Search Results (124)

TiVCr-based alloys are well-explored body-centered cubic (BCC) materials for hydrogen storage applications that can potentially store higher amounts of hydrogen at moderate temperatures. The challenge remains in optimizing the alloy-hydrogen stability, and several transition elements have been found to support the reduction in the hydride stability. In this study, Ni and Nb transition elements were incorporated into the TiVCr alloy system to thoroughly understand their influence on the (de)hydrogenation kinetics and thermodynamic properties. Three different compositions, (TiVCr)₉₅Ni₅, (TiVCr)₉₀ Ni₁₀, and (TiVCr)₉₅Ni₅Nb₅, were prepared via arc melting. The as-prepared samples showed the formation of a dual-phase BCC solid solution and secondary phase precipitates. The samples were characterized using hydrogen sorption studies. Among the studied compositions, (TiVCr)₉₀Ni₁₀ exhibited the highest hydrogen absorption capacity of 3 wt%, whereas both (TiVCr)₉₅Ni₅ and (TiVCr)₉₀Ni₅Nb₅ absorbed up to 2.5 wt% hydrogen. The kinetics of (de)hydrogenation were modeled using the JMAK and 3D Jander diffusion models. The kinetics results showed that the presence of Ni improved hydrogen adsorption at the interface level, whereas Nb substitution enhanced diffusion and hydrogen release at room temperature. Thus, the addition of Ni and Nb to Ti-V-Cr-based high-entropy alloys significantly improved the hydrogen absorption and desorption properties at room temperature for gas-phase hydrogen storage. Full article

In this work we revisit a vast amount of existing data on physical properties of Ti-Zr-Nb-(Cu,Ni,Co) glassy alloys over a broad range of concentrations (from the high-entropy range to that of conventional Cu-, Ni- or Co-rich alloys). By using our new approach based on the total content of late transition metal(s), we derive a number of physical parameters of a hypothetical amorphous TiZrNb alloy: lattice parameter $a=(3.42\pm 0.02)$ Å, Sommerfeld coefficient $\gamma =6.2\mathrm{mJ/mol}$${\mathrm{K}}^2$, density of states at $N\left(E_F\right)=2.6{\left(\mathrm{at}\mathrm{eV}\right)}^{-1}$, magnetic susceptibility $(2.00\pm 0.05)$mJ/${\mathrm{T}}^2$mol, superconducting transition temperature $T_c=(8\pm 1)$K, upper critical field ${\mathrm{\mu }}_0{H}_{c2}\left(0\right)=(20\pm 5)$T, and coherence length $\xi \left(0\right)=(40\pm 3)$Å. We show that our extrapolated results for the amorphous TiZrNb alloy would be similar to that of crystalline TiZrNb, except for superconducting properties (most notably the upper critical field $H_{c2}\left(0\right)$), which might be attributed to the strong topological disorder of the amorphous phase. Also, we offer an explanation of the discrepancy between the variations in $T_c$ with the average number of valency electrons in neighboring alloys of 4d transition metals and some high-entropy alloys. Overall, we find that our novel method of systematic analysis of results is rather general, as it can provide reliable estimates of the properties of any alloy which has not been prepared as yet. Full article

In this study, the effect of aging heat treatment on the superelastic properties and microstructure of [001]-oriented Fe₄₁Ni₂₈Co₁₇Al_11.5Ti_1.25Nb_1.25 (at.%) single crystals was investigated using the cyclic superelastic strain test and a transmission electron microscope (TEM). The TEM results reveal that the average precipitate size is around 3–5 nm in the 600 °C/24 h samples, 6–8 nm in the 600 °C/48 h samples, and 10–12 nm in the 600 °C/72 h samples. The results indicate that precipitate size increases as aging time increases from 24 to 72 h. EDS analysis results show decreased Fe and increased Ni when the analyzed line crosses the precipitate region. The diffraction pattern results show that the precipitate has an L1₂ crystal structure. The thermo-magnetization curves of single crystals under the three aging conditions (600 °C/24 h, 600 °C/48 h, and 600 °C/72 h) show that the values of the transformation temperatures increased from 24 to 72 h. Magnetization was saturated at 140 emu/g under the magnetic field of 7 Tesla. When increasing the magnetic field from 0.05 to 7 Tesla, the transformation temperatures rose. The results indicate that magnetic fields can activate martensitic transformation. From the results of the superelasticity test at room temperature, [001]-oriented FeNiCoAlTiNb single crystals aged at 600 °C for 24, 48, and 72 h presented recoverable strains of 3%, 5.1%, and 2.6%, respectively. Digital image correlation (DIC) results of the aged samples show that two martensite variants were activated during the superelasticity test. The two variants form corresponding variant pairs (CVPs) and improve the recoverable strain of superelasticity. Although maximum recoverable strain was obtained for the 600 °C/48 h samples, the samples show poor cyclic stability at room temperature after applying the 6% strain. According to the DIC results, the retained martensite, which is pinned by dislocations, was observed after the test. The irrecoverable strain was attributed to the residual martensite. For the 600 °C/72 h samples, the large size of the precipitates poses an obstacle to dislocation transformation and formation. The dislocations increase the stress hysteresis width and stabilize the martensite, causing poor recoverability. Full article

