Search Results (85)

Iron-based shape memory alloys (Fe-SMAs) are promising for structural retrofitting because of their low cost, corrosion resistance, and manufacturability. However, the effect of strain rate on the coupled thermo-microstructural evolution during cyclic training remains underexplored. In this study, samples underwent cyclic tensile training at quasi-static and impact strain rates. After each cycle, DSC was adopted to obtain transformation temperatures and enthalpies, and selected cycles were characterized by EBSD (KAM and IPF) to quantify phase fractions and variant statistics. Results show tensile loading shifts transformation temperatures, with the principal difference between regimes appearing in the evolution of martensite finish temperature. Under impact loading, the transformation enthalpy increases more rapidly (0.18 to 0.8 J/g in absolute value), and the driving force decreases more markedly by the fourth cycle (−0.0578 to −0.1117 J/g), indicating faster thermodynamic changes at high strain rates. Internal stress and dislocation storage accumulate faster under impact, lowering the effective stress (−17.01 MPa) for transformation and promoting martensite nucleation/growth. EBSD reveals increasing lattice distortion; in impact-trained samples, single-variant martensite and higher stored energy reduce interface resistance and enable elastic energy release, accelerating transformation and improving shape recovery. Full article

This study presents an experimental investigation into the seismic performance of seismically deficient reinforced concrete (RC) bridge columns retrofitted with passive and active confinement systems. Four single-cantilever RC columns, representing 1/3-scale bridge piers, were constructed with poor transverse reinforcement detailing to simulate seismic deficiency. One column was left un-strengthened for baseline comparison, while the remaining three were retrofitted using: (1) a CFRP jacket, (2) welded Fe-SMA plates, and (3) bolted Fe-SMA plates. All columns were subjected to quasi-static lateral cyclic push-only loading reaching extreme drift levels exceeding 16% and high loading rates up to 6 mm/s. The study specifically explores the confinement effectiveness of CFRP and thermally activated Fe-SMA plates, comparing their contributions to lateral strength, ductility, energy dissipation, failure mode, and damage suppression. The results show that while the as-built column failed at 3.65% drift due to brittle flexural-shear failure, all retrofitted columns demonstrated significantly enhanced ductility, drift capacity, and post-peak behaviour. The CFRP and Fe-SMA jackets effectively delayed damage initiation, minimized core degradation, and improved energy dissipation. The bolted Fe-SMA system exhibited the highest and full restoration of lateral strength, while the welded system achieved the greatest increase in cumulative energy dissipation of around 40%. This research highlights the practical advantages and seismic effectiveness of Fe-SMA and CFRP confinement systems under extreme drift levels. However, future work should explore full-scale column applications, refine anchorage techniques for improved composite interaction, and investigate long-term durability under cyclic environmental conditions. Full article

This study proposes a hybrid flexural strengthening technique for reinforced concrete (RC) beams by combining the near-surface mounted (NSM) and externally bonded reinforcement (EBR) methods. In this technique, iron-based shape memory alloy (Fe-SMA) strips are used for the NSM component, while either a carbon fiber reinforced polymer (CFRP) sheet or an Fe-SMA sheet is applied as the EBR component. The proposed hybrid-strengthening method aims to enhance the flexural load capacity and ductility of existing RC beams. To evaluate the effectiveness of the proposed method, numerical models were developed using ABAQUS software and validated against experimental results. A comprehensive numerical investigation was carried out on 52 RC beams, categorized into six groups with various hybrid-strengthening configurations. In addition, the effect of the prestressing of NSM Fe-SMA strips and the prestressing of EBR CFRP or EBR Fe-SMA sheet on the flexural performance of the beams was also examined. The results indicated that the hybrid-strengthening method significantly improved the cracking, yielding, and ultimate load capacities of the beams; however, in most cases, it reduced their deflection. Notably, prestressing the EBR Fe-SMA sheet in beams with higher reinforcement ratios produced a pronounced improvement in ductility. Full article

