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19 pages, 6809 KB  
Article
Balancing Strength and Flexibility: Mechanical Characterization of Carbon Fiber-Reinforced PLA Composites in FDM 3D Printing
by Boston Blake, Ryan Mendenhall and Babak Eslami
J. Manuf. Mater. Process. 2025, 9(9), 288; https://doi.org/10.3390/jmmp9090288 - 22 Aug 2025
Viewed by 135
Abstract
Fused Deposition Modeling (FDM) is a commonly used 3D printing process characterized by its versatility in material selection; however, FDM’s layer-by-layer process often leads to lower strength properties. This study explores the mechanical properties of FDM 3D-printed composite materials printed with varying nozzle [...] Read more.
Fused Deposition Modeling (FDM) is a commonly used 3D printing process characterized by its versatility in material selection; however, FDM’s layer-by-layer process often leads to lower strength properties. This study explores the mechanical properties of FDM 3D-printed composite materials printed with varying nozzle diameters, specifically on the influence of Carbon Fiber-reinforced Polylactic Acid (PLA-CF) on tensile and flexural strength when reinforcing Polylactic Acid (PLA) parts. Composite samples were printed with varying ratios of PLA and PLA-CF, ranging from 0% to 100% PLA-CF in 20% increments, with layer groups stacked vertically, while also using three different nozzle diameters (0.4 mm, 0.6 mm, and 0.8 mm). Tensile testing revealed a proportional increase in strength as PLA-CF content increased, indicating that carbon fiber reinforcement significantly enhances tensile performance. However, flexural testing demonstrated a decrease in bending strength with higher PLA-CF content, suggesting a trade-off between stiffness and flexibility. Mid-range ratios (40–60% PLA-CF) provided a balance between tensile and flexural properties. Finally, atomic force microscopy was utilized to provide a better understanding of the microscale morphology and surface properties of PLA and PLA-CF thin films. The results highlight the potential of PLA-CF/PLA composites to allow for more direct control over the tensile–flexural trade-off during the printing process, as opposed to manufacturing filaments with fixed fiber percentages. These results provide a path for tailoring the mechanical behavior of printed parts without requiring specialized filaments. Full article
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23 pages, 3081 KB  
Article
Physico-Mechanical Properties of 3D-Printed Filament Materials for Mouthguard Manufacturing
by Maciej Trzaskowski, Gen Tanabe, Hiroshi Churei, Toshiaki Ueno, Michał Ziętala, Bartłomiej Wysocki, Judyta Sienkiewicz, Agata Szczesio-Włodarczyk, Jerzy Sokołowski, Ewa Czochrowska, Małgorzata Zadurska, Elżbieta Mierzwińska-Nastalska, Jolanta Kostrzewa-Janicka and Katarzyna Mańka-Malara
Polymers 2025, 17(16), 2190; https://doi.org/10.3390/polym17162190 - 10 Aug 2025
Viewed by 431
Abstract
Mouthguards are recommended for all sports that may cause injuries to the head and oral cavity. Custom mouthguards, made conventionally in the thermoforming process from ethylene vinyl acetate (EVA), face challenges with thinning at the incisor area during the process. In contrast, additive [...] Read more.
