Search Results (2,059)

A solar–air source absorption heat pump (SAAHP), which mainly consists of a solar collector, a fan coil, and an absorption heat pump equipped with a gas-fired combustor, was proposed for water heating. This system runs in either SD (solar-energy-driving) or GD (gas-combustion-heat-driving) mode and is designed to utilize renewable energies whenever possible. The models for each component were built, and the corresponding heat and mass balance equations were established. The SAAHP’s performance with the LiBr/H₂O and LiNO₃/H₂O working fluids was simulated and compared with an air source absorption heat pump (AAHP) using LiBr/H₂O. The results indicated that the LiNO₃/H₂O-based SAAHP has a higher solar energy utilization rate than the LiBr/H₂O-based pump due to its lower solar collector inlet temperature in SD mode. Similarly, it achieved a higher primary energy COP throughout the year than both the LiBr/H₂O- and LiNO₃/H₂O-based SAAHPs. Compared to a gas-fired hot water boiler, the SAAHPs based on LiNO₃/H₂O and LiBr/H₂O achieved yearly primary energy-saving rates of 46.2% and 40.0%, respectively, whereas the AAHP only achieved a rate of 12.2%. Thus, the LiNO₃/H₂O-based SAAHP shows significant energy-saving potential in building energy use. Full article

This study evaluates the applicability of ERA5 wind speed (WS) and wind direction (WD) in the East China Sea, using high-resolution vertical wind profiles measured by a floating LiDAR at the Shanghai Nanhui Offshore Wind Farm from 15 January 2022 to 15 January 2023. Key findings are as follows: (1) Strong positive correlations exist between LiDAR-measured and ERA5 WS across all evaluated heights, with correlation coefficients of 0.76 (ground level), 0.86 (50 m), 0.88 (100 m), and 0.90 (200 m), respectively, and corresponding root mean square errors (RMSEs) of 2.33 m/s, 1.78 m/s, 1.73 m/s, and 1.77 m/s. This systematic improvement in correlation and modest reduction in RMSE with increasing height indicate that ERA5 captures vertical wind structure with progressively higher fidelity above the surface layer. (2) Both the ERA5 dataset and LiDAR measurements consistently show dominant wind frequencies in the NNE and SSE directions, with peaks at approximately 1000 occurrences. The minimal differences in the two datasets demonstrate the ERA5’s robust representation of near-surface offshore WD climatology. (3) The ERA5 reanalysis data of typhoon Muifa can better illustrate the increase in the initial WS and its subsequent decreases. However, the peak WS lags behind measurements by 2 h, and the extreme WS is significantly lower than that measured. Evaluations of the multi-year return period WS demonstrate an underestimation of extreme WS by 16.06–16.51% for the ERA5 data. Regarding the WD, the measured direction is clockwise, while that of the ERA5 is counterclockwise, revealing a fundamental deficiency in its representation of mesoscale cyclonic wind structure. Therefore, ERA5 reanalysis data provides reliable characterization of typical offshore WS and WD within the operational wind turbine hub-height range (100–200 m). For typhoon-related wind engineering assessments, the applicability of ERA5 data necessitates caution and potentially bias correction. Full article

Ultrasound patches represent a transformative advancement beyond conventional ultrasonography, evolving into intelligent theranostic systems for personalized healthcare. This evolution is propelled by synergistic innovations in flexible piezoelectric materials and integrated designs. The development of piezoelectric polymers, lead-free ceramics, and bio-composite materials has laid the foundation for long-term, conformal, and biosafe interfacing with the human body. Structurally, miniaturized transducer arrays (e.g., CMOS-integrated arrays achieving ~200 μm focal spots and 100 kPa focal pressure), multimodal integration, and bioinspired interfaces have enabled high-precision deep-tissue sensing and spatiotemporally controlled energy delivery—exemplified by strain-sensing feedback improving the signal-to-noise ratio by 5 dB for precise neuromodulation. These capabilities are converging to create closed-loop platforms, as demonstrated in continuous cardiovascular monitoring (up to 164 mm depth for 12 h), image-guided neuromodulation for neurological disorders, on-demand drug delivery (achieving 100% higher plasma concentration than ultrasound alone), and integrated tumor therapy with real-time feedback. Despite persistent challenges in material biocompatibility, energy efficiency, and clinical standardization, the future of ultrasound patches lies in their deep integration with multimodal sensing, machine learning, and adaptive control algorithms. This path will ultimately realize their potential for intelligent, closed-loop theranostics in chronic disease management, telemedicine, and personalized therapy. Full article

