Advances in Catalysis for Various Carbonaceous Materials Transformations into Liquid Fuels

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Biomass Catalysis".

Deadline for manuscript submissions: closed (15 December 2020) | Viewed by 5395

Special Issue Editor


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Guest Editor
Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, St. Lucia, QLD 4072, Australia
Interests: catalytic fast pyrolysis; syngas to oxygenates; structured catalytic reactors; biomass vapour upgrading; catalytic CO2 to alcohol; nonrecyclable plastic to chemicals and fuels feedstock

Special Issue Information

Dear Colleagues,

To meet energy and materials demand of our modern society, we continue to rely on fossil-based carbon feedstock without closing the carbon loop. This led to the accumulation of non-degradable plastic in oceans and CO2 in the atmosphere. Also, the circular economy and recycling efforts are incentivized and promoted in some countries, but its widespread industrial applications are still limited. Significant efforts are made to treat and convert mixed-waste into liquid fuels, but these are limited to catalyst-free processes. In this issue, we seek original articles on catalytic conversion of mixed-waste into liquid fuels; these include hydrothermal and solvent liquefaction, co-pyrolysis, gasification, microwave, solar thermal with or without CO2 co-feeding. Particular interest on synergetic effect of each feedstock for instance: (i) co-feeding CO2 during plastic, tyres, biomass thermal degradation,  (ii)intermediates reactivity with catalytic active sites, (iii) improving selectivity towards diesel-range hydrocarbons and (iv) catalysts promoting C-C coupling, heteroatom (O2, S, N) removal.

Dr. Muxina Konarova
Guest Editor

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Keywords

  • Catalytic co-pyrolysis
  • Catalytic solvent liquefaction
  • Catalytic hydrothermal liquefaction
  • Synergetic effect of CO2 co-feeding
  • Catalyst deactivation /regeneration
  • Catalytic microwave degradation

Published Papers (1 paper)

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Research

21 pages, 3949 KiB  
Article
Supermagnetic Nano-Bifunctional Catalyst from Rice Husk: Synthesis, Characterization and Application for Conversion of Used Cooking Oil to Biodiesel
by Balkis Hazmi, Umer Rashid, Yun Hin Taufiq-Yap, Mohd Lokman Ibrahim and Imededdine Arbi Nehdi
Catalysts 2020, 10(2), 225; https://doi.org/10.3390/catal10020225 - 13 Feb 2020
Cited by 44 | Viewed by 4804
Abstract
The present work investigated the biodiesel production from used cooking oil catalyzed by nano-bifunctional supermagnetic heterogeneous catalysts (RHC/K2O/Fe) derived from rice husk doped with K2O and Fe synthesized by the wet impregnation method. The synthesized catalysts (RHC/K2O/Fe) [...] Read more.
The present work investigated the biodiesel production from used cooking oil catalyzed by nano-bifunctional supermagnetic heterogeneous catalysts (RHC/K2O/Fe) derived from rice husk doped with K2O and Fe synthesized by the wet impregnation method. The synthesized catalysts (RHC/K2O/Fe) were characterized for crystallinity by X-ray diffraction spectroscopy (XRD), total acidity and basicity using CO2/NH3-TPD, textural properties through Brunauer-Emmett-Teller (BET), thermal stability via thermogravimetric analyzer (TGA), functional group determination by Fourier-transform infrared spectroscopy (FTIR), surface morphology through field emission scanning electron microscopy (FESEM), and magnetic properties by vibrating sample magnetometer (VSM). The VSM result demonstrated that the super-paramagnetic catalyst (RHC/K2O-20%/Fe-5%) could be simply separated and regained after the reaction using an external magnetic field. The operating conditions such as catalyst loading, methanol/oil molar ratio, temperature, and reaction duration were studied. The screened RHC/K2O-20%/Fe-5% catalyst was selected for further optimization and the optimum reaction parameters found were 4 wt % of catalyst, a molar ratio of methanol/oil of 12:1, 4 h reaction duration, and 75 °C reaction temperature with a maximal yield of 98.6%. The reusability study and reactivation results revealed that the nano-bifunctional magnetic catalyst (RHC/K2O-20%/Fe-5%) could be preserved by high catalytic activity even after being reused five times. Full article
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