Search Results (12)

Sr₂LaF₇:xPr³⁺ (x = 0.2, 1, 2, 3, 5, 10, and 25 mol%) nanophosphors with a cubic Fm3m structure were hydrothermally synthesized, forming nearly spherical nanoparticles with an average diameter of approximately 32 nm. Diffuse reflectance measurement and excitation spectra showed a primary excitation peak of Pr³⁺ at 443 nm, corresponding to the ground state to the ³P₂ level transition. Upon blue light excitation, Pr³⁺-activated Sr₂LaF₇ nanophosphors showed rich emission structure across the visible region of the spectrum, with blue (~483 nm), green (~525 nm), orange (~600 nm), and red (~640 nm) emissions, blue and orange being the most prominent ones. The relative intensities of these emissions varied with Pr³⁺ concentration, leading to tunable emission colors. The chromaticity showed slight variation with the Pr³⁺ content (0.350 < x < 0.417, 0.374 < y < 0.380), while the CCT value increased from 3118 K to 4901 K as the doping concentration increased. The optimized Sr₂LaF₇ with 2 mol% Pr³⁺ had the most intense emission with correlated color temperature (CCT) of 3628 K, corresponding to the warm white color. The proposed Pr³⁺-doping strategy offers valuable insights into discovering or optimizing single-phase phosphors for white-light-emitting applications. Full article

Accurate temperature measurement is critical across various scientific and industrial applications, necessitating advancements in thermometry techniques. This study explores luminescence thermometry, specifically utilizing machine learning methodologies to enhance temperature sensitivity and accuracy. We investigate the performance of principal component analysis (PCA) on the Eu³⁺-doped Y₂Mo₃O₁₂ luminescent probe, contrasting it with the traditional luminescence intensity ratio (LIR) method. By employing PCA to analyze the full emission spectra collected at varying temperatures, we achieve an average accuracy (ΔT) of 0.9 K and a resolution (δT) of 1.0 K, significantly outperforming the LIR method, which yielded an average accuracy of 2.3 K and a resolution of 2.9 K. Our findings demonstrate that while the LIR method offers a maximum sensitivity (Sr) of 5‰ K⁻¹ at 472 K, PCA’s systematic approach enhances the reliability of temperature measurements, marking a crucial advancement in luminescence thermometry. This innovative approach not only enriches the dataset analysis but also sets a new standard for temperature measurement precision. Full article

Detailed analysis covered the optical and structural properties of Eu³⁺-doped NaY₉Si₆O₂₆ oxyapatite phosphors, which were obtained via hydrothermal synthesis. X-ray diffraction patterns of NaY₉Si₆O₂₆:xEu³⁺ (x = 0, 1, 5, 7, 10 mol% Eu³⁺) samples proved a single-phase hexagonal structure (P63/m (176) space group). Differential thermal analysis showed an exothermic peak at 995 °C attributed to the amorphous to crystalline transformation of NaY₉Si₆O₂₆. Electron microscopy showed agglomerates composed of round-shaped nanoparticles ~53 nm in size. Room temperature photoluminescent emission spectra consisted of emission bands in the visible spectral region corresponding to ⁵D₀ → ⁷F_J (J = 0, 1, 2, 3, 4) f-f transitions of Eu³⁺. Lifetime measurements showed that the Eu³⁺ concentration had no substantial effect on the rather long ⁵D₀-level lifetime. The Eu³⁺ energy levels in the structure were determined using room-temperature excitation/emission spectra. Using the ⁷F₁ manifold, the Nv-crystal field strength parameter was calculated to be 1442.65 cm⁻¹. Structural, electronic, and optical properties were calculated to determine the band gap value, density of states, and index of refraction. The calculated direct band gap value was 4.665 eV (local density approximation) and 3.765 eV (general gradient approximation). Finally, the complete Judd–Ofelt analysis performed on all samples confirmed the experimental findings. Full article