Mouthguards are recommended for all sports that may cause injuries to the head and oral cavity. Custom mouthguards, made conventionally in the thermoforming process from ethylene vinyl acetate (EVA), face challenges with thinning at the incisor area during the process. In contrast, additive manufacturing (AM) processes enable the precise reproduction of the dimensions specified in a computer-aided design (CAD) model. The potential use of filament extrusion materials in the fabrication of custom mouthguards has not yet been explored in comparative studies. Our research aimed to compare five commercially available filaments for the material extrusion (MEX) also known as fused deposition modelling (FDM) of custom mouthguards using a desktop 3D printer. Samples made using Copper 3D PLActive, Spectrum Medical ABS, Braskem Bio EVA, DSM Arnitel ID 2045, and NinjaFlex were compared to EVA Erkoflex, which served as a control sample. The samples underwent tests for ultimate tensile strength (UTS), split Hopkinson pressure bar (SHPB) performance, drop-ball impact, abrasion resistance, absorption, and solubility. The results showed that Copper 3D PLActive and Spectrum Medical ABS had the highest tensile strength. DSM Arnitel ID 2045 had the highest dynamic property performance, measured with the SHPB and drop-ball tests. On the other hand, NinjaFlex exhibited the lowest abrasion resistance and the highest absorption and solubility. DSM Arnitel ID 2045’s absorption and solubility levels were comparable to those of EVA, but had significantly lower abrasion resistance. Ultimately, DSM Arnitel ID 2045 is recommended as the best filament for 3D-printing mouthguards. The properties of this biocompatible material ensure high-impact energy absorption while maintaining low fluid sorption and solubility, supporting its safe intra-oral application for mouthguard fabrication. However, its low abrasion resistance indicated that mouthguards made from this material may need to be replaced more frequently. Full article
(This article belongs to the Special Issue Polymers Composites for Dental Applications, 2nd Edition)
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20 pages, 3145 KB  
Article
Determination of Dynamic Elastic Properties of 3D-Printed Nylon 12CF Using Impulse Excitation of Vibration
by Pedro F. Garcia, Armando Ramalho, Joel C. Vasco, Rui B. Ruben and Carlos Capela
Polymers 2025, 17(15), 2135; https://doi.org/10.3390/polym17152135 - 4 Aug 2025
Viewed by 447
Abstract
Material Extrusion (MEX) process is increasingly used to fabricate components for structural applications, driven by the availability of advanced materials and greater industrial adoption. In these contexts, understanding the mechanical performance of printed parts is crucial. However, conventional methods for assessing anisotropic elastic [...] Read more.
Material Extrusion (MEX) process is increasingly used to fabricate components for structural applications, driven by the availability of advanced materials and greater industrial adoption. In these contexts, understanding the mechanical performance of printed parts is crucial. However, conventional methods for assessing anisotropic elastic behavior often rely on expensive equipment and time-consuming procedures. The aim of this study is to evaluate the applicability of the impulse excitation of vibration (IEV) in characterizing the dynamic mechanical properties of a 3D-printed composite material. Tensile tests were also performed to compare quasi-static properties with the dynamic ones obtained through IEV. The tested material, Nylon 12CF, contains 35% short carbon fibers by weight and is commercially available from Stratasys. It is used in the fused deposition modeling (FDM) process, a Material Extrusion technology, and exhibits anisotropic mechanical properties. This is further reinforced by the filament deposition process, which affects the mechanical response of printed parts. Young’s modulus obtained in the direction perpendicular to the deposition plane (E33), obtained via IEV, was 14.77% higher than the value in the technical datasheet. Comparing methods, the Young’s modulus obtained in the deposition plane, in an inclined direction of 45 degrees in relation to the deposition direction (E45), showed a 22.95% difference between IEV and tensile tests, while Poisson’s ratio in the deposition plane (v12) differed by 6.78%. This data is critical for designing parts subject to demanding service conditions, and the results obtained (orthotropic elastic properties) can be used in finite element simulation software. Ultimately, this work reinforces the potential of the IEV method as an accessible and consistent alternative for characterizing the anisotropic properties of components produced through additive manufacturing (AM). Full article
(This article belongs to the Special Issue Mechanical Characterization of Polymer Composites)
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17 pages, 5022 KB  
Article
The Impact of Elevated Printing Speeds and Filament Color on the Dimensional Precision and Tensile Properties of FDM-Printed PLA Specimens
by Deian Dorel Ardeljan, Doina Frunzaverde, Vasile Cojocaru, Raul Rusalin Turiac, Nicoleta Bacescu, Costel Relu Ciubotariu and Gabriela Marginean
Polymers 2025, 17(15), 2090; https://doi.org/10.3390/polym17152090 - 30 Jul 2025
Viewed by 423
Abstract
This study examines the effect of elevated printing speeds (100–600 mm/s) on the dimensional accuracy and tensile strength of PLA components fabricated via fused deposition modeling (FDM). To isolate the influence of printing speed, all other parameters were kept constant, and two filament [...] Read more.
