Search Results (24)

The continuous emission of persistent and bioaccumulative pollutants into aquatic environments has become a critical global issue. Among these, per- and polyfluoroalkyl substances (PFASs) are of particular concern due to their exceptional stability, extensive industrial use, and adverse impacts on ecosystems and human health. Their resistance to conventional physical, chemical, and biological treatments stems from the strength of the carbon–fluorine bond, which prevents efficient degradation under standard conditions. This review provides a concise and updated assessment of emerging advanced oxidation processes (AOPs) for PFAS remediation, with emphasis on heterogeneous photocatalysis and electrochemical oxidation. Photocatalytic systems based on In₂O₃, Bi-based oxyhalides, and Ga₂O₃ exhibit high PFAS degradation under UV light, while heterojunctions and MOF-derived catalysts improve defluorination under solar irradiation. Electrochemical oxidation—particularly using Ti₄O₇ reactive electrochemical membranes and BDD anodes—achieves near-complete mineralization with comparatively low specific energy demand. Energy consumption (E_EO) was calculated from literature data for UV- and simulated-solar-driven photocatalytic systems, enabling a direct comparison of their energy performance. Although solar-driven processes offer clear environmental advantages, they generally exhibit higher E_EO values, mainly due to lower apparent quantum yields and less efficient utilization of the incident solar photons compared to UV-driven systems. Hybrid systems coupling photocatalysis and electro-oxidation emerge as promising strategies to enhance degradation efficiency and reduce energy requirements. Overall, the review highlights key advances and future research directions toward scalable, energy-efficient, and environmentally sustainable AOP-based technologies for PFAS removal. Full article

Per- and polyfluoroalkyl substances (PFAS) are emerging contaminants that persist in soil environments, necessitating reliable models to predict their fate and transport. This study evaluates the performance of three theoretical models in estimating the maximum adsorption capacity (Qmax) of perfluorooctanoic acid (PFOA) on kaolinite and montmorillonite clay minerals. The models assessed include a van der Waals interaction-based approach, a monolayer adsorption capacity model, and a surface site density model emphasizing reactive hydroxyl groups at mineral edges. Benzene, nitrogen, and glyphosate molecules were used as reference compounds for model validation. Results indicated that the van der Waals model significantly underestimated Qmax (0.0007 mg·g⁻¹ for kaolinite), while the monolayer capacity model produced substantial overestimations (17.51 mg·g⁻¹) compared to the experimental range (0.10–10.0 mg·g⁻¹). The surface site density model provided the most accurate predictions (3.39 mg·g⁻¹ for kaolinite), although it slightly underestimated values for montmorillonite (0.20 mg·g⁻¹) by excluding interlayer adsorption. These discrepancies demonstrate that simplified models cannot adequately capture the complex adsorption behavior of PFAS. Accurate prediction requires site-specific approaches incorporating electrostatic forces, hydrogen bonding, and steric effects. As PFAS accumulation in soil directly contributes to groundwater contamination, improving adsorption models is essential for accurate risk assessment and the development of effective remediation strategies. Full article

Hypertension is a major public health problem worldwide, and high-salt diets are one of the main causes of hypertension. The intestinal mucosal immune system is the largest immune organ in vertebrates. Hypertension was associated with increased intestinal permeability and an inflammatory state. The bacterial communities attached to the intestinal mucosa played a significant role in the development and maturation of the autoimmune system, as well as inflammation and immunity to disease. In this review, we focused on the relationship between the impaired intestinal barrier and the development and progression of hypertension under the high-salt dietary pattern. We systematically reviewed how a high-salt diet caused hypertension by disrupting the intestinal mechanical, chemical, and microbial barriers, interacting with immunogenic isolevuglandin (IsoLG)-protein adducts and microbiota, and activating the mitogen-activated protein kinase (MAPK)/nuclear factor-kappa B (NF-κB) signaling pathway. Meanwhile, this review also summarizes the dietary therapy for hypertension, which involves supplementing natural antihypertensive substances and adjusting dietary patterns to repair the intestinal barrier and assist in lowering blood pressure. Such measures included supplementing plant-based foods, polyunsaturated fatty acids (PFAs), probiotics, prebiotics, food–medicine homologous substances (FMHS), vitamins, and minerals, as well as transforming high-salt dietary patterns into the dietary approaches to stop hypertension (DASH), the Mediterranean diet (MD), and the ketogenic diet (KD), with the aim of providing a reference for the occurrence, development, and dietary prevention and control of high-salt hypertension. Full article

