Search Results (44)

Methane, a greenhouse gas which has a global warming potential 80 times greater than carbon dioxide on a 20-year time scale, greatly contributes to global warming. Removing 1 Gt of atmospheric methane by 2050 would limit global temperature increase from reaching 1.5 °C. Currently, biotrickling filter systems for removing atmospheric methane via methanotrophs exist, but not for very low methane concentrations (<1 v%). Recent work at the University of Washington to isolate and improve a microbial strain which thrives at 500 ppmv CH₄ has removed one obstacle in making this technology feasible. In this study, techno-economic and environmental life cycle assessment analyses conducted on this process have assessed its economic feasibility, greenhouse gas reduction potential, and possible areas of improvement. Study results show that at 500 ppmv CH₄, this process could remove atmospheric methane at a cost of USD 3992–5224/tCH₄. The best-performing case also produces annual net reductions in warming potential by 276–311 tCO₂e/120 m³ process unit deployed. Many opportunities exist to improve the outcomes of the baseline analysis even further, especially related to reducing the transport distance of media and harvested biomass. Full article

Direct air capture (DAC) has recently gained interest as a carbon dioxide removal (CDR) method to reduce atmospheric CO₂. DAC is mainly studied through standalone separation technologies, especially adsorption and absorption. Hybrid DAC, combining separation technologies, is rarely investigated and is the main topic of this work. This study investigates hybrid DAC using adsorption for pre-concentration up to a few percent or tens of percent depending on the case studied and membrane separation to concentrate the CO₂ stream to high purity (>90%). Adsorption regeneration by temperature swing adsorption (TSA) and vacuum thermal swing adsorption (VTSA) are compared, and VTSA regeneration achieved higher pre-concentration outlet CO₂ purity (15–30%) than TSA regeneration (1–10%). Membrane separation is studied depending on inlet CO₂ purity and outlet-required purity (90 or 95%), which influence the energy requirement and cost of capture. For all cases studied, the cost of capture remained high (>1700 €/tCO₂) with a high energy requirement (>2 MWh_e/tCO₂ and >27 GJ/tCO₂). The adsorption pre-concentration step accounted for the majority (>80%) of the energy requirement and cost of capture, and future work should be focused on preferentially improving adsorption step performance. Full article

The choice of carbon inequality metrics can significantly influence demand-side mitigation policies and their equity outcomes. We propose integrated carbon inequality metrics, including juxtaposing carbon inequality with economic inequality, disparity ratios across income and age groups, and structural income–urbanization inequality patterns. We then apply these new metrics and use the household expenditure survey data from China Family Panel Studies as a case study to examine household consumption-based carbon emissions in China. We assess the extent to which household consumption patterns, household expenditure, age, and urbanization contribute to the gap in per-capita household carbon footprints (CF) across income groups. We find that in relative terms, the top 20% income group accounts for 38% of total emissions, whereas the bottom 20% emit about 8% in China. Per-capita CFs vary slightly widely in their inequality than expenditure. The CF disparity ratios of all eight consumption categories across provinces concentrate around 4.5. CF disparity ratios of households with elderly members range from 1 to 3 and decrease with increasing household size. Rural CF-Gini exhibit a slightly wider range (0.15 to 0.52) than urban CF-Gini (0.16 to 0.42). Per capita CF of urban inhabitants was substantially larger than that of the rural ones, with 8.83 tCO₂ per capita in urban regions vs. 2.68 tCO₂ in rural regions. This study provides a nuanced understanding of within-country disparities to inform equitable demand-side mitigation solutions. Full article

Rare-earth (RE) doping has been found to be a potent method to improve the structural, optical, electronic, and magnetic properties of ZnO, positioning it as a versatile material for future optoelectronic devices. This review herein thoroughly discusses the latest developments in RE-doped ZnO based on the role of the dopant type, concentration, synthesis method, and consequences of property modifications. The 4f electronic states of rare-earth elements create strong visible emissions, control charge carriers, and design defects. These structural changes lead to tunable bandgap energies and increased light absorption. Also, RE doping considerably enhances ZnO’s performance in electronic devices, like UV photodetectors, LEDs, TCOs, and gas sensors. Though, challenges like solubility constraints and lattice distortions at higher doping concentrations are still key challenges. Co-doping methodologies and new synthesis techniques to further optimize the incorporation of RE into ZnO matrices are also reviewed in this article. By showing a systematic comparison of different RE-doped ZnO systems, this paper sheds light on their future optoelectronic applications. The results are useful for the design of advanced ZnO-based materials with customized functionalities, which will lead to enhanced device efficiency and new photonic applications. Full article

