Search Results (83)

The degradation process of HVOF-MCrAlY + APS-nanostructured YSZ (APS-nYSZ) thermal barrier coatings, produced using gas turbine OEM-approved MCrAlY powders, is investigated by studying the TGO growth and crack propagation behaviors in a thermal cycling environment. The TGO growth yields a parabolic mechanism on the surfaces of all HVOF-MCrAlYs, and the growth rate increases with the aluminum content in the “classical” MCrAlYs. The APS-nYSZ layer comprises micro-structured YSZ (mYSZ) and nanostructured YSZ (nYSZ) zones. Both mYSZ/mYSZ and mYSZ/nYSZ interfaces appear to be crack nucleation sites, resulting in crack propagation and consequent crack coalescence within the APS-nYSZ layer in the APS-nYSZ/HVOF-MCrAlY vicinity. Crack propagation in the TBCs can be characterized as a steady-state crack propagation stage, where crack length has a nearly linear relationship with TGO thickness, and an accelerating crack propagation stage, which is apparently a result of the coalescence of neighboring cracks. All TBCs fail in the same way as APS-/HVOF-MCrAlY + APS-conventional YSZ analogs, but the difference in thermal cycling lives is not substantial, although the HVOF-low Al-NiCrAlY encounters chemical failure in the early stage of thermal cycling. Full article

This paper presents the results of a comprehensive study of the structure, phase composition, thermal corrosion, and tribological properties of multilayer gradient coatings based on YSZ/NiCrAlY obtained using detonation spraying. X-ray phase analysis showed that the coatings consist entirely of metastable tetragonal zirconium dioxide (t’-ZrO₂) phase stabilized by high temperature and rapid cooling during spraying. SEM analysis confirmed the multilayer gradient phase distribution and high density of the structure. Wear resistance, optical profilometry, wear quantification, and coefficient of friction measurements were used to evaluate the operational stability. The results confirm that the structural parameters of the coating, such as porosity and phase gradient, play a key role in improving its resistance to thermal corrosion and CMAS melt, which makes such coatings promising for use in high-temperature applications. It is shown that a dense and thick coating effectively prevents the penetration of aggressive media, providing a high barrier effect and minimal structural damage. Tribological tests in the temperature range from 21 °C to 650 °C revealed that the best characteristics are observed at 550 °C: minimum coefficient of friction (0.63) and high stability in the stage of stable wear. At room temperature and at 650 °C, there is an increase in wear due to the absence or destabilization of the protective layer. Full article

The main purpose of this work is to suppress the rate of thermal and oxidative corrosion of copper substrates using double-ceramic-layer thermal barrier coatings (TBCs). Herein, the orthogonal spray experiment was employed to optimize the spraying parameters for TBCs consisting of Cu/NiCoCrAlY/8YSZ/(Y_0.5Gd_0.5)TaO₄. The thermal cycling and average mass loss rate of TBCs prepared by atmospheric plasma spraying (APS) with optimum spraying parameters correspond to 20 cycles and 0.56‰, respectively. The thermal conductivity (0.39 W·m⁻¹·K⁻¹ at 900 °C) of (Y_0.5Gd_0.5)TaO₄ is 71.68% and 52.7% lower than that of (Y_0.5Gd_0.5)TaO₄ bulk and 8YSZ, respectively. Meanwhile, the bond strength increased from 8.86 MPa to 14.03 MPa as the heat treatment time increased from 0 h to 24 h, benefiting from the heat treatment to release the residual stresses inside the coating. Additionally, the hardness increased from 5.88 ± 0.56 GPa to 7.9 ± 0.64 GPa as the heat treatment temperature increased from room temperature to 1000 °C, resulting from the healing of pores and increased densification. Lastly, crack growth driven by thermal stress mismatch accumulated during thermal cycling is the main cause of coating failure. The above results demonstrated that 8YSZ/(Y_0.5Gd_0.5)TaO₄ can increase the service span of copper substrate. Full article

Aircraft gas turbine blades operate in aggressive, generally oxidizing, atmospheres. A solution to mitigate the degradation and improve the performance of such components is the deposition of thermal barrier coatings systems (TBCs). High-velocity air fuel (HVAF) is a very efficient process for coating deposition in TBC systems, particularly for bond coats in aerospace applications. However, its low-temperature variant has received little attention in the literature and could be a promising alternative to limit oxidation during spraying when compared to conventional methods. This study has the main objective of analyzing how the geometry of the low-temperature HVAF gun influences the microstructure and the in-flight oxidation of MCrAlX coatings. To that end, a low-temperature HVAF torch is used to deposit MCrAlX coatings on a steel substrate with different nozzle lengths. In-flight particle diagnosis is used to measure the MCrAlX particle velocity, and to correlate to the nozzle geometry and to analyze its influence on the final coating. The microstructure of the coatings is assessed by scanning electron microscopy (SEM) and the material oxidation is analyzed and measured on a field emission scanning transmission electron microscope (FE-STEM) equipped with focused ion beam (FIB) and by Energy Dispersive Spectroscopy (EDS). Full article