Coagulation–flocculation, historically reliant on simple inorganic salts, has evolved into a technically sophisticated process that is central to the removal of turbidity, suspended solids, organic matter, and an expanding array of micropollutants from complex wastewaters. This review synthesizes six decades of research, charting the transition from classical aluminum and iron salts to high-performance polymeric, biosourced, and hybrid coagulants, and examines their comparative efficiency across multiple performance indicators—turbidity removal (>95%), COD/BOD reduction (up to 90%), and heavy metal abatement (>90%). Emphasis is placed on recent innovations, including magnetic composites, bio–mineral hybrids, and functionalized nanostructures, which integrate multiple mechanisms—charge neutralization, sweep flocculation, polymer bridging, and targeted adsorption—within a single formulation. Beyond performance, the review highlights persistent scientific gaps: incomplete understanding of molecular-scale interactions between coagulants and emerging contaminants such as microplastics, per- and polyfluoroalkyl substances (PFAS), and engineered nanoparticles; limited real-time analysis of flocculation kinetics and floc structural evolution; and the absence of predictive, mechanistically grounded models linking influent chemistry, coagulant properties, and operational parameters. Addressing these knowledge gaps is essential for transitioning from empirical dosing strategies to fully optimized, data-driven control. The integration of advanced coagulation into modular treatment trains, coupled with IoT-enabled sensors, zeta potential monitoring, and AI-based control algorithms, offers the potential to create “Coagulation 4.0” systems—adaptive, efficient, and embedded within circular economy frameworks. In this paradigm, treatment objectives extend beyond regulatory compliance to include resource recovery from coagulation sludge (nutrients, rare metals, construction materials) and substantial reductions in chemical and energy footprints. By uniting advances in material science, process engineering, and real-time control, coagulation–flocculation can retain its central role in water treatment while redefining its contribution to sustainability. In the systems envisioned here, every floc becomes both a vehicle for contaminant removal and a functional carrier in the broader water–energy–resource nexus. Full article

Deforestation and wildfires drastically impact vegetation cover, consequently affecting water dynamics. These hazards alter the different components of the water cycle, including evapotranspiration, runoff, infiltration, and groundwater recharge. Overall, runoff increases while infiltration and groundwater recharge decrease. Furthermore, these hazards significantly alter the chemistry of both surface water and groundwater. The main changes to water quality relate to turbidity, bacterial load, mineralization and nutrients. Forest fires can also release contaminants such as heavy metals, polycyclic aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs). Other contaminants can be introduced by products used in firefighting, such as retardants and perfluoroalkyl substances (PFAS). This paper reviews the impact of deforestation and wildfires on water resources, especially with a view to their use as raw water for drinking water production. The paper identifies the magnitude of the changes induced in water quantity and quality. Even if the results are climate- and site-specific, they provide an indication of the possible magnitude of these impacts. Finally, the various changes brought about by these hazards are ranked according to their potential impact on drinking water production. Full article

Per- and polyfluoroalkyl substances (PFAS) are a diverse group of synthetic fluorinated compounds widely used in industrial and consumer products due to their exceptional thermal stability and hydrophobicity. However, these same properties contribute to their environmental persistence, bioaccumulation, and potential adverse health effects, including hepatotoxicity, immunotoxicity, endocrine disruption, and increased cancer risk. Traditional water treatment technologies, such as coagulation, sedimentation, biological degradation, and even advanced membrane processes, have demonstrated limited efficacy in removing PFAS, as they primarily separate or concentrate these compounds rather than degrade them. In response to these limitations, photoassisted processes have emerged as promising alternatives capable of degrading PFAS into less harmful products. These strategies include direct photolysis using UV or VUV irradiation, heterogeneous photocatalysis with materials such as TiO₂ and novel semiconductors, light-activated persulfate oxidation generating sulfate radicals, and photo-Fenton reactions producing highly reactive hydroxyl radicals. Such approaches leverage the generation of reactive species under irradiation to cleave the strong carbon–fluorine bonds characteristic of PFAS. This review provides a comprehensive overview of emerging photoassisted technologies for PFAS removal from water, detailing their fundamental principles, degradation pathways, recent advancements in material development, and integration with hybrid treatment processes. Moreover, it discusses current challenges related to energy efficiency, catalyst deactivation, incomplete mineralization, and scalability, outlining future perspectives for their practical application in sustainable water treatment systems to mitigate PFAS pollution effectively. Full article