In order to study the characteristics of the thermal runaway process of a full-size prefabricated cabin energy storage system, a full-scale prefabricated cabin energy storage physical fire test platform was designed using 100% SOC energy storage battery packs as the thermal runaway object, and full-scale prefabricated cabin energy storage system physical fire experiments were conducted. This experiment analyzes the early change rules of parameters such as temperature, voltage, CO, and VOC after the energy storage system enters thermal runaway and explores the technical methods to improve the fire protection of electrochemical energy storage systems. The results show that the time when the surface temperature of the runaway cell undergoes a sudden change is 37 s later than the time when the voltage undergoes a sudden change; the CO at the bottom and middle of the runaway cluster reaches the alarm threshold 25 s and 39 s earlier than that at the top of the cluster, respectively, and the peak concentration of CO at the bottom and middle of the cluster is more than three times that at the top of the cluster. The opening of the fan causes the CO concentration on the left side of the thermal runaway cluster to be higher than that of the runaway cluster; before the battery thermal runaway, the VOC concentration at the middle and top of the runaway cluster is generally higher than that at the bottom of the cluster. After thermal runaway occurs, the VOC concentration at the bottom of the thermal runaway cluster exceeds that at other positions of the runaway cluster and the adjacent cluster; the t_VOC at the top, middle, and bottom of the thermal runaway cluster is 2296 s, 1681 s, and 1464 s earlier than the t_CO, respectively, but the initial detection value of VOC fluctuates more than that of CO. Full article

The expansion of silicon heterojunction (SHJ) solar cell production has prompted concerns regarding the rising consumption of indium. To address the issue of indium scarcity, the use of benign hydrometallurgical conditions for the recovery of indium—a rare noble metal—from the transparent conductive oxide (TCO) layer of the cells was investigated. The results showed that due to the insufficient adhesion between the silver fingers and the TCO layer, the complete recovery of the silver fingers could be accomplished without damaging the cell by the etching process involving 10% NaOH at 90 °C for 10 min. The optimal chemical treatment conditions were adjusted to ensure the efficient dissolution of indium metal from the cell into solution. The subsequent solvent extraction stripping process yielded an indium concentration of 6232 mg/L, a 24-fold increase over the initial leach solution concentration. Finally, a 12-h replacement reaction using aluminum plates was employed to achieve higher indium purity. The final recovery of indium from SHJ cells was determined to be approximately 85%, and an approximate cost analysis was conducted to assess the potential future of SHJ cell recycling. Full article

This study examined the carbon cycling dynamics in the tropical Atlantic Ocean from 1985 to 2023, focusing on factors influencing the surface partial pressure of CO₂ (pCO₂), freshwater input, total alkalinity (ALK), total dissolved carbon (TCO₂), and pH levels. The time series data revealed significant trends, with average pCO₂ concentrations rising from approximately 350 μatm in the early 1990s to over 400 μatm by 2023. The TCO₂ levels increased from about 2000 μmol/kg to 2200 μmol/kg, while ALK rose from approximately 2300 μmol/kg to 2500 μmol/kg. This increase highlights the ocean’s role as a carbon sink, particularly in areas with high biological productivity and upwelling where TCO₂ also rose. This study employed Empirical Orthogonal Functions (EOFs) to identify variability modes and understand spatial patterns of pCO₂. Freshwater dynamics significantly affect TCO₂ concentrations, particularly in coastal regions, where pH can shift from 8.2 to 7.9, exacerbating acidification. Rising sea surface temperatures have been linked to elevated pCO₂ values. These findings support the need for ongoing monitoring and effective management strategies to mitigate the impacts of climate change and ensure the sustainability of marine resources. This study documented the long-term trends in tropical Atlantic CO₂ parameters linked to the North Atlantic Oscillation (NAO) and Atlantic Multidecadal Oscillation (AMO). Full article

Soil in karst areas is rare and precious, and karst carbon sinks play an important role in the global carbon cycle. Therefore, the purpose of karst soil improvement is to improve soil productivity and a carbon sink effect. Biomass amendment experiments in this study included three schemes: filter mud (FM), filter mud + straw + biogas slurry (FSB), and filter mud + straw + cow manure (FSC). The characteristics of soil CO₂ production, transport, and the effect on soil respiration carbon emissions in two years were compared and analyzed. The results were as follows: 1. The rate, amount, and depth of CO₂ concentration were affected by the combinations with biogas slurry (easy to leach) or cow manure (difficult to decompose). 2. The diurnal variation curves of soil respiration in the FSB- and FSC-improved soils lagged behind those in the control soil for three hours. While the curves of FM-improved soil and the control soil were nearly the same. 3. Soil–air carbon emissions increased by 35.2 tCO₂/(km²·a⁻¹) under the FM scheme, decreased by 212.9 tCO₂/(km²·a⁻¹) under the FSB scheme, and increased by 279.5 tCO₂/(km²·a⁻¹) under the FSC scheme. The results were related to weather CO₂ accumulation in the deep or surface layers under different schemes. Full article