Increasing demand to deposit dense and oxidation-resistant bond coats requires reliable and efficient deposition techniques. High-Velocity Air-Fuel (HVAF), among other thermal spray processes, is showcasing consistent potential to optimize spraying techniques and deposition strategies for depositing NiCoCrAlY coatings. NiCoCrAlY coatings are sensitive to high-temperature oxidation, and preserving the aluminum reservoir in the bond coats is of the highest priority to potentially resist oxidation during thermal cycling. Contrary to the existing literature on comparing carbide-based HVAF deposition with other processes, this work investigates the specific role of nozzle configurations. It primarily focuses on in-flight particle characteristics using diagnostic tools and the corresponding inflight particle oxidation of NiCoCrAlY feedstock. This work details individual splat and coating characteristics, revealing the significant influence of nozzle configurations. A comprehensive understanding of process–material–microstructure correlations was established using a commercially available NiCoCrAlY coating system. Comprehensive discussions on nozzle configurations over various feedstock powder characteristics were carried out in this work. Advanced characterization techniques were employed to assess the in-flight particle oxidation and coating microstructure using focused ion beam (FIB), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Full article

In this paper, the oxidation behavior of the 310H alloy coated with NiCrAlY using the EB-PVD method is studied after exposure to water at a high temperature and pressure (550 °C and 25 MPa) for different periods (720 h, 1440 h, and 2160 h). The Electron Beam Physical Vapor Deposition (EB-PVD) method was used to obtain the NiCrAlY coating. After testing, the coating performance was carried out by gravimetric analysis, grazing incidence X-ray diffraction (GIXRD), scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), and the linear polarization method. GIXRD analysis highlighted the presence of chromium oxide (Cr₂O₃) and the Corundum phase (Al₂O₃) on the surface of the oxidized NiCrAlY-coated 310H samples. On the surface of the 310H alloy, the existence of the NiCrAlY coating and of the oxide film generated during oxidation are evident according to the EIS spectra, which show two capacitive semicircles in the Nyquist diagram. Furthermore, an increase in diameter semicircles with the oxidation time increasing was observed in the Nyquist diagram. Very low corrosion rates of 4.8 × 10⁻⁵ mm × year⁻¹, which were observed for oxidization for 2160 h NiCrAlY-coated samples, indicated that the oxide films are more protective and provide better corrosion resistance, which is also evidenced by the EIS analysis. Considering the obtained results, a significant relationship between the electrochemical technique, scanning electron microscopy, and gravimetric analysis was established. Full article

CoNiCrAlY coatings are widely used as typical high-temperature materials to enhance the surface performances of nickel-based superalloy materials, which can be used as bond coats in thermal barrier coatings and abradable seal coatings. In this study, high-pressure cold spray technology was used to deposit CoNiCrAlY coatings on nickel-based superalloy substrates. The microstructure characteristics and oxidation behaviors of CoNiCrAlY coatings prepared by different gas types and cold spray parameters were systematically investigated. EBSD analysis showed that the deformation of the helium coating was more distinct, and the grain size of the coating fabricated by helium was smaller than that by nitrogen as seen from the grain morphology. The high-temperature oxidation results showed that the coating oxide film thickness varied parabolically with time for both coatings after 500 h isothermal oxidation at 800 °C, 900 °C, and 1000 °C, and the oxidation rate of the coating after heat treatment was lower than that of the as-sprayed coating. In addition, the shrinkage of the aluminum reservoir inside the coating, the element diffusion rate, and the amount and type of oxide generation on the surface all affected the oxidation process. Additionally, the helium coating had a lower oxidation growth rate and better oxidation resistance. Therefore, cold spray can be an alternative way to fabricate high-quality CoNiCrAlY coatings. Full article