Laccases, a class of multicopper oxidases found in diverse biological sources, have emerged as key green biocatalysts with significant potential for eco-friendly pollutant degradation. Their ability to drive electron transfer reactions using oxygen, converting pollutants into less harmful products, positions laccases as promising tools for scalable and sustainable treatment of wastewater, soil, and air pollution. This review explores laccase from a translational perspective, tracing its journey from laboratory discovery to real-world applications. Emphasis is placed on recent advances in production optimization, immobilization strategies, and nanotechnology-enabled enhancements that have improved enzyme stability, reusability, and catalytic efficiency under complex field conditions. Applications are critically discussed for both traditional pollutants such as synthetic dyes, phenolics, and pesticides and emerging contaminants, including endocrine-disrupting chemicals, pharmaceuticals, personal care products, microplastic additives, and PFAS. Special attention is given to hybrid systems integrating laccase with advanced oxidation processes, bioelectrochemical systems, and renewable energy-driven reactors to achieve near-complete pollutant mineralization. Challenges such as cost–benefit limitations, limited substrate range without mediators, and regulatory hurdles are evaluated alongside solutions including protein engineering, mediator-free laccase variants, and continuous-flow bioreactors. By consolidating recent mechanistic insights, this study underscores the translational pathways of laccase, highlighting its potential as a cornerstone of next-generation, scalable, and eco-friendly remediation technologies aligned with circular bioeconomy and low-carbon initiatives. Full article

PFASs, compounds to which the C-F bond—the strongest known in nature—bestows high resistance to degradation, have been detected in surface and groundwater worldwide, including drinking water supplies. Current regulations on long-chain PFASs resulted in the shift to short-chain PFASs in industrial uses, with their increasing environmental detection. Currently, suggested BATs for PFAS removal from aqueous solutions include mainly adsorption or membrane filtration; however, different response behavior to even simple treatment was observed concerning long- and short-chain PFAS molecules. In order to permanently destroy (mineralize) PFASs and their precursors, treatment technologies that can deliver sufficiently high energy to crack the C-F bond are needed. This paper discusses current PFAS removal technologies and state of the art advanced methods for PFAS removal and destruction, critically discussing their efficiency, applicability, emerging issues, and future prospects. Full article

PFASs, or per- and polyfluoroalkyl substances, comprise a diverse group of synthetic chemicals known for their widespread use, persistence, and potential environmental and health risks. The sonolytic treatment of PFASs is one of the technologies with the ability to complete destruction without harmful byproducts. This study aims to provide a theoretical explanation for the sonolytic treatment of PFAS. Combining insights from molecular dynamics simulations with experimental data, the influence of chain length and functional headgroups on the PFAS destruction mechanism was investigated. The findings revealed that the impact on functional head groups and chain length on PFAS degradation via sonolysis treatment is complex and multifaceted. The preliminary degradation step is attributed to be headgroup cleavage, while differences in degradation rates between perfluorocarboxylic acids (PFCAs) and perfluorosulfonic acids (PFSAs) are primarily influenced by adsorption at the air–water interface of micro/nanobubbles created by ultrasound and dictated by compound hydrophobicity characteristics. Moreover, longer-chain PFAS compounds tend to degrade faster than shorter-chain counterparts due to their enhanced hydrophobic characteristics, facilitating adsorption and subsequent mineralization. The sonolytic environment significantly influences PFAS degradation, with aqueous sonolysis proving the most effective compared to dry pyrolysis or thermal combustion, highlighting the importance of considering environmental factors in remediation strategies. These insights provide valuable guidance for designing effective PFAS remediation strategies, emphasizing the need to consider molecular structure and environmental conditions. Further research and technological innovation are essential for developing sustainable approaches to mitigate PFAS pollution’s adverse impacts on human health and the environment. Full article

