Search Results (21,651)

To address the demand for lightweight commercial vehicle suspensions, this study investigates the replacement of traditional spring steel with E-glass fiber/epoxy composite materials. An equal-width, variable-thickness parabolic single-leaf spring was designed, with orthotropic mechanical properties obtained via ASTM standard tests. Finite element analysis (FEA) was combined with multi-objective optimization using a genetic algorithm, adjusting layup parameters to optimize stiffness, strength, and mass. Furthermore, to address the high failure risk at composite joints, a symmetric two-hole bolted end connection and a mid-span clamping structure were designed. The structural integrity was evaluated under vertical load, emergency braking, and steady-state cornering conditions using the Tsai–Wu tensor strength criterion. The optimization results demonstrate an 8.84% mass reduction for the composite spring main body compared to the initial design. The complete composite leaf spring assembly achieved approximately a 60.6% weight reduction relative to the original steel counterpart. The results indicate that the proposed design and optimization methodology effectively fulfills lightweighting objectives while satisfying all suspension performance and operational reliability requirements. Full article

Against the background of climate change intensifying extreme hail events, the photovoltaic module industry faces a critical trade-off between improving hail resistance and maintaining environmental sustainability. This study establishes an emergy–life cycle coupling assessment framework to systematically evaluate the environmental sustainability of six typical hail resistance enhancement designs across four hail risk scenarios in China. Five hierarchical hypotheses are proposed and validated through quantitative analysis. The optimal design point occurs at 30 mm hail resistance using 3.2 mm tempered glass, achieving a minimum unit environmental impact per impact resistance UEIC of 9.63 × 10¹² sej/mm. The ranking divergence index SDR between coupled emergy–LCA and conventional LCA methods is 0.267, with ecosystem service dependence ESD reaching 0.241 for composite backsheet designs, revealing natural capital overlooked by traditional methods. A complete ranking reversal occurs at a threshold hail frequency of 1.3 events per year, above which the 3.2 mm glass design outperforms standard modules with life cycle emergy input LCEA of 3.20 × 10¹⁴ sej versus 3.41 × 10¹⁴ sej under high-risk scenarios. Material type dominates environmental impact over structural parameters by a factor of 2.32, with recycled aluminum frames reducing ELCI by 12.4%. The dual-optimum design is identified as the 3.2 mm tempered glass scheme, achieving a combined sustainability score CSS of 0.782 and emergy yield ratio EYR of 3.86, outperforming the industry average of 3.61. Multi-objective optimization using NSGA-II yields a Pareto front of 12 non-dominated solutions, with the 3.2 mm glass design maintaining Pareto optimal status in 72% of Monte Carlo iterations. This research provides a quantitative decision-making framework recommending standard modules for regions below one annual hail event, the 3.2 mm glass design for regions between one and four annual events, and steel frame combinations above four annual events, demonstrating that moderate enhancement achieves the optimal balance between hail protection and environmental sustainability. Full article

Road construction contributes to embodied carbon in infrastructure, with asphalt-bound layers often dominating construction-stage greenhouse gas emissions in flexible pavements. Reclaimed asphalt pavement (RAP) and high-modulus asphalt concrete can reduce virgin material demand and improve structural efficiency, but their sustainability benefit depends on maintaining equivalent pavement performance. This study develops a climate-informed, mechanistic, environmental, and economic Pareto optimization framework for RAP-modified high-performance asphalt concrete (RAP-HPAC) pavement sections in Alberta. The framework couples fitted dynamic modulus master curves, monthly pavement temperature inputs, ALVA layered elastic analysis, Asphalt Institute fatigue and rutting criteria, A1–A5 global warming potential (GWP), and Alberta 2026 installed unit-price cost data. The RAP-HPAC mixture contains 50% RAP and was designed through a balanced mix design to target approximately 80% effective RAP binder activation. Three traffic classes were evaluated: 731, 1300, and 5426 ESAL/day/direction, each with 2% annual compound growth over a 20-year design period. Relative to independently optimized conventional HMA controls, Pareto-selected RAP-HPAC sections reduced P50 construction-stage GWP by approximately 19–30% and first cost by approximately 6–11% at a conservative 0.90× RAP-HPAC cost multiplier. The results show that RAP-HPAC is most beneficial when used as a structural-bound base that replaces conventional asphalt-bound capacity while preserving sufficient granular support. The framework provides a reproducible design-stage approach for comparing recycled high-modulus asphalt mixtures using performance, carbon, and cost criteria simultaneously. Full article