Gel polymer electrolytes (GPEs) typically suffer from sluggish kinetics and interfacial instability at elevated temperatures and high voltages. Herein, 3-(trifluoromethyl)-1H-1,2,4-triazole (TTA) is employed to construct an ultrathin (~25 μm), robust, and homogeneous GPE. TTA acts as a molecular bridge, significantly improving compatibility between the PVDF-HFP (Poly(vinylidene fluoride-co-hexafluoropropylene)) matrix and LLZTO (Li_6.4La₃Zr_1.4Ta_0.6O₁₂) fillers to create continuous ion-conducting pathways. Consequently, the TTA-GPEs exhibits high ionic conductivity (0.267 mS cm⁻¹ at room temperature), low activation energy (0.181 eV), and an increased lithium-ion transference number (0.425). Advanced surface analysis reveals that TTA preferentially reacts to form a dense, gradient hierarchical interphase (solid electrolyte interphase/cathode electrolyte interphase, SEI/CEI) enriched with inorganic species (LiF, Li₃N, and Li₂S) on the inner side. This architecture suppresses parasitic reactions and lithium dendrite growth. Accordingly, NCM811(LiNi_0.8Co_0.1Mn_0.1O₂)//Li batteries with TTA-GPEs demonstrate stable cycling at 80 °C and 1C, retaining 57.68% capacity after 125 cycles—significantly outperforming benchmarks. This study offers a molecular engineering strategy to simultaneously optimize bulk transport and interfacial stability for high-energy-density solid-state batteries. Full article

Naturally occurring halloysite nanotubes (HNTs), a clay mineral characterized by a unique dual-charge architecture, offer a promising strategy for enhancing the performance of composite polymer electrolyte (CPE). In this work, HNTs are introduced as a low-cost, functional filler to simultaneously address two key limitations of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)-based CPE: low ionic conductivity and inadequate lithium-ion transference number. The negatively charged outer surface of HNTs facilitates Li⁺ transport, while the positively charged inner lumen confines anions such as TFSI⁻. Controlled acid etching (6 M HCl, 12 h) further optimizes this structure by removing surface impurities and enlarging the lumen, thereby enhancing both charge-directed ion transport pathways. The resulting HNT-modified CPE achieves a high ionic conductivity of 6.1 × 10⁻⁴ S⋅cm⁻¹ and a Li⁺ transference number of 0.73. When assembled into Li||CPE||LiFePO₄ cells, the electrolyte enables stable cycling over 300 cycles at 0.2C, retains 119.2 mAh/g at 2C, and delivers 85.7 mAh/g even at 5C, demonstrating excellent cycling stability and rate capability. This study reveals the potential of mineral-derived nanomaterials, with their inherent structural and physicochemical properties, to serve as key functional components in high-performance batteries. Full article

The incorporation of reclaimed asphalt pavement (RAP) in asphalt mixtures improves sustainability but significantly reduces the intrinsic self-healing capacity due to binder aging. This study aimed to quantify whether epoxy-coated rejuvenator microcapsules could restore and enhance the self-healing performance of RAP-containing recycled asphalt mixtures. Four mixture types (AC-10C, AC-13C, AC-16C, and SMA-13C) containing 20% RAP were evaluated using a fracture–healing–refracture bending test (Repair index, R_C) and a splitting healing strength ratio (S_HSR) test to determine the effects of healing time, temperature, and microcapsule dosage. R_C increased rapidly during the first 8 h of healing and then approached stabilization, with the growth rate falling below 2%, indicating 8 h as the practical optimum healing duration. R_C increased from 0 °C to 45 °C due to enhanced binder mobility and diffusion, and slightly decreased at 60 °C because temperature-induced softening reduced peak bending strength. The highest self-healing capacity was obtained at a microcapsule dosage of 4% (by RAP mass). Under the optimum healing condition (8 h and 45 °C), R_C increased by 10.38%–13.50% and S_HSR increased by 14.35%–25.27% compared with mixtures without microcapsules. Among the mixtures, SMA-13C exhibited the highest self-healing capacity, followed by AC-13C, AC-10C, and AC-16C. The contribution of this study lies in quantifying the healing enhancement in RAP-containing mixtures, identifying practical optimum healing conditions based on a growth-rate criterion, and demonstrating consistent trends between two healing indices across different mixture structures. Full article