As one of the most rapidly developing provinces in China in the past two decades, Anhui Province has seen an increasing demand for clean energy in recent years due to industrial transformation and the requirements of dual carbon targets. This paper opts to investigate roof-mounted distributed photovoltaics, which are more suitable for development in densely populated areas. Current research on distributed photovoltaics largely focuses on vague estimations of power generation potential, without adequately considering the specific development conditions of different regions. This paper starts from the actual situation affecting the development of roof-mounted distributed photovoltaics and selects a smaller number of factors that are more in line with reality for hierarchical analysis, constructing a relatively simple but practical evaluation system (“meteorological-geographical-socio-economic”). At the same time, this paper innovatively proposes different schemes for the full lifecycle power generation and emission reduction benefits of roof-mounted distributed photovoltaics and compares them, providing a foundation for subsequent in-depth research. Key findings include the following: The northern regions of Anhui Province exhibit higher suitability for rooftop distributed PV, with residential areas being the primary influencing factor, followed by solar radiation considerations; the annual power generation potential of rooftop distributed PV in Anhui Province constitutes around 80% of the total electricity consumption in 2021, but the potential is predominantly concentrated in rural areas, resulting in spatial disparities in power generation and consumption across the province; developing the rooftop distributed PV industry based on suitability can yield substantial power generation and emission reduction benefits, translating to an estimated reduction of approximately 1.28 × 10⁸ tCO₂ annually, representing around one-third of Anhui Province’s carbon emissions in 2021. Full article

In recent years, transparent conducting oxide semiconductor materials have found applications in both science and technology, especially in the areas of semiconductors, optoelectronics, and a wide range of energy efficiency devices. These TCO materials are the building blocks of various optoelectronic devices, such as transparent thin-film transistors, solar cells, and light-emitting diodes. This work concentrates on the structure, morphology, and optical properties of ZnO and Zn_0.95La_0.05O thin films at 673 K using a chemical spray technique. The polycrystalline nature and wurtzite structure of ZnO were confirmed by using XRD analysis with preferred growth along the (1 0 1) plane. The Zn_0.95La_0.05O deposits showed maximum crystallinity of 15.4 nm and a strain value of 2.4 × 10⁻³. The lattice constants increased for lanthanum-doped ZnO thin films due to the ionic radii mismatch of the doping material, which causes lattice expansion. Fibrous morphology was observed for ZnO, and a mixed structure of grains and fibers was observed for Zn_0.95La_0.05O films, which confirms the insertion of La³⁺ into the Zn²⁺ position. The Zn_0.95La_0.05O deposits showed transmittance above 80% due to the increased crystalline quality and a bandgap of 3.32 eV. The photoluminescence spectra showed peaks corresponding to e-h recombination, zinc defects (Zn_i and O_zn), and oxygen vacancy (O_i and V_o). The lanthanum-doped ZnO films showed increased band-edge emission and decreased defect-related peaks due to the increased crystalline quality. Hence, the doping of La³⁺ ions into a ZnO lattice enhances the crystalline quality and increases the transparency of the host ZnO matrix, which is suitable for optoelectric device applications. Full article

Co-doped ZnO thin films have attracted much attention in the field of transparent conductive oxides (TCOs) in solar cells, displays, and other transparent electronics. Unlike conventional single-doped ZnO, co-doped ZnO utilizes two different dopant elements, offering enhanced electrical properties and more controllable optical properties, including transmittance and haze; however, most previous studies focused on the electrical properties, with less attention paid to obtaining high haze using co-doping. Here, we prepare high-haze Ga- and Zr-co-doped ZnO (GZO:Zr or ZGZO) using atmospheric pressure plasma jet (APPJ) systems. We conduct a detailed analysis to examine the interplay between Zr concentrations and film properties. UV-Vis spectroscopy shows a remarkable haze factor increase of 7.19% to 34.8% (+384%) for the films prepared with 2 at% Zr and 8 at% Ga precursor concentrations. EDS analysis reveals Zr accumulation on larger and smaller particles, while SIMS links particle abundance to impurity uptake and altered electrical properties. XPS identifies Zr mainly as ZrO₂ because of lattice stress from Zr doping, forming clusters at lattice boundaries and corroborating the SEM findings. Our work presents a new way to fabricate Ga- and Zr-co-doped ZnO for applications that require low electrical resistivity, high visible transparency, and high haze. Full article