Shape memory alloys (SMAs) are known for their exceptional mechanical properties, particularly their superior wear resistance compared to conventional alloys with similar surface hardness. Rare earth oxides are often used as additives to further improve these characteristics. This study investigates the effects of different CeO₂ (cerium dioxide) concentrations (0.01 wt.%, 0.1 wt.%, 0.5 wt.%, and 1.0 wt.%) on the properties of CuAlMnFe alloys produced via powder metallurgy (PM). Various analyses were performed, including scanning electron microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-ray diffraction (XRD), as well as hardness, wear, and corrosion tests. The increase in wear rate is closely related to the formation of precipitates from CeO₂ addition. Improvements in wear resistance and hardness are attributed to the effects of grain refinement and solid solution strengthening due to CeO₂. Specifically, the wear rate increased from 1.5 × 10⁻³ mm³/(Nm) to 3.4 × 10⁻³ mm³/(Nm) with higher CeO₂ content. Additionally, the friction coefficient of the CuAlMnFe alloy was reduced with CeO₂ addition, indicating enhanced frictional properties. The optimal CeO₂ concentration of 0.5% was found to improve grain uniformity, resulting in better wear resistance. Incorporating CeO₂ particles into CuAlMnFe alloy enhances hardness and reduces wear rate when used in appropriate amounts. Additionally, it exhibits superior corrosion resistance, as evidenced by a positive shift in corrosion potential in Tafel measurements in solutions and a decrease in corrosion current density. The C0.5 specimen showed the highest corrosion potential (E_corr, −588 V) and the lowest corrosion current density (i_corr, 6.17 μA/cm²) during electrochemical corrosion in 3.5 wt.% NaCl solution. Full article

This study examines how the frequency of an innovative energy harvester is tuned and how it behaves. This harvester transforms thermal energy into mechanical oscillations of two polyvinylidene fluoride (PVDF) piezoelectric beams, which produce electrical energy via a shape memory alloy (SMA) thread. The oscillation frequency is modified by two magnetic weights that are positioned symmetrically on the SMA thread and interact with stationary NdFeB permanent magnets. The SMA thread shifts laterally due to longitudinal thermal contraction and expansion induced by a constant-temperature heater. Temperature gradients above the heater trigger cyclical variations in the length of the SMA thread, leading to autonomous vibrations of the masses in both the vertical and horizontal planes. An experimental apparatus was constructed to analyze the harvester by tracking the motions of the masses and the voltages produced by the piezoelectric beams. Information was gathered regarding the correlation between output voltage and power with the consumer’s load resistance. These outcomes were confirmed using a multiphysics dynamic simulation that incorporated the interconnections among mechanical, thermal, magnetic, and electrical systems. The findings indicate that the use of permanent magnets increases the bending vibration frequency from 8.3 Hz to 9.2 Hz. For a heater maintained at 70 °C, this boosts the output power from 1.9 µW to 8.18 µW. A notable property of the considered energy harvester configuration is its ability to operate at cryogenic temperatures. Full article

Reinforced concrete (RC) beams with openings in shear spans exhibited a significantly reduced structural performance due to disruptions in load transfer mechanisms. This numerical study investigated the influence of pre-stressed iron-based Shape Memory Alloy (Fe-SMA) rebars on the behavior of RC beams with web openings, focusing on the effect of shear-oriented design parameters, including the stirrup spacing, stirrup diameter, and horizontal reinforcement around the opening. A nonlinear finite element analysis (NLFEA) was conducted using ABAQUS/CAE software 2020 to simulate the response of RC beams under these conditions. The results showed that the presence of web openings in RC beams reduced the ultimate load capacity and stiffness. However, the pre-stressed Fe-SMA reinforcement effectively mitigated these adverse effects, restoring much of the solid beam’s performance. Among the studied parameters, reducing the stirrup spacing significantly improved the load-bearing capacity, with the smallest spacing (100 mm) restoring 86% of the solid beam’s ultimate load. Increasing the Fe-SMA stirrup diameter further enhanced performance, with T16 stirrups recovering 92% of the solid beam’s ultimate load capacity. The most substantial improvement occurred when horizontal reinforcement was introduced, particularly with T16 stirrups, achieving a 95% load recovery, nearly matching the solid RC beam structural performance. These findings demonstrated the promising potential of pre-stressed Fe-SMA reinforcement as a viable solution for restoring the structural strength of RC beams with web openings. Full article

