Nanoenergy Advances

The surface chemistry of cesium lead halide perovskite nanocrystals has been elaborately studied in recent years and has proved the critical role of carboxylic acids and amines in the formation and stability of the nanocrystals. Specifically, a slight change in the concentration and ratio of the frequently used oleic acid and oleylamine critically influences the resultant phase and physical properties. Thus, understanding the delicate surface of cesium lead halide perovskite nanocrystals mainly relies on chemical bonding and the dynamic ligand environment of these two organic species. In this aspect, this review summarizes experimental findings about the critical role of oleic acid and oleylamine on the nucleation, growth, stability, phase, and morphology of cesium lead halide perovskite nanocrystals and their effect under different circumstances. Full article

With the global energy shortages, sustainable energy scavenging from the natural environment is desperately needed. Unlike solar cell or wind power, which depends heavily on weather conditions, triboelectric nanogenerator (TENG) has received extensive attention as an efficient all–weather energy–harvesting technology. Based on the coupling principle of contact electrification (CE) and electrostatic induction, conventional TENGs convert mechanical energy into an alternating current (AC) output. However, the typically distributed sensor systems in the ubiquitous Internet of Things (IoTs) request a direct current (DC) input. Direct current triboelectric nanogenerators (DC-TENGs) with the constant output characteristic are critical to satisfy the above requirements. Here, DC-TENGs were reviewed from the perspective of material selections. As device performance is mainly determined by material properties, the development of DC-TENGs could be divided into three categories based on dielectric materials, semiconductor materials, and materials for iontronic rectifications. The operating mechanism and influencing factors of various types of DC-TENG were summarized, representative applications were demonstrated, and the main challenges of future developments were also discussed. Full article

Collecting ambient energy to power various wearable electronics is considered a prospective approach to addressing their energy consumption. Mechanical and thermal energies are abundantly available in the environment and can be efficiently converted into electricity based on different physical effects. Hydrogel-based energy harvesters have turned out to be a promising solution, owing to their unique properties including flexibility and biocompatibility. In this review, we provide a concise overview of the methods and achievements in hydrogel-based energy harvesters, including triboelectric nanogenerators, piezoelectric nanogenerators, and thermoelectric generators, demonstrating their applications in power generation, such as LED lighting and capacitor charging. Furthermore, we specifically focus on their applications in self-powered wearables, such as detecting human motion/respiration states, monitoring joint flexion, promoting wound healing, and recording temperature. In addition, we discuss the progress in the sensing applications of hydrogel-based self-powered electronics by hybridizing multiple energy conversion in the field of wearables. This review analyzes hydrogel-based energy harvesters and their applications in self-powered sensing for wearable devices, with the aim of stimulating ongoing advancements in the field of smart sensors and intelligent electronics. Full article

In recent years, the development of the Internet of Things has challenged traditional energy supply methods. Suddenly rising maintenance costs and serious environmental pollution have led to great concern over energy supply methods such as wired transmission and batteries. Fluid energy is a kind of clean energy widely existing in nature, which can effectively reduce costs and environmental pollution. In the field of collecting fluid energy, fluid energy converters based on triboelectric nanogenerators (FEC-TENGs) have always been a research hotspot. This paper reviews the latest research progress of FEC-TENGs. Firstly, the basic working principle and working mode of FEC-TENGs are introduced. Then, the theoretical process and application examples of converting fluid energy into electrical energy or electrical signals are analyzed in detail. According to the calculation process of energy conversion efficiency and the performance evaluation parameters, the structural design, performance output, and application fields of FEC-TENGs are summarized. Finally, this paper points out the challenges and shortcomings of the current FEC-TENGs and provides our views on the future development of this field. Full article

Backpack transportation is everywhere in daily life. Suspended-load backpacks (SUSBs) based on forced vibration have attracted lots of attention because of their ability to effectively reduce the cost on the body during motion. The smaller the natural frequency of SUSBs, the better the cost reduction. The natural frequency is determined by the elastic components of SUSBs. It is currently common to use rubber ropes and pulleys as elastic components. In the first part of this paper, we propose a pre-compression design for SUSBs, which has a simple structure and breaks through the limitation of rubber material. To make the natural frequency small enough, rubber ropes and compression springs require sufficient space. This leads to the current SUSBs being large and, therefore, not suitable for children to carry. Inspired by biology, here we propose a new design strategy of pre-rotation with pre-rotation spiral springs as elastic components. The pre-rotation design not only has the advantages of avoiding the inconvenience of material aging and the ability to adjust the downward sliding distance of the backpack but also greatly saves the space occupied by the elastic components, which can be adopted by small SUSBs. We have developed a theoretical model of the pre-rotation SUSBs and experimentally confirmed the performance of the pre-rotation SUSBs. This work provides a unique design approach for small SUSBs and small suspended-load devices. And the relative motion between the components inside the SUSB has a huge potential to be used by triboelectric nanogenerators for energy scavenging. Full article