In this study, a strategy was adopted to promote the formation of NiAl precipitates with the aim of enhancing strength by incorporating a 0.2 wt.% Al into a traditional ultra-low carbon bainitic (ULCB) steel alloy. By integrating thermo-mechanical control processing (TMCP) and a tailored tempering process, a new-generation steel with an outstanding combination of properties has been successfully developed for shipbuilding and marine engineering equipment. It features a yield strength of 880 MPa, a yield ratio of 0.84, and an impact toughness of 175 J. The precipitation characteristics of nanoscale particles in this steel, including NiAl intermetallics and carbides, were systematically investigated. The results show that the alloy with low Al addition formed NiAl precipitates during tempering. The high-density distributions of NiAl, (Mo, V)C, and (Ti, V, Nb)C precipitates, which exhibit slow coarsening kinetics, played a dominant role in enhancing the strength of the tempered steel. In addition to precipitation, the microstructure before and after tempering was also analyzed. It was observed that a granular bainite morphology was favorable for decreasing the yield ratio. Additionally, the formation of reverse-transformed austenite during tempering was critical for retaining toughness despite substantial strength gains. Finally, theoretical modeling was employed to quantitatively assess the contributions of these microstructural modifications to yield strength enhancement of thermo-mechanical controlled processing (TMCP) and tempered steel. This study establishes a fundamental basis for subsequent industrial-scale development and practical engineering applications of novel products. Full article

Ti-2Al-9.2Mo-2Fe (2A2F) alloy is a low-cost β-Ti alloy in which the expensive β-stabilizing elements (Ta, Nb, W, Ni) are replaced with relatively inexpensive Mo and Fe for use in low-cost applications in various industries. The 2A2F alloy exhibits excellent mechanical properties such as high specific strength and low elastic modulus compared to conventional steel alloys but is prone to brittleness owing to the formation of the ω phase when heat-treated at relatively low temperatures. Therefore, an appropriate aging treatment should be performed to control the precipitation of the isothermal ω phase and secondary α phase. This study aims to derive the appropriate aging-treatment conditions following a solution treatment at 790 °C for 1 h, which is below the β-transus temperature of 815 °C. The aging treatments are conducted at holding temperatures in the range of 450–600 °C and holding times between 1 and 18 h. At relatively low aging temperatures of 450 °C and 500 °C, the precipitation of the isothermal ω phase resulted in significantly high hardness and compressive strength. As the aging temperature and holding time increased, the ω phase gradually transformed into the secondary α phase, leading to a balanced combination of strength and ductility. However, at excessively high aging temperatures and prolonged durations, excessive precipitation and growth of secondary α phases occurred, which caused a reduction in hardness and compressive strength, accompanied by an increase in ductility. In this study, the effects of precipitation evolution on mechanical properties such as tensile strength and hardness under various heat treatment conditions were comparatively analyzed. Full article

GH2097, a Fe-Ni-Co-based superalloy extensively employed in high-temperature critical components such as aircraft engines, was investigated to elucidate the influence of Si content on its precipitation behavior and mechanical properties. By systematically adjusting Si concentrations, it was demonstrated that Si significantly modulates the size, distribution, and stability of γ′ phase (Ni₃TiNb). As Si content increases, γ′ phase coarsening (mean size: 30.1→40.3 nm) results in a marginal increase in volume fraction of 2%. Mechanical testing revealed a direct correlation between Si content and yield strength enhancement, achieving a maximum increment of 97.1 MPa. Post solution-aging treatment, γ′ strengthening dominated the strengthening mechanisms in GH2097, contributing over 50% to the overall strength. Microstructural characterization (SEM/TEM) further confirmed that optimal Si addition balances precipitation kinetics and grain boundary stabilization without inducing detrimental phases. Therefore, it is important to consider the role of the Si element in the microstructure control of GH2907 alloy. Full article