This study examines the effect of elevated printing speeds (100–600 mm/s) on the dimensional accuracy and tensile strength of PLA components fabricated via fused deposition modeling (FDM). To isolate the influence of printing speed, all other parameters were kept constant, and two filament variants—natural (unpigmented) and black PLA—were analyzed. ISO 527-2 type 1A specimens were produced and tested for dimensional deviations and ultimate tensile strength (UTS). The results indicate that printing speed has a marked impact on both geometric precision and mechanical performance. The optimal speed of 300 mm/s provided the best compromise between dimensional accuracy and tensile strength for both filaments. At speeds below 300 mm/s, under-extrusion caused weak layer bonding and air gaps, while speeds above 300 mm/s led to over-extrusion and structural defects due to thermal stress and rapid cooling. Black PLA yielded better dimensional accuracy at higher speeds, with cross-sectional deviations between 2.76% and 5.33%, while natural PLA showed larger deviations of up to 8.63%. However, natural PLA exhibited superior tensile strength, reaching up to 46.59 MPa, with black PLA showing up to 13.16% lower UTS values. The findings emphasize the importance of speed tuning and material selection for achieving high-quality, reliable, and efficient FDM prints. Full article
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16 pages, 1758 KB  
Case Report
3D Printing Today, AI Tomorrow: Rethinking Apert Syndrome Surgery in Low-Resource Settings
by Maria Bajwa, Mustafa Pasha and Zafar Bajwa
Healthcare 2025, 13(15), 1844; https://doi.org/10.3390/healthcare13151844 - 29 Jul 2025
Viewed by 404
Abstract
Background/Objectives: This case study presents the first documented use of a low-cost, simulated, patient-specific three-dimensional (3D) printed model to support presurgical planning for an infant with Apert syndrome in a resource-limited setting. The primary objectives are to (1) demonstrate the value of 3D [...] Read more.
Background/Objectives: This case study presents the first documented use of a low-cost, simulated, patient-specific three-dimensional (3D) printed model to support presurgical planning for an infant with Apert syndrome in a resource-limited setting. The primary objectives are to (1) demonstrate the value of 3D printing as a simulation tool for preoperative planning in low-resource environments and (2) identify opportunities for future AI-enhanced simulation models in craniofacial surgical planning. Methods: High-resolution CT data were segmented using InVesalius 3, with mesh refinement performed in ANSYS SpaceClaim (version 2021). The cranial model was fabricated using fused deposition modeling (FDM) on a Creality Ender-3 printer with Acrylonitrile Butadiene Styrene (ABS) filament. Results: The resulting 3D-printed simulated model enabled the surgical team to assess cranial anatomy, simulate incision placement, and rehearse osteotomies. These steps contributed to a reduction in operative time and fewer complications during surgery. Conclusions: This case demonstrates the value of accessible 3D printing as a simulation tool in surgical planning within low-resource settings. Building on this success, the study highlights potential points for AI integration, such as automated image segmentation and model reconstruction, to increase efficiency and scalability in future 3D-printed simulation models. Full article
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9 pages, 1551 KB  
Proceeding Paper
Tensile Testing of Polymer Material Specimens Obtained by Fused Deposition Modeling
by Miglena Paneva, Peter Panev and Veselin Tsonev
Eng. Proc. 2025, 100(1), 50; https://doi.org/10.3390/engproc2025100050 - 18 Jul 2025
Viewed by 282
Abstract
In this work, a comparative analysis of polymer test specimens from different types of filaments, manufactured using FDM technology, was performed. A tensile strength test was executed on test specimens after 3D additive printing, made from different groups of materials—PLA, PLA Wood, PETG, [...] Read more.