In aerospace applications, engine parts, especially those around the rotor blade tips, are coated with an abradable seal, a specific material layer. Its design produces a tighter seal without harming the blades by allowing it to wear down or “abrade” somewhat when the blade tips come into contact. In turbines and compressors, this reduces gas leakage between high- and low-pressure zones, increasing engine efficiency. Abradable seals are crucial to contemporary jet engines because they enhance performance and lower fuel consumption. The materials selected for these seals are designed to balance durability and abrasion resistance under high temperatures and speeds. Metal matrix, oxide particles, and porosity are the three most prevalent phases. An ideal mix of characteristics, such as hardness and erosion resistance, determines how effective a seal is, and this is accomplished by keeping the right proportions of elements in place throughout production. The primary objective of this research is to optimize abradability by utilizing various FEM tools to simulate the rub rig test and modify testing parameters, including Young’s modulus, yield stress, and tangent modulus, to analyze their impact on the wear behavior of the abradable seal and blade. Two microstructure models (CoNiCrAlY–BN–polyester coating) were found to perform optimally at porosity levels of 56% and 46%, corresponding to hardness values of 48 HR15Y and 71 HR15Y, respectively. Changing factors like yield stress and tangent modulus makes the seal more abrasive while keeping its hardness, porosity, and Young’s modulus the same. Furthermore, altering the Young’s modulus of the shroud material achieves optimal abradability when tangent modulus and yield stress remain constant. These findings provide valuable insights for improving material performance in engineering applications. To improve abradability and forecast characteristics, this procedure entails evaluating the effects of every single parameter setting, culminating in the creation of the best abradable materials. This modeling technique seems to provide reliable findings, providing a solid basis for coating design in the future. Full article

To improve high-temperature oxidation resistance for Ti6Al4V alloy, Al_xCoCrCu_yFeNi (x = 0, 0.3, 0.5, 0.7, 1.0; y = 1.0, 0.7, 0.5, 0.3, 0, x + y = 1.0) high-entropy alloy (HEA) coatings were prepared on the Ti6Al4V alloy substrate by a laser cladding technique. The results show that the coatings were mainly composed of FCC, BCC, and Ti-rich phases. Severe segregation of the Cu element occurred in the CoCrCuFeNi HEA coatings as a Cu-rich phase (FCC2). The Cu-rich phases decreased with a decreasing Cu content and completely disappeared until the Al content reached 1.0. The microhardnesses of the Cu_1.0, Cu_0.7Al_0.3, Cu_0.5Al_0.5, Cu_0.3Al_0.7, and Al_1.0 HEA coatings were 2.01, 2.06, 2.08, 2.09, and 2.11 times that of the substrate, and compared with those of a Ti6Al4V alloy substrate, the oxidation rates of the HEA coatings decreased by 55%, 51%, 47%, 42%, and 35%, respectively. The surface oxides of the five coatings were mainly composed of CuO, TiO₂, Fe₃O₄, Cr₂O₃, and Al₂O₃. The increase in the Al content promoted the generation of Al₂O₃ film and Cr₂O₃ on the surfaces of the coatings, which significantly improved the high-temperature antioxidant performance of the high-entropy alloy coatings for 50 h at 800 °C. When x = 1.0, the coating showed the best high-temperature antioxidant performance. Full article

The Ti-6Al-4V alloy is widely utilized in the aerospace industry for applications such as turbine blades, where it is valued for its mechanical strength at high temperatures, low specific gravity, and resistance to corrosion and oxidation. This alloy provides crucial protection against oxidation and thermal damage. A thermal barrier coating (TBC) typically consists of a metallic substrate, a bond coating (BC), a thermally grown oxide (TGO), and a topcoat ceramic (TC). This study aimed to investigate laser parameters for forming a TBC with a NiCrAlY bond coating and a zirconia ceramic topcoat, which contains 16.0% equimolar yttria and niobia. The coatings were initially deposited in powder form and then irradiated using a CO₂ laser. The parameters of laser power and beam scanning speed were evaluated using scanning electron microscopy and X-ray diffraction. The results indicated that the optimal laser scanning speed and power for achieving the best metallurgical bonding between the substrate/BC and the BC-TGO/TC layers were 70 mm/s at 100 W and 550 mm/s at 70 W, respectively. Laser-based layer formation has proven to be a promising technique for the application of TBC. Full article

High-entropy alloy (HEA) coatings have attracted wide scientific attention in academic research and industrial innovation. In the present paper, the NiCoCrAlY HEA coatings are successfully synthesized on the surface of M50 steel to improve the corrosion resistance and tribocorrosion resistance of M50 steel in salt-contaminated lubricating oil. The corrosion and tribocorrosion behaviors of M50 steel and NiCoCrAlY coatings are studied systemically under the same conditions. The experimental results show that NiCoCrAlY coatings have good, densified microstructures and improve effectively the corrosion resistance and tribocorrosion resistance of M50 steel because the protective passivation films and oxide films are formed on the surface of NiCoCrAlY coatings. NiCoCrAlY coatings have high corrosion potential, a low corrosion current density, and a corrosion rate that is comparable with M50 steel. The corrosion potential of M50 steel decreases and the corrosion current density increases with the increase in load due to wear-induced corrosion. The corrosion and tribocorrosion mechanisms of M50 steel and coatings are discussed in light of the experimental results. The wear mechanism of M50 steel is abrasive wear. It is accompanied by corrosion wear for M50 steel and oxidative wear for NiCoCrAlY coatings. Full article