The significant CO₂ emissions from cement manufacturing and overuse of natural aggregates, especially river sand mining, have been a global environmental concern for decades. This is a review study that aimed to evaluate the solution by reviewing past studies on the incorporation of supplementary cementitious materials (SCMs) and recycled aggregates (RAs) to produce sustainable concrete (SC). Regarding environmental consequences, the results highlighted that the cement industry accounts for a 5–8% carbon footprint. Concurrently, the demand for high-quality river sand has escalated, leading to widespread river degradation, altered channel morphology, and effects on river ecosystems. Past studies’ experimental results indicate that silica fume (SF), as an effective SCM, enhances the strength and durability of sustainable concrete to its optimal levels. However, the higher RA content resulted in reductions in engineering properties. The published studies also reported that lower percentages of SF combined with RAs had a positive effect on the strength and durability of design mix concrete, thereby further strengthening the findings of this review. This factor was found to be missing in most studies. A cost–benefit analysis for combined SCMs and RAs was introduced in this study. This review study evaluated the cost–benefit analysis of 1 m³ of sustainable concrete. The highest benefit was observed at 20.97% in a study when optimized 10%SF + 100 RAs were combined. It showed that the combined use of SCMs with RAs at optimal levels satisfied the strength and durability requirements. In addition, the benefits of sustainable concrete were achieved without any cost increase, a new outcome revealed by this review. Full article

The transition towards carbon-neutral construction materials requires innovative solutions that combine reduced embodied energy, enhanced durability and improved building energy efficiency. This study investigates and compares two novel bioaerated low-density composites—BAAC and BIOAERMAC—developed through biologically driven aeration processes incorporating industrial byproducts. BAAC is produced using Saccharomyces cerevisiae and hydrogen peroxide, replacing conventional aluminum powder and improving safety while enabling the valorization of waste-derived yeast. BIOAERMAC is a gypsum-based composite incorporating synthetic anhydrite, microorganisms, peroxides, and recycled rubber from end-of-life tires. The materials were characterized in terms of hygrothermal behavior and dimensional stability, and compared with commercial autoclaved aerated concrete under equivalent mechanical strength conditions. The results highlight significant differences in moisture transport and shrinkage, primarily governed by pore structure and connectivity. BAAC exhibits behavior comparable to conventional AAC, whereas BIOAERMAC shows reduced capillary and hygroscopic absorption, indicating limited pore connectivity, but higher drying shrinkage. These findings demonstrate the effectiveness of bioaeration in tailoring pore structure and controlling the trade-off between moisture transport, durability, and dimensional stability, highlighting the potential of bioaerated composites for low-carbon and energy-efficient building applications. Full article

Photosynthetic biogas upgrading (PBU) using microalgae is a promising biological approach for converting raw biogas into biomethane while recovering nutrients and fixing part of the biogenic CO₂ into algal biomass. Unlike conventional physicochemical technologies, which mainly separate CO₂ from CH₄, PBU can combine gas upgrading with wastewater or digestate treatment, nutrient recycling, and biomass production. This review assesses the current state of PBU technology, with particular emphasis on high-rate algal ponds, absorption columns, and closed photobioreactors. It examines the main operating parameters that control gas–liquid mass transfer, carbonate buffering, and photosynthetic activity, including the liquid-to-gas ratio, pH, alkalinity, temperature, light regime, light intensity, and gas retention time. Special attention is given to the combined effects of the L/G ratio, pH, and alkalinity, as these parameters strongly influence CO₂ absorption, CH₄ enrichment, and O₂ contamination of the upgraded gas. The use of wastewater or anaerobic digestate instead of synthetic growth media is identified as an important sustainability advantage, particularly at wastewater treatment plants with existing anaerobic digestion and nutrient-rich side streams. However, digestate use may also create operational challenges related to turbidity, ammonium inhibition, solids, and variable composition. Available studies indicate that PBU may reduce operating costs and greenhouse gas emissions under favorable conditions while creating additional value from algal biomass. Nevertheless, wider deployment is still limited by high land requirements, seasonal variability, O₂ contamination, biomass harvesting, and limited evidence from large-scale systems. Future development should therefore focus on improved oxygen management, more efficient reactor designs, nanoparticle-assisted enhancement of photosynthetic activity, better integration with wastewater treatment, and AI-supported monitoring and control to improve process stability and support scale-up. Full article