Papillary thyroid cancer (PTC) is the most common endocrine malignancy with especially high incidence in Middle Eastern populations. While classical hereditary syndromes explain a minority of cases, the broader germline landscape of non-syndromic PTC remains unclear. Whole-exome sequencing was performed on 245 unselected Saudi PTC patients to identify germline pathogenic or likely pathogenic variants (PVs/LPVs) in cancer predisposition genes. Clinical and molecular characteristics, and family history were integrated to assess phenotypic correlations. Eleven patients (4.5%) harbored germline PVs/LPVs in cancer susceptibility genes including STK11, TP53, BRCA1, BRCA2, FANCA, SLX4, RAD50, MSH6, POLD1 and NF1. Four patients (36.4%) carried PVs/LPVs in canonical FA pathway genes; this increased to five patients (45.5%) when RAD50 was included. Two unrelated patients harbored the same STK11 variant (p.R304Q) without classical Peutz–Jeghers syndrome features. A TP53 hotspot mutation (p.R175H) was identified in a patient with a personal history of gastric cancer, a malignancy associated with Li–Fraumeni syndrome. Notably, the BRCA1 PV detected matches a known Saudi founder mutation in hereditary breast cancer, now observed in PTC. Most germline positive cases lacked syndromic manifestations, underscoring limitations of phenotype or family history-driven genetic testing strategies. These findings suggest that a small subset of non-syndromic PTC cases may carry germline PVs/LPVs in cancer predisposition genes, highlighting the need for broader genetic screening frameworks. Unbiased whole-exome analysis in unselected cohorts can uncover under-recognized genetic risk and guide screening strategies to address the unique hereditary landscape of thyroid cancer in underrepresented populations. Full article

This study aimed to investigate the influence of the synthesis parameters on the corrosion resistance of 3D-printed Inconel 718 components. Samples were fabricated using laser powder bed fusion (PBF-LB/M) with different angles of inclination. Corrosion tests were conducted by immersion for 1000 h in a 3.5% aqueous NaCl solution at 20 °C and 45 °C, and by the potentiodynamic polarization measurements. Detailed analysis of changes in morphology, chemical composition, and roughness of 3D prints was performed using scanning electron microscopy, combined with energy-dispersive X-ray spectroscopy, and optical profilometry. To quantify the dissolution of alloy components during the long-term measurements, the post-corrosion solutions were analyzed using microwave plasma–atomic emission spectroscopy. The obtained results demonstrate that inclination angle significantly affects corrosion rate and electrochemical kinetics, with measurable differences in mass loss, Icorr values, and surface degradation morphology observed between orientations. The findings indicate that build orientation governs microstructural anisotropy and surface characteristics, which in turn influence corrosion susceptibility. The novelty of this work lies in the systematic and multi-method evaluation of inclination angle as an independent structural parameter controlling corrosion kinetics in PBF-LB/M-fabricated Inconel 718, providing new insight into structure–corrosion relationships in additively manufactured nickel-based superalloys. Full article

Background/Objectives: Jaw osteomyelitis (OM) is a refractory purulent inflammation caused by bacterial infection, characterized by persistent infection, excessive bone resorption, and resultant bone defects. Currently, mainstream therapies for jaw OM struggle to eradicate persistent infections, avoid antibiotic resistance, and repair infected bone defects, posing a critical challenge in clinical practice. Methods: Herein, the Fe₃O₄@ZIF-8 core–shell nanoparticles (NPs) platform designed for jaw OM treatment consisted of Fe₃O₄ as the core and zeolitic imidazolate framework-8 (ZIF-8) as the shell. Results: The core–shell platform not only integrated the pH-responsive degradation capability of ZIF-8 but also retained the superparamagnetism of Fe₃O₄ NPs. In the acidic, infectious microenvironment, Fe₃O₄@ZIF-8 NPs underwent continuous degradation, releasing Zn²⁺, thereby conferring potent antibacterial activity. The specific antibacterial mechanism of the nanoparticles lies in the fact that high concentrations of Zn²⁺ directly disrupted bacterial cell membranes and inhibited the bacterial heat shock response. This dysregulates bacterial proteostasis, rendering the bacteria more sensitive to external adverse stresses, ultimately leading to bacterial death. With ZIF-8 framework degradation, the encapsulated Fe₃O₄ NPs were released. Under static magnetic field (SMF) synergy, Fe₃O₄ NPs collaborated with Zn²⁺ to promote bone regeneration and repair infected bone defects in jaw OM lesions. Conclusions: As a multifunctional core–shell platform, Fe₃O₄@ZIF-8 NPs meet the dual clinical needs of antibiosis and osteogenesis, offering a promising translational strategy for jaw OM therapy. Full article

