply chains, representing promising feedstocks for biochar production. In this study, biochar was obtained at 600 °C in a fixed-bed reactor under a N₂ atmosphere from four representative feedstocks: olive pruning (OPr), citrus pruning (CPr), olive pomace (OPo), and citrus peel (CPe). The resulting biochar was characterized in terms of physico-chemical, energetic, and structural properties, including proximate and ultimate analyses, fuel properties, cation exchange capacity (CEC), pH, elemental ratios (O/C, H/C, N/C), thermal stability, bulk density, metal content, and surface morphology (SEM), in order to assess parameters relevant to environmental potential applications. The results highlighted clear feedstock-dependent differences. OPoB and CPeB exhibited the highest thermal stability (0.56–0.66), indicating a strong potential for long-term carbon sequestration. CPeB showed the highest CEC (47.2 cmol kg⁻¹). From an application-oriented perspective, this high CEC suggests that, when applied to soil at typical amendment rates (2–5 wt%), CPeB could potentially increase soil CEC by approximately 10–30%, thereby improving nutrient retention and cation availability. Energy yields were highest for citrus-derived biochar (42.0–47.5%), while OPoB exhibited the lowest solid yield due to its higher volatile content. SEM analysis revealed marked structural differences, with OPrB retaining an ordered lignocellulosic porous structure, whereas OPoB and CPeB displayed highly irregular morphologies, favorable for surface reactivity. Overall, this study demonstrates that olive and citrus residues are suitable feedstocks for producing biochar with differentiated properties, and that a rapid screening methodology can support feedstock selection and biochar design for targeted energy, soil amendment, and carbon management applications. Full article

Barley is a marginalized crop subjected to several types of abiotic stress but need to intensify for future climate smart crop. This study investigated the drought resistance of barley landraces focusing on agro-morphological and physiological traits under controlled drought conditions. The experiment employed a two-factorial completely randomized design (CRD) with 14 barley landraces (of which 8 completed the maturity period examination) subjected to drought stress at three growth stages (CRI, tillering, and grain filling). Key parameters such as SPAD values (chlorophyll content), tiller number, and yield attributes were measured and analyzed using drought tolerance indices. Fourteen genotypes were initially tested, of which six failed to reach maturity; eight genotypes completed the full growth cycle and were used for yield and stress index analysis. Results revealed significant genotypic variation in drought response. Eight landraces exhibited higher SPAD values under drought, indicating better photosynthetic retention. Notably, AFU202501 demonstrated high yield stability (Stress Tolerance Index, STI = 1.782) under both stress and non-stress conditions, while Saptari Local showed exceptional drought avoidance (low Stress Susceptibility Index, SSI = −0.068) through early maturity and minimal yield reduction. In contrast, genotypes like Muktinath and NGRC 6010 were highly sensitive to drought, with significant yield losses (49–87%). Physiological traits such as chlorophyll retention and phenological plasticity (e.g., accelerated maturity under stress) were critical for drought adaptation. The findings highlight the potential of landraces like AFU202501 and Saptari Local as genetic resources for breeding climate-resilient barley varieties. The study underscores the importance of integrating traditional landraces into modern breeding programs to enhance food security in drought-prone regions. Full article

Water deficit is a major constraint limiting the growth and yield of faba bean (Vicia faba L.). A pot experiment was conducted under controlled conditions to evaluate the effect of inoculation with Rhizobium leguminosarum bv. viciae BIHB 1148 (strain F14) and Pseudomonas alkylphenolica PF9 (strain L13) on faba bean drought resilience. Two irrigation regimes were applied: well-watered (80% of field capacity) versus water-stressed (40% of field capacity). Strain F14 was used to ensure effective biological nitrogen fixation, while strain L13 was applied in co-inoculation to evaluate its biostimulatory effects. The control plants received nitrogen in its chemical form. Results indicated that water deficit significantly (p < 0.001) reduced plant growth, nodulation, and photosynthesis-related parameters, and increased hydrogen peroxide (H₂O₂) and malondialdehyde (MDA) levels, which are key markers of oxidative stress. However, co-inoculation with strains F14 and L13 significantly enhanced shoot and root biomass, as well as most agro-morphological traits. It also stimulated (p < 0.05) the antioxidant activities of superoxide dismutase (3-fold), guaiacol peroxidase (12%), and catalase (104%), and increased proline content (119%), which led to lower levels of MDA (54% decrease) and H₂O₂ (55% decrease), improved membrane stability, water status, and enhanced photosynthesis. Overall, co-inoculation of faba bean with Rhizobium leguminosarum bv. viciae BIHB 1148 and Pseudomonas alkylphenolica PF9 offers a promising and sustainable approach to improve plant resilience under water deficit. Full article