This study systematically investigated the behavior of impurity removal during the electron beam melting (EBM) process of V-Al alloy. Characterization techniques such as ICP, GDMS, SEM, EPMA, and TEM were used to analyze the composition content and microscopic element distribution of V-Al alloy and purified metal samples. Additionally, based on thermodynamic principles, the saturation vapor pressure and evaporation coefficients of impurity elements were calculated. The results indicate that the evaporation coefficients of Al, Fe, Co, Ni, Cr, and Ti exceed 1, enabling their effective removal during the melting process, thereby reducing their concentrations. In contrast, Si, Mo, Nb, and W exhibit evaporation coefficients significantly lower than 1, making their removal difficult. Instead, their concentrations increase due to the enrichment effect. Microstructural analysis reveals that Al migrates toward high-temperature regions, forming enrichment zones at the surface layer in contact with the electron beam. In contrast, Si, C, and O exhibit bidirectional migration characteristics, accumulating at both the upper and lower surfaces of the plate-shaped ingot. TEM observations indicate that some C reacts with V to form V₂C, which has a higher melting point than vanadium, making further removal difficult. Full article

Medium-entropy alloys (MEAs) allow the formation of different phases, generally in a solid-solution state, and compounds that favor obtaining alloys with properties superior to those of conventional alloys. In this study, medium-entropy CuNiSiCrCoTiNbx alloys were fabricated via melting in a vacuum induction furnace. The influence of the Nb addition (X = 0, 0.5 and 1 wt%) alloying elements on the microstructure, hardness, and wear resistance of the CuNiSiCrCoTiNb₀ (M1), CuNiSiCrCoTiNb_0.5 (M2), and CuNiCoCrSiTiNb₁ (M3) alloys were explored using X-ray diffraction (XRD), scanning electron microscopy (SEM), and a ball-on-disc tribometer, respectively. In general, the results indicated that the incorporation of Nb alloying element promoted the evolution of the microstructure, increased the hardness, and improvement of the wear resistance. The XRD and SEM findings demonstrate that higher Nb addition and aging heat treatment (AT) modification mainly favored the formation of dendritic regions and the precipitation of the Co₂Nb, Cr₃Si, and Ni₂Si phases, which promoted the refinement and strengthening of the microstructure. Significant increases in hardness were recorded: 11.95% increased, promoted by the addition of Nb before (E1) and after (E2, E3, and E4) the heat treatments. The maximum hardness values recorded were 92 ± 0.11 (AC) and 103 ± 0.5 HRB (AT-60 min) for the M3 alloy. The increase in hardness caused by Nb addition and aging heat treatments contributed to the dry sliding wear resistance response, decreasing material loss by 20%. This was related to the high concentration of precipitated phases rich in CoNb, CrSi, and NiSi with high hardness. Finally, the M3 alloy aged for 60 min exhibited the best specific wear rate behavior, with a material loss of 1.29 ${\mathrm{m}\mathrm{m}}^3$. The commercial Cu-Be C17510 alloy experienced a maximum hardness of 83.47 Hardness Rockwell B, HRB, and a high wear rate of 3.34 mm³. Full article

This work presents an integrated directed energy deposition (DED) approach utilizing a multi-powder feeder with real-time continuously variable composition functionality, a multi-powder mixer and a multi-powder nozzle to fabricate Ti-Ni-Nb gradient alloys with controlled compositional variations. The high-throughput methodology enables rapid alloy design and optimization by allowing precise manipulation of chemical composition and phase structures within a single deposited track. The EDS analysis confirms a gradual increase in titanium content, a nearly constant nickel content and a decrease in niobium along the scanning path, aligning with the expected powder-feeding trends. X-ray diffraction (XRD) analysis further reveals a phase transition from niobium-rich intermetallic compounds (NbNi₄, Nb₈Ni) at the beginning of the deposition to titanium-rich phases (Ti, Ti₂Ni) at the end, demonstrating the ability to tailor phase distributions through real-time composition control. This high-throughput methodology enables rapid alloy design and optimization by integrating theoretical predictions with experimental phase screening. This study establishes a novel framework for the rapid discovery and optimization of functionally graded materials, paving the way for advanced applications in aerospace, biomedical implants and high-performance structural components. Full article