Solid polymer electrolytes (SPEs) hold great potential in high-safety energy storage but face two key bottlenecks: low room-temperature ionic conductivity and insufficient mechanical strength. This study proposes a synergistic optimization strategy of “long-carbon-chain regulation of polymer microstructure combined with porous polyimide (PI) support”. A linear random copolyester, poly(1,3-propylene-co-1,4-butylene succinate-co-sebacate) (PBPSS), was synthesized via melt polycondensation using 1,3-propanediol, 1,4-butanediol, succinic acid, and sebacic acid as monomers. Subsequently, the PBPSS-75 composite electrolyte was prepared with this copolyester as the matrix and porous PI as support. Results show that long-carbon-chain sebacic acid effectively regulates polymer segment flexibility and free volume, synergistically enhancing ionic conductivity and interfacial mechanical stability with lithium metal. Experimental data indicate that PBPSS-75 composite electrolyte exhibits an ionic conductivity of up to 4.25 × 10⁻⁵ S cm⁻¹ (30 °C), a lithium-ion transference number of 0.81, and an electrochemical stability window of 4.48 V (vs. Li/Li⁺). In LiFePO₄//Li batteries, it maintains nearly 100% capacity retention after 300 cycles at 0.5 C, and achieves stable cycling for over 800 h in lithium symmetric cells. This study confirms that the combined strategy effectively addresses the conductivity-mechanical property trade-off of SPEs, providing theoretical guidance and technical reference for high-performance solid-state battery material design. Full article

The effect of LiPF₆ acidity, represented by LiPF₆·xHF adduct formation and its interaction with fluoride species, on the surface reactivity and stability of LiPF₆ was investigated using density functional theory (DFT) calculations performed with the Vienna Ab initio Simulation Package (VASP). The exchange–correlation energy was described using the Perdew–Burke–Ernzerhof (PBE) functional within the Generalized Gradient Approximation (GGA). Four distinct surface terminations of the (003) and (101) facets—F4–P2–Li, P2–F3–Li, Li2–F3–P, and F4–Li2–P were systematically examined. Surface and adsorption energies were evaluated together with key electronic descriptors, including the work function, dipole moment, electron localization function (ELF), electrostatic potential, band structure, and density of states, to elucidate the mechanisms governing adsorption and stability. The (101) facet exhibits a pronounced susceptibility to HF-induced solvation, driven by enhanced surface polarity, a low work function, and intermolecular H–F interactions at lithium-exposed terminations. In contrast, the thermodynamically dominant (003) facet shows greater resistance to HF interaction, with adsorption remaining predominantly molecular and progressing toward deliquescence only at elevated HF concentrations. Fluorine-rich and charge-balanced terminations on both facets display enhanced stability, characterized by high work functions, minimal ELF redistribution, and suppressed charge transfer. Full article

Amid growing environmental pressure and increasing demand for resource sustainability, the efficient recovery of valuable metals from spent lithium-ion batteries (LIBs) has become a critical challenge in the field of resource recycling. Therefore, a novel approach is presented for selective lithium (Li) and manganese (Mn) separation from LiNi_xCo_yMn_1−x−yO₂ by combining carbothermic reduction roasting and selective leaching. Low-cost glucose (C₆H₁₂O₆) was selected as the reduction roasting reductant, which converts the cathode materials into water-soluble lithium carbonate (Li₂CO₃), water-insoluble cobalt (Co), nickel (Ni), and manganese oxide (MnO). Wet magnetic separation was employed to preferentially extract Li while simultaneously removing excess carbon from Ni, Co, and MnO. Under optimal roasting conditions at 600 °C for 90 min followed by wet magnetic separation with a liquid–solid ratio of 30 mL/g for 30 min, 95.42% of Li was preferentially extracted. Subsequently, at a formic acid (HCOOH) concentration of 1.6 mol/L, liquid–solid ratio of 6 mL/g, and leaching time of 30 min, 94.29% of Mn was selectively extracted from the wet magnetic separation products, whereas Ni and Co were leached at 6.13% and 7.22%, respectively. The acid-leaching residue can be recycled as a Ni-Co alloy. Full article