The Monkeypox virus (MPXV), a DNA virus classified under the Orthpoxvirus genus alongside variola virus, has recently garnered significant global health attention due to its increasing transmission and emerging genomic mutations. Point-of-care testing is essential for effective clinical response and outbreak mitigation. In this article, we developed a novel class of colored microspheres designed for application in a lateral flow immunoassay (LFIA) platform targeting MPXV-specific biomarkers. Polystyrene-maleic anhydride (SMA-MAA) microspheres were synthesized with a high-temperature soap-free emulsion polymerization optimized in our lab. Subsequent alkali and acid treatments were employed to introduce porosity into the microsphere matrix. Solvent Red 27 and Disperse Red 60 were incorporated via solvent-swelling and thermal-swelling methods, respectively, to generate high brightness (HB) carriers. A surface coating composed of a tannic acid–iron (TA–Fe³⁺) coordination complex was applied to form a stable metal–polyphenol film (MPF). This coating not only minimized dye leaching by establishing a robust shell but also improved dye distribution, thereby enhancing overall color intensity. The final HB-LFIA system, configured in a sandwich immunoassay format, demonstrated favorable sensitivity and linear detection range for Monkeypox antigen, indicating strong potential for clinical diagnostic use. Full article

Renal fibrosis is a critical pathological feature of various chronic kidney diseases, with hypoxia being recognized as an important factor in inducing fibrosis. Yaks have long inhabited high-altitude hypoxic environments and do not exhibit fibrotic damage under chronic hypoxia. However, the underlying protective mechanisms remain unclear. This study compared the renal tissue structure and collagen volume between low-altitude cattle and high-altitude yaks, revealing that yaks possess a significantly higher number of renal tubules than cattle, though collagen volume showed no significant difference. Under hypoxic treatment, we observed that chronic hypoxia induced renal fibrosis in cattle, but did not show a significant effect in yaks, suggesting that the hypoxia adaptation mechanisms in yaks may have an anti-fibrotic effect. Further investigation demonstrated a significant upregulation of P-AMPK/AMPK, Parkin, PINK1, LC3Ⅱ/Ⅰ, and BECN1, alongside a downregulation of P-mTOR/mTOR in yak kidneys. Additionally, hypoxia-induced renal tubular epithelial cells (RTECs) showed increased expression of mitophagy-related proteins, mitochondrial membrane depolarization, and an increased number of lysosomes, indicating that hypoxia induces mitophagy. By regulating the mitophagy pathway through drugs, we found that under chronic hypoxia, activation of mitophagy upregulated E-cadherin protein expression while downregulating the expression of Vimentin, α-SMA, Collagen I, and Fibronectin. Simultaneously, there was an increase in SLC7A11, GPX4, and GSH levels, and a decrease in ROS, MDA, and Fe²⁺ accumulation. Inhibition of mitophagy produced opposite effects on protein expression and cellular markers. Further studies identified ferroptosis as a key mechanism promoting renal fibrosis. Moreover, in renal fibrosis models, mitophagy reduced the accumulation of ROS, MDA, and Fe²⁺, thereby alleviating ferroptosis-induced renal fibrosis. These findings suggest that chronic hypoxia protects yaks from hypoxia-induced renal fibrosis by activating mitophagy to inhibit the ferroptosis pathway. Full article