This study investigated the thermophysical properties of TWIP steel with respect to grain size. The coefficient of thermal expansion (β) of TWIP steel was approximately 22.4 × 10⁻⁶ °C⁻¹, and this value was hardly affected by the grain size. Therefore the density of TWIP steel was also unaffected by grain size within the tested range. The β in TWIP steel was higher than that of plain carbon steels (13–15 × 10⁻⁶ °C⁻¹) such as interstitial free (IF) steel and low-carbon steel, and stainless steels (18–21 × 10⁻⁶ °C⁻¹) such as X10NiCrMoTiB1515 steel and 18Cr-9Ni-2.95Cu-0.58Nb-0.1C steel. The specific heat capacity (c_p) increased with temperature because the major factor affecting c_p is the lattice vibrations. As the temperature increases, atomic vibrations become more active, allowing the material to store more thermal energy. Meanwhile, c_p slightly increased with increasing grain size since grain boundaries can suppress lattice vibrations and reduce the material’s ability to store thermal energy. The thermal conductivity (k) in TWIP steel gradually increased with temperature, consistent with the behavior observed in other high-alloy metals. k slightly increased with grain size, especially at lower temperatures, due to the increased grain boundary scattering of free electrons and phonons. This trend aligns with the Kapitza resistance model. While TWIP steel with refined grains exhibited higher yield and tensile strengths, this came with a decrease in total elongation and k. Thus, optimizing grain size to enhance both mechanical and thermal properties presents a challenge. The k in TWIP steel was substantially lower compared with that of plain carbon steels such as AISI 4340 steel, especially at low temperatures, due to its higher alloy content. At room temperature, the k of TWIP steels and plain carbon steels were approximately 13 W/m°C and 45 W/m°C, respectively. However, in higher temperature ranges where face centered cubic structures are predominant, the difference in k of the two steels became less pronounced. At 800 °C, for example, TWIP and plain carbon steels exhibited k values of approximately 24 W/m°C and 29 W/m°C, respectively. Full article

The relevance of the study is related to the need to join dissimilar copper and nickel alloys by laser direct energy and material deposition (LDED). The purpose of research is studying the distribution of elements, structure, and properties of contact zone of nickel-based super alloy and CuCr1 bronze obtained by direct energy and material deposition with preliminary formation of relief of contact surface. For the purposes of research, samples were made from UNS C18200 copper alloy CuCr1 without relief, with a relief of 0.5 mm depth, and with a relief of 1 mm depth. The Ni₅₀Cr₃₃W_4.5Mo_2.8TiAlNb (EP648) alloy powder was deposited onto the bronze samples with a micro-relief. The deposition was produced by direct injection of energy and material. The influence of interphase interaction of CuCr-chromium carbide system on the possibility of initiation of a crack in the area of carbide secretions is not significant and does not exceed 3.1% according to CIC criterion from the background level for CuCr1 (CIC = 1.54% for CuCr1-Al₄C₃ interface and CIC = 3.1% for CuCr1-Cr₂₃C₆ interface). An X-ray analysis revealed the presence of tensile residual macro-stresses, arising from differences in thermal expansion coefficients in the CuCr1-EP648 interface area, which may be the main cause of crack formation. Cracks are generated and run along the grain boundaries, on which traces of excretion are visible. The contact surface in the CuCr1-EP648 interface area has no visible defects, which indicates the good adhesion of materials when applying an initial layer of EP648 by LDED. The presence of a 0.5-mm micro-relief on CuCr1 has a positive effect on the strength of the connection, as it increases the surface area of the contact CuCr1-EP648 and therefore reduces the contact stress of the breakout. Full article

The present study investigates the microstructural, mechanical, and tribological properties of Inconel 718 alloy produced by selective laser melting (SLM) in relation to heat treatment. The SLM-processed samples received a two-step heat treatment: solutionizing at 1065 °C for 1 h, followed by double aging at 720 °C for 8 h and 620 °C for 6 h. The as-built sample exhibited a grain structure mostly characterized by fine Laves phases, while the hardening phases γ′ ((Ni₃ (Al, Ti)) and γ″ (Ni₃Nb) precipitated during the heat treatment. Following heat treatment, a transformation in crystallographic texture and dislocation density occurred, yielding a random texture and reduced dislocation density, particularly in the XZ direction, attributed to the formation of new grains via recrystallization in the microstructure. The grain size in the XY plane decreased following heat treatment, whereas the texture in the <001> direction remained unaffected. The heat-treated samples had significantly higher tensile strength (1330 MPa vs. 960 MPa) and hardness (530 HV vs. 340 HV) relative to the as-built samples. The wear resistance of heat-treated samples surpassed that of the as-built sample due to enhanced mechanical properties resulting from the fine and dispersed γ′ and γ″ precipitates in the microstructure with heat treatment. Full article

