Search Results (108)

This paper aims to analyse the microstructure and properties of the titanium- and boron-alloyed high-carbon medium-manganese 140Mn6Cr3TiB steel deposit before and after high-frequency mechanical impact (HFMI) treatment. XRD, SED, and EDS analyses were applied to evaluate the microstructural peculiarities of the studied deposit. Nanoindentation and scratch/sliding tests respectively revealed distinct correlations between the phase composition and the deformation/wear behaviour. HFMI results in the formation of the strain-induced ε- and α’-martensites (~66% and 3–6%, respectively), a significant grains/crystallites refinement (down to 31–54 nm), and dislocation density, which support essential hardening (by ~50%). The HFMI regime (load = 100 N, amplitude = 10 µm, and time = 60 s) was found to be the best, which led to the enhanced wear resistance (decreased wear volume) by ~4 times. The heterogeneous nature of the steel deposit creates a “shield-and-buffer” effect, where the hard eutectic framework resists penetration and tough matrix prevents brittle failure, maintaining a high tolerance to abrasion damage. The HFMI-hardening changed the wear mechanism from the ‘wedge/pile-up’ formation to ploughing. Thus, the HFMI shows a good efficiency in finishing the protective medium-manganese steel deposits of enhanced wear resistance to prolong the operation life of responsible parts. Full article

Wall thickness affects local heat accumulation during laser powder bed fusion (LPBF), but its role in governing the as-built martensitic morphology and tensile response of near-α TA15 alloy remains unclear. In this study, TA15 walls with thicknesses from 0.5 mm to 30 mm were fabricated under identical LPBF parameters. Optical microscopy, scanning electron microscopy, electron backscatter diffraction, tensile testing, fractography, and finite-element thermal simulation were used to correlate wall-thickness-dependent cyclic reheating with α′ lath evolution and mechanical behavior. Increasing wall thickness promoted α′ lath coarsening and the formation of colony-like lath structures with enlarged similarly oriented regions. The average α′ lath width increased from approximately 0.28 μm in the 0.5-T specimen to 1.55 μm in the 30-T specimen. The yield strength reached a maximum of 972.3 ± 5.29 MPa in the 1-T specimen, whereas elongation increased from 9.5 ± 0.6% to 17.8 ± 1.7% with increasing wall thickness. These results indicate a strong correlation between wall-thickness-dependent cyclic reheating, α′/α lath coarsening, lath-network evolution, and tensile-property variation in LPBF-fabricated TA15 alloy. Full article

A three-factor, four-level orthogonal design was employed to optimize the overall forming quality of powder bed fusion with a laser beam (PBF-LB)-fabricated TC4 alloy containing 0.3 wt.% YH₂. Sixteen process-parameter combinations were established, and two specimens were fabricated for each combination. Laser power, scanning speed, and hatch spacing were selected as the investigated variables. Relative density, surface roughness, and Vickers hardness were evaluated using the entropy weight method combined with the weighted-sum method. On this basis, the microstructure of the specimens produced under the optimal process parameters was systematically characterized. The results showed that the influence of the investigated factors on overall forming quality followed the order: hatch spacing > laser power > scanning speed. The optimal process parameters were a laser power of 200 W, a scanning speed of 1100 mm/s, and a hatch spacing of 0.10 mm, under which the specimens exhibited superior overall forming quality. The addition of 0.3 wt.% YH₂ did not significantly alter the dominant phase constitution of the alloy, but promoted α′ martensite refinement and weakened the texture through the in situ formation of Y₂O₃ nano-oxide particles. Full article

