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26 pages, 6611 KiB  
Article
The Geochronology, Geochemical Characteristics, and Tectonic Settings of the Granites, Yexilinhundi, Southern Great Xing’an Range
by Haixin Yue, Henan Yu, Zhenjun Sun, Yanping He, Mengfan Guan, Yingbo Yu and Xi Chen
Minerals 2025, 15(8), 813; https://doi.org/10.3390/min15080813 (registering DOI) - 31 Jul 2025
Viewed by 157
Abstract
The southern Great Xing’an Range is located in the overlap zone of the Paleo-Asian Ocean metallogenic domain and the Circum-Pacific metallogenic domain. It hosts numerous Sn-polymetallic deposits, such as Weilasituo, Bianjiadayuan, Huanggang, and Dajing, and witnessed multiple episodes of magmatism during the Late [...] Read more.
The southern Great Xing’an Range is located in the overlap zone of the Paleo-Asian Ocean metallogenic domain and the Circum-Pacific metallogenic domain. It hosts numerous Sn-polymetallic deposits, such as Weilasituo, Bianjiadayuan, Huanggang, and Dajing, and witnessed multiple episodes of magmatism during the Late Mesozoic. The study area is situated within the Huanggangliang-Ganzhuermiao metallogenic belt in the southern Great Xing’an Range. The region has witnessed extensive magmatism, with Mesozoic magmatic activities being particularly closely linked to regional mineralization. We present petrographic, zircon U-Pb chronological, lithogeochemical, and Lu-Hf isotopic analyses of the Yexilinhundi granites. The results indicate that the granite porphyry and granodiorite were emplaced during the Late Jurassic. Both rocks exhibit high SiO2, K2O + Na2O, differentiation index (DI), and 10,000 Ga/Al ratios, coupled with low MgO contents. They show distinct fractionation between light and heavy rare earth elements (LREEs and HREEs), exhibit Eu anomalies, and have low whole-rock zircon saturation temperatures (Tzr), collectively demonstrating characteristics of highly fractionated I-type granites. The εHf(t) values of the granites range from 0.600 to 9.14, with young two-stage model ages (TDM2 = 616.0~1158 Ma), indicating that the magmatic source originated from partial melting of Mesoproterozoic-Neoproterozoic juvenile crust. This study proposes that the granites formed in a post-collisional/post-orogenic extensional setting associated with the subduction of the Mongol-Okhotsk Ocean, providing a scientific basis for understanding the relationship between the formation of Sn-polymetallic deposits and granitic magmatic evolution in the study area. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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28 pages, 11235 KiB  
Article
Petrogenesis, Tectonic Setting, and Metallogenic Constraints of Tin-Bearing Plutons in the Karamaili Granite Belt of Eastern Junggar, Xinjiang (NW China)
by Shuai Yuan, Qiwei Wang, Bowen Zhang, Xiaoping Gong and Chunmei Su
Minerals 2025, 15(7), 710; https://doi.org/10.3390/min15070710 - 3 Jul 2025
Viewed by 580
Abstract
The Karamaili Granite Belt (KGB) in the southern margin of the Eastern Junggar is the most important tin metallogenic belt in the southwestern Central Asian Orogenic Belt. The plutons in the western part have a close genetic relationship with tin mineralization. The zircon [...] Read more.
The Karamaili Granite Belt (KGB) in the southern margin of the Eastern Junggar is the most important tin metallogenic belt in the southwestern Central Asian Orogenic Belt. The plutons in the western part have a close genetic relationship with tin mineralization. The zircon U-Pb ages of the Kamusite, Laoyaquan, and Beilekuduke plutons are 315.1 ± 3.4 Ma, 313.6 ± 2.9 Ma, and 316.5 ± 4.6 Ma, respectively. The plutons have high silica (SiO2 = 75.53%–77.85%), potassium (K2O = 4.43%–5.42%), and alkalis (K2O + Na2O = 8.17%–8.90%) contents and low ferroan (Fe2O3T = 0.90%–1.48%), calcium, and magnesium contents and are classified as metaluminous–peraluminous, high-potassium, calc-alkaline iron granite. The rocks are enriched in Rb, Th, U, K, Pb, and Sn and strongly depleted in Ba, Sr, P, Eu, and Ti. They have strongly negative Eu anomalies (δEu = 0.01–0.05), 10,000 Ga/Al = 2.87–4.91 (>2.6), showing the geochemical characteristics of A-type granite. The zircon U/Pb ratios indicate that the above granites should be I- or A-type granite, which is generally formed under high-temperature (768–843 °C), low-pressure, and reducing magma conditions. The high Rb/Sr ratio (a mean of 48 > 1.2) and low K/Rb ratio (53.93–169.94) indicate that the tin-bearing plutons have undergone high differentiation. The positive whole-rock εNd(t) values (3.99–5.54) and the relatively young Nd T2DM model ages (616–455 Ma) suggest the magma is derived from partially melted juvenile crust, and the underplating of basic magma containing mantle materials that affected the source area. The results indicate the KGB was formed in the tectonic transition period in the late Carboniferous subduction post-collision environment. Orogenic compression influenced the tin-bearing plutons in the western part of the KGB, forming highly differentiated and reduced I, A-type transition granite. An extensional environment affected the plutons in the eastern sections, creating A-type granite with dark enclaves that suggest magma mixing with little evidence of tin mineralization. Full article
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18 pages, 6412 KiB  
Article
Geochemistry and Zircon U-Pb Chronology of West Kendewula Late Paleozoic A-Type Granites in the East Kunlun Orogenic Belt: Implications for Post-Collision Extension
by Bang-Shi Dong, Wen-Qin Wang, Gen-Hou Wang, Pei-Lie Zhang, Peng-Sheng Li, Zhao-Lei Ding, Ze-Jun He, Pu Zhao, Jing-Qi Zhang and Chao Bo
Appl. Sci. 2025, 15(12), 6661; https://doi.org/10.3390/app15126661 - 13 Jun 2025
Viewed by 495
Abstract
The Late Paleozoic granitoids widely distributed in the central section of the East Kunlun Orogenic Belt (EKOB) are responsible for the constraints on its post-collisional extensional processes. We report the whole-rock geochemical compositions, zircon U-Pb ages, and zircon Hf isotope data of granites [...] Read more.