Backpack transportation is commonly used in daily life. Reducing the cost of the backpack on the human body is a widely researched subject. Suspended-load backpacks (SUSBs) based on forced vibration can effectively reduce the cost during movement. The intrinsic frequency of the SUSB is determined by the elastic components of the SUSB. Previous researchers used pulleys and rubber ropes as the elastic components. We propose a pre-compression design strategy based on pre-compression springs. Compared with previous studies, the use of pre-compression springs as elastic elements improves the reliability of the SUSB structure, avoids the inconvenience of nonlinearity and material aging, and adds the ability to flexibly adjust the sliding distance of the backpack. Moreover, previous studies utilized the relative motion between the carrying part and the backpack part to scavenge the vibration energy. We propose that the vibration energy can also be scavenged by the relative motion between the elastic components. A theoretical model is developed for the pre-compression SUSB. We experimentally confirm the performance of the pre-compression SUSB. This work provides new design ideas for SUSBs with reduced energy costs. In Part 2, we propose a bio-inspired pre-rotation design that has the advantage of occupying less space. Full article

Triboelectric nanogenerators (TENGs) are key technologies for the Internet of Things with energy harvesting. To improve energy conversion efficiency and convert mechanical energy into electrical energy, high charge density in TENGs plays a crucial role in the design of triboelectric materials and device structures. This paper proposes mechanisms and strategies to increase TENGs’ charge density through multi-charge storage layers. We also discuss the realization of higher charge densities through material and structure design. The implementation of novel charge storage strategies holds the potential for significant improvements in charge density. Full article

As a new technology for harvesting distributed energy, the triboelectric nanogenerator (TENG) has been widely used in harvesting wind energy. However, the wind-driven TENG (WD-TENG) faces the problems of high frictional resistance and low mechanical energy conversion efficiency. Here, based on optimizing the structure of the wind turbine, a rotational double-electrode-layer WD-TENG (DEL-WD-TENG) is developed. When the rotational speed is less than 400 round per minute (rpm), the dielectric triboelectric layer rubs with the inner electrode layer under its gravity; when the rotational speed is higher than 400 rpm, the dielectric triboelectric layer rubs with the outer electrode layer under the centrifugal force. The double-electrode-layer structure avoids the energy loss caused by other forces except gravity, centrifugal, and electrostatic adsorption, which improves the mechanical energy conversion efficiency and prolongs the working life of the DEL-WD-TENG. The conversion efficiency from mechanical energy to electricity of the DEL-WD-TENG can reach 10.3%. After 7 million cycles, the transferred charge of the DEL-WD-TENG is reduced by about 5.0%, and the mass loss of dielectric triboelectric layer is only 5.6%. The DEL-WD-TENG with low frictional resistance and high energy conversion efficiency has important application prospects in wind energy harvesting and self-powered sensing systems. Full article

Zinc oxide nanowires (ZnO NWs) have gained considerable attention in the field of piezoelectricity in the past two decades. However, the impact of growth-process conditions on their dimensions and polarity, as well as the piezoelectric properties, has not been fully explored, specifically when using pulsed-liquid injection metal–organic chemical vapor deposition (PLI-MOCVD). In this study, we investigate the influence of the O₂ gas and DEZn solution flow rates on the formation process of ZnO NWs and their related piezoelectric properties. While the length and diameter of ZnO NWs were varied by adjusting the flow-rate conditions through different growth regimes limited either by the O₂ gas or DEZn reactants, their polarity was consistently Zn-polar, as revealed by piezoresponse force microscopy. Moreover, the piezoelectric coefficient of ZnO NWs exhibits a strong correlation with their length and diameter. The highest mean piezoelectric coefficient of 3.7 pm/V was measured on the ZnO NW array with the length above 800 nm and the diameter below 65 nm. These results demonstrate the ability of the PLI-MOCVD system to modify the dimensions of ZnO NWs, as well as their piezoelectric properties. Full article