Mechanical milling is a relevant preliminary processing operation that is widely used for the reuse of various types of agro-industrial waste. The objective of this study was to conduct milling experiments of hazelnut (Corylus avellana L.) shell waste at different times (0.5, 1 and 1.5 min) and subsequently evaluate the particle size distribution (PSD) of the powders obtained by sieving methodology. In addition, flowability parameters were determined for the particles retained on the sieves, and their morphology and microstructure were examined using several microscopy techniques. The results demonstrated that the hazelnut shells were successfully fractionated under the milling conditions investigated (short milling times ≤ 1.5 min), and the histograms of the PSD exhibited a wide dispersion of sizes (≤1.7 mm). The particles retained from sieve₁₀₀ to residue exhibited poor or no flow, attributable to the high degree of cohesion between them. Morphological analysis based on optical microscopy and image analysis revealed that there was an increase in the aspect ratio parameter when the particle size decreased, meaning that the particles had elongated shapes. Microscopic analysis (SEM, AFM and CLSM) showed that the particles exhibited complex shapes and a comparable microstructure, comprising tightly packed clusters of sclerenchyma cells. From the microscopy images obtained (SEM and AFM), it was inferred that the cracks generated during blade impacts propagate along the middle lamella of the cells, allowing the cluster-like arrangement to be preserved. The CLSM results demonstrated that as the size of hazelnut shell particles decreases, the exposure of lignin on its surface is favored. The findings of this study demonstrate that hazelnut shell waste can be readily pre-processed using a blade grinder, thereby facilitating its reuse in applications that demand fine particle sizes (e.g., bioadsorption of pollutants and the production of biocomposite materials). Likewise, the results concerning the flowability parameters, microstructural arrangement, and morphological features of the different particle fractions obtained are crucial variables that must be considered. These variables significantly influence the possible applications for the revalorization of this type of agro-industrial waste. Full article

Coffee quality arises from the interaction among genotype, environment, and postharvest management, yet few large-scale studies jointly integrate agronomic, phytochemical, and processing traits. We characterized 150 Coffea arabica L. accessions from six Peruvian regions, evaluated in the INIA coffee germplasm collection, quantifying agro-morphological traits, colorimetric parameters in cherries and beans, fermentation indicators, bioactive compounds, and antioxidant activity. Correlation analyses showed that total phenolics (TPCs) and total flavonoids (TFCs) were strongly associated with antioxidant activity, whereas caffeine content (CAF) varied, largely independently. Several chromatic parameters in parchment and green coffee (a*, b*, C*) showed positive correlations with phenolic content and antioxidant activity (ABTS, DPPH, FRAP), while final fermentation pH (FPH) was negatively associated with these compounds, supporting both color metrics and pH as operational indicators of chemical quality. Principal component analysis disentangled a morphometric gradient from a functional (phenolic–antioxidant) gradient, indicating that bean size and antioxidant potential can be improved in a semi-independent manner. Hierarchical clustering identified complementary ideotypes, and a multi-trait selection index highlighted promising accessions—PER1002197 (Cajamarca), PER1002222 (Cajamarca), PER1002288 (Pasco), and PER1002184 (Cajamarca)—that combine high phenolic/antioxidant levels, favorable chlorogenic acid (CGA)/trigonelline (TGN) profiles, contrasting (high/low) caffeine, and competitive yield (YPP)/bean size. These accessions represent promising candidates for breeding climate-smart and nutraceutical-oriented coffee. Full article

As a strategic crop of dry farming in northern China, the photosynthetic characteristics and stress resistance of foxtail millet (Setaria italica L.) are crucial to yield formation. This study aimed to explore the physiological characteristics of various foxtail millet varieties and screen high-efficiency varieties adapted to semi-arid climates. In the agro-pastoral ecotone of northern Shanxi Province, the physiological and ecological parameters, etc. of six cultivars were measured. The results showed that different cultivars had bimodal diurnal photosynthetic curves with distinct peak values and midday depression degrees, reflecting varied responses to high midday temperature and light stress. Dabaigu and Jingu 21 performed superiorly, with mean daily net photosynthetic rates (Pn) of 22.99 and 20.72 µmol·m⁻²·s⁻¹, significantly higher than Jinmiao K1 (12.87 µmol·m⁻²·s⁻¹). Chlorophyll fluorescence analysis showed Dabaigu had higher potential activity (F_v/F₀) of 3.98 than Jinmiao K1 (2.40). Jingu 21 synergistically optimized plant height, stem diameter, and biomass accumulation. Dabaigu and Jingu 21 are elite cultivars for the agro-pastoral ecotone of northern Shanxi Province due to high photosynthetic efficiency, strong photoprotection, and morphological plasticity. Full article