The Late Paleozoic granitoids widely distributed in the central section of the East Kunlun Orogenic Belt (EKOB) are responsible for the constraints on its post-collisional extensional processes. We report the whole-rock geochemical compositions, zircon U-Pb ages, and zircon Hf isotope data of granites in the western Kendewula area. The granites, dated between 413.7 Ma and 417.7 Ma, indicate emplacement during the Early Devonian period. The granite is characterized by high silicon content (72.45–78.96 wt%), high and alkali content (7.59–9.35 wt%), high 10,000 × Ga/Al values, and low Al2O3 (11.29–13.32 wt%), CaO (0.07–0.31 wt%), and MgO contents (0.16–0.94 wt%). The rocks exhibit enrichment in large-ion lithophile element (LILE) content and high-field-strength element (HFSE) content, in addition to strong losses, showing significant depletion in Ba, Sr, P and Eu. These geochemical characteristics correspond to A2-type granites. The values of Rb/N and Ba/La and the higher zircon saturation temperature (800~900 °C) indicate that the magma source is mainly crustal, with the participation of mantle materials, although limited. In addition, the zircon εHf(t) values (−4.3–3.69) also support this view. In summary, the A2-type granite exposed in the western Kendewula region formed against a post-collisional extensional setting background, suggesting that the Southern Kunlun Terrane (SKT) entered a post-orogenic extensional phase in the evolution stage since the Early Devonian. The upwelling of the asthenospheric mantle of the crust, triggered by crustal detachment and partial melting, likely contributed to the flare-up of A2-type granite during this period. By studying the nature of granite produced during orogeny, the evolution process of the formation of orogenic belts is discussed, and our understanding of orogenic is enhanced. Full article
(This article belongs to the Special Issue Technologies and Methods for Exploitation of Geological Resources)
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40 pages, 10288 KiB  
Review
A Review of ε-Ga2O3 Films: Fabrications and Photoelectric Properties
by Siwei Wang, Jie Jian, Cong Xu, Xiaoheng Dong, Jielong Yang, Maolin Zou, Wangwang Liu, Qinglong Tu, Mengyao Li, Cheng Cao and Xiangli Liu
Materials 2025, 18(11), 2630; https://doi.org/10.3390/ma18112630 - 4 Jun 2025
Viewed by 883
Abstract
Gallium oxide (Ga2O3), as an ultra-wide bandgap semiconducting material, has attracted extensive research interest in recent years. Owing to its outstanding electrical and optical properties, as well as its high reliability, Ga2O3 shows great potential in [...] Read more.
Gallium oxide (Ga2O3), as an ultra-wide bandgap semiconducting material, has attracted extensive research interest in recent years. Owing to its outstanding electrical and optical properties, as well as its high reliability, Ga2O3 shows great potential in power electronics, optoelectronics, memory devices, and so on. Among all the different polymorphs, ε-Ga2O3 is the second most thermally stable phase. It has a hexagonal crystal structure, which contributes to its isotropic physical properties and its suitable growth on low-cost commercial substrates, such as Al2O3, Si (111). However, there are far fewer research works on ε-Ga2O3 in comparison with the most thermally stable β phase. Aiming to provide a comprehensive view on the current works of ε-Ga2O3 and support future research, this review conducts detailed summarizations for the fabrication processes of ε-Ga2O3 thin films and the photoelectrical properties of ε-Ga2O3-based photodetectors. The effects of different deposition parameters on film phases and qualities are discussed. The forming mechanisms of ε phase prepared by chemical vapor depositions (CVDs) and physical vapor depositions (PVDs) are analyzed, respectively. Conclusions are made concerning the relationships between film microstructures and properties. In addition, strategies for further improving ε-Ga2O3 film performance are briefly summarized. Full article
(This article belongs to the Special Issue The Microstructures and Advanced Functional Properties of Thin Films)
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17 pages, 7715 KiB  
Article
Petrogenesis and Tectonic Implications of the Early–Middle Ordovician Granodiorites in the Yaogou Area of the North Qilian Orogenic Belt
by Dechao Li, Yang Yang, Yao Xiao, Pengde Liu, Xijun Liu, Gang Chen, Xiao Liu, Rongguo Hu, Hao Tian and Yande Liu
Minerals 2025, 15(6), 551; https://doi.org/10.3390/min15060551 - 22 May 2025
Viewed by 398
Abstract
A diverse range of granitoids in the North Qilian Orogenic Belt (NQOB) offers valuable insights into the region’s tectonomagmatic evolution. In this study, we undertook a geochronological, mineralogical, geochemical, and zircon Hf isotopic analysis of granodiorites from the Yaogou area of the NQOB. [...] Read more.
