Applications of Electrocatalysts for Water Treatment: Recent Advances

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: closed (31 May 2023) | Viewed by 2862

Special Issue Editors


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Guest Editor
Division of Environmental Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Korea
Interests: electrocatalysts and electrochemical processes for water treatment coupled with energy conversion

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Guest Editor
Department of Environment Science and Biotechnology, Jeonju University, Keonju-si 560-759, Korea
Interests: wastewater electrolysis cell for wastewater treatment; capacitive deionization(CDI) for resource recovery from wastewater; membrane bioreactor for wastewater treatment

Special Issue Information

Dear Colleagues,

Growing concerns regarding hitherto-unforeseen aqueous micropollutants along with more stringent requirements for water treatment have led us to variable advanced redox processes. In particular, electrochemical processes with electrocatalysts as core components would be one of the most direct methods to control and monitor the redox transformation and separation of aqueous pollutants. Moreover, parallel water splitting and direct electron transfer from energy-rich pollutants have allowed wastewater electrolysis cells or fuel cells to meet the blooming need for energy recovery during water treatment, partly in combination with renewable energy sources. The electrocatalytic water treatment process involves direct charge transfer, generation of reactive O/Cl/H species, and capacitive sorption of ions, among others. The key requirements to achieving a broad application is to engineer the electrocatalytic materials with suitable properties, such as electrochemically active surface area, electrical conductivity, adsorption energy to reactant/product, and capacitance. On the other hand, the electrochemical water treatment processes have been commercially available for many years. However, results of long-term field operation focusing on problems associated with side reactions in natural (waste)water have rarely been shared in this community.

Submissions to this Special Issue on “Applications of Electrocatalysts for Water Treatment: From Lab to Field” are welcome in the form of original research papers or short reviews on all aspects of electrochemical water treatment, featuring the state-of-the-art developments on electrocatalysts and electrochemical processes as well as the application of existing materials/processes in field environments. Research findings on electrochemical redox processes are of prime importance to this Special Issue, while parallel attention will be given to electro-deionization technologies.

Prof. Dr. Kangwoo Cho
Prof. Dr. Chong Min Chung
Guest Editor

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Keywords

  • electro-oxidation/reduction
  • electrochemical activation of oxidants
  • electro-flotation/coagulation/deposition
  • capacitive deionization/electrodialysis
  • wastewater electrolysis cell
  • wastewater fuel cell

Published Papers (1 paper)

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Research

11 pages, 2214 KiB  
Article
Revisiting Gas to Solids Ratio for Activated Sludge Clarification by Electrolytic Hydrogen Bubbles: Theoretical and Experimental Evaluations
by Jiseon Kim, Chong Min Chung, Kangwoo Cho and Tai Hak Chung
Catalysts 2021, 11(11), 1413; https://doi.org/10.3390/catal11111413 - 22 Nov 2021
Cited by 3 | Viewed by 1861
Abstract
Molecular hydrogen (H2), as the green energy carrier from water electrolysis, can be utilized for separation of suspended micro-particles as electroflotation (EF). This study provides practical guidelines for the gas to solids (G/S) ratio as the governing parameter in EF, based [...] Read more.
Molecular hydrogen (H2), as the green energy carrier from water electrolysis, can be utilized for separation of suspended micro-particles as electroflotation (EF). This study provides practical guidelines for the gas to solids (G/S) ratio as the governing parameter in EF, based on theoretical estimations and experiments for clarification of activated sludge. The G/S ratio in EF was controlled linearly by current density (j), under quasi-consistent current efficiency (at j > 8 mA/cm2) for H2 (~1) and O2 (~0.4) bubble generations on Ti cathode and IrTaOx anode, respectively. Based on the measured sizes of bubbles (approximated to 35 µm) and biological flocs (discretized to mean sizes of 22.5, 40, 60, 135, and 150 µm), batch flotation experiments estimated the maximum collision-attachment efficiency of 0.057. The rise velocities of floc-bubble aggregate were computed to derive the limiting G/S ratio to overcome the given influent hydraulic loading. Consequently, the estimates (5.23 × 10−4 and 5.92 × 10−4 at hydraulic loading of 0.87 and 1.73 cm/min, respectively) were compatible with the continuous EF experiments. Full article
(This article belongs to the Special Issue Applications of Electrocatalysts for Water Treatment: Recent Advances)
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