Addressing the increasing development of IoT networks and the associated energy requirements, rotating triboelectric nanogenerators (R-TENGs) are proving to be strong candidates in the field of energy harvesting, as well as to that of self-powered devices and autonomous sensors. In this work, we review the theoretical framework surrounding the operating principles and key design parameters of R-TENGs, while also associating them with their output characteristics. Furthermore, we present an overview of the core designs used by the research community in energy harvesting applications, as well as variations of these designs along with explicit solutions for the engineering and optimization of the electrical output of R-TENGs. Last but not least, a comprehensive survey of the potential applications of R-TENGs outside the energy harvesting scope is provided, showcasing the working principles of the various designs and the benefits they confer for each specific scenario. Full article

Indoor organic photovoltaics (IOPVs) have attained considerable research attention as a power source for a low-power consumption self-sustainable electronic device for Internet of Things (IoT) applications. This study aims to develop an efficient cathode interfacial layer (CIL) based on a polyethyleneimine (PEIE) derivative, processed at room temperature, for the advancement of non-fullerene acceptor (NFA)-based IOPVs. Using a simple chemical reaction between polyethyleneimine and cobalt (II) chloride, we developed a 3D network-structured CIL. Through quaternary ammonium salts and chelating, metal ions act as mediators and induce metal-ion doping. An inverted device architecture with wide-bandgap and low-bandgap photo-absorber layer is utilized to understand the role of CILs under standard 1 sun and low-light or indoor light illuminations. The IOPV devices with modified CIL (Co-PEIE) having PBDB-T: IT-M and PBDB-T-2F: BTP-4F photo-absorber layers demonstrate a power conversion efficiency of 22.60% and 18.34% under 1000 lux LED lamp (2700 K) illumination conditions, respectively, whereas the IOPV devices with pristine PEIE CIL realized a poor device performance of 18.31% and 14.32% for the PBDB-T: IT-M and PBDB-T-2F: BTP-4F active layers, respectively. The poor device performance of PEIE interlayer-based IOPV under low-light conditions is the result of the significantly high leakage current and low shunt resistance that directly affect the open-circuit voltage (V_OC) and fill factor (FF). Therefore, the adjustable energy barrier and notably low leakage current exhibited by the Co-PEIE CIL have a crucial impact on mitigating losses in V_OC and FF when operating under low-light conditions. Full article

Lithium-ion batteries (LIBs) dominate the market of rechargeable power sources. To meet the increasing market demands, technology updates focus on advanced battery materials, especially cathodes, the most important component in LIBs. In this review, we provide an overview of the development of materials and processing technologies for cathodes from both academic and industrial perspectives. We briefly compared the fundamentals of cathode materials based on intercalation and conversion chemistries. We then discussed the processing of cathodes, with specific focuses on the mechanisms of a drying process and the role of the binders. Several key parameters for the development of thick electrodes were critically assessed, which may offer insights into the design of next-generation batteries. Full article

As wearable devices continue to be updated and iterated, there is an increasing demand for energy supplies that are small, portable and capable of working continuously for extended periods of time. Here, a hybrid triboelectric-electromagnetic nanogenerator (HNG) based on a biomechanical energy harvester is demonstrated. The HNG is designed to be worn on the wrist according to the curve of the wearer’s arm swing. During the swinging of the arm, the magnet covered by the PTFE film will move relative to the curved cavity of the HNG and take on a negative charge by rubbing against the inner wall of the Cu coated cavity, resulting in a change in the potential difference between the two copper electrodes on the inner wall of the curved cavity. The movement of the magnet causes the magnetic flux of the three pairs of coils on both sides of the arc track to change to produce the induced electric potential, which converts the mechanical energy generated by the arm swing into electrical energy. After the rational design, the HNG is integrated into a small size device to achieve the collection of biomechanical energy. Several experiments were conducted to verify the HNG’s usability. Experiments show that the HNG takes 90 s to charge from 0 V to 1.2 V for a 1000 μF capacitor. In addition, the HNG can light up 23 LEDs simultaneously and provide a continuous supply of energy to portable electronic devices, such as temperature sensors and electronic watches after the capacitor has stored the energy. Furthermore, the HNG is experimentally verified by volunteers wearing the HNG to achieve continuous and stable output in all three states of slow swing, fast swing and running swing. This work not only provides a useful reference for human biomechanical energy harvesting, but can also provide a continuous, clean source of energy for wearable devices. Full article

