Spectroscopy in Archaeometry and Conservation Science

A special issue of Heritage (ISSN 2571-9408).

Deadline for manuscript submissions: 15 March 2025 | Viewed by 2220

Special Issue Editor

Special Issue Information

Dear Colleagues,

For many years, scientific research has been employed in cultural heritage research as well as archaeological and conservation issues, especially because of its ability to analyse and characterise complex materials such as those sourced from archaeological sites, museums, private collections, and much more.

In this context, spectroscopy has played a key role in studying such materials; in fact, the development of even more efficient, non-destructive, and, in most cases, portable instruments have made these techniques the most effective and suitable for the study of inorganic and organic substances of cultural heritage interest, e.g., paintings, ceramics, textiles, sculptures, and archaeological findings. Moreover, the possibility of applying spectroscopy to the study of products of degradation, which are mainly due to time and/or improper environmental conditions, opens the field to interdisciplinary research in which air quality monitoring and environmental biological characteristics can be related to the corruption of artworks.

Finally, the massive amount of data usually acquired in such studies can possibly leverage the use of chemometrics and artificial intelligence, with these techniques able to help in properly analysing and modelling complex and challenging problems associated with the interpretation of outcomes.

This Special Issue aims to collect research works that benefit from the application of the most up-to-date non-destructive and/or in-situ spectroscopic methods, spectral imaging techniques, and data processing techniques.

Dr. Vittoria Guglielmi
Guest Editor

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Keywords

  • Raman spectroscopy
  • FTIR
  • XRF
  • SEM-EDX
  • UV-visible-NIR spectroscopy
  • imaging
  • chemometrics
  • artificial intelligence

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Published Papers (2 papers)

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Research

14 pages, 2001 KiB  
Article
Glass Finds from the Elite House of Roue, a Sasanian City Building in Western Iran: Composition and Classification Using XRF and Raman Spectroscopy
by Farahnaz Koleini, Philippe Colomban, Narges Doosti Sani and Lily Niakan
Heritage 2024, 7(11), 6137-6150; https://doi.org/10.3390/heritage7110288 - 29 Oct 2024
Viewed by 811
Abstract
The Silk Road connected the east of Iran to the western world. Roue city is close to the Road. Six glass samples from Roue were classified on the basis of morphology, archaeological context and compositions. The samples were analysed by means of XRF [...] Read more.
The Silk Road connected the east of Iran to the western world. Roue city is close to the Road. Six glass samples from Roue were classified on the basis of morphology, archaeological context and compositions. The samples were analysed by means of XRF and Raman spectroscopy and two specific groups, namely Roue type 1 and Roue type 2, with close composition to high alumina plant-ash glass in circulation from the 6th to 10th centuries CE in Mesopotamia, Iran and Syria, were identified. The simultaneous occurrence of two types of glass in the excavated layers shows that the house was inhabited in the early Islamic period. Colours (black, amber-green, light and aqua blue) were produced mainly by the amount of iron and sulphur ions required for the amber chromophore and copper ions for the blue colour and the controlling of reducing conditions in the furnace. Full article
(This article belongs to the Special Issue Spectroscopy in Archaeometry and Conservation Science)
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13 pages, 3326 KiB  
Article
The Nitrate Cellulose Negatives: Degradation Study via Chemometric Methods
by Anastasia Povolotckaia, Svetlana Kaputkina, Irina Grigorieva, Dmitrii Pankin, Evgenii Borisov, Anna Vasileva, Valeria Kaputkina and Maria Dynnikova
Heritage 2024, 7(9), 4712-4724; https://doi.org/10.3390/heritage7090223 - 30 Aug 2024
Viewed by 1041
Abstract
Photographic artifacts carry important historical and cultural information. Materials used in photography at the turn of the XIXth and XXth centuries tend to degrade both over time and if the temperature and humidity conditions of storage are violated. In this connection, the question [...] Read more.
Photographic artifacts carry important historical and cultural information. Materials used in photography at the turn of the XIXth and XXth centuries tend to degrade both over time and if the temperature and humidity conditions of storage are violated. In this connection, the question arises of determining the safety degree and monitoring the condition of photographic materials. Close attention should be paid to photographic materials that become flammable as a result of decomposition. This class of objects includes photographic films based on cellulose nitrate. This study was aimed at examining 100 negatives and stereonegatives from the collection of Karl Kosse dating from 1902 to 1917 as typical examples of these hazard class objects. The degradation of individual negatives was accompanied by a significant change in color—yellowing. The base of photographic negatives (cellulose nitrate and camphor) was determined by Raman spectroscopy, and the presence of a gelatin layer was determined by ATR-FTIR spectroscopy. Using chemometric analysis methods based on the RGB components of digital photos of negatives, an approach has been proposed for determining the state of degradation. The use of the support vector machine approach allows for obtaining a decision boundary, which can be later used to analyze a large data array. Full article
(This article belongs to the Special Issue Spectroscopy in Archaeometry and Conservation Science)
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