Strain tolerance is a crucial factor affecting the thermal life of coatings, and a higher strain tolerance can effectively alleviate the thermal stresses on coatings during thermal shock. To improve the strain tolerance, the coating structure was optimized by introducing an intermediate transition layer in this study. The intermediate transition layer material was prepared using a 1:1 volume ratio mixture of 6–8 wt. % Yttria-stabilized zirconia (YSZ) and NiCrAlY powders in the experiments. The coating structure consisted of an Al₂O₃-GdAlO₃ (AGAP) anti-erosion layer, a YSZ layer, an intermediate transition layer, and a bonding layer from top to bottom. After thermal shock experiments at 1500 °C, the coatings with the addition of the intermediate transition layer exhibited different failure modes, with the crack location shifting from between the YSZ and the bonding layer to within the intermediate transition layer, compared to the coatings without the intermediate transition layer. Finite element simulation analysis showed that the intermediate transition layer effectively increased the strain tolerance of the coating and significantly reduced the thermal stress. Furthermore, incorporating an embedded micron agglomerated particle-based (EMAP) thermal barrier coating structure into the intermediate transition layer effectively alleviated thermal stresses and enhanced the coating’s thermal insulation performance. Full article

In this study, CoCrFeNiY_x (x = 0, 0.1, 0.2, 0.3) high entropy alloy (HEA) coatings were produced on Ti6Al4V by laser cladding. The influence of Y on the microstructure and mechanical properties of CoCrFeNi HEA coatings was systematically examined. The analysis uncovered that the coatings primarily consist of three principal phases: α(Ti), Ti₂Ni, and TiC. The incorporation of Y led to enhanced lattice distortion, which positively influenced solid solution strengthening. Moreover, grain refinement resulted in a denser microstructure, significantly reducing internal defects and thereby enhancing the coating’s performance. The average microhardness of the CoCrFeNiY_0.2 coating was 702.46 HV_0.2. The wear rates were 1.16 × 10⁻³ mm³·N⁻¹·m⁻¹ in air and 3.14 × 10⁻³ mm³·N⁻¹·m⁻¹ in a neutral solution, which were 27.0% and 30.8% lower than those of the CoCrFeNi coatings, respectively, indicating superior wear resistance. The Y content in the CoCrFeNiY_0.3 coating was excessively high, resulting in the formation of Y-rich clusters. The accumulation of these impurities at the grain boundaries led to crack and pore formation, thereby reducing the wear resistance of the coating. Our study demonstrated that laser cladding an optimal amount of Y-doped CoCrFeNi HEA coatings on the Ti6Al4V substrate significantly enhanced the microstructure and mechanical properties of the substrate, particularly its wear resistance in both air and neutral environments, thereby improving the durability and reliability of titanium alloys in practical applications. Full article

This paper presents the results of a study of layer gradient thermal protection coatings based on NiCrAlY and YSZ obtained by detonation spraying. Modern gas turbines and high-temperature units operate under extreme temperatures and aggressive environments, which requires effective protection of components from wear, corrosion, and thermal shocks. In this study, the use of layer gradient coatings consisting of alternating layers of NiCrAlY and YSZ was investigated with the aim of solving the problem of thermal stress accumulation due to a smooth change in the composition of the layers. Microstructural and phase analysis showed that alternating layers of NiCrAlY and YSZ formed a dense layer gradient structure with clear interphase boundaries and low porosity. Detonation spraying led to a complete transformation of the monoclinic ZrO₂ phase into a tetragonal one, which significantly increased the mechanical strength of the coating and its resistance to thermal shocks. Sample 1D1 demonstrated excellent tribological and corrosion properties in a 3.5% NaCl solution, which can be explained by its higher density and reduced number of pores. Mechanical tests revealed stable values of hardness and wear resistance of the coating, especially for the 1D1 coating. Studies have shown that coatings are resistant to thermal shocks, but thicker layers show a tendency to peel off after thermal cycling. The obtained results indicate high prospects for the use of layer gradient coatings based on NiCrAlY and YSZ for the protection of gas turbine components and other high-temperature installations operating under extreme loads and aggressive environments. Full article