The present study investigates the effect of low-temperature ion plasma nitriding on the phase composition, microstructure, tribological behavior, and corrosion resistance of 30Cr13 martensitic stainless steel. Plasma nitriding was carried out at temperatures of 400, 450, and 480 °C in a dissociated ammonia atmosphere using a pulsed DC glow discharge. The phase composition and structural evolution of the surface layer were analyzed by X-ray diffraction, while the morphology and thickness of the modified zone were examined using scanning electron microscopy. The tribological properties were evaluated under dry sliding conditions using a ball-on-disk configuration, and corrosion resistance was assessed by potentiodynamic polarization in a 3.5 wt.% NaCl solution. It was established that low-temperature ion plasma nitriding leads to the formation of nitrogen supersaturated martensite (α′N) and the nitride phase ε-(Fe_2–3)N, with their relative fraction governed by the treatment temperature. An increase in the nitriding temperature resulted in a rise in the surface’s microhardness up to 1100–1150 HV and a change in the thickness of the modified layer, reflecting nitrogen redistribution between the solid solution and nitride constituents. The predominance of the α′N phase at 400–450 °C ensured the most stable tribological behavior and reduced corrosion rate, whereas an increased fraction of ε-(Fe_2–3)N at 480 °C led to a higher microhardness and a greater abrasive wear component while maintaining satisfactory corrosion resistance. The obtained results confirm the decisive role of phase composition in the nitrided layer in determining the tribological and corrosion performance of 30Cr13 steel, and may be used for optimizing the surface hardening parameters of components operating under combined friction and corrosive environments. Full article

In this study, hardfacing and a flux-cored/self-shielded powder wire of the FCAW-S-90G13N4 type was employed to produce and investigate the deposits of high-manganese steel. The effects of high-frequency mechanical impact (HFMI) treatment on the microstructure, hardening, and scratch resistance of the deposits were studied to evaluate and predict the impact wear resistance of the hardfacing deposits under controlled impact load conditions. As observed by XRD, SEM, and nanoindentation, the microstructure of deposited metal comprised a soft austenite matrix, dispersed hard carbides, and an ε phase (~26 vol.%). The wear resistance is thus not controlled by carbides alone but arises from the synergistic action of a hard carbide network within a ductile matrix. HFMI resulted in twinning, an increase in dislocation density, a grown volume fraction of ε (>60%) and α′-martensite. The interaction between twins, martensites, and dislocations provides a double/triple increase in microhardness (from HV_0.2 = 2.78 GPa to HV_0.2 = 6–7.69 GPa). After HFMI, scratch tests showed lower restored depths of scratch tracks and a 36–68% deceleration in the wear rate regarding those of the initial deposit. The underlying wear mechanisms were assessed accounting for the SEM observations of the scratch track morphologies and a ‘counterbody penetration vs. shear stresses ratio’ map. The initial plastic deformation-related mechanism (wedge/pile-up formation) changed by HFMI to ploughing. The obtained results allow one to evaluate and predict the impact wear resistance of the hardfacing deposits under controlled impact load conditions. Full article

Damage is inevitably induced in titanium alloy laser-welded (LW) joints after prolonged service, making weld repair an economical and effective restoration method. This study employed gas tungsten arc welding (GTAW) to repair pre-damaged TC4 LW joints, with a systematic investigation on the microstructural and mechanical properties of the repaired joints. The results indicate that both the LW and the GTAW-repaired (GTAW-R) joints exhibit acicular α′ martensite in the fusion zone (FZ). However, the maximum length and width of the α′ phase in the FZ of the GTAW-R joint are 67% and 78% larger than those in the LW joint, respectively. The heat-affected zone (HAZ) of both types of joints comprises α′, α, and β phases. Similarly, due to the higher heat input in GTAW, the α′ phase in the HAZ of the GTAW-R joint is coarser. Differences in acicular martensite size result in an average microhardness of 356.3 HV in the FZ of the GTAW-R joint, which is 15.2 HV lower than that of the LW joint. The higher heat input of GTAW leads to a prolonged duration at elevated temperatures in the HAZ, promoting the formation of acicular α′ phase and, consequently, a slightly higher microhardness compared to the HAZ of the LW joint. The average tensile strength of the GTAW-R joint is 1032 MPa, equivalent to 98.4% of the LW joint strength (1049 MPa) and 96.8% of the BM strength (1066 MPa). Tensile fracture in the LW joint occurs in the BM region, whereas the coarser microstructure in the repair weld leads to fracture in the FZ for the GTAW-R joint. This study demonstrates that when the damage length in an LW joint is less than 20%, GTAW repair can effectively restore the joint strength. Full article

