Search Results (32)

The antibacterial activity of g-C₃N₄ and Cu-g-C₃N₄ was evaluated against E. coli, with their disinfection capabilities influenced by structural characteristics, photocatalytic properties, and modulation under a static magnetic field. The incorporation of Cu²⁺ does not significantly affect the (210) reflection in XRD analysis, indicating that the alignment of aromatic layers remains stable. However, the presence of copper enables complete disinfection, in contrast to graphitic carbon nitride, which achieves only partial disinfection. Cu²⁺ is likely positioned at N-aliphatic sites and coexists with hydroxylated species, which may influence photocatalytic performance by modifying reactant adsorption and ROS generation. SEM-EDS analysis confirmed that Cu²⁺ modification did not significantly alter the material’s morphology, although a 3% copper content was detected, suggesting a heterogeneous surface distribution. Thermodynamic analysis showed that exposure to a magnetic field increased the Gibbs free energy of adsorption from 6.34 J/m² to 10.52 J/m², reducing interactions with key reactants essential for ROS formation. As a result, both disinfection and photodegradation efficiency were significantly diminished. Additionally, the presence of a magnetic field was found to modify the surface properties of the material, affecting its photocatalytic performance. In Cu-C₃N₄ materials, a decrease in the contact angle suggests enhanced hydrophilicity, while an increase in surface tension may influence the adsorption of water and hydroxyl radicals. This study underscores the effect of a magnetic field on the photocatalytic behavior of materials deposited on polymeric substrates with intrinsic electronic properties, ultimately impacting overall disinfection efficiency. Full article

This review reports a critical study on the effect of magnetic fields on the precipitation process of calcium carbonate scale from hard water. Indeed, the harmful consequences of the water scaling phenomenon urged researchers to find effective solutions. One of the interesting antiscaling processes is the magnetic treatment of water, which triggers a reduction in the precipitation of calcium carbonate on the walls when in contact with hard water. In the present review, we discuss selected examples related to this process in a combined analysis of the latest advances and the mechanism of action of the magnetic field. Despite the diversity of studies investigating this phenomenon, the effectiveness of this treatment remains a controversial issue, and it is not possible to obtain a clear explanation of the phenomenon. This review proposes, finally, interesting hypotheses which can effectively explain the effect of magnetic treatment on the behavior of hard waters and the precipitation of calcium carbonate, which include magnetohydrodynamics and the hydration effect. Full article

The development of novel synthesis and assembly strategies is critical to achieving a ferromagnetic organic semiconductor with high Curie temperature. In this study, we report a high magnetic field (HMF)-modified solvothermal approach for the reduction in neutral perylene diimide (PDI) into the dianion species to prepare the PDI magnets comprising radical anions after subsequent oxidation processes. The PDI materials, assembled from the dianion solution by an HMF-modified reduction, exhibit a smaller crystallite size and an enlarged distance of the π-π stacking in the PDI aggregates. Furthermore, the PDI magnets obtained from the process under a 9T field reveal weakened ferromagnetism and the rapid degradation of electrical conductivity compared to those prepared without a magnetic field. Based on spectral and structural characterizations, such performance deterioration originates from the enhanced instability of the radical anions exposed to air, as well as the decreased crystallinity for the radical PDIs synthesized from the HMF-modified reduction process. This work demonstrates that magnetic fields offer an effective way in the material synthesis process to manipulate the structure and magnetic properties of the radical-based organic magnets. Full article

The development of a catalyst for the conversion of CO₂ and epoxides to the corresponding cyclic carbonates is still a very attractive topic. Magnetic nano-catalysts are widely used in various organic reactions due to their magnetic separation and recycling properties. Here, a magnetic nano-catalyst containing a Schiff base unit was designed, synthesized and used as a heterogeneous catalyst to catalyze CO₂ and epoxides to form cyclic carbonates without solvents and co-catalysts. The catalyst was characterized using Fourier transform infrared (FTIR), X-ray diffraction (XRD), thermogravimetric (TG), VSM, SEM, TEM and BET. The results show that the magnetic nano-catalyst containing the Schiff base unit has a high activity in the solvent-free cycloaddition reaction of CO₂ with epoxide under mild conditions, and is easily separated from the reaction mixture driven by external magnetic force. The recovered catalyst maintains a high performance after five cycles. Full article

In this paper, we study the effects of viscosity on the evolution of the double tearing mode (DTM) in a pair of adjacent Harris sheets based on the resistive MHD model in the NIMROD code. Similar to the tearing mode in the conventional single Harris sheet, a transition is observed in the generation of both normal and monster plasmoids at Prandtl number $P_r=1$. In the $P_r<1$ regime of the DTM, normal plasmoids (small plasmoids) are generated along with monster plasmoid, whereas in the single tearing mode (STM) cases, such a generation is not observed. When $P_r$ is above the critical value, the generation of monster plasmoid is halted. Correspondingly, in the $P_r<1$ regime, a quadrupolar flow advects along the poloidal direction, but in the $P_r>1$ regime this flow advection is inhibited. Full article