Tunable blue/red dual-emitting Eu³⁺-doped, Bi³⁺-sensitized SrF₂ phosphors were synthesized utilizing a solvothermal-microwave method. All phosphors have cubic structure (Fm-3m (225) space group) and well-distinct sphere-like particles with a size of ~20 nm, as examined by X-ray diffraction and transmission electron microscopy. The diffuse reflectance spectra reveal a redshift of the absorption band in the UV region as the Bi³⁺ concentration in SrF₂: Eu³⁺ phosphor increases. Under the 265 nm excitation, photoluminescence spectra show emission at around 400 nm from the host matrix and characteristic orange ⁵D₀ → ⁷F_1,2 and deep red ⁵D₀ → ⁷F₄ Eu³⁺ emissions. The red emission intensity increases with an increase in Bi³⁺ concentration up to 20 mol%, after which it decreases. The integrated intensity of Eu³⁺ red emission in the representative 20 mol% Bi³⁺ co-doped SrF₂:10 mol% Eu³⁺ shows twice as bright emission compared to the Bi³⁺-free sample. To demonstrate the potential application in LEDs for artificial light-based plant factories, the powder with the highest emission intensity, SrF₂: 10Eu, 20 Bi, was mixed with a ceramic binder and placed on top of a 275 nm UVC LED chip, showing pinkish violet light corresponding to blue (409 nm) and red (592, 614, and 700 nm) phosphors’ emission. Full article

A set of Eu³⁺-doped molybdates, Y₂₋xEuxMo₃O₁₂ (x = 0.04; 0.16; 0.2; 0.4; 0.8; 1; 1.6; 2), was synthesized using a solid-state technique and their properties studied as a function of Eu³⁺ concentration. X-ray diffraction showed that the replacement of Y³⁺ with larger Eu³⁺ resulted in a transformation from orthorhombic (low doping concentrations) through tetragonal (high doping concentrations), reaching monoclinic structure for full replacement in Eu₂Mo₃O₁₂. The intensity of typical Eu³⁺ red emission slightly increases in the orthorhombic structure then rises significantly with dopant concentration and has the highest value for the tetragonal Y₂Mo₃O₁₂:80mol% Eu³⁺. Further, the complete substitution of Y³⁺ with Eu³⁺ in the case of monoclinic Eu₂Mo₃O₁₂ leads to decreased emission intensity. Lifetime follows a similar trend; it is lower in the orthorhombic structure, reaching slightly higher values for the tetragonal structure and showing a strong decrease for monoclinic Eu₂Mo₃O₁₂. Temperature-sensing properties of the sample with the highest red Eu³⁺ emission, Y₂Mo₃O₁₂:80mol% Eu³⁺, were analyzed by the luminescence intensity ratio method. For the first time, the peak-sharpening algorithm was employed to separate overlapping peaks in luminescence thermometry, in contrast to the peak deconvolution method. The Sr (relative sensitivity) value of 2.8 % K⁻¹ was obtained at room temperature. Full article

The method of measuring temperature using luminescence by analyzing the emission spectra of Pr³⁺-doped YF₃ using principal component analysis is presented. The Pr³⁺-doped YF₃ is synthesized using a solid-state technique, and its single-phase orthorhombic crystal structure is confirmed using X-ray diffraction. The emission spectra measured within the 93–473 K temperature range displays characteristic Pr³⁺ f-f electronic transitions. The red emission from the ³P_0,1→³H₆,³F₂ electronic transition mostly dominates the spectra. However, at low temperatures, the intensity of the green emissions from the ³P_0,1→³H₅, deep-red ³P_0,1→³F₄, and the deep-red emissions from the ³P_0,1→³F₄ transitions are considerably lower compared to the intensity of the red emissions. Temperature variations directly impact the photoluminescent spectra, causing a notable increase in the green and deep-red emissions from the ³P₁ excited state. We utilized the entire spectrum as an input for principal component analysis, considering each temperature as an independent group of data. The first principal component explained 99.3% of the variance in emission spectra caused by temperature and we further used it as a reliable temperature indicator for luminescence thermometry. The approach has a maximum absolute sensitivity of around 0.012 K⁻¹. The average accuracy and precision values are 0.7 K and 0.5 K, respectively. Full article