Polyethylene terephthalate (PET) is one of the most widely used plastics for single-use applications, with annual global production exceeding 80 Mt. Enzymatic degradation of PET has emerged as a promising and sustainable alternative to conventional recycling methods, enabling the hydrolysis of PET into its constituent monomers. While amorphous PET can be efficiently degraded by polyester hydrolases identified from environmental sources, crystalline PET remains highly recalcitrant to enzymatic attack and constitutes a major bottleneck for the industrial implementation of enzymatic PET recycling. Although physicochemical pretreatments can increase PET amorphicity, these approaches often require substantial energy input, thereby compromising the overall sustainability of the process. Consequently, the development of enzymes capable of directly degrading crystalline PET has long been sought; however, currently engineered enzymes exhibit insufficient catalytic activity toward highly crystalline PET owing to multiple factors, including limited substrate surface accessibility, highly ordered polymer morphology, incompatible binding-pocket geometries, restricted chain mobility, and unfavorable conformational energetics at the polymer–enzyme interface. This review aims to evaluate the factors limiting the enzymatic degradation of crystalline PET and to assess current strategies for overcoming low degradation rates. Specifically, it examines advances in substrate modification as well as enzyme- and process-engineering approaches designed to improve the depolymerization of crystalline PET. The advantages and limitations of these strategies are critically compared and discussed, highlighting the remaining challenges and future directions toward efficient and scalable biocatalytic PET recycling. Full article

This study critically addresses the challenge of selecting optimal insulation materials for contemporary, energy-efficient building envelopes, a decision with profound environmental, structural, and occupational health consequences. The paper responds to the growing demand for sustainable, resilient solutions by comparing wool, a bio-based, regenerative material, and expanded polystyrene (EPS), a synthetic polymer widely implemented in the construction industry, and advanced laboratory testing (thermal conductivity, moisture buffering, freeze–thaw resistance) is discussed in a comprehensive synthesis of the recent literature. Also, field evaluations from European retrofits and pilot projects (UK, Denmark, Finland, Iceland, Norway, Sweden, Germany and France) further contextualize performance outcomes, and life cycle impacts are considered. Recent results reveal that wool insulation achieves a moisture buffering value (MBV) between 1.8 and 2.7 (g/m²) % RH, minimal vapor resistance (mvr = 1–2), and preserves functional and structural integrity through more than 100 freeze–thaw cycles, leading to significant stabilization of the interior microclimate and enhanced durability. In contrast, EPS delivers lower thermal conductivity (0.032–0.037 (W/mK), critical for reducing heating/cooling demand, but exhibits limited vapor permeability (lvp = 60–150 MN·s/(g·m)), increased risk of condensation and mold, and reduced compressive strength (<22% after 30 cycles), especially when ventilation details are inadequate. Hybrid envelope systems leveraging both EPS and wool are demonstrated to optimize energy efficiency (up to 23% seasonal savings) and reduce interior humidity fluctuations, while lifecycle and recycling assessments show wool panels to be markedly superior in carbon footprint reduction and circularity. The stratification of insulation layers incorporating wool for vapor and moisture control, and EPS for pure thermal resistance is emerging as best practice in sustainable retrofit and new-build projects. Recommendations highlight the necessity for rigorous laboratory validation, international standards alignment, and integrated material design for robust hygrothermal comfort and environmental performance. The review also covers wool- and EPS-based hybrid composites, showing how natural fibers can improve key mechanical properties without compromising thermal insulation performance or environmental benefits. Full article