In this work, a comparative analysis of polymer test specimens from different types of filaments, manufactured using FDM technology, was performed. A tensile strength test was executed on test specimens after 3D additive printing, made from different groups of materials—PLA, PLA Wood, PETG, PC, PA6, ASA, CPE HG100 and FilaFlex SEBS. Test specimens from the same materials were subjected to accelerated aging, after which they were tested again for tensile strength. The results of all tests were analyzed and compared. Full article
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22 pages, 6286 KB  
Article
Thermal Degradation and Flame Resistance Mechanism of Phosphorous-Based Flame Retardant of ABS Composites Used in 3D Printing Technology
by Rafał Oliwa, Katarzyna Bulanda and Mariusz Oleksy
Materials 2025, 18(13), 3202; https://doi.org/10.3390/ma18133202 - 7 Jul 2025
Viewed by 389
Abstract
As part of the work, polymer composites dedicated to rapid prototyping were developed, especially for 3D printing using the material extrusion technique. For this purpose, a polymer matrix was selected, which was an acrylonitrile-butadiene-styrene (ABS) terpolymer and a flame retardant, which was tetrakis [...] Read more.
As part of the work, polymer composites dedicated to rapid prototyping were developed, especially for 3D printing using the material extrusion technique. For this purpose, a polymer matrix was selected, which was an acrylonitrile-butadiene-styrene (ABS) terpolymer and a flame retardant, which was tetrakis (2,6-dimethylphenyl)-m-phenylenebisphosphate, commercially known as PX200. The effect of the presence and amount (5, 10, 15 and 20 wt.%) of the introduced additive on the rheological properties, structural properties, flammability (limiting oxygen index, LOI; UL94) and flame retardant properties (microcone calorimeter, MLC) of ABS-based composites was investigated. In addition, the mechanism of thermal degradation and flame resistance was investigated using thermogravimetric analysis, TGA and Fourier transform infrared spectroscopy, FT-IR of the residue after the MLC test. In the first part of the work, using the author’s technological line, filaments were obtained from unfilled ABS and its composites. Samples for testing were obtained by 3D printing in Fused Deposition Modeling (FDM) technology. In order to determine the quantitative and qualitative spread of fire and the effectiveness of the phosphorus flame retardant PX200 in the produced composites, the Maximum Average Rate of Heat Emission (MARHE); Fire Growth Rate Index (FIGRA); Fire Potential Index (FPI) and Flame Retardancy Index (FRI) were determined. Based on the obtained results, it was found that the aryl biphosphate used in this work exhibits activity in the gas phase, which was confirmed by quantitative assessment using data from a microcone calorimeter and non-residues after combustion and thermolysis at 700 °C. As a result, the flammability class did not change (HB40), and the LOI slightly increased to 20% for the composite with 20% flame retardant content. Moreover, this composite was characterized by the following flammability indices: pHRR = 482.9 kW/m2 (−40.3%), MARHE = 234 kW/m2 (−40.7%), FIGRA = 3.1 kW/m2·s (−56.3%), FPI = 0.061 m2·s/kW (+64.9%), FRI = 2.068 (+106.8%). Full article
(This article belongs to the Special Issue 3D Printing of Polymeric Materials)
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9 pages, 2824 KB  
Proceeding Paper
Approaches to Creating Colorful 3D-Printed Parts and Reliefs
by Mihail Zagorski, Radoslav Miltchev, Boyan Dochev and Nikolay Stoimenov
Eng. Proc. 2025, 100(1), 9; https://doi.org/10.3390/engproc2025100009 - 2 Jul 2025
Viewed by 337
Abstract
The present article aims to examine different approaches and technologies for producing multi-color 3D printed parts and reliefs using FDM/FFF printing technology. Several examples of parts used in the fields of technology, architecture, marketing and art are presented. The innovative HueForge software version [...] Read more.