The microfluidics of magnetic fluids is gaining popularity due to the possibility of the non-contact control of liquid composite systems using a magnetic field. The dynamics of non-magnetic droplets and gas bubbles in magnetic fluids were investigated for various configurations of magnetic fields, coatings, and channel geometries, as well as the rate of component supply and their physical properties. Optimal regimes for forming droplet and bubble flows were determined. The mechanism for non-contact control of the size of droplets and bubbles using a magnetic field is proposed in this article. The dependences of the sizes of non-magnetic inclusions in magnetic liquids on the continuous phase flow rate and the displacement of magnets were obtained. The obtained dependences of the volume of non-magnetic inclusions on the flow rate of the continuous phase follow the classic dependences. Changing the size of air bubbles can be achieved by shifting the magnet from −5 mm to +2 mm. The ratio of the maximum and minimum breakaway inclusion varies from 5 to 2 depending on the flow rates of the continuous phase. The range of changing the size of oil droplets with the displacement of magnets is from 1.1 to 1.51. These studies show how, with the help of various mechanisms of influence on microfluidic flows, it is possible to control the size of bubbles and droplets forming in microchannels. The obtained data can be applied for controlled microfluidic dosing and counting devices. Full article

Traditional dc magnetron sputtering has a low ionization rate when preparing metallic thin films. With the development of thin film science and the market demand for thin film material applications, it is necessary to improve the density of magnetron-sputtered films. High-power pulsed magnetron sputtering (HiPIMS) technology is a physical vapor deposition technology with a high ionization rate and high energy. Therefore, in this work, HiPIMS was applied to prepare metallic tungsten films and compare the surface morphology and microstructure of metallic tungsten films deposited using HiPIMS and dc magnetron sputtering (dcMS) technology under different pulse lengths, as well as related thermal resistance performance, followed by annealing treatment for comparative analysis. We used AFM, SEM, XRD, and plasma characterization testing to comprehensively analyze the changes in the TCR value, stability, repeatability and other related performance of the metallic tungsten thin-film sensor deposited by the HiPIMS technology. It was determined that the thin film prepared by the HiPIMS method is denser, with fewer defects, and the film sensor was stable. The 400 °C annealed sample prepared using HiPIMS with a 100 μs pulse length reaches the largest recorded TCR values of 1.05 × 10⁻³ K⁻¹. In addition, it shows better stability in repeated tests. Full article

We study the latitudinal extent of the near-relativistic electron events of 10 June 2000 and 26 December 2001, observed by both Ulysses and ACE. From the observations it is shown that the intensity of ACE was quite different from that of Ulysses. Through the numerical simulations, we obtain the SEPs time-intensity profiles, which generally fit well to the observations. To compare the observations we obtained the best fit parameters for the simulations. We suggest that the transport effects, especially the perpendicular diffusion effect, can cause the difference between the intensity profiles of ACE and Ulysses, which is dominated by particle transport at a large radial distance and high-latitude when a spacecraft has poor magnetic connection to the particle source. Furthermore, we present the particle source from the best fit parameters to show that the start and peak times of the particle sources are between the onset and max times of a flare in all the energy channels. Moreover, we propose models for the peak intensity and half width of the particle source, and the time interval from the flare onset to the particle source peak time. We show that the models generally agree with the best fit parameters. Full article

Solar energetic particles (SEPs) are produced by solar eruptions and are harmful to spacecraft and astronauts. The four source function parameters of particle injection for SEP events and the magnetic turbulence level can be collectively referred to as key parameters. We reproduce the electron intensity-time profiles with simulations for five SEP events observed by multispacecraft such as ACE, STEREO-A, and STEREO-B, so we can obtain the five fitted key parameters for each of the events. We analyze the relationship among the five fitted key parameters, and also the relationship between these parameters and the observed event features. Thus, the model of key parameters are established. Next, we simulate another 12 SEP events with the key parameters model. Though the predicted electron intensity-time profiles do not fit the observed ones well, the peak flux and event-integrated fluence can be predicted accurately. Therefore, the model can be used to estimate the radiation hazards. Full article

With the advent of soft X-ray imaging enabling global magnetopause detection, it is critical to use reconstruction techniques to derive the 3-dimensional magnetopause location from 2-dimensional X-ray images. One of the important assumptions adopted by most techniques is that the direction with maximum soft X-ray emission is the tangent direction of the magnetopause, which has not been validated in observation so far. This paper analyzes a magnetospheric solar wind charge exchange (SWCX) soft X-ray event detected by XMM–Newton during relatively stable solar wind and geomagnetic conditions. The tangent direction of the magnetopause is determined by an empirical magnetopause model. Observation results show that the maximum SWCX soft X-ray intensity gradient tends to be the tangent of the magnetopause’s inner boundary, while the maximum SWCX soft X-ray intensity tends to be the tangent of the magnetopause’s outer boundary. Therefore, it is credible to use the assumption that the tangent direction of the magnetopause is the maximum SWCX soft X-ray intensity or its gradient when reconstructing the 3-dimensional magnetopause location. In addition, since these two maxima tend to be the inner and outer boundaries of the magnetopause, the thickness of magnetopause can also be revealed by soft X-ray imaging. Full article