Waste lubricating oils (WLOs) represent a major stream of hazardous petroleum-based residues, with global generation exceeding 24 million tons annually. Improper disposal of WLOs poses risks to soil, water, and air quality, while their chemical composition makes them a potential secondary resource within circular economy frameworks. This review summarizes conventional, advanced, and emerging technologies reported for the recycling and valorization of WLOs into high-value petrochemicals and carbon-based materials. Established processes such as acid–clay treatment, solvent extraction, and vacuum distillation are discussed together with more recent approaches, including catalytic upgrading, hydrotreatment, membrane separation, and thermochemical conversion methods such as pyrolysis and catalytic cracking. Reported data on process performance, environmental considerations, techno-economic indicators, and life cycle assessment outcomes are comparatively analyzed to outline current trends, technical challenges, and future development directions in WLO recycling. Particular attention is given to thermochemical pathways capable of generating carbonaceous materials, including carbon black, porous carbons, and functional carbon nanostructures with potential applications in adsorption, catalysis, electrochemical systems, and tribological formulations. Hybrid and integrated process configurations described in the literature are highlighted for their potential to improve recovery efficiency, enhance product quality, and reduce environmental burdens. In addition, recent life cycle assessment (LCA) and techno-economic analysis (TEA) studies are reviewed to provide insight into the environmental and economic implications of advanced re-refining systems. Overall, the reviewed literature indicates that WLO recycling represents not only an important element of sustainable lubricant management but also a promising waste-to-carbon strategy for the production of value-added carbon-based materials and petrochemical products. Full article

Asphalt concrete pavements in many regions suffer from premature deterioration caused by low-temperature cracking and rutting resistance under heavy traffic loads and high summer temperatures. While polymer-modified bitumen is widely used to improve pavement performance, the high cost of commercial polymers restricts its extensive application. This study evaluates the potential of polymer waste as an alternative modifier for asphalt binders to enhance mechanical performance while reducing economic and environmental costs. Experimental results demonstrate that an optimal plastic waste content of 1.0–1.5% significantly improves rutting resistance and increases binder rigidity. The incorporation of 1.5% low-density polyethylene (LDPE) and high-density polyethylene (HDPE) enhances deformation resistance, elastic modulus, and temperature stability. LDPE exhibits better compatibility with bitumen and dissolves more readily, contributing to improved binder homogeneity, whereas HDPE provides higher stiffness and thermal stability. The combined use of polymer waste with styrene–butadiene–styrene (SBS) produces a pronounced synergistic effect, leading to improvements in physical and mechanical properties exceeding 25% compared to Kazakhstan regulatory standards. Increasing polymer waste content further enhances the rigidity of both the binder and asphalt concrete, thereby improving rutting resistance and plastic deformation at elevated temperatures. The proposed approach offers a cost-effective and sustainable solution for road construction, promoting plastic waste recycling, reducing reliance on virgin polymers, and improving pavement durability, particularly under the climatic and traffic conditions of Kazakhstan. Full article

Lithium has become one of the key raw materials for the energy transition due to the central role of lithium-ion batteries in electromobility, energy storage, and the integration of renewable energy sources. However, the rapid increase in demand reveals growing environmental, social, geopolitical, and market tensions. The aim of the paper is a critical synthesis of global lithium utilization from the perspective of challenges, technological innovations, and integrative strategies supporting a more sustainable material–energy system. A broad, systematic literature review covering the entire value chain was applied: resources, extraction, processing, end-use applications, second life of batteries, recycling, and governance. The analysis shows that the strategic importance of lithium arises from the increasing demand pressure from electric vehicles and stationary storage, while the sustainability of the current model is constrained by supply concentration, uneven control over downstream stages, the water–carbon footprint of extraction and processing, social conflicts, and incomplete integration of secondary loops. At the same time, innovations such as direct lithium extraction (DLE), recovery from geothermal brines, design for recycling, second life, and battery passports can partially alleviate these tensions, but they do not eliminate the need for primary supply in the short term. The conclusion of the work is that sustainable global lithium utilization requires simultaneous diversification of sources, development of circular value chains, and multi-level governance integrating resource security, environmental efficiency, and social legitimacy. Full article

Ionic liquids remain attractive alternatives as multifunctional media for the sustainable biosynthesis of lactones. Their unique physicochemical properties, including negligible vapor pressure, high thermal stability, and tunable polarity, offer significant advantages in terms of biocatalyst stabilization and reaction selectivity. For lactone synthesis, ionic liquids facilitate improved control over enzymatic transformations, enable efficient catalyst recycling, and reduce solvent consumption. This review summarizes recent advances in the application of ionic liquids as solvents or support modifiers in enzymatic lactone synthesis, focusing also on ε-caprolactone biosynthesis. A green chemistry metrics evaluation was also performed for selected examples from the literature. The role of ionic liquids in enhancing process efficiency and supporting green, sustainable process design is critically discussed, highlighting their potential for the development of more sustainable and environmentally friendly lactone production technologies. Full article