A diverse range of granitoids in the North Qilian Orogenic Belt (NQOB) offers valuable insights into the region’s tectonomagmatic evolution. In this study, we undertook a geochronological, mineralogical, geochemical, and zircon Hf isotopic analysis of granodiorites from the Yaogou area of the NQOB. Zircon U-Pb dating reveals that the Yaogou granodiorites formed during the Early–Middle Ordovician (473–460 Ma). The Yaogou granodiorites have high SiO2 (63.3–71.1 wt.%), high Al2O3 (13.9–15.8 wt.%) contents, and low Zr (96–244 ppm), Nb (2.9–18 ppm), as well as low Ga/Al ratios (10,000 × Ga/Al ratios of 1.7–2.9) and FeOT/MgO ratios (1.9–3.2), and are characterized by elevated concentrations of light rare earth elements and large-ion lithophile elements such as Rb, Th, and U, coupled with significant depletion in heavy rare earth elements and high-field-strength elements including Nb, Ta, and Ti. Additionally, the presence of negative europium anomalies further reflects geochemical signatures typical of I-type granitic rocks. The zircon grains from these rocks display negative εHf(t) values (−14.6 to −10.7), with two-stage Hf model ages (TDM2) from 2129 to 1907 Ma. These characteristics suggest that the magmatic source of the Yaogou granodiorites likely originated from the partial melting of Paleoproterozoic basement-derived crustal materials within a tectonic environment associated with subduction in the North Qilian Ocean. Integrating regional geological data, we suggest that during the Early Paleozoic, the North Qilian Oceanic slab underwent double subduction: initially southward, followed by a northward shift. Due to the deep northward subduction of the Qaidam continental crust and oceanic crust along the southern margin of the Qilian Orogenic Belt, the southward subduction of the North Qilian ocean was obstructed, triggering a reversal in subduction polarity. This reversal likely decelerated the southward subduction and initiated northward subduction, ultimately leading to the formation of the Yaogou granodiorites. These findings enhance our understanding of the complex tectonic processes that shaped the North Qilian Orogenic Belt during the Early Paleozoic, emphasizing the role of subduction dynamics and continental interactions in the region’s geological evolution. Full article
(This article belongs to the Special Issue Geochronology and Geochemistry of Alkaline Rocks)
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30 pages, 16603 KiB  
Article
Petrogenesis and U–Pb Dating of Variscan S-Type Granites from the Junqueira Batholith (Central Iberian Zone)
by Luís Portela, Maria Rosário Azevedo, Beatriz Valle Aguado, Maria Mafalda Costa and Jorge Medina
Minerals 2025, 15(5), 481; https://doi.org/10.3390/min15050481 - 4 May 2025
Viewed by 620
Abstract
The Junqueira massif is a syn- to late-kinematic Variscan batholith intruded into Ediacaran-Cambrian metasedimentary rocks of the Douro-Beiras Supergroup (DBSG) in the Central Iberian Zone. The batholith occupies the axial zone of the Porto-Viseu antiform, a large NW-SE trending megascopic domal structure formed [...] Read more.
The Junqueira massif is a syn- to late-kinematic Variscan batholith intruded into Ediacaran-Cambrian metasedimentary rocks of the Douro-Beiras Supergroup (DBSG) in the Central Iberian Zone. The batholith occupies the axial zone of the Porto-Viseu antiform, a large NW-SE trending megascopic domal structure formed during the last Variscan ductile deformation event. Field and petrographic evidence reveals that the Junqueira batholith comprises several units of leucocratic granites distinguished by variations in grain size and relative proportions of the main rock-forming minerals. This work provides new petrographical, geochemical, Sr–Nd isotope data and ID-TIMS U–Pb ages for the Junqueira batholith. U–Pb dating of zircon and monazite by ID-TIMS gives a crystallization age of ca. 312–309 Ma for this batholith. Combined geochemical and Sr–Nd isotopic data for the different granite units (ASI > 1.1; high SiO2 and K2O contents, low CaO, MgO, Ba, Sr, moderately fractionated REE patterns, Eu negative anomalies, 87Sr/86Sri > 0.713, εNd310 = −3.5 to −5.9; TDM = 1.1–1.4 Ga) support a provenance by fluid-absent melting processes of exclusively supracrustal sources (mainly metapelites), similar to the adjoining country rocks of the Beiras Group of the DBSG. Full article
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28 pages, 9029 KiB  
Article
Petrogenesis, Geochemistry, and Geological Significance of the Kongco Granitic Porphyry Dykes in the Northern Part of the Central Lhasa Microblock, Tibet
by Anping Xiang, Hong Liu, Wenxin Fan, Qing Zhou, Hong Wang and Kaizhi Li
Minerals 2025, 15(3), 283; https://doi.org/10.3390/min15030283 - 11 Mar 2025
Viewed by 780
Abstract
The Kongco area of Nima in the northern part of the Lhasa terrane has a suite of alkaline granitic porphyry dykes associated with Early Cretaceous granites and accompanied by Cu/Mo mineralization. LA-ICP-MS 206Pb/238U zircon geochronology performed on the dykes produced [...] Read more.