Transparent Conductive Oxides (TCOs) have been widely used as sensors for various hazardous gases. Among the most studied TCOs is SnO₂, due to tin being an abundant material in nature, and therefore being accessible for moldable-like nanobelts. Sensors based on SnO₂ nanobelts are generally quantified according to the interaction of the atmosphere with its surface, changing its conductance. The present study reports on the fabrication of a nanobelt-based SnO₂ gas sensor, in which electrical contacts to nanobelts are self-assembled, and thus the sensors do not need any expensive and complicated fabrication processes. The nanobelts were grown using the vapor–solid–liquid (VLS) growth mechanism with gold as the catalytic site. The electrical contacts were defined using testing probes, thus the device is considered ready after the growth process. The sensorial characteristics of the devices were tested for the detection of CO and CO₂ gases at temperatures from 25 to 75 °C, with and without palladium nanoparticle deposition in a wide concentration range of 40–1360 ppm. The results showed an improvement in the relative response, response time, and recovery, both with increasing temperature and with surface decoration using Pd nanoparticles. These features make this class of sensors important candidates for CO and CO₂ detection for human health. Full article

Following the Deepwater Horizon (DWH) oil spill in 2010, poor pulmonary health and reproductive failure in bottlenose dolphins (Tursiops truncatus) in the northern Gulf of Mexico were well-documented. One postulated etiology for the increased fetal distress syndrome and pneumonia found in affected perinatal dolphins was maternal hypoxia caused by lung disease. The objective of this study was to evaluate the utility of blood gas analysis and capnography in determining oxygenation status in bottlenose dolphins with and without pulmonary disease. Blood and breath samples were collected from 59 free-ranging dolphins in Barataria Bay, Louisiana (BB), during a capture–release health assessment program, and from 30 managed dolphins from the U.S. Navy Marine Mammal Program in San Diego, CA. The former was the oil-exposed cohort and the latter served as a control cohort with known health histories. Capnography and select blood gas parameters were compared based on the following factors: cohort, sex, age/length class, reproductive status, and severity of pulmonary disease. Animals with moderate–severe lung disease had higher bicarbonate concentrations (p = 0.005), pH (p < 0.001), TCO₂ (p = 0.012), and more positive base excess (p = 0.001) than animals with normal–mild disease. Capnography (ETCO₂) was found to have a weak positive correlation with blood PCO₂ (p = 0.020), with a mean difference of 5.02 mmHg (p < 0.001). Based on these findings, indirect oxygenation measures, including TCO₂, bicarbonate, and pH, show promise in establishing the oxygenation status in dolphins with and without pulmonary disease. Full article

A numerical simulation is a valuable tool since it allows the optimization of both time and the cost of experimental processes for time optimization and the cost of experimental processes. In addition, it will enable the interpretation of developed measurements in complex structures, the design and optimization of solar cells, and the prediction of the optimal parameters that contribute to manufacturing a device with the best performance. In this sense, a detailed simulation study was carried out in this work by the Solar Cell Capacitance Simulator (SCAPS). In particular, we evaluate the influence of absorber and buffer thickness, absorber defect density, work function in back contact, R_s, R_sh, and carrier concentration on a CdTe/CdS cell to maximize its performance. Furthermore, the incorporation effect of ZnO:Al (TCO) and CuSCN (HTL) nanolayers was studied for the first time. As a result, the efficiency of the solar cell was maximized from 16.04% to 17.74% by increasing the J_sc and V_oc. This work will play an essential role in enhancing the performance of CdTe-based devices with the best performance. Full article

Pairs of pyrrolysyl-tRNA synthetase (PylRS) and tRNA^Pyl from Methanosarcina mazei and Methanosarcina barkeri are widely used for site-specific incorporations of non-canonical amino acids into proteins (genetic code expansion). Previously, we achieved full productivity of cell-free protein synthesis for bulky non-canonical amino acids, including N^ε-((((E)-cyclooct-2-en-1-yl)oxy)carbonyl)-L-lysine (TCO*Lys), by using Methanomethylophilus alvus PylRS with structure-based mutations in and around the amino acid binding pocket (first-layer and second-layer mutations, respectively). Recently, the PylRS·tRNA^Pyl pair from a methanogenic archaeon ISO4-G1 was used for genetic code expansion. In the present study, we determined the crystal structure of the methanogenic archaeon ISO4-G1 PylRS (ISO4-G1 PylRS) and compared it with those of structure-known PylRSs. Based on the ISO4-G1 PylRS structure, we attempted the site-specific incorporation of N^ε-(p-ethynylbenzyloxycarbonyl)-L-lysine (pEtZLys) into proteins, but it was much less efficient than that of TCO*Lys with M. alvus PylRS mutants. Thus, the first-layer mutations (Y125A and M128L) of ISO4-G1 PylRS, with no additional second-layer mutations, increased the protein productivity with pEtZLys up to 57 ± 8% of that with TCO*Lys at high enzyme concentrations in the cell-free protein synthesis. Full article