Basalt-fiber-reinforced recycled aggregate concrete (BFRAC) produced with 100% recycled coarse aggregate is still constrained by the inferior quality of recycled aggregate and the difficulty of optimizing fiber reinforcement parameters. This study investigated the effects of basalt fiber length configuration and dosage on the mechanical performance and pore structure of recycled aggregate concrete incorporating recycled coarse aggregate subjected to two-step pretreatment with nano-silica and cement slurry. Four fiber length configurations, namely 6, 12, and 24 mm and a mixed-length system, were evaluated at volume fractions of 0.1, 0.2, and 0.3%. The reinforcing effect was assessed through compressive strength, splitting tensile strength, scanning electron microscopy, mercury intrusion porosimetry, and statistical analysis. The pretreatment improved recycled aggregate quality, reducing water absorption from 4.97% to 3.11% and crushing index from 20.5% to 13.4%. Basalt fiber incorporation generally enhanced mechanical performance, although the response depended on fiber length and dosage. At 28 days, BF24V1 achieved the highest compressive strength, whereas BFmixV1 exhibited the best overall performance by combining high compressive strength with the highest splitting tensile strength. Relative to the average performance of the corresponding single-length mixtures at the same dosage, the mixed-length system showed a positive synergistic effect. Microstructural observations indicated that this behavior was associated with more effective crack bridging and refinement of the pore-size distribution. The results demonstrate that a low-dosage mixed-length basalt fiber system provides an effective route for upgrading pretreated waste-derived aggregate into higher-performance recycled aggregate concrete. Full article

The increasing accumulation of glass-fiber-reinforced polymer (GFRP) waste poses significant environmental challenges, calling for effective and scalable recycling strategies. In this work, a solvent-assisted cold mixing process was employed to incorporate very high amounts of GFRP (up to 75 wt%) into recycled expanded polystyrene (ePS). The composites were deeply characterized, with particular attention to the role of particle size distribution and filler content. The results demonstrated that GFRP granulometry played a key role in determining composite performance. Intermediate particle sizes (0.25 mm) provided the best balance between dispersion, interfacial interaction, and mechanical properties, whereas excessively fine fractions introduced defects and reduced impact resistance (from 0.7 to 2.0 kJ/m² going from dust to 0.25 mm at 75 wt%). Notably, the solvent-assisted approach has been widely recognized as an effective strategy to ensure homogeneous dispersion even at high filler contents, allowing subsequent melt processing without re-agglomeration. Recycled composites retained most of their chemical and mechanical properties after reprocessing, with only moderate performance losses mainly related to fiber fragmentation. Overall, this study demonstrates an effective and sustainable route for the simultaneous valorization of ePS and GFRP waste, enabling the production of highly loaded composites with preserved functionality and improved resource efficiency. Full article

Cellulose is the most promising abundant renewable polymer material with the highest potential for the future low-carbon biorefineries. However, its utilization in industry is limited by the structural recalcitrance as a result of organization of crystalline domains, fibrillar architecture hierarchy and intramolecular and intermolecular hydrogen bonding which is responsible for access restriction for the catalysts and consequent cleavage of the glycosidic bonds. Therefore, efficient depolymerization of cellulose is of paramount importance as a step in biomass conversion into the low molecular products. In this review, the recent advances in cellulose depolymerization are discussed. The chemical, enzymatic, thermal, thermochemical, mechanochemical, oxidative and hybrid catalytic method is thoroughly discussed. Attention is paid to the mechanism of the depolymerization reaction steps as glycosidic bond activation as hydrolytic, radical mediated, and energy assisted pathways. Selectivity and conversion efficiency based on substrate morphology, solvent system and catalyst design are also discussed. Further, there is a comparison of key performance metrics which are relevant for the industrial process as product yield, carbon efficiency, energy demand, stability of the catalyst, solvent recyclability and impact to the environmental lifecycle. The pros and cons of the various methods are also represented. Processes based on mineral acids enable rapid conversion. However, they suffer from corrosion, waste handling issues and degradation by-products. On the other hand, enzymatic depolymerization processes offer relatively high selectivity but they are limited in terms of feedstock sensitivity and slow reaction kinetics. The downstream valorization mechanisms are also described with the result being that no single available technology is capable of satisfying all industrial requirements. Thus, future progress expects integrated circular processes where advanced catalysis, process intensification and digital optimization strategies take place. Full article