The Kongco area of Nima in the northern part of the Lhasa terrane has a suite of alkaline granitic porphyry dykes associated with Early Cretaceous granites and accompanied by Cu/Mo mineralization. LA-ICP-MS 206Pb/238U zircon geochronology performed on the dykes produced an age of 104.15 ± 0.94 Ma (MSWD = 0.98), indicating the Early Cretaceous emplacement of the dykes. The dykes exhibit high silica (SiO2 = 76.22~77.90 wt.%), high potassium (K2O = 4.97~6.21 wt.%), high alkalinity (K2O + Na2O = 8.07~8.98 wt.%), low calcium (CaO = 0.24~0.83 wt.%), low magnesium (MgO = 0.06~0.20 wt.%), and moderate aluminum content (Al2O3 = 11.93~12.45 wt.%). The Rieterman index (σ) ranges from 1.93 to 2.34. A/NK (molar ratio Al2O3/(Na2O + K2O)) and A/CNK (molar ratio Al2O3/(CaO + Na2O + K2O)) values of the dykes range from 1.06 to 1.18 and 0.98 to 1.09, respectively. The dykes are relatively enriched in Rb, Th, U, K, Ta, Ce, Nd, Zr, Hf, Sm, Y, Yb, and Lu, and they show a noticeable relative depletion in Ba, Nb, Sr, P, Eu, and Ti, as well as an average differentiation index (DI) of 96.42. The dykes also exhibit high FeOT/MgO ratios (3.60~10.41), Ga/Al ratios (2.22 × 10−4~3.01 × 10−4), Y/Nb ratios (1.75~2.40), and Rb/Nb ratios (8.36~20.76). Additionally, they have high whole-rock Zr saturation temperatures (884~914 °C), a pronounced Eu negative anomaly (δEu = 0.04~0.23), and a rightward-sloping “V-shaped” rare earth element pattern. These characteristics suggest that the granitic porphyry dykes can be classified as A2-type granites formed in a post-collisional tectonic environment and that they are weakly peraluminous, high-potassium, and Calc-alkaline basaltic rocks. Positive εHf(t) values = 0.43~3.63 and a relatively young Hf crustal model age (TDM2 = 826~1005 Ma, 87Sr/86Sr ratios = 0.7043~0.7064, and εNd(t) = −8.60~−2.95 all indicate lower crust and mantle mixing. The lower crust and mantle mixing model is also supported by (206Pb/204Pb)t = 18.627~18.788, (207Pb/204Pb)t = 15.707~15.719, (208Pb/204Pb)t = 39.038~39.110). Together, the Hf, Sr and Pb isotopic ratios indicate that the Kongco granitic porphyry dykes where derived from juvenile crust formed by the addition of mantle material to the lower crust. From this, we infer that the Kongco granitic porphyry dykes are related to a partial melting of the lower crust induced by subduction slab break-off and asthenospheric upwelling during the collision between the Qiangtang and Lhasa terranes and that they experienced significant fractional crystallization dominated by potassium feldspar and amphibole. These dykes are also accompanied by significant copper mineralization (five samples, copper content 0.2%), suggesting a close relationship between the magmatism associated with these dykes and regional metallogenesis, indicating a high potential for mineral exploration. Full article
(This article belongs to the Special Issue Using Mineral Chemistry to Characterize Ore-Forming Processes)
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24 pages, 3160 KiB  
Article
Inherited Dyslipidemic Splenomegaly: A Genetic Macrophage Storage Disorder Caused by Disruptive Apolipoprotein E (APOE) Variants
by Elise A. Ferreira, Machteld M. Oud, Saskia N. van der Crabben, Miranda Versloot, Susan M. I. Goorden, Clara D. M. van Karnebeek, Jeffrey Kroon and Mirjam Langeveld
Genes 2025, 16(3), 289; https://doi.org/10.3390/genes16030289 - 27 Feb 2025
Viewed by 1102
Abstract
Background: Persistent splenomegaly, often an incidental finding, can originate from a number of inherited metabolic disorders (IMDs). Variants of APOE are primarily known as risk factors in terms of cardiovascular disease; however, severe dysfunction of APOE can result in a disease phenotype with [...] Read more.