Laser Powder Bed Fusion (L-PBF) can enable in situ microstructural tailoring of metallic components by precisely controlling the layer-wise processing parameters. Layer rescanning is one such strategy used to induce localized microstructural modification. In this study, we investigated the effect of a lattice-based selective rescanning approach applied to different base scan strategies for Ti-6Al-4V samples. The lattice regions were selectively rescanned at 50% reduced laser power relative to the initial scan along the same laser path. Relative density, porosity, martensitic α′ morphology, phase fraction, and Vickers microhardness were compared with those of non-rescanned reference counterparts. Different scan strategies, including unidirectional, stripes, and chess, exhibited distinct responses to selective rescanning, resulting in localized variations in martensitic phase formation and hardness values. The extent of localized microstructural modification and hardness enhancement was strongly governed by the underlying scan strategy. Selective rescanning using the stripes strategy yielded the largest contrast between non-rescanned and rescanned regions. The unidirectional strategy showed strong effects of rescanning, but the heat-affected zones extended to the non-rescanned regions. In contrast, the chess strategy exhibited comparatively moderate changes owing to its inherent thermal-management characteristics. These findings demonstrate that selective rescanning can provide an effective, localized approach for tailoring microstructure and hardness enhancement in L-PBF Ti-6Al-4V, with its effectiveness strongly dependent on the underlying scan strategy. Full article

Metastable β titanium alloys with low elastic modulus and excellent plasticity represent highly attractive materials for biomedical stent application. Our work shows that Zr plays a crucial role in regulating β stability to significantly reduce the modulus and enhance plasticity. A series of Ti-25Nb-2Mo-xZr (x = 0, 3, 9, 12 wt%) alloys were designed based on the d-electron theory, and the influence of Zr content on the microstructure, mechanical properties, and deformation mechanism were systematically investigated. The results demonstrated that as the Zr content increases, the β phase stability was significantly enhanced. This leads to, first, the suppressed formation of the high modulus α″ phase and ω phase, which results in the decrease in apparent overall elastic modulus. Second, the dominant mode of deformation shifts from martensite dislocation slip (0Zr) to martensitic variant reorientation (3Zr), then to stress-induced martensite transform (SIMT, 9Zr), and finally to a combination of SIMT and deformation twinning (12Zr). Such shifting effectively increases the alloy’s tensile plasticity. Among the series, the Ti-25Nb-2Mo-12Zr alloy exhibited the lowest elastic modulus of 56.3 GPa, together with the highest elongation to failure of 48.2%, demonstrating that the alloy possesses considerable potential for biomedical applications. Full article

Additive manufacturing (AM) of titanium alloys enables the production of complex, high-performance components, but the steep thermal gradients and rapid solidification involved make it challenging to control crystallographic texture and phase evolution. This review synthesizes the current understanding of how these thermal conditions influence grain morphology, texture intensity, and solid-state transformations in key alloys such as Ti-6Al-4V (Ti64), Ti-6Al-2Sn-4Zr-2Mo (Ti6242), Ti-5Al-5Mo-5V-3Cr (Ti5553), and metastable β-Ti systems processed by powder bed fusion-based processes (PBF) such as laser powder bed fusion (LPBF) and electron beam powder bed fusion (EBPBF/EBM). Emphasis is placed on mechanisms governing epitaxial columnar β-grain growth, α′ martensite formation, and the development of heterogeneous α/β distributions. The impact of processing variables on texture development and transformation kinetics is critically examined, alongside phase fractions. Across studies, AM-induced textures are consistently linked to mechanical anisotropy, with performance strongly dependent on build direction and alloy chemistry. Post-processing strategies, including tailored heat treatments and hot isostatic pressing (HIP), show clear potential to modify grain structure, reduce texture intensity, and stabilize desirable phase balances in titanium alloys. These insights highlight the emerging ability to deliberately engineer microstructures for reliable, application-specific properties in powder-based AM titanium alloys. Full article