The present article aims to examine different approaches and technologies for producing multi-color 3D printed parts and reliefs using FDM/FFF printing technology. Several examples of parts used in the fields of technology, architecture, marketing and art are presented. The innovative HueForge software version 0.8.1 is used to create a multi-color relief. The process of establishing the Transmission Distance parameter of a given filament, which is key to creating colored reliefs with HueForge, is also examined. Full article
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23 pages, 4048 KB  
Article
Experimental Study on Hybrid Additive and Subtractive Manufacturing Processes for Improving Surface Quality
by Monika Jabłońska
Materials 2025, 18(13), 3136; https://doi.org/10.3390/ma18133136 - 2 Jul 2025
Viewed by 3224
Abstract
Hybrid machining has considerable potential for industrial applications. The process allows the limitations of additive manufacturing to be reduced and high-precision components to be produced. This article discusses tests determining the impact of 3D printing parameters, machining parameters, and selected milling tools on [...] Read more.
Hybrid machining has considerable potential for industrial applications. The process allows the limitations of additive manufacturing to be reduced and high-precision components to be produced. This article discusses tests determining the impact of 3D printing parameters, machining parameters, and selected milling tools on achieving defined surface roughness values in parts made of PETG (polyethylene terephthalate glycol). Perpendicular-shaped samples were printed by fused deposition modelling (FDM) using variable layer heights of 0.1 mm and 0.2 mm and variable feed rates of 90, 100, 110, and 120 mm/s. Surface roughness values, topography, and Abbott–Firestone curves were determined using a Keyence VR-6000 profilometer. Straight grooves were machined in the test samples using a DMG MORI CMX 600V milling machine with a rotary burr, single-edge spiral burr cutter and spiral endmill. The microstructure was examined using a Motic inverted microscope. The surface roughness parameters of the grooves were investigated. The results confirmed that the use of hybrid machining (with a printed layer height Lh = 0.1 mm, Vfeed = 120 mm/s, and a cutter–rotary burr) allows for lower surface roughness parameters, i.e., Ra = 1.54 μm. The relationships developed between printing, cutting, and milling tool parameters can be employed to predict the roughness parameters of filaments with similar characteristics. Full article
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34 pages, 4957 KB  
Article
Influence of Cooling Lubricants and Structural Parameters on the Tensile Properties of FFF 3D-Printed PLA and PLA/Carbon Fiber Composites
by Aljaž Rogelj, David Liović, Elvis Hozdić, Marina Franulović and Budimir Mijović
Polymers 2025, 17(13), 1797; https://doi.org/10.3390/polym17131797 - 27 Jun 2025
Viewed by 383
Abstract
This study addresses the lack of comprehensive understanding regarding how both structural printing parameters and environmental factors influence the mechanical properties of additively manufactured polymer and composite materials. The main problem stems from insufficient data on the combined effects of infill density, number [...] Read more.
This study addresses the lack of comprehensive understanding regarding how both structural printing parameters and environmental factors influence the mechanical properties of additively manufactured polymer and composite materials. The main problem stems from insufficient data on the combined effects of infill density, number of perimeters, layer height, and exposure to cooling lubricants on the tensile performance of 3D-printed products, which is crucial for their reliable application in demanding environments. In this research, the influence of four critical parameters—infill density, number of perimeters, layer height, and exposure to cooling lubricants—on the tensile properties of specimens produced by fused filament fabrication (FFF), also known as fused deposition modeling (FDM), from polylactic acid (PLA) and polylactic acid reinforced with carbon fibers (PLA+CF) was investigated. Tensile tests were performed in accordance with