Background: Persistent splenomegaly, often an incidental finding, can originate from a number of inherited metabolic disorders (IMDs). Variants of APOE are primarily known as risk factors in terms of cardiovascular disease; however, severe dysfunction of APOE can result in a disease phenotype with considerable overlap with lysosomal storage disorders (LSDs), including splenomegaly and gross elevation of N-palmitoyl-O-phosphocholine-serine (PPCS). Methods: A case study (deep phenotyping, genetic and FACS analysis) and literature study was conducted. Results: The index patient, with a family history of early-onset cardiovascular disease, presented with splenic infarctions in a grossly enlarged spleen. The identified genetic cause was homozygosity for two APOE variants (c.604C>T, p.(Arg202Cys) and c.512G>A, p.(Gly171Asp); ε1/ε1), resulting in a macrophage storage phenotype resembling an LSD that was also present in the brother of the index patient. A FACS analysis of the circulating monocytes showed increased lipid content and the expression of activation markers (CD11b, CCR2, CD36). This activated state enhances lipoprotein intake, which eventually converts these monocytes/macrophages into foam cells, accumulating in tissues (e.g., spleen and vascular wall). A literature search identified seven individuals with splenomegaly caused by APOE variants (deletion of leucine at position 167). The combined data from all patients identified male gender, splenectomy and obesity as potential modifiers determining the severity of the phenotype (i.e., degree of triglyceride increase in plasma and/or spleen size). Symptoms are (partially) reversible by lipid-lowering medication and energy restricted diets and splenectomy is contra-indicated. Conclusions: Inherited dyslipidemic splenomegaly caused by disruptive APOE variants should be included in the differential diagnoses of unexplained splenomegaly with abnormal lipid profiles. A plasma lipid profile consistent with dysbetalipoproteinemia is a diagnostic biomarker for this IMD. Full article
(This article belongs to the Collection Genetics and Genomics of Rare Disorders)
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24 pages, 6320 KiB  
Article
Industrial Investigations of S355 Steel-Grade Homogenization in a 100-Tonne Ladle Furnace
by Dariusz Jochymczyk, Marek Warzecha and Artur Hutny
Materials 2025, 18(1), 180; https://doi.org/10.3390/ma18010180 - 3 Jan 2025
Viewed by 833
Abstract
The paper presents the results of industrial research and numerical simulations of the chemical homogenization of liquid steel. The research object was a ladle furnace with a working capacity of the ladle of 100 t at the steel plant of Huta Częstochowa, currently [...] Read more.
The paper presents the results of industrial research and numerical simulations of the chemical homogenization of liquid steel. The research object was a ladle furnace with a working capacity of the ladle of 100 t at the steel plant of Huta Częstochowa, currently Liberty Częstochowa Sp. z o.o. Industrial research was carried out under standard production conditions of the steelworks. The research included automatic steel sampling, measurement of the bath temperature, controlled measurement of argon flow at a given intensity, and the determination of the concentration of elements in steel samples using a spectrometric analyser. The element introduced in the form of a ferroalloy (FeMn and FeSiMn) played the role of a marker in the study of changes in the chemical composition during the process of dissolution and mixing of the alloying additive. Monitoring changes in the chemical composition of steel after the introduction of the marker was carried out by taking metal samples. The initial and boundary parameters of the modelled processes necessary to perform numerical simulations were determined successively through industrial measurements or determined on the basis of empirical relationships. A two-equation k-ε turbulence model was used to assess the flow inside the tested ladle furnace, and a discrete phase model was used to model gas bubbles. The mixing characteristics of the steel bath after introducing the alloying additive to it were determined. The comparison of the results of numerical simulations with experimental data was based on the analysis of the chemical homogenization process. Full article
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24 pages, 6880 KiB  
Article
Petrogenesis of Granitoids from the Waxing Mo Polymetallic Deposit, NE China: Implications for Magma Fertility and Mineralization
by Yang Liu, De-You Sun, Yang Gao, Hong-Chao Wang, Yu-Xin Ma, Jun Xu and Xin-Tong Liu
Minerals 2024, 14(11), 1104; https://doi.org/10.3390/min14111104 - 29 Oct 2024
Viewed by 887
Abstract
The Waxing Mo polymetallic deposit is located in the central part of the Lesser Xing’an–Zhangguangcai Range (LXZR), NE China. The Mo (Cu) mineralization in the deposit is dominantly hosted by quartz veinlets and stockworks and is closely related to silicification and potassic alteration, [...] Read more.