An Fe-based shape memory alloy (Fe-SMA) is an alloy that has a characteristic of being able to return to its original shape when heated, even after undergoing plastic deformation. Many researchers have conducted various studies to understand the effectiveness of using Fe-SMA in concrete structures. Most studies selected the heating temperature of Fe-SMA to be below 160 °C based on the logic that concrete hydrolyzes when its temperature exceeds 160 °C. However, because the recovery stress of Fe-SMA increases as the heating temperature increases, it is expected that greater prestress could be introduced when the heating temperature is high. In this study, to confirm this, a numerical study was conducted to evaluate the effect of Fe-SMA heating temperature on the flexural performance of concrete members through finite element (FE) analysis. The analysis results showed that the initial crack load of the specimen increased by about 89% to 173% as the heating temperature of Fe-SMA increased. In addition, the accuracy of the proposed FE model (FEM) was verified through experiments. As a result, it was confirmed that the proposed FE analysis can relatively accurately predict the failure mode and load–displacement relationship of the specimen. Full article

The superelasticity of CuZr shape memory alloys (SMAs) originates from stress-induced transformations between the B2 (austenite) and B19’ (martensite) phases. Grain size is a key parameter affecting the superelasticity of shape memory alloys. Previous studies on NiTi, Fe-based, and Cu-based SMAs confirm that altering grain size effectively regulates superelasticity. Current research on the influence of grain size on the superelasticity of CuZr shape memory alloys (SMAs) is relatively sparse. This study employs molecular dynamics simulations to evaluate the effect of grain size on the superelasticity of CuZr SMAs through uniaxial loading–unloading tests. Polycrystalline samples with grain sizes of 6.59 nm, 5 nm, and 4 nm were analyzed. The results indicate that reducing grain size can decrease the irrecoverable strain, thereby enhancing superelasticity. The improvement in superelasticity is attributed to a higher recovery rate of the martensite-to-austenite transformation, allowing more plastic deformation within the grain interior to recover during unloading, and thereby reducing the irrecoverable strain. The recovery rate of the martensite-to-austenite transformation is closely related to the elastic strain energy accumulated within the grain interior during loading. Full article

Botryocladia leptopoda is a red macroalga known for its bioactive compounds with antioxidant, anti-inflammatory, and skin-regenerative properties. The study aimed to examine their effects on UV protection, collagen synthesis, fibroblast proliferation, and pigmentation modulation. Bioactive compounds were extracted using two solvents, producing ethanol extract (FE) and alkaline extracts (AE). Methods involved characterizing extracts using mass spectrometry and assessing their effects on human fibroblasts under UVB-induced damage. UV absorbance, ROS production, and collagen synthesis were evaluated. The FE extract, which comprised 4-hydroxyquinoline, phytosphingosine, and docosapentaenoic acid, reinstated procollagen type I synthesis to 113% of baseline levels and reduced TGF-β1-mediated fibroblast proliferation to 87.78%. FE also suppressed Smad2 and α-SMA by 71% and 68%, respectively, indicating modulation of fibrosis-associated pathways. AE, containing 4-hydroxyquinoline and phenylalanine betaine, demonstrated dose-responsive cellular repair, reducing fibroblast proliferation to 97.86% and collagen Type I expression by 73% at 1000 μg/mL. Both extracts decreased ROS production, with FE and AE reducing levels by 21.4% and 19.7%, respectively, under UVB-induced oxidative stress. FE showed superior scar inhibition, while AE excelled in skin regeneration and pigmentation management. Full article

The prestressed active reinforcement of concrete structures using iron-based shape memory alloys (Fe-SMAs) is investigated in this experimental study through three connecting methods: adhesive–bolted hybrid connection, bolted connection, and adhesively bonded connection by activating at elevated temperatures (heating and cooling) and constraining deformation to generate prestress inside Fe-SMAs, through which compressive stress is generated in the parent concrete structures. In tests, the Fe-SMA is activated at 250 °C using a hot air gun, generating a prestress of 184.6–246 MPa. The experimental results show that local stress concentration in the concrete specimen and Fe-SMA plate around the hole is caused by the bolted connection. The adhesively bonded connection is prone to softening and slip of the structural adhesive during the activation process, thereby reducing the overall recovery force of Fe-SMAs. The adhesive–bolted hybrid connection effectively mitigates the local stress concentration problem of concrete and Fe-SMAs at anchor holes, while avoiding the prestress loss caused by the softening and slip of structural adhesive during elevated-temperature activation, achieving good reinforcement effect. This study on the connection methods of an Fe-SMA for reinforcing concrete structures provides both experimental support and practical guidance for its engineering application, offering new perspectives for future research. Full article