ISO 527-2 on specimens printed with honeycomb infill structures under controlled process conditions. The results show that increasing infill density from 40% to 100% led to an approximately 60% increase in tensile strength for both PLA (from 30.75 MPa to 49.11 MPa) and PLA reinforced with carbon fibers (PLA+CF; from 17.75 MPa to 28.72 MPa). Similarly, increasing the number of perimeters from 1 to 3 resulted in a 51% improvement in tensile strength for PLA and 50% for PLA+CF. Reducing layer height from 0.40 mm to 0.20 mm improved tensile strength by 5.4% for PLA and 3.1% for PLA+CF, with more pronounced gains in stiffness observed in the composite material. Exposure to cooling lubricants led to mechanical degradation: after 30 days, PLA exhibited a 15.2% decrease in tensile strength and a 3.4% reduction in Young’s modulus, while PLA+CF showed an 18.6% decrease in strength and a 19.5% drop in modulus. These findings underscore the significant impact of both structural printing parameters and environmental exposure on tailoring the mechanical properties of FFF-printed materials, particularly when comparing unfilled PLA with carbon fiber-reinforced PLA. Full article
(This article belongs to the Special Issue Polymer Composites: Structure, Properties and Processing, 2nd Edition)
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17 pages, 3640 KB  
Article
Sustainable Development of PLA-Based Biocomposites Reinforced with Pineapple Core Powder: Extrusion and 3D Printing for Thermal and Mechanical Performance
by Kawita Chattrakul, Anothai Pholsuwan, Athapon Simpraditpan, Ekkachai Martwong and Wichain Chailad
Polymers 2025, 17(13), 1792; https://doi.org/10.3390/polym17131792 - 27 Jun 2025
Viewed by 551
Abstract
This study developed sustainable biocomposites composed of polylactic acid (PLA) and surface-treated pineapple core powder (PACP), fabricated via extrusion and fused deposition modelling (FDM). PACP loadings of 1–3 vol% were combined after chemical modification with NaOH and silane to improve interfacial bonding. Particle [...] Read more.
This study developed sustainable biocomposites composed of polylactic acid (PLA) and surface-treated pineapple core powder (PACP), fabricated via extrusion and fused deposition modelling (FDM). PACP loadings of 1–3 vol% were combined after chemical modification with NaOH and silane to improve interfacial bonding. Particle morphology showed increased porosity and surface roughness following treatment. The melt flow index (MFI) increased from 31.56 to 35.59 g/10 min at 2 vol% PACP, showing improved flowability. Differential scanning calorimetry (DSC) showed the emergence of cold crystallization (Tcc ~121 °C) and an increase in crystallinity from 35.7% (neat PLA) to 47.3% (2 vol% PACP). Thermogravimetric analysis showed only slight decreases in T5 and Tmax, showing the thermal stability. The mechanical testing of extruded filaments showed increased modulus (1463 to 1518 MPa) but a decrease in tensile strength and elongation. For the 3D-printed samples, elongation at break increased slightly at 1–2 vol% PACP, likely because of the improvement in interlayer fusion. Though, at 3 vol% PACP, the mechanical properties declined, consistent with filler agglomeration observed in SEM. Overall, 2 vol% PACP offered the optimal balance between printability, crystallinity, and mechanical performance. These results reveal the possibility of PACP as a value-added biowaste filler for eco-friendly PLA composites suitable for extrusion and 3D printing applications. Full article
(This article belongs to the Special Issue Sustainable Biopolymers and Bioproducts from Bioresources)
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15 pages, 2767 KB  
Article
Solid-to-Solid Manufacturing Processes for High-Performance Li-Ion Solid-State Batteries
by David Orisekeh, Byeong-Min Roh and Xinyi Xiao
Polymers 2025, 17(13), 1788; https://doi.org/10.3390/polym17131788 - 27 Jun 2025
Viewed by 716
Abstract
Batteries are used as energy storage devices in various equipment. Today, research is focused on solid-state batteries (SSBs), replacing the liquid electrolyte with a solid separator. The solid separators provide electrolyte stability, no leakage, and provide mechanical strength to the battery. Separators are [...] Read more.