The Waxing Mo polymetallic deposit is located in the central part of the Lesser Xing’an–Zhangguangcai Range (LXZR), NE China. The Mo (Cu) mineralization in the deposit is dominantly hosted by quartz veinlets and stockworks and is closely related to silicification and potassic alteration, while the W mineralization is most closely related to greisenization. Zircon samples from granodiorite, biotite monzogranite, granodiorite porphyry, and syenogranite in the Waxing deposit yielded U-Pb ages of 172.3 Ma, 172.8 Ma, 173.0 Ma, and 171.4 Ma, respectively. Six molybdenite samples from porphyry Mo ores yielded a Re-Os isochron age of 172.0 ± 1.1 Ma. The granitoids in the ore district are relatively high in total alkali (Na2O + K2O), are metaluminous to weakly peraluminous, and are classified as I-type granitoids. The zircon samples from all granitoids showed a relatively consistent Hf isotopic composition, as shown by positive εHf(t) values (3.1–8.3) and young TDM2 ages (0.69–1.25 Ga). These results, combined with the whole-rock geochemistry, suggest that the magma source of these rocks most likely derived from partial melting of a juvenile middle-lower continental crust, with a minor contribution from the mantle. These granitoids have compositional characteristics of adakites such as relatively high Sr contents (e.g., >400 ppm) and Sr/Y ratios (e.g., >33), as well as weak Eu anomalies (e.g., Eu/Eu* = 0.8–1.1), indicating extensive fractionation crystallization of a hydrous magma. The apatite geochemistry indicates that the ore-related magma in Waxing is F-rich and has a relatively low content of sulfur. The zircon geochemistry reveals that the granodiorite, biotite monzogranite, and granodiorite porphyry have relatively high oxygen fugacity (i.e., ΔFMQ = +1.1~1.3), whereas the fO2 values of the granite porphyry and syenogranite are relatively low (i.e., ΔFMQ = +0.1~0.5). The whole-rock and mineral geochemistry suggest that the Mo mineralization in Waxing is probably genetically related to granitoids (i.e., granodiorite, biotite monzogranite, and granodiorite porphyry), with higher oxygen fugacity and a high water content, whereas the magmatic S concentration is not the key factor controlling the mineralization. A comparison of the geochemical compositions of ore-forming and barren stocks for porphyry Mo deposits in the LXZR showed that geochemical ratios, including Eu/Eu* (>0.8), 10,000*(Eu/Eu*)/Y (>600), Sr/Y (>33), and V/Sc (>8), could be effective indicators in discriminating fertile granitoids for porphyry Mo deposits from barren ones in the region. Full article
(This article belongs to the Special Issue Recent Developments in Rare Metal Mineral Deposits)
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21 pages, 13736 KiB  
Article
Gold Mineralization at the Syenite-Hosted Anwangshan Gold Deposit, Western Qinling Orogen, Central China
by Wenyuan Chen, Zhibo Yan, Jin Yuan, Yuanyuan Zhao, Xinyu Xu, Liqiang Sun, Xinbiao Lü and Jian Ma
Minerals 2024, 14(10), 1057; https://doi.org/10.3390/min14101057 - 21 Oct 2024
Viewed by 1580
Abstract
The Anwangshan gold deposit is located in the northwestern part of the Fengtai Basin, Western Qinling Orogen (WQO). The gold ore is hosted within quartz syenite and its contact zone. The U–Pb weighted mean age of the quartz syenite is 231 ± 1.8 [...] Read more.
The Anwangshan gold deposit is located in the northwestern part of the Fengtai Basin, Western Qinling Orogen (WQO). The gold ore is hosted within quartz syenite and its contact zone. The U–Pb weighted mean age of the quartz syenite is 231 ± 1.8 Ma. It is characterized by high potassium (K2O = 10.13%, K2O/Na2O > 1) and high magnesium (Mg# = 55.31 to 72.78) content, enriched in large ion lithophile elements (Th, U, and Ba) and light rare earth elements (LREE), with a typical “TNT” (Ti, Nb, and Ta) deficiency. The geochemical features and Hf isotope compositions (εHf(t) = −6.68 to +2.25) suggest that the quartz syenite would form from partial melting of an enriched lithospheric mantle under an extensional setting. Three generations of gold mineralization have been identified, including the quartz–sericite–pyrite (Py1) stage I, the quartz–pyrite (Py2)–polymetallic sulfide–early calcite stage II, and the epidote–late calcite stage III. In situ sulfur isotope analysis of pyrite shows that Py1 (δ34S = −1.1 to +3.8‰) possesses mantle sulfur characteristics. However, Py2 has totally different δ34S (+5.1 to +6.7‰), which lies between the typical orogenic gold deposits in the WQO (δ34S = +8 to +12‰) and mantle sulfur. This suggests a mixed source of metamorphosed sediments and magmatic sulfur during stage II gold mineralization. The fluid inclusions in auriferous quartz have three different types, including the liquid-rich phase type, pure (gas or liquid)-phase type, and daughter-minerals-bearing phase type. Multiple-stage fluid inclusions indicate that the ore fluids are medium-temperature (concentrated at 220 to 270 °C), medium-salinity (7.85 to 13.80% NaCleq) CO2–H2O–NaCl systems. The salinity is quite different from typical orogenic gold deposits in WQO and worldwide, and this is more likely to be a mixture of magmatic and metamorphic fluids as well. In summary, the quartz syenite should have not only a spatio-temporal but also a genetical relationship with the Anwangshan gold deposit. It could provide most of the gold and ore fluids at the first stage, with metamorphic fluids and/or gold joining in during the later stages. Full article
(This article belongs to the Special Issue The Formation and Evolution of Gold Deposits in China)
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19 pages, 5698 KiB  
Article
Mesoproterozoic (ca. 1.3 Ga) A-Type Granites on the Northern Margin of the North China Craton: Response to Break-Up of the Columbia Supercontinent
by Bo Liu, Shengkai Jin, Guanghao Tian, Liyang Li, Yueqiang Qin, Zhiyuan Xie, Ming Ma and Jiale Yin
Minerals 2024, 14(6), 622; https://doi.org/10.3390/min14060622 - 18 Jun 2024
Viewed by 1658
Abstract
Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this [...] Read more.
Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this period. This study investigated porphyritic granites from the Huade–Kangbao area on the northern margin of the NCC. Zircon dating indicates the porphyritic granites were intruded during the Mesoproterozoic between 1285.4 ± 2.6 and 1278.6 ± 6.1 Ma. The granites have high silica contents (SiO2 = 63.10–73.73 wt.%), exhibit alkali enrichment (total alkalis = 7.71–8.79 wt.%), are peraluminous, and can be classified as weakly peraluminous A2-type granites. The granites have negative Eu anomalies (δEu = 0.14–0.44), enrichments in large-ion lithophile elements (LILEs; e.g., K, Rb, Th, and U), and depletions in high-field-strength elements (HFSEs; e.g., Nb, Ta, and Ti). εHf(t) values range from –6.43 to +2.41, with tDM2 ages of 1905–2462 Ma, suggesting the magmas were derived by partial melting of ancient crustal material. The geochronological and geochemical data, and regional geological features, indicate the Mesoproterozoic porphyritic granites from the northern margin of the NCC formed in an intraplate tectonic setting during continental extension and rifting, which represents the response of the NCC to the break-up of the Columbia supercontinent. Full article
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20 pages, 5892 KiB  
Article
Geochemistry and Geochronology of the Huangcha Pluton and Tectonic Significance
by Shuping Cao, Lun Li, Chonghui Yang and Yongqiang Yang
Minerals 2024, 14(5), 520; https://doi.org/10.3390/min14050520 - 17 May 2024
Viewed by 1229
Abstract
The Zanhuang Complex is situated on the eastern margin of the Trans-North China Orogen, with the Huangcha Pluton being a constituent of this complex. To ascertain the nature of the approximately 2.5-billion-year-old Huangcha Pluton, crucial evidence for understanding its extensional setting was sought [...] Read more.
The Zanhuang Complex is situated on the eastern margin of the Trans-North China Orogen, with the Huangcha Pluton being a constituent of this complex. To ascertain the nature of the approximately 2.5-billion-year-old Huangcha Pluton, crucial evidence for understanding its extensional setting was sought through petrogenesis and dating investigations. LA-ICP-MS dating of zircon from the granite yielded an age of (2488 ± 6) Ma. Primarily composed of porphyritic monzonite with sporadic melanocratic enclaves, the Pluton’s phenocrysts are predominantly feldspar with minor quartz. The granite exhibits high SiO2 content (72.64%–74.16%) and alkali levels, with Na2O + K2O ranging from 7.59% to 9.07%, classifying it as a shoshonitic series with a slightly peraluminous feature. Enrichment in large-ion lithophile (LIL) elements (Rb, Th, and U) and depletion in Sr, V, Cr, Co, and Ni were observed, with high Rb/Sr and Ga/Al ratios ranging from 0.73 to 2.72 and 2.75 × 10−4 to 3.11 × 10−4, respectively. The rock exhibits high εNd(t) values, ranging from −0.06 to 0.88, with TDM2 ages falling between 2.79 and 2.87 billion years. Zircon grains display 176Hf/177Hf ratios ranging from 0.281266 to 0.281412 and εHf(t) values spanning from 0.96 to 6.18, calculated using the 207Pb/206Pb age. It is suggested that the Huangcha Pluton represents A-type granite formed via anatexis of the Neoarchean TTG in an extensional setting following orogenic processes. The formation of the Huangcha Pluton further corroborates the stabilization of the North China Craton towards the end of the Neoarchean. This finding supports the hypothesis that the North China Craton may belong to the Rae-family cratons, sharing similar magmatic and tectono-metamorphic records around ~2.5 billion years ago. Full article
(This article belongs to the Special Issue Geochemistry and Geochronology of High-Grade Metamorphic Rocks)
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15 pages, 6032 KiB  
Article
Numerical Investigation of a Two-Phase Ejector Operation Taking into Account Steam Condensation with the Presence of CO2
by Tomasz Kuś and Paweł Madejski
Energies 2024, 17(9), 2236; https://doi.org/10.3390/en17092236 - 6 May 2024
Cited by 3 | Viewed by 1616
Abstract
The application of a two-phase ejector allows for the mixing of liquid and gas and provides effective heat transfer between phases. The aim of the study is a numerical investigation of the performance of a water-driven, condensing two-phase ejector. The research was performed [...] Read more.