Physical property inversion techniques are the methods to reveal the internal structures of Earth’s lithosphere. In this study, we introduce an Occam-type inversion algorithm into a spherical coordinate system, and invert the magnetization based on the three-component magnetic anomalies. The synthetic model tests show that the inversion effects of the vertical components are relatively stable, while the anti-noise ability is strong. We apply the algorithm to a set of vertical component anomalies derived from the satellite magnetic field model and obtain Dabie orogen 3D magnetization distribution. Multiple magnetic sources are identified within the orogen and adjacent areas, and the related tectonic evolution processes are analyzed. The significant magnetization characteristics of the orogen can be associated with mantle upwelling caused by the Early Cretaceous lithospheric delamination, along with the partial melting of the mafic–ultramafic lower crust that had not participated in the delamination. The magnetic sources near the Mozitan–Xiaotian fault, and those located in the western Dabie area, are also restricted by Mesozoic and Jurassic–Cretaceous deep melt activities, respectively. The study provides evidence for the suture line position of the plate subduction in the deep lithosphere. Furthermore, the results display certain indications of mineralization activities in the middle–lower Yangtze Valley metallogenic belt. Full article

As an external field, a magnetic field can change the electrocatalytic activity of catalysts through various effects. Among them, electron spin polarization on the catalyst surface has attracted much attention. Herein, we investigate the sensitive response behavior of a Cu₂O nanocubes to an in situ magnetic field. Under a 3 T strong magnetic field, the total transferred electron quantity in IT test (−1.1 V_RHE) and the current density in the polarization curve increase by 28.7% and 54.7%, respectively, while the onset potential decreases significantly by 114 mV. Moreover, it was found that product selectivity was also altered by the magnetic field. The Faraday efficiency of C₁ increases substantially, along with the inhibition of C₂₊ reaction paths and the HER. Our experimental results and DFT calculation demonstrate that a hybrid magnetic effect accelerates the CO₂RR kinetic and generates spin polarization of the catalyst surface. The polarized surface changes the binding energy of *OCHO/*COOH and inhibits singlet C–C coupling, which restrains the C₂₊ reduction path and thus more CO₂ is reduced to HCOOH. Full article

A MoN_x coating serves as an effective wear protection layer and is crucial for the investigation of its tribological characteristics at various temperatures. This study examined the tribological characteristics of MoN_x coatings that were deposited through high-power pulsed magnetron sputtering (HiPIMS) in an Ar/N₂ environment with varying N₂ partial pressures. The microstructures and mechanical properties of the coatings were elucidated using scanning electron microscopy, grazing-incidence-angle X-ray diffraction, energy-dispersive spectroscopy, and nanoindentation. The dry friction performances of the coatings at different heating temperatures were studied using a ball-on-disk tribometer. The MoN_x coating produced by HiPIMS was composed primarily of fcc−Mo₂N and featured a fine, dense column crystal with a maximum hardness of 28.8 GPa. The MoN_x coatings exhibited excellent lubrication and wear reduction properties at room temperature (RT). The dry friction performances of the MoN_x coatings at elevated temperatures were expected to depend on the growth of the MoO₃ tribolayer. At relatively low temperatures (300 °C and 400 °C), the MoO₃ tribolayer grew slowly and was not enough to provide good lubrication, causing increases in the dry friction of the coatings. However, the δ−MoN phase formed in the MoN_x coating deposited at a high N₂ partial pressure could facilitate the formation of MoO₃ and thus decreased the friction coefficient at 400 °C. At the relatively high heating temperature of 500 °C, however, the MoO₃ tribolayer grew so rapidly that the oxide layer became thick, resulting in an increase in the wear rate. It is believed that tuning the growth rate of MoO₃ via optimizing the composition and structure of the MoN_x coatings might be a useful way to improve the dry friction at various elevated temperatures. Full article

Earth’s radiation belt and ring current are donut-shaped regions of energetic and relativistic particles, trapped by the geomagnetic field. The strengthened solar wind dynamic pressure (P_dyn) can alter the structure of the geomagnetic field, which can bring about the dynamic variation of radiation belt and ring current. In the study, we firstly utilize group test particle simulations to investigate the phase space density (PSD) under the varying geomagnetic field modeled by the International Geomagnetic Reference Field (IGRF) and T96 magnetic field models from 19 December 2015 to 20 December 2015. Combining the observation of the Van Allen Probe, we find that the PSD of outer radiation belt electrons evolves towards different states under different levels of P_dyn. In the first stage, the P_dyn (~7.94 nPa) results in the obvious rise of electron anisotropy. In the second stage, there is a significant reduction in PSD for energetic electrons at all energy levels and pitch angles under the action of intense P_dyn (~22 nPa), which suggests that the magnetopause shadowing and outward radial diffusion play important roles in the second process. The result of the study can help us further understand the dynamic evolution of the radiation belt and ring current during a period of geomagnetic disturbance. Full article