Facing the energy consumption of a huge number of distributed wireless Internet of Things (IoT) sensor nodes, scavenging energy from the ambient environment to power these devices is considered to be a promising method. Moreover, abundant energy sources of various types are widely distributed in the surrounding environment, which can be converted into electrical energy by micro-nano energy harvesters based on different mechanisms. In this review paper, we briefly introduce the development of different energy harvesters according to the classification of target energy sources, including microscale and nanoscale energy harvesters for vibrational energy sources, microscale energy harvesters for non-vibrational energy sources, and micro-nano energy harvesters for hybrid energy sources. Furthermore, the current advances and future prospects of the applications of micro-nano energy harvesters in event-based IoT systems and self-sustained systems are discussed. Full article

Anthropogenetic environmental deterioration and climate change caused by energy production and consumption pose a significant threat to the future of humanity. Renewable, environmentally friendly, and cost-effective energy sources are becoming increasingly important for addressing future energy demands. Mechanical power is the most common type of external energy that can be converted into useful electric power. Because of its strong electromechanical coupling ability, the piezoelectric mechanism is a far more successful technique for converting mechanics energy to electrical energy when compared to electrostatic, electromagnetic, and triboelectric transduction systems. Currently, the scientific community has maintained a strong interest in piezoelectric micro-power generators because of their great potential for powering a sensor unit in the distributed network nodes. A national network usually has a large mass of sensor units distributed in each city, and a self-powered sensor network is eagerly required. This paper presents a comprehensive review of the development of piezoelectric micro-power generators. The fundamentals of piezoelectric energy conversion, including operational modes and working mechanisms, are introduced. Current research progress in piezoelectric materials including zinc oxide, ceramics, single crystals, organics, composite, bio-inspired and foam materials are reviewed. Piezoelectric energy harvesting at the nano- and microscales, and its applications in a variety of fields such as wind, liquid flow, body movement, implantable and sensing devices are discussed. Finally, the future development of multi-field coupled, hybrid piezoelectric micropower generators and their potential applications are discussed. Full article

Metal–support interaction (MSI) is considered a key effect of electronic and geometric structures of catalysts on tuning catalytic performance. The oxygen evolution reaction (OER) is a crucial process during energy conversion and storage. However, the OER process requires the help of noble metal catalysts to reduce the reaction overpotential, enhance reactivity with intermediates, and maintain good operating stability. Carbon–supported metal catalysts have been considered candidates for noble metal catalysts for OER. MSI occurs at the interface of carbon supports and metals, affecting the catalytic performance through electronic and geometric modulation. MSI can influence the catalytic performance and change reaction pathways from charge redistribution, electron transfer, chemical coordination and bonding, and steric effect. Connecting MSI effects with the OER mechanism can provide theoretical guidance and a practical approach to the design of efficient catalysts, including the modulation of particle size, morphology, heteroatom doping, defect engineering, and coordination atom and number. Advantage can be taken of MSI modulation between metal compounds and carbon supports to provide guidance for catalyst design. Full article

Zinc–air batteries are promising candidates as stationary power sources because of their high specific energy density, high volumetric energy density, environmental friendliness, and low cost. The oxygen-related reactions at the air electrode are kinetically slow; thus, the air electrode integrated with an oxygen electrocatalyst is the most critical component, and inevitably determines the performance of a Zn–air battery. The aim of this paper was to document progress in researching bifunctional catalysts for Zn–air batteries. The catalysts are divided into several categories: noble metal, metal nanoparticle (single and bimetallic), multicomponent nanoparticle, metal chalcogenide, metal oxide, layered double hydroxide, and non-metal materials. Finally, the battery performance is compared and discussed. Full article

Contact electrification exists everywhere and between every phase of matter. However, its mechanism still remains to be studied. The recent triboelectric nanogenerator serves as a probe and provides some new clues about the mechanism present in solid–solid, solid–liquid, and liquid–liquid contact electrification. The gas–solid model still remains to be exploited. Here, we investigated the contact electrification between gases and solids based on the single-electrode triboelectric nanogenerator. Our work shows that the amount of transferred charges between gas and solid particles increases with surface area, movement distance, and initial charges of particle increase. Furthermore, we find that the initial charges on the particle surface can attract more polar molecules and enhance gas collisions. Since ions in gas–solid contact are rare, we speculate that gas–solid contact electrification is mainly based on electron transfer. Further, we propose a theoretical model of gas–solid contact electrification involving the gas collision model and initial charges of the particle. Our study may have great significance to the gas–solid interface chemistry. Full article