The aim of this study was to evaluate structural changes and their impact on the functional properties of Ti-6Al-4V and Ti-6Al-7Nb titanium alloys produced by L-PBF. In the as-built condition, these alloys, despite high strength due to the presence of metastable α’ martensite, exhibit limited ductility. The samples were subjected to heat treatment at 850–1000 °C for 1 h, followed by aging at 500 °C for 4 h in an argon atmosphere. Analysis revealed a gradual microstructural transformation from the columnar structure characteristic of L-PBF to an equilibrium Widmanstätten microstructure. As a result of the decomposition of martensite and the formation of an α + β phase mixture, changes in microhardness and mechanical properties were observed. After heat treatment, the microhardness decreased by 15% for Ti-6Al-4V (from 427 ± 1 HV to 362 ± 25 HV) and by 12% for Ti-6Al-7Nb (from 408 ± 6 HV to 359 ± 15 HV). The Ti-6Al-7Nb alloy exhibited higher maximum elongation (7.7 ± 1.1%) than Ti-6Al-4V (4.8 ± 0.5%) due to a greater fraction of the β phase. The results highlight the critical role of the controlled α′→α + β transformation in tailoring the properties of titanium alloys and provide a basis for optimizing manufacturing processes for medical and aerospace components. Full article

Metals with a hexagonal close-packed (HCP) structure such as magnesium, titanium and zirconium constitute key structural materials in the aerospace, automotive, biomedical and nuclear energy industries. Their welding and regeneration by conventional methods is hindered due to the limited number of slip systems, high reactivity and susceptibility to the formation of defects. Laser technologies offer precise energy control, minimization of the heat-affected zone and the possibility of producing joints and coatings of high quality. This article constitutes a comprehensive review of the state of knowledge concerning laser welding, cladding and regeneration of HCP metals. The physical mechanisms of laser beam interactions are discussed including the dynamics of the keyhole channel, Marangoni flows and the formation of gas defects. The characteristics of the microstructure of joints are presented including the formation of α′ martensite in titanium, phase segregation in magnesium and hydride formation in zirconium. Particular attention is devoted to residual stresses, techniques of cladding protective coatings for nuclear energy with Accident Tolerant Fuel (ATF) and advanced numerical modeling using artificial intelligence. The perspectives for the development of technology are indicated including the concept of the digital twin and intelligent real-time process control systems. Full article

The γ ⟶ α′-transformation under implantation of austenitic-ferritic steel CF8 with ⁵⁷Fe ions to fluences of 1 × 10¹⁶, 5 × 10¹⁶ and 1 × 10¹⁷ ion/cm², as well as the reverse α′ ⟶ γ–transformation under thermal treatment, was studied using transmission Mössbauer spectroscopy (MS), conversion electron Mössbauer spectroscopy (CEMS), and X-ray diffraction (XRD) methods. It was found that implantation, which causes radiation damage with 36 dpa, results in the formation of α′-martensite. At higher fluences of implanted ions, the amount of α′-martensite increased, reaching 86 at.% within the irradiated layer. Annealing in the temperature range of 600–850 °C resulted in the observed reverse transformation of α′-martensite to γ-austenite. The dependence of the average effective magnetic field on the annealing temperature was established. Full article