The high-entropy alloy (HEA) has recently attracted significant interest due to its novel alloy design concept and exceptional mechanical properties, which may exhibit either a single or multi-phase structure. Specifically, refractory high-entropy alloys (RHEA) composed of titanium, niobium, and nickel-based HEA demonstrate remarkable mechanical properties at elevated temperatures. Additive manufacturing (AM), specifically Direct Energy Deposition (DED), is efficient in fabricating high-entropy alloys (HEA) owing to its fast-cooling rates, which promote uniform microstructures and reduce defects. This study involved the fabrication of the Ti33Nb28Cr11V11Ni17 (Ti-Nb-Cr-V-Ni) RHEA utilizing DED. Additionally, the post-processing of the fabricated alloy is conducted using conventional machining (CM) and laser-assisted machining (LAM). The results indicate thermal conductivity and specific heat increased, whereas tensile strength reduced with rising temperature. Significant softening was observed above 800 °C, resulting in a considerable decrease in tensile strength. Furthermore, the LAM caused material softening and reduced the cutting force by 60.0% relative to CM. Furthermore, the chemical composition of Ti-Nb-Cr-V-Ni remained unaffected even after post-processing with CM and LAM. The research indicates that post-processing with LAM is essential for developing resilient RHEA for practical use. Full article

Novel multicomponent Nb–Ni–Ti–Zr–Co alloys with 20–55 at.% Nb were synthesized from metal powders by arc melting. The resulting alloys consist primarily of Nb-rich and eutectic body-centered (BCC) phases. The content of the eutectic BCC phase is highest for an equimolar composition, while the content of the Nb-rich BCC phase increases with Nb content in the alloy. The content of secondary phases is the highest for the alloy with 32 at.% Nb. According to ab initio calculations, hydrogen occupies tetrahedral interstitial sites in the Nb-rich phase and octahedral sites in the eutectic BCC phase. For different Nb concentrations, hydrogen-binding energies were calculated. An increase in the Nb-rich phase leads to softening of multicomponent alloys. The alloys with 20 and 32 at.% Nb demonstrate high hydrogen permeability (1.05 and 0.96 × 10⁻⁸ molH₂m⁻¹s⁻¹Pa^−0.5, respectively) at 400 °C, making them promising for hydrogen purification membrane application. Multicomponent alloys with a high Nb content (55 at.%) have low resistance to hydrogen embrittlement. Full article

Fe–Ni–Co–Al-based systems have attracted a lot of interest due to their large recoverable strain. In this study, the microstructure and thermal cycling behaviors of Fe₄₁Ni₂₈Co₁₇Al_11.5Ti_1.25Nb_1.25 (at.%) 98.5% cold-rolled alloys after annealing treatment at 1277 °C for 1 h, followed by aging for 48 h at 600 °C, were investigated. From the electron backscatter diffraction results, we see that the texture intensity increased from 9.4 to 16.5 mud and the average grain size increased from 300 to 400 μm as the annealing time increased from 0.5 h to 1 h. The hardness results for different aging heat treatment conditions show the maximum value was reached for samples aged at 600 °C for 48 h (peak aging condition). The orientation distribution functions (ODFs) displayed by Goss, brass, and copper were the main textural features in the FeNiCoAlTiNb cold-rolled alloy. After annealing, strong Goss and brass textures were formed. The transmission electron microscopy (TEM) results show that the precipitate size was ~10 nm. The X-ray diffraction (XRD) results show a strong peak in the (111) and (200) planes of the austenite (⁠⁠γ, FCC) structure for the annealed sample. After aging, a new peak in the (111) plane of the precipitate (⁠⁠γ′, L12) structure emerged, and the peak intensity of austenite (⁠⁠γ, FCC) decreased. The magnetization–temperature curves of the aged sample show that both the magnetization and transformation temperature increased with the increasing magnetic fields. The shape memory properties show a fully recoverable strain of up to 2% at 400 MPa stress produced in the three-point bending test. However, the experimental recoverable strain values were lower than the theoretical values, possibly due to the fact that the volume fraction of the low-angle grain boundary (LABs) was small compared to the reported values (60%), and it was insufficient to suppress the beta phases. The beta phases made the grain boundaries brittle and deteriorated the ductility. On the fracture surface of samples after the three-point bending test, the fracture spread along the grain boundary, and the cross-section microstructural results show that the faces of the grain boundary were smooth, indicating that the grain boundary was brittle with an intergranular fracture. Full article