The sensitivity of luminescent Boltzmann thermometers is restricted by the energy difference between the thermally coupled excitement levels of trivalent lanthanides, and their values further decrease with increases in temperature, rendering their use at high temperatures difficult. Here, we demonstrate how to overcome this sensitivity limitation by employing multiparameter and multilevel cascade temperature readings. For this purpose, we synthesized Dy³⁺:Y₂SiO₅, a phosphor whose emission is known to begin quenching at very high temperatures. Its photoluminescence-emission features, later used for thermometry, consisted of two blue emission bands centered around 486 nm and 458 nm, and two bands centered around 430 nm and 398 nm, which were only visible at elevated temperatures. Next, we performed thermometry using the standard luminescence-intensity ratio (LIR) method, which employs the ⁴F_9/2 and ⁴I_15/2 Dy³⁺ levels’ emissions and the multilevel cascade method, which additionally uses the ⁴G_11/2 level and overlapping intensities of ⁴I_13/2, ⁴M_21/2, ⁴K_17/2, and ⁴F_7/2 levels to create two LIRs with a larger energy difference than the standard LIR. This approach yielded a sensitivity that was 3.14 times greater than the standard method. Finally, we simultaneously exploited all the LIRs in the multiparameter temperature readings and found a relative sensitivity that was 30 times greater than that of the standard approach. Full article

We report the procedure for hydrothermal synthesis of ultrasmall Yb³⁺/Tm³⁺ co-doped Sr₂LaF₇ (SLF) upconversion phosphors. These phosphors were synthesized by varying the concentrations of Yb³⁺ (x = 10, 15, 20, and 25 mol%) and Tm³⁺ (y = 0.75, 1, 2, and 3 mol%) with the aim to analyze their emissions in the near IR spectral range. According to the detailed structural analysis, Yb³⁺ and Tm³⁺ occupy the La³⁺ sites in the SLF host. The addition of Yb³⁺/Tm³⁺ ions has a huge impact on the lattice constant, particle size, and PL emission properties of the synthesized SLF nanophosphor. The results show that the optimal dopant concentrations for upconversion luminescence of Yb³⁺/Tm³⁺ co-doped SLF are 20 mol% Yb³⁺ and 1 mol% Tm³⁺ with EDTA as the chelating agent. Under 980 nm light excitation, a strong upconversion emission of Tm³⁺ ions around 800 nm was achieved. In addition, the experimental photoluminescence lifetime of Tm³⁺ emission in the SLF host is reported. This study discovered that efficient near IR emission from ultrasmall Yb³⁺/Tm³⁺ co-doped SLF phosphors may have potential applications in the fields of fluorescent labels in bioimaging and security applications. Full article

The sensitivity of luminescence thermometry is enhanced at high temperatures when using a three-level luminescence intensity ratio approach with Dy³⁺- activated yttrium aluminum perovskite. This material was synthesized via the Pechini method, and the structure was verified using X-ray diffraction analysis. The average crystallite size was calculated to be around 46 nm. The morphology was examined using scanning electron microscopy, which showed agglomerates composed of densely packed, elongated spherical particles, the majority of which were 80–100 nm in size. The temperature-dependent photoluminescence emission spectra (ex = 353 nm, 300–850 K) included Dy³⁺ emissions in blue (458 nm), blue (483 nm), and violet (430 nm, T 600 K). Luminescence intensity ratio, the most utilized temperature readout method in luminescent thermometry, was used as the testing method: a) using the intensity ratio of Dy³⁺ ions and ⁴I_15/2→⁶H_15/2/⁴F_9/2→⁶H_15/2 transitions; and b) employing the third, higher energy ⁴G_11/2 thermalized level, i.e., using the intensity ratio of ⁴G_11/2→⁶H_15/2/⁴F_9/2→⁶H_15/2 transitions, thereby showing the relative sensitivities of 0.41% K⁻¹ and 0.86% K⁻¹ at 600 K, respectively. This more than doubles the increase in sensitivity and therefore demonstrates the method’s usability at high temperatures, although the major limitation of the method is the chemical stability of the host material and the temperature at which the temperature quenching commences. Lastly, it must be noted that at 850 K, the emission intensities from the energetically higher levels were still increasing in YAP: Dy³⁺. Full article