In this study, microstructure, mechanical, and shape memory properties of the welded Fe-based shape memory alloy (Fe-SMA) plates with a nominal composition of Fe-17Mn-5Si-10Cr-4Ni-(V, C) (wt.%) by gas tungsten arc welding were investigated. The optimal heat input to ensure full penetration of the Fe-SMA plate with a thickness of 2 mm was found to be 0.12 kJ. The solidified grain morphology adjacent to the partially melted zone was columnar, whereas the equiaxed morphology emerged as solidification proceeded. The ultimate tensile decreased after welding owing to the much larger grain size of the fusion zone (FZ) and heat-affected zone (HAZ) than that of the base material (BM). Weldment showed lower pseudoelastic (PE) recovery strain and higher shape memory effect (SME) than those of the plate, which could be ascribed to the large grain size of the FZ and HAZ. Recovery stress (RS) slightly decreased after welding owing to lower mechanical properties of weldment. On the other hand, aging treatment significantly improved all PE recovery, SME, and RS via carbide precipitation. Digital image correlation analysis revealed that HAZ showed the lowest SME after heating and cooling, implying that the improved SME of FZ compensated for the low SME of the HAZ. Full article

This paper presents the experimental results of a study evaluating the mechanical and fatigue performance of welded Fe-Mn-Si SMA. For the experimental study, welded and welded-and-heat-treated Fe-Mn-Si SMA specimens were fabricated, and fatigue tests were performed at various stress amplitudes. In addition, direct tensile tests and recovery stress tests were also performed to evaluate the material properties of Fe-Mn-Si SMAs. The elastic modulus, yield strength, and tensile strength of the welded specimens were reduced by 35.4%, 12.1%, and 8.6%, respectively, compared to the values of the non-welded specimens. On the other hand, the elastic modulus, yield strength, and tensile strength of the welded-and-heat-treated Fe-Mn-Si SMA specimens were increased by 18.6%, 4.9%, and 1.3%, respectively, compared to the values of the welded specimens. Both welded and welded-and-heat-treated Fe-Mn-Si SMAs failed at lower cycles than the conventional Fe-Mn-Si SMAs at the same stress amplitude. High-cycle fatigue failure, characterized by cycles exceeding 10⁴, typically occurs at relatively low stress levels within the elastic region, whereas low-cycle fatigue failure, generally occurring within cycles below 10⁴, involves high stress levels that encompass both elastic and plastic deformation. Regardless of the welding condition, the stress amplitude at which Fe-Mn-Si SMA transitions from high-cycle to low-cycle failure exceeded the yield strength. Full article

Iron-based shape memory alloys (Fe-SMAs), traditionally manufactured, are favored in engineering applications owing to their cost-effectiveness and ease of fabrication. However, the conventional manufacturing process of Fe-SMAs is time-consuming and raw-material-wasting. In contrast, additive manufacturing (AM) technology offers a streamlined approach to the integral molding of materials, significantly reducing raw material usage and fabrication time. Despite its potential, research on AMed Fe-SMAs remains in its early stages. This review provides updated information on current AM technologies utilized for Fe-SMAs and their applications. It provides an in-depth discussion on how printing parameters, defects, and post-printing microstructure control affect the mechanical properties and shape memory effect (SME) of AMed Fe-SMAs. Furthermore, this review identifies existing challenges in the AMed Fe-SMA approach and proposes future research directions, highlighting potential areas for development. The insights presented aim to guide improvements in the material properties of AMed Fe-SMAs by optimizing printing parameters and enhancing the SME through microstructure adjustment. Full article