This study investigates the impact of an innovative mineral additive, ICRETE, on steel-reinforced concrete’s compressive strength and corrosion resistance. Nineteen concrete mixes were designed incorporating recycled industrial by-products, including Ground Granulated Blast Furnace Slag (GGBS) and Pulverized Fuel Ash (PFA), with varying dosages of ICRETE. Compressive strength was tested using cube specimens, cured, and assessed at 3, 7, and 28 days following IS 516-2018 standards. Corrosion behavior was evaluated in accordance with ASTM G109, employing macrocell potential monitoring and electrochemical methods, including Tafel extrapolation and linear polarization resistance. The results revealed that ICRETE-enhanced mixes achieved compressive strengths of 56.93 MPa at a water–cement ratio of 0.35 and 50.61 MPa at 0.38, surpassing the control mix’s 50.9 MPa at 0.33. Microstructural analysis via X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that ICRETE improved hydration, reduced porosity, and refined the microstructure, contributing to more excellent durability. Meanwhile, results demonstrated that the ICRETE additive reduced corrosion rates, displaying lower corrosion current densities and higher polarization resistance values where the corrosion rate dropped from 0.01 mmpy in control samples to 0.0081 mmpy with ICRETE. Environmental assessments indicated that ICRETE could significantly lower CO₂ emissions, reducing up to 46.50 kg CO₂ per cubic meter of concrete. These findings highlight ICRETE’s potential to enhance strength and durability, supporting its use in sustainable, eco-friendly concrete applications. Full article

Per-and Polyfluoroalkyl substances (PFASs) are recalcitrant organofluorine contaminants, which demand urgent attention due to their bioaccumulation potential and associated health risks. While numerous current treatments technologies, including certain plasma-based treatments, can degrade PFASs, their complete destruction or mineralization is seldom achieved. Extensive aqueous PFAS mineralization capability coupled with industrial-level scaling potential makes gliding arc plasma (GAP) discharges an interesting and promising technology in PFAS mitigation. In this study, the effects of GAP discharge’s thermal and reactive properties on aqueous perfluorooctanesulfonic acid (PFOS) mineralization were investigated. Treatments were conducted with air and nitrogen GAP discharges at different plasma gas temperatures to investigate the effects of plasma thermal environment on PFOS mineralization; the results show that treatments with increased plasma gas temperatures lead to increased PFOS mineralization, and discharges in air were able to mineralize PFOS at relatively lower plasma gas temperatures compared to discharges in nitrogen. Studies were conducted to identify if GAP-based PFOS mineralization is a pure thermal process or if plasma reactive chemistry also affects PFOS mineralization. This was done by comparing the effects of thermal environments with and without plasma species (air discharge and air heated to plasma gas temperatures) on PFOS mineralization; the results show that while GAP discharge was able to mineralize PFOS, equivalent temperature air without plasma did not lead to PFOS mineralization. Finally, mineralization during treatments with GAP discharges in argon and air at similar gas temperatures were compared to investigate the role of plasma species in PFOS mineralization. The results demonstrate that treatments with argon (monoatomic gas with higher ionization) lead to increased PFOS mineralization compared to treatments with air (molecular gas with lower ionization), showing the participation of reactive species in PFOS mineralization. Full article

Per- and polyfluoroalkyl substances (PFAS) are fluorinated and refractory pollutants that are ubiquitous in industrial wastewater. Photocatalytic destruction of such pollutants with catalysts such as TiO₂ and ZnO is an attractive avenue for removal of PFAS, but refined forms of such photocatalysts are expensive. This study, for the first time, utilized milled unrefined raw mineral ilmenite, coupled to UV-C irradiation to achieve mineralization of the two model PFAS compounds perfluorooctanoic acid (PFOA) and perfluoro octane sulfonic acid (PFOS). Results obtained using a bench-scale photocatalytic reactor system demonstrated rapid removal kinetics of PFAS compounds (>90% removal in less than 10 h) in environmentally-relevant concentrations (200–1000 ppb). Raw ilmenite was reused over three consecutive degradation cycles of PFAS, retaining >80% removal efficiency. Analysis of degradation products indicated defluorination and the presence of shorter-chain PFAS intermediates in the initial samples. End samples indicated the disappearance of short-chain PFAS intermediates and further accumulation of fluoride ions, suggesting that original PFAS compounds underwent mineralization due to an oxygen-radical-based photocatalytic destruction mechanism induced by TiO₂ present in ilmenite and UV irradiation. The outcome of this study implies that raw ilmenite coupled to UV-C is suitable for cost-effective reactor operation and efficient photocatalytic destruction of PFAS compounds. Full article