The antibacterial performance and cytotoxic examination of in situ prepared silver nanoparticles (Ag NPs), on inorganic-organic hybrid nanopowder consisting of zirconium dioxide nanoparticles (ZrO₂ NPs) and dihydroquercetin (DHQ), was performed against Gram (−) bacteria Escherichia coli and Gram (+) bacteria Staphylococcus aureus, as well as against human cervical cancer cells HeLa and healthy MRC-5 human cells. The surface modification of ZrO₂ NPs, synthesized by the sol-gel method, with DHQ leads to the interfacial charge transfer (ICT) complex formation indicated by the appearance of absorption in the visible spectral range. The prepared samples were thoroughly characterized (TEM, XRD, reflection spectroscopy), and, in addition, the spectroscopic observations are supported by the density functional theory (DFT) calculations using a cluster model. The concentration- and time-dependent antibacterial tests indicated a complete reduction of bacterial species, E. coli and S. aureus, for all investigated concentrations of silver (0.10, 0.25, and 0.50 mg/mL) after 24 h of contact. On the other side, the functionalized ZrO₂ NPs with DHQ, before and after deposition of Ag NPs, do not display a significant decrease in the viability of HeLa MRC-5 cells in any of the used concentrations compared to the control. Full article

A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La_0.95Eu_0.05PO₄) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu³⁺) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu³⁺ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La_0.95Eu_0.05PO₄ host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La_0.95Eu_0.05PO₄ from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La_0.95Eu_0.05PO₄ increases more than three times when the Eu³⁺ excitation is supported by the localized surface plasmon resonance in the Ag/La_0.95Eu_0.05PO₄ nanostructures. Full article

The emission of Er³⁺ provides three combinations of emission bands suitable for ratiometric luminescence thermometry. Two combinations utilize ratios of visible emissions (²H_11/2→⁴I_15/2 at 523 nm/ ⁴S_3/2→⁴I_15/2 at 542 nm and ⁴F_7/2→⁴I_15/2 at 485 nm/ ⁴S_3/2→⁴I_15/2 at 545 nm), while emissions from the third combination are located in near-infrared, e.g., in the first biological window (²H_11/2→⁴I_13/2 at 793 nm/ ⁴S_3/2→⁴I_13/2 at 840 nm). Herein, we aimed to compare thermometric performances of these three different ratiometric readouts on account of their relative sensitivities, resolutions, and repeatability of measurements. For this aim, we prepared Yb³⁺,Er³⁺:YF₃ nanopowders by oxide fluorination. The structure of the materials was confirmed by X-ray diffraction analysis and particle morphology was evaluated from FE-SEM measurements. Upconversion emission spectra were measured over the 293–473 K range upon excitation by 980 nm radiation. The obtained relative sensitivities on temperature for 523/542, 485/542, and 793/840 emission intensity ratios were 1.06 ± 0.02, 2.03 ± 0.23, and 0.98 ± 0.10%K⁻¹ with temperature resolutions of 0.3, 0.7, and 1.8 K, respectively. The study showed that the higher relative temperature sensitivity does not necessarily lead to the more precise temperature measurement and better resolution, since it may be compromised by a larger uncertainty in measurement of low-intensity emission bands. Full article