Fruit wastes have been considered as environmental pollution. Jackfruit is a good source of nutrients and bioactive compounds, meaning that its use in animal feed could contribute to waste reduction. The objective of this research was to evaluate the different parts of jackfruit (seed, pulp, and peel) as an agro-industrial waste on the productive parameters, carcass traits, and meat quality of rabbits. For this study, 144 thirty-five-day-old rabbits were randomly divided into four treatments, control (C), 2.5% pulp powder (PY), 2.5% seed powder (SY), and 2.5% peel powder (CY), with six repetitions and 6 rabbits for each repetition. The fattening period was 30 days. The best feed conversion ratios were found in the C, PY, and CY groups (p < 0.05). The highest chilled carcass yield was observed in the PY group (p < 0.05). Similar results were observed for intestinal morphology in all treatments (p > 0.05). The meat color obtained from the PY group had higher whiteness, redness, and chroma values (p < 0.05). Higher taste and general acceptability values for meat were observed in the groups using jackfruit (SY, PY, and CY). It is concluded that the addition of jackfruit peel powders can be used in rabbit feed, as they improve the final weight, feed conversion, carcass yield, and meat texture, while the sensory analysis demonstrates that the meat is well accepted by consumers. Full article

The exponential increase in medical waste production has increased the difficulty of waste management, resulting in higher medical waste dispersion into the environment. By employing a circular economy approach, it is possible to develop new materials by waste valorization. The employment of biodegradable and renewable agro-food, waste-derived materials may reduce the environmental impact caused by the dispersion of medical waste. In this work, tomato peel recovered cutin was blended with poly(L-lactide-co-ε-caprolactone) (PLAPCL) to develop new textiles for medical application through electrospinning. The textile fabrication process was studied by varying Cut content in the starting suspensions and by optimizing fabrication parameters. Devices with dense and porous structures were developed, and their morphological, thermal, and physical–chemical properties were evaluated through scanning electron microscopy, differential scanning calorimetry, thermogravimetric analysis, and Fourier transformed infrared spectroscopy. Textile material stability to γ-irradiation was evaluated through gel permeation chromatography, while its wettability, mechanical properties, and biocompatibility were analyzed through contact angle measurement, tensile test, and MTT assay, respectively. The LCA methodology was used to evaluate the environmental impact of textile production, with a specific focus on greenhouse gas (GHG) emissions. The main results demonstrated the suitability of PLAPCL–cutin blends to be processed through electrospinning and the obtained textile’s suitability to be used to develop surgical face masks or patches for wound healing. Full article

Azadirachta indica was designated the “Tree of the 21st century” by the United Nations, as it is believed to be the largest natural depository of bioactive phytochemicals. This study investigates genetic variability among 152 Candidate Plus Trees (CPTs) of A. indica selected from three agro-climatic zones (ACZs) in eastern India: the Lower Gangetic Plains (ACZ III), Middle Gangetic Plains (ACZ IV), and the Eastern Plateau and Hills region (ACZ VII). Phenotypic characters, fruit and seed morphology, kernel oil content (KOC), and Azadirachtin concentration (AC) were assessed to characterize the genetic diversity. Significant variation was observed across all parameters among individual CPTs. Girth at breast height ranged from 0.9 to 2.8 m, tree height from 6 to 16 m, and crown volume from 146.95 to 2339.86 m³. Fruit length varied from 13.55 to 21.55 mm and seed length from 9.21 to 17.37 mm. KOC ranged from 36.51 to 58.86%, with a mean of 47.22% (±0.4), while AC showed extreme variability (19.46–1823.45 μg/g seed). KOC exhibited strong positive correlations with crown diameter (R = 0.57, p ≤ 0.001) and crown volume (R = 0.45, p ≤ 0.001). Interestingly, AC did not correlate significantly with any studied parameter. Analysis of variance revealed significant differences (p < 0.05) between ACZs, but only for some traits. All of the parameters demonstrated high heritability and moderate to high genetic advance. Cluster analysis using Ward’s minimum variance criterion based on Euclidean square (D²) distances performed in RStudio grouped the CPTs into five clusters as per pooled effects of all parameters. The highest inter-cluster distance was observed between Clusters III and V (7.703), indicating a potential for heterosis in hybridization between these groups. Each cluster contained CPTs from all three ACZs, suggesting uniformly distributed variation across the study area rather than zone-specific patterns. This study provides valuable insights for improvement programs of the species and emphasizes the need for further research, including progeny trials, to comprehensively understand the genetic variability of A. indica in eastern India. Full article