Per- and polyfluoroalkyl substances (PFAS) are a group of fluorinated synthetic chemicals that are highly recalcitrant, toxic, and bio-accumulative and have been detected in biosolids worldwide, posing potential risks to humans and the environment. Recent studies suggest that the organic C-F bond in PFAS can be destructed and potentially mineralised into inorganic fluorides during thermal treatment. This study focuses on thermodynamic equilibrium investigations and the fate of fluorine compounds post-PFAS destruction during biosolid thermal treatment. The results indicate that gas-phase fluorine compounds are mainly hydrogen fluoride (HF) and alkali fluorides, whereas solid-phase fluorine compounds include alkaline earth fluorides and their spinels. High moisture and oxygen content in the volatiles increased the concentration of HF in the gas phase. However, adding minerals reduced the emission of HF in the gas phase significantly and enhanced the capture of fluorine as CaF₂ spinel in the solid phase. This study also investigates the effect of feedstock composition on the fate of fluorine. High ash content and low volatile matter in the feedstock reduced HF gas emissions and increased fluorine capture in the solid product. The findings of this work are useful in designing thermal systems with optimised operating conditions for minimising the release of fluorinated species during the thermal treatment of PFAS-containing biosolids. Full article

Heat pumps have the potential for several applications across various industrial sectors, showcasing significant promise, especially in sectors such as pulp and paper, food and beverage, chemical, non-metallic minerals, and machinery. Envisioning the near future, there is confidence that heat pumps can achieve temperatures above 200 °C, offering substantial potential for utilization in these sectors. Nevertheless, a crucial aspect for the advancement of high-temperature heat pumps is the selection of the fluid. Fluid selection involves considerations of both thermodynamic efficiency and environmental impact, requiring fluids with zero ODP, negligible GWP, and no PFAS. Moreover, it is essential to consider the risks to human health associated with a specific fluid. Despite extensive research, particularly in the realm of vapour compression heat pumps, choosing the most suitable working fluid for these applications is a complex undertaking. Therefore, this paper conducts a theoretical analysis to evaluate potential fluids with suitable thermodynamic properties for high-temperature heat pumps (HTHPs). The comparative results gleaned from this study provide valuable insights for the comprehensive analysis of fluids, showing promise within temperature ranges dictated by specific applications. The metrics employed in the comparison emphasise the merits of fluids in terms of the overall performance, dimensions, and operating ranges of applicable compressor, heat exchange capacity, transport properties, and safety. One noteworthy finding from the analysis is that maintaining a constant HTHP lift (at 40 K) results in having the highest COP across all fluids when the condensing temperature ranges between 85% and 90% of their respective critical temperatures. According to the results of the analysis, natural fluids, including water and alcohols like ethanol or methanol, emerge as particularly compelling candidates. Full article

Mineral wool ceilings supported by iron sheet-backed painted runners are commonly used in public buildings without specific seismic design intensity requirement, which is not good for resilient civil infrastructure. However, standard and fundamental seismic capacity data concerned with the use of mineral wool ceilings are lacking. Accordingly, in this study, nine groups of prototype specimens of basic ceiling units were designed based on construction requirements, and 90 different test scenarios were conducted. The PGAx input increased from 0.10 g to 1.50 g over ten runs for each group of specimens. Two failure processes and six types of damage phenomena as well as their corresponding repair measures were identified. Moreover, the influence of suspension devices, panel specifications, boundary conditions, and other construction features on the seismic response was investigated. When peak floor acceleration (PFA) was low, the hanger rod and hanger rod–diagonal wire effectively reduced the percentage of fallen ceiling panels. However, when the PFA was high, the hanger rod–diagonal wire aggravated the damage. The use of an additional wire hanger on the main runners, a large lightweight ceiling panel, a high suspension height, and a fixed boundary effectively reduced the percentage of panels falling from the basic ceiling unit and improved the seismic capacity. The use of a large panel in which the amount of material was increased by 1.7% effectively reduced the percentage of fallen ceiling panels. Moreover, fixing the boundary joints with adhesive was a convenient method for improving seismic capacity at a low cost. The results contribute to enhancing resilient civil infrastructure and sustainability. Full article