Optimizing traffic performance using artificial intelligence (AI) has consistently been a prominent direction in the development of intelligent transportation systems. While numerous studies have proposed methodologies for integrating cooperative connected and autonomous vehicles (CCAVs) with traffic signal systems via V2X communication, they often rely on simplified control strategies or lack effective coordination between signal timing and vehicle behavior. In this study, we propose a novel, integrated traffic signal control strategy combined with CAVs using deep reinforcement learning. Our key differentiation lies in the simultaneous optimization of signal phases using the Soft Actor–Critic (SAC) algorithm and the regulation of CCAVs via cooperative adaptive cruise control and Green Light Optimal Speed Advisory. This dual approach allows the signal controller to leverage rich state information from CAVs and the road infrastructure, enabling more anticipatory and cooperative decisions. The proposed approach is implemented and evaluated through various scenarios using the Simulation of Urban MObility (SUMO) platform. The results demonstrate the superior learning performance and robustness of the proposed model. Specifically, our proposed model achieves a significant reduction in average vehicle waiting time by up to over 80% compared to baseline models under high-demand scenarios (4800–6000 veh/h). These findings underscore the critical importance of joint optimization in future intelligent transportation systems, paving the way for more resilient urban traffic management. Full article

Background: Tantalum in cytotoxicity tests showed no toxicity effect, as well as promoting bone regeneration through the differentiation, proliferation, mineralisation and adhesion of osteoblasts in in vitro and in vivo studies. This study aims to determine and compare the chemical composition, roughness and wettability of non-coated commercially pure titanium (CpTi) disc surfaces with CpTi discs that have been coated with tantalum oxynitride film (TaON) via a modified plasma sputtering coating technique. Methods: Two groups were tested that included the TaON-coated CpTi discs and non-coated CpTi discs. A modified reactive plasma sputtering apparatus was used for coating the CpTi discs with TaON at different time durations, i.e., 4, 6, and 8 h. The surface properties of the coated and non-coated discs were studied using X-ray diffraction (XRD) analysis, energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), and contact angle measurement. Results and Conclusions: The results showed that 8 h was the best coating duration. The XRD analysis showed the presence of a new peak in the case of the TaON-coated CpTi disc that was absent in the non-coated CpTi disc. Furthermore, the SEM analysis revealed that the TaON-coated CpTi disc showed a better distribution of surface roughness compared to the non-coated disc. The non-coated CpTi discs showed lower wettability compared to the TaON-coated CpTi discs. The result shows the importance of a TaON coat in changing the surface properties of CpTi which will be used in dental implants; this result will enhance the idea of surface treatment and its relationship with the enhancement and acceleration of bone formation around dental implants in future. The novelty of the newly modified reactive plasma sputtering technique used in this study as a coating technique for CpTi discs lies in the promising tantalum oxynitride, as Ta had no toxicity effect in cytotoxicity tests and promoted adhesion, proliferation, differentiation, the mineralisation of osteoblasts and bone regeneration in vitro and in vivo. The mean target of the work is to enhance the osseointegration of CPTi dental implants with different surface coatings including Ta oxide, nitride and oxynitride. The results of the first two coatings are already published, and the third coating technique is investigated in this study. Full article

Biohydrometallurgical processing of spent lithium-ion batteries offers a low-impact route for critical metal recovery compared with conventional hydrometallurgy. In this work, the iron-oxidizing bacterium Acidithiobacillus ferrooxidans was evaluated for the bioleaching of cobalt (Co), nickel (Ni), lithium (Li) and copper (Cu) from pyrolyzed industrial black mass derived primarily from LiCoO₂-based batteries, containing both LiCoO₂ and LiNiO₂ layered oxide phases. Batch experiments were conducted in 9K medium at 30 °C, varying pulp density (1%–2%, w/v), inoculum volume (10–20 mL in 200 mL medium) and initial pH (with and without adjustment). At 1% pulp density and 10% v/v inoculum, metal recoveries after 6–7 days reached about 64%–70% Co, 57%–72% Ni, 52%–60% Li and 81%–100% Cu, with most dissolution occurring in the first 6 days. Higher inoculum loads without initial pH adjustment increased Li recovery up to 79%, but did not further improve Co and Cu, indicating a trade-off between microbial activity, metal toxicity and ferric iron availability. The temporal evolution of pH and metal dissolution is consistent with indirect redoxolysis by biogenic Fe³⁺ and sulfuric acid generated during ferrous iron and elemental sulfur oxidation. Overall, the results confirm the feasibility of A. ferrooxidans-assisted bioleaching as a green option for Co, Ni, Li and Cu recovery from spent LiCoO₂ batteries and provide operating windows for subsequent process optimization and scale-up. Full article