Batteries are used as energy storage devices in various equipment. Today, research is focused on solid-state batteries (SSBs), replacing the liquid electrolyte with a solid separator. The solid separators provide electrolyte stability, no leakage, and provide mechanical strength to the battery. Separators are mostly manufactured by either traditional processes or 3D printing technologies. These processes involve making a slurry of plastic, active and conductive material and usually adding a plasticizer when making thin films or filaments for 3D printing. This study investigates the additive manufacturing of solid-state electrolytes (SSEs) by employing fused deposition modeling (FDM) with recyclable, bio-derived polylactic acid (PLA) filaments. Precise control of macro-porosity is achieved by systematically varying key process parameters, including raster orientation, infill percentage, and interlayer adhesion conditions, thereby enabling the formation of tunable, interconnected pore networks within the polymer matrix. Following 3D printing, these engineered porous frameworks are infiltrated with lithium hexafluorophosphate (LiPF6), which functions as the active ionic conductor. A tailored thermal sintering protocol is then applied to promote solid-phase fusion of the embedded salt throughout the macro-porous PLA scaffold, resulting in a mechanically robust and ionically conductive composite separator. The electrochemical ionic conductivity and structural integrity of the sintered SSEs are characterized through electrochemical impedance spectroscopy (EIS) and standardized mechanical testing to assess their suitability for integration into advanced solid-state battery architectures. The solid-state separator achieved an average ionic conductivity of 2.529 × 10−5 S·cm−1. The integrated FDM-sintering process enhances ion exchange at the electrode–electrolyte interface, minimizes material waste, and supports cost-efficient, fully recyclable component fabrication. Full article
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22 pages, 4126 KB  
Article
Investigation of Toy Parts Produced Using Injection Molding and FDM and Selection of the Best Manufacturing Method: A Multi-Criteria Approach
by Şeyda Değirmenci and Ali Osman Er
Appl. Sci. 2025, 15(12), 6725; https://doi.org/10.3390/app15126725 - 16 Jun 2025
Viewed by 416
Abstract
Three-dimensional (3D) printing has become a promising alternative to conventional methods in plastic part production, particularly for customized or low-volume applications such as toys. This study compares toy components produced by Fused Deposition Modeling (FDM) using polylactic acid (PLA) and acrylonitrile butadiene styrene [...] Read more.
Three-dimensional (3D) printing has become a promising alternative to conventional methods in plastic part production, particularly for customized or low-volume applications such as toys. This study compares toy components produced by Fused Deposition Modeling (FDM) using polylactic acid (PLA) and acrylonitrile butadiene styrene (ABS) filaments and those produced by traditional injection molding using ABS pellets. Unlike in many previous studies based on standardized test samples, a real toy part was evaluated in terms of compressive strength, dimensional accuracy, surface quality, and cost. Experimental results revealed that ABS parts produced by injection molding exhibited the highest compressive strength (3.93 kN), followed by PLA-FDM (2.97 kN) and ABS-FDM (0.95 kN). Similarly, injection-molded parts showed superior surface smoothness and dimensional accuracy. Cost analysis indicated that injection molding is economically viable only when production exceeds 735 pieces, while FDM becomes more attractive for smaller batches due to its low initial cost. A multi-criteria decision-making analysis using the TOPSIS method was conducted to integrate technical and economic factors. Results showed that injection molding is preferable for mass production, whereas PLA-FDM is more suitable for low-quantity, cost-sensitive scenarios. Full article
(This article belongs to the Section Additive Manufacturing Technologies)
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22 pages, 7285 KB  
Article
Effect of 3D Printing Parameters on the Viscoelastic Behavior of Acrylonitrile Butadiene Styrene: Fractional Calculus Modeling and Statistical Optimization
by Flor Y. Rentería-Baltiérrez, Jesús G. Puente-Córdova, Juan M. Hernández-Ramos, Arlethe Y. Aguilar-Villarreal and Nasser Mohamed-Noriega
Polymers 2025, 17(12), 1650; https://doi.org/10.3390/polym17121650 - 13 Jun 2025
Viewed by 683
Abstract
This study addresses the challenge of optimizing the viscoelastic performance of acrylonitrile butadiene styrene (ABS) parts manufactured by fused deposition modeling (FDM), where printing parameters strongly influence mechanical properties. The objective was to systematically evaluate the effects of four key factors—infill pattern, build [...] Read more.