Ti65 high-temperature titanium alloy, known for its exceptional high-temperature mechanical properties and oxidation resistance, demonstrates considerable potential for aerospace applications. Nevertheless, conventional manufacturing techniques are often inadequate for achieving high design freedom and fabricating complex geometries. This study presents a systematic investigation into the process optimization, microstructure characterization, and mechanical performance of Ti65 alloy produced by laser powder bed fusion (LPBF). Via meticulously designed single-track, multi-track, and bulk sample experiments, the influences of laser power (P), scanning speed (V), and hatch spacing (h) on molten pool behavior, defect formation, microstructural evolution, and surface roughness were thoroughly examined. The results indicate that under optimized parameters, the specimens attain ultra-high dimensional accuracy, with a near-full density (>99.99%) and reduced surface roughness (Ra = 3.9 ± 1.3 μm). Inadequate energy input (low P or high V) led to lack-of-fusion defects, whereas excessive energy (high P or low V) resulted in keyhole porosity. Microstructural analysis revealed that the rapid solidification inherent to LPBF promotes the formation of fine acicular α′-phase (0.236–0.274 μm), while elevated laser power or reduced scanning speed facilitated the development of coarse lamellar α′-martensite (0.525–0.645 μm). Tensile tests demonstrated that samples produced under the optimized parameters exhibit high ultimate tensile strength (1489 ± 7.5 MPa), yield strength (1278 ± 5.2 MPa), and satisfactory elongation (5.7 ± 0.15%), alongside elevated microhardness (446.7 ± 1.7 HV_0.2). The optimized microstructure thereby enables the simultaneous achievement of high density and superior mechanical properties. The fundamental mechanism is attributed to precise control over volumetric energy density, which governs melt pool mode, defect generation, and solidification kinetics, thereby tailoring the resultant microstructure. This study offers valuable insights into defect suppression, microstructure control, and process optimization for LPBF-fabricated Ti65 alloy, facilitating its application in high-temperature structural components. Full article

Phase transformations significantly influence the mechanical properties of Fe-based alloys, making their understanding essential for the design of high-performance alloy materials. This study investigates microstructural evolution and martensitic transformations induced by B2 phase precipitation in an Fe-20Ni-4.5Al-1.0C (wt.%) alloy. The alloy was solution-treated at 1100 °C, followed by isothermal holding between 750 °C and 1000 °C, and water quenching. Microstructural analysis revealed that the as-quenched alloy consisted of a single-phase austenite (γ). Isothermal holding led to the precipitation of a (Ni,Al)-rich B2 phase within the grains and along grain boundaries. An α′-martensitic phase was also observed within γ-grains adjacent to the B2 precipitates in the isothermally held samples. Martensitic transformation is attributed to localized nickel depletion in the matrix surrounding B2, which reduced γ-phase stability and raised the martensite start temperature (Ms), promoting γ-to-α′ transformation during cooling. The co-existence of B2 and α′ phases significantly increased the hardness of the alloy, with a maximum observed at an 850 °C holding temperature. At higher temperatures, coarsening and partial dissolution of B2, as well reduced martensite formation, led to a decline in hardness. These findings highlight the role of B2 precipitation in promoting martensitic transformation and optimizing mechanical properties through controlled heat treatment. Full article

The influence of cold rolling deformation degree (15%, 30%, 45%, 60%, 75%, and 90%) on the microstructural evolution and the mechanical properties of type 347H austenitic heat-resistant steel was investigated using optical microscopy, X-ray diffraction, magnetic hysteresis loop measurement, transmission electron microscopy, and a hardness test. Two types of martensite formed in the deformed specimens, as thin ε-martensite in the cold-rolled steels when the deformation degree was less than 60%, and α′-martensite in the heavily cold-rolled steels when the deformation degree ranged from 60% to 90%. Furthermore, the amount of α′-martensite increases rapidly with the increase in the cold rolling deformation degree. Hence, 60% is considered as the critical point of cold rolling reduction for the formation of α′-martensite. If the specimen experienced a cold rolling reduction of 90%, ε-martensite was hardly observed, while the volume faction of the α′-martensite amounts to 25%. It is verified by the TEM observations that the α′-martensite is transformed from the austenitic matrix as well as the preformed ε-martensite. Full article