Alloy Nanocatalysts for Fuel Cells

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: closed (31 October 2021) | Viewed by 3137

Special Issue Editors


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Guest Editor
Fuel Cell Nanomaterials Center, University of Yamanashi, 6-43 Miyamae-cho, Yamanashi, Kofu 400-0021, Japan
Interests: electrocatalysis; polymer electrolyte fuel cells; density functional theory

E-Mail Website
Guest Editor
Fuel Cell Nanomaterials Center, University of Yamanashi, 6-43 Miyamae-cho, Kofu, Yamanashi 400-0021, Japan
Interests: electrochemistry; electrocatalysis; nanomaterials; fuel cells; electrolyzers

Special Issue Information

Dear Colleagues,

Alloying is one of the most powerful tools available to the designer of metallic catalysts. Alloying can be used to modify both the activity and the durability of a catalyst, both of which help to lower the cost, which is particularly important when such catalysts employ precious and/or rare metals. Catalysts for fuel cells are no different. Platinum alloys have been investigated for the last half-century, particularly for the oxygen cathode, because the oxygen reduction reaction (ORR) is in greater need of catalytic assistance than the hydrogen anode in acidic electrolytes. Alloys are also important for the hydrogen anode, because the hydrogen oxidation reaction (HOR) can be easily poisoned by carbon monoxide present in hydrogen fuels produced from natural gas. More recently, platinum alloys have also been intensively investigated for the hydrogen anode in alkaline electrolytes, because the HOR activity decreases drastically with increasing pH. Fuel cells are not limited to hydrogen as a fuel, but can also utilize alcohols and even hydrocarbons, and alloys are also extremely useful for their catalytic reactions. Despite the extensive research already devoted to such alloys, new insights continue to be revealed, and more are indeed needed to fully understand how they work. With deeper understanding, we can design even more active, more durable, lower-cost catalysts. This Special Issue entitled “Alloy Nanocatalysts for Fuel Cells” aims to bring together contributions from a diverse range of fuel cells and their associated fuels and electrolytes in order to cross-fertilize ideas that are common to all. We also welcome contributions from a wide range of viewpoints, from the applied to the fundamental.

Prof. Dr. Donald Tryk
Dr. Guoyu Shi
Guest Editor

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Keywords

  • new electrocatalysts
  • platinum alloys
  • oxygen reduction reaction
  • hydrogen oxidation reaction
  • methanol oxidation reaction
  • CO-tolerant catalysts
  • ammonia oxidation reaction
  • hydrazine oxidation reaction
  • density functional theory

Published Papers (1 paper)

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Research

17 pages, 4702 KiB  
Article
Bimetallic Pd-Co Nanoparticles Supported on Nitrogen-Doped Reduced Graphene Oxide as Efficient Electrocatalysts for Formic Acid Electrooxidation
by SK Safdar Hossain, Mohammad Mudassir Alwi, Junaid Saleem, Hussain Taj Al-Hashem, Gordon McKay, Said Mansour and Syed Sadiq Ali
Catalysts 2021, 11(8), 910; https://doi.org/10.3390/catal11080910 - 28 Jul 2021
Cited by 8 | Viewed by 2719
Abstract
In this work, bimetallic PdxCoy nanoparticles supported on nitrogen-doped reduced graphene oxide catalysts were synthesized and tested for formic acid oxidation as potentially efficient and durable electrocatalysts. Graphene oxide was nitrogen doped through hydrothermal chemical reduction with urea as a [...] Read more.
In this work, bimetallic PdxCoy nanoparticles supported on nitrogen-doped reduced graphene oxide catalysts were synthesized and tested for formic acid oxidation as potentially efficient and durable electrocatalysts. Graphene oxide was nitrogen doped through hydrothermal chemical reduction with urea as a nitrogen source. The PdxCoy nanoparticles were deposited on the nitrogen-doped graphene oxide support using the impregnation-reduction method with sodium borohydride as a reducing agent and sodium citrate dihydrate as a stabilizing agent. The structural features, such as phases, composition, oxidation states, and particle sizes, of the nanoparticles were characterized using X-ray diffraction, transmission electron microscopy, scanning electron microscopy–energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The Pd nanoparticle sizes in Pd1Co1/N-rGO, Pd/N-rGO, and Pd1Co1/CNT were 3.5, 12.51, and 4.62 nm, respectively. The electrochemical performance of the catalysts was determined by CO stripping, cyclic voltammetry, and chronoamperometry. Pd1Co1/N-rGO showed the highest mass activity of 4833.12 mA–1 mg Pd, which was twice that of Pd1Co1/CNT. Moreover, Pd1Co1/N-rGO showed a steady-state current density of 700 mA–1 mg Pd after 5000 s in chronoamperometry carried out at +0.35 V. Apart from the well-known bifunctional effect of Co, nitrogen-doped graphene contributed to the performance enhancement of the Pd1Co1/N-rGO catalyst. Full article
(This article belongs to the Special Issue Alloy Nanocatalysts for Fuel Cells)
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