This study evaluates the impact of different irrigation scenarios on the yield of quinoa (Chenopodium quinoa) in the Chilean Altiplano. The research was conducted in Ancovinto, Tarapacá, Chile, using “Pandela” quinoa seeds. Four irrigation treatments were implemented: rainfed (T0) and irrigation at 100% ETc (T1), 66% ETc (T2), and 33% ETc (T3). Various climatic variables, the soil moisture content, and agromorphological parameters were measured. The results indicated that rainfed conditions (T0) led to higher dry matter production in roots, stems, leaves, and panicles at the end of the growth cycle compared to irrigated treatments. The Leaf Area Index (LAI) was also higher in rainfed conditions during the flowering stage, demonstrating the crop’s adaptability to adverse water conditions. Additionally, the ability of quinoa plants under rainfed conditions to tolerate frost during critical growth stages was a key factor in their superior performance, contributing to a higher grain yield and harvest indices. Plants under rainfed conditions reached greater heights and showed higher harvest indices (HI) and grain yield than those under irrigation. The Water Use Efficiency (WUE) was significantly higher in rainfed conditions, suggesting more effective water utilization under water scarcity. This research represents a one-year study that provides orientations for future research, considering the interannual variability of precipitation in the region. The results obtained show that quinoa plants under traditional management (rainfed) exhibited the best response in the measured growth, development, and production variables, leading to higher production and harvest rates. Additionally, there was greater efficiency in water use, equivalent to 15.87 and 12.7 times that of the 100% and 33% ETc treatments, respectively. These findings highlight quinoa’s remarkable adaptability to harsh hydric conditions and the efficiency of traditional rainfed farming practices in the Altiplano. Full article

The building and construction sector is the largest emitter of greenhouse gases, accounting for 37% of global emissions. The production and use of materials such as cement, steel, and aluminum contribute significantly to this carbon footprint. Utilizing valorized agricultural by-products, such as hemp shiv and sunflower pith, in construction can enhance the insulating properties of materials and reduce their environmental impact by capturing CO₂. Additionally, during the formulation process, molecules such as polyphenols and sugars are released, depending on process parameters like pH and temperature. In some cases, these releases can cause issues, such as delaying the hardening of agro-based concrete or serving as binding agents in binderless particle boards. This study focuses on the molecules released during the processing of these materials, with particular attention to the effects of pH and temperature, and the modifications to the plant particles resulting from these conditions. Physical, chemical, and morphological analyses were conducted on the treated hemp shiv particles (HS1 and HS2). No physical or morphological differences were observed between the samples. However, chemical differences, particularly in the lignin and soluble compound content, were noted and were linked to the release of plant substances during the process. Full article

Gully erosion poses a significant global concern due to its role in land degradation and soil erosion, particularly pronounced in Northeast China’s diverse agro-geomorphic regions. However, there is a lack of comprehensive studies on gully characteristics, development rates, and the topographic threshold of gully formation in these areas. To address this gap, we selected three different agro-geomorphic watersheds, named HL (Hailun), ML (Muling), and YKS (Yakeshi), with areas of 30.88 km², 31.53 km², and 21.98 km², respectively. Utilizing high-resolution (2.1 m, 2 m) remote sensing imagery (ZY-3, GF-1), we analyzed morphological parameters (length, width, area, perimeter, etc.) and land use changes for all permanent gullies between 2013 and 2023. Approximately 30% of gullies were selected for detailed study of the upstream drainage area and gully head slopes to establish the topographic threshold for gully formation (S = a·A^−b). In HL, ML, and YKS, average gully lengths were 526.22 m, 208.64 m, and 614.20 m, respectively, with corresponding widths of 13.28 m, 8.45 m, and 9.32 m. The gully number densities in the three areas were 3.14, 25.18, and 0.82/km², respectively, with a gully density of 1.65, 5.25, and 0.50 km km⁻², and 3%, 5%, and 1% of the land has disappeared due to gully erosion, respectively. YKS exhibited the highest gully head retreat rate at 17.50 m yr⁻¹, significantly surpassing HL (12.24 m yr⁻¹) and ML (7.11 m yr⁻¹). Areal erosion rates were highest in HL (277.79 m² yr⁻¹) and lowest in YKS (105.22 m² yr⁻¹), with ML intermediate at 243.36 m² yr⁻¹. However, there was no significant difference in gully expansion rate (0.37–0.42 m yr⁻¹) among the three areas (p > 0.05). Differences in gully development dynamics among the three regions were influenced by land use, slope, and topographic factors. The topographic threshold (S = a·A^−b) for gully formation varied: HL emphasized drainage area (a = 0.052, b = 0.52), YKS highlighted soil resistance (a = 0.12, b = 0.36), and the parameters a and b of ML fell within the range between these of HL and YKS (a = 0.044, b = 0.27). This study has enriched the scope and database of global gully erosion research, providing a scientific basis for gully erosion prevention and control planning in Northeast China. Full article