This study addresses the challenge of optimizing the viscoelastic performance of acrylonitrile butadiene styrene (ABS) parts manufactured by fused deposition modeling (FDM), where printing parameters strongly influence mechanical properties. The objective was to systematically evaluate the effects of four key factors—infill pattern, build orientation, layer height, and filament color—on storage modulus, damping factor, and glass transition temperature. A combined experimental design approach was employed: Taguchi’s L9 orthogonal array efficiently screened parameter effects, while response surface methodology (RSM) enabled detailed analysis of interaction effects and multiresponse optimization. Results revealed that build orientation and layer height had the greatest impact, increasing instantaneous stiffness (Eu) by up to 81%, equilibrium modulus (E0) by 128%, and glass transition temperature (Tg) by 1.46%, while decreasing the damping factor (tan δ) by 3.4% between optimized and suboptimal conditions. To complement the statistical optimization, the fractional Zener model (FZM) was applied to characterize the viscoelastic response of two representative samples optimized for either high stiffness or high flexibility. The flexible sample exhibited a higher fractional order (α=0.24), indicating enhanced elastic mobility, while the stiff sample showed a higher activation energy (Ea=0.52 eV), consistent with restricted molecular motion. This integrated approach provides a robust and generalizable framework for improving material performance in polymer additive manufacturing. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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28 pages, 7841 KB  
Article
Investigation of the Effect of Exposure to Liquid Chemicals on the Strength Performance of 3D-Printed Parts from Different Filament Types
by Arslan Kaptan
Polymers 2025, 17(12), 1637; https://doi.org/10.3390/polym17121637 - 12 Jun 2025
Viewed by 1318
Abstract
Additive manufacturing (AM), particularly fused deposition modeling (FDM) 3D printing, has emerged as a versatile and accessible technology for prototyping and functional part production across a wide range of industrial applications. One of the critical performance-limiting factors in AM is the chemical resistance [...] Read more.
Additive manufacturing (AM), particularly fused deposition modeling (FDM) 3D printing, has emerged as a versatile and accessible technology for prototyping and functional part production across a wide range of industrial applications. One of the critical performance-limiting factors in AM is the chemical resistance of thermoplastic materials, which directly influences their structural integrity, durability, and suitability in chemically aggressive environments. This study systematically investigates the chemical resistance of eight different widely utilized FDM filaments—acrylonitrile butadiene styrene (ABS), acrylonitrile styrene acrylate (ASA), polyamide (PA, Nylon), polycarbonate (PC), polyethylene terephthalate glycol (PETG), polylactic acid (PLA), polypropylene (PP), and polyvinyl butyral (PVB)—by examining their tensile strength and impact resistance after immersion in representative chemical agents: distilled water, ethanol (99.5%), isopropyl alcohol (75% and 99%), acetic acid (8%), hydrochloric acid (37%), hydrogen peroxide (30%), and acetone (99.5%). Quantitative mechanical testing was conducted in accordance with ASTM D638 and ASTM D256 standards, and statistical variability was accounted for using triplicate measurements with standard deviation analysis. The results reveal that PP exhibits the highest chemical resilience, retaining over 97% of its mechanical properties even after 7 days of immersion in aggressive solvents like acetone. PETG and ASA also demonstrated quite successful stability (>90% retention) in mildly corrosive environments such as alcohols and weak acids. In contrast, PLA, due to its low crystallinity and polar ester backbone, and PVB, due to its high amorphous content, showed substantial degradation: tensile strength losses exceeding 70% and impact resistance dropping below 20% in acetone. Moderate resistance was observed in ABS and PC, which maintained structural properties in neutral or weakly reactive conditions but suffered mechanical deterioration (>50% loss) in solvent-rich media. A strong correlation (r > 0.95) between tensile and impact strength reduction was found for most materials, indicating that chemical attack affects both static and dynamic mechanical performance uniformly. The findings of this study provide a robust framework for selecting appropriate 3D printing materials in applications exposed to solvents, acids, or oxidizing agents. PP is recommended for harsh chemical environments; PETG and ASA are suitable for moderate exposure scenarios, whereas PLA and PVB should be limited to low-risk, esthetic, or disposable applications. Full article
(This article belongs to the Special Issue Polymer Mechanochemistry: From Fundamentals to Applications)
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