The application of a two-phase ejector allows for the mixing of liquid and gas and provides effective heat transfer between phases. The aim of the study is a numerical investigation of the performance of a water-driven, condensing two-phase ejector. The research was performed using CFD methods, which can provide an opportunity to analyze this complex phenomenon in 2D or 3D. The 2D axisymmetric model was developed using CFD software Siemens StarCCM+ 2022.1.1. The Reynolds-Averaged Navier–Stokes (RANS) approach with the Realisable k-ε turbulence model was applied. The multiphase flow was calculated using the mixture model. The boiling/condensation model, where the condensation rate is limited by thermal diffusion, was applied to take into account direct contact condensation. Based on the mass balance calculations and developed pressure and steam volume fraction distributions, the ejector performance was analyzed for various boundary conditions. The influence of the suction pressure (range between 0.812 and 0.90) and the steam mass flow rate (range between 10 g/s and 25 g/s) is presented to investigate the steam condensation phenomenon inside the ejector condenser. The provided mixture of inert gas (CO2) with steam (H2O) in the ejector condenser was investigated also. The weakening of the steam condensation process by adding CO2 gas was observed, but it is still possible to achieve effective condensation despite the presence of inert gas. Full article
(This article belongs to the Special Issue Advances in Numerical Modeling of Multiphase Flow and Heat Transfer)
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20 pages, 9159 KiB  
Article
Petrogenesis of the Newly Discovered Neoproterozoic Adakitic Rock in Bure Area, Western Ethiopia Shield: Implication for the Pan-African Tectonic Evolution
by Junsheng Jiang, Wenshuai Xiang, Peng Hu, Yulin Li, Fafu Wu, Guoping Zeng, Xinran Guo, Zicheng Zhang and Yang Bai
Minerals 2024, 14(4), 408; https://doi.org/10.3390/min14040408 - 16 Apr 2024
Cited by 1 | Viewed by 1538
Abstract
The Neoproterozoic Bure adakitic rock in the western Ethiopia shield is a newly discovered magmatic rock type. However, the physicochemical conditions during its formation, and its source characteristics are still not clear, restricting a full understanding of its petrogenesis and geodynamic evolution. In [...] Read more.
The Neoproterozoic Bure adakitic rock in the western Ethiopia shield is a newly discovered magmatic rock type. However, the physicochemical conditions during its formation, and its source characteristics are still not clear, restricting a full understanding of its petrogenesis and geodynamic evolution. In this study, in order to shed light on the physicochemical conditions during rock formation and provide further constraints on the petrogenesis of the Bure adakitic rock, we conduct electron microprobe analysis on K-feldspar, plagioclase, and biotite. Additionally, we investigate the trace elements and Hf isotopes of zircon, and the Sr-Nd isotopes of the whole rock. The results show that the K-feldspar is orthoclase (Or = 89.08~96.37), the plagioclase is oligoclase (Ab = 74.63~85.99), and the biotite is magnesio-biotite. Based on the biotite analysis results, we calculate that the pressure during rock formation was 1.75~2.81 kbar (average value of 2.09 kbar), representing a depth of approximately 6.39~10.2 km (average value of 7.60 km). The zircon thermometer yields a crystallization temperature of 659~814 °C. Most of the (Ce/Ce*)D values in the zircons plotted above the Ni-NiO oxygen buffer pair, and the calculated magmatic oxygen fugacity (logfO2) values vary from −18.5 to −4.9, revealing a relatively high magma oxygen fugacity. The uniform contents of FeO, MgO, and K2O in the biotite suggest a crustal magma source for the Bure adakitic rock. The relatively low (87Sr/86Sr)i values of 0.70088 to 0.70275, positive εNd(t) values of 3.26 to 7.28, together with the positive εHf(t) values of 7.64~12.99, suggest that the magma was sourced from a Neoproterozoic juvenile crust, with no discernable involvement of a pre-Neoproterozoic continental crust, which is coeval with early magmatic stages in the Arabian Nubian Shield elsewhere. Additionally, the mean Nd model ages demonstrate an increasing trend from the northern parts (Egypt, Sudan, Afif terrane of Arabia, and Eritrea and northern Ethiopia; 0.87 Ga) to the central parts (Western Ethiopia shield; 1.03 Ga) and southern parts (Southern Ethiopia Shield, 1.13 Ga; Kenya, 1.2 Ga) of the East African Orogen, which indicate an increasing contribution of pre-Pan-African crust towards the southern part of the East African Orogen. Based on the negative correlation between MgO and Al2O3 in the biotite, together with the Lu/Hf-Y and Yb-Y results of the zircon, we infer that the Bure adakitic rock was formed in an arc–arc collision orogenic environment. Combining this inference with the whole rock geochemistry and U-Pb age of the Bure adakitic rock, we further propose that the rock is the product of thickened juvenile crust melting triggered by the Neoproterozoic Pan-African Orogeny. Full article
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