Chemical Characterization of Urban Air Pollution

A special issue of Atmosphere (ISSN 2073-4433). This special issue belongs to the section "Air Quality".

Deadline for manuscript submissions: 15 September 2026 | Viewed by 1602

Special Issue Editor


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Guest Editor
Department of Environmental Science and Engineering, Fudan University, Shanghai 200438, China
Interests: atmospheric chemistry for N-containing compounds; microplastics; organic acids; PAHs

Special Issue Information

Dear Colleagues,

Urban environments are hotspots for complex and dynamic air pollution driven by emissions from traffic, industry, and residential sources, as well as atmospheric chemical transformations. Understanding the chemical composition, sources, and processes of urban air pollutants is essential for developing effective mitigation strategies and assessing adverse health effects.

This Special Issue invites original research and review articles focused on the chemical characterization of urban air pollution, including but not limited to:

  • Chemical speciation of PM2.5 and PM10, e.g., water-soluble ionic species, potentially toxic elements, and organic carbon/elemental carbon (OC/EC);
  • Volatile organic compounds (VOCs) and their ozone formation potential;
  • Secondary organic aerosols (SOAs) and formation and evolution mechanisms of SOAs;
  • Atmospheric reactive nitrogen compounds and secondary formation of inorganic nitrate and nitrogen-containing organic aerosols;
  • Source apportionment of major pollutants using isotopic techniques, e.g,. ammonium, nitrate, sulfate, and their gas precursors;
  • Emerging pollutants in urban air environment, e.g., microplastics, plastic additive, tire wear particles, and Poly- and Perfluoroalkyl Substances (PFASs);
  • Development and application of novel analytical methods;
  • Case studies from megacities or emerging urban areas;
  • Links between pollutant chemistry and adverse health effects.

Prof. Dr. Xingnan Ye
Guest Editor

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Keywords

  • urban pollution
  • ion chemistry
  • potentially toxic elements
  • N-containing compounds
  • VOCs
  • SOA
  • source apportionment
  • atmospheric chemistry
  • atmospheric monitoring
  • emerging pollutants
  • stable isotopic signature
  • health effects

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Published Papers (2 papers)

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Research

27 pages, 5371 KB  
Article
An Improved Nearness Grey Incidence Model and Its Application in the Analysis of Air Pollutants in Beijing-Tianjin-Hebei Region
by Siqi Wang, Jing Sun and Chao Hua
Atmosphere 2026, 17(4), 358; https://doi.org/10.3390/atmos17040358 - 31 Mar 2026
Viewed by 325
Abstract
A new nearness grey incidence model that not only measures the degree of correlation but also measures the direction is proposed to analyze the distribution characteristics of air pollutants in the Beijing–Tianjin–Hebei region, from 2016 to 2024. To be specific, improvements in this [...] Read more.
A new nearness grey incidence model that not only measures the degree of correlation but also measures the direction is proposed to analyze the distribution characteristics of air pollutants in the Beijing–Tianjin–Hebei region, from 2016 to 2024. To be specific, improvements in this proposed model lie in the following aspects: First, the calculation method of the symbol judgement factor is updated, so that the final nearness grey incidence degree can better reflect the nearness degree and nearness direction between any two sequences, which improves the stable robustness of the grey incidence degree. Second, the anti-fluctuation factor is introduced into the new model, and the relative volatility between series is included in the calculation process of the grey incidence degree. Third, several practical properties of the proposed model are elaborated to further interpret the feasibility and adaptability of the proposed model. In experiments, based on the daily data of the six pollutants in the Beijing–Tianjin–Hebei region from 2016 to 2024, using the new model as a tool, the main pollutants in the Beijing–Tianjin–Hebei region are identified, the temporal and spatial distribution of different pollutants is analyzed, the changes in trends of air pollution processes in the past 9 years are identified, and a comparison with pollution levels of other cities in Beijing–Tianjin–Hebei and Beijing is also detailed. Finally, the superlative performance of the proposed model is confirmed by the model comparison, Monte Carlo analysis and example analysis. Full article
(This article belongs to the Special Issue Chemical Characterization of Urban Air Pollution)
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17 pages, 1315 KB  
Article
Evolution of Microplastic Properties and Tetracycline Adsorption During Aging in Laboratory and Natural Environments
by Yunhang Wang, Qihong Miao, Qi An and Hongbo Fu
Atmosphere 2026, 17(1), 32; https://doi.org/10.3390/atmos17010032 - 26 Dec 2025
Cited by 1 | Viewed by 746
Abstract
With the continuous rise in global plastic production and emissions, microplastics (MPs) have become ubiquitous across environmental compartments, including the atmosphere. Aging in natural settings substantially alters MP physicochemical properties and, in turn, their interactions with coexisting contaminants. Here, polyethylene (PE), polyethylene terephthalate [...] Read more.
With the continuous rise in global plastic production and emissions, microplastics (MPs) have become ubiquitous across environmental compartments, including the atmosphere. Aging in natural settings substantially alters MP physicochemical properties and, in turn, their interactions with coexisting contaminants. Here, polyethylene (PE), polyethylene terephthalate (PET), and polystyrene (PS) were subjected to ultraviolet (UV)-accelerated aging and natural exposure in marine intertidal zones, freshwater lakes, and the atmosphere, and changes in their properties and tetracycline (TC) adsorption were systematically compared. Aging intensity followed the order seawater > freshwater > air. Fourier-transform infrared spectroscopy showed the formation and enrichment of oxygen-containing functional groups, and naturally aged samples exhibited stronger oxidation signatures than those aged solely under UV irradiation. Adsorption kinetics indicated higher equilibrium capacities and rate constants for aged MPs; after 324 h of UV exposure in seawater, TC adsorption on PE, PS, and PET increased by 64.6%, 56.6%, and 64.0%, respectively. Mechanistic analysis suggests that surface roughening, oxygenated functional groups, and enhanced negative surface charge collectively promote TC adsorption, dominated by electrostatic interactions and hydrogen bonding. These findings not only elucidate how different aging pathways modulate the interactions between MPs and pollutants but also offer new insights into assessing the carrier potential of microplastics in environments such as the atmosphere and their adsorption of other contaminants. Full article
(This article belongs to the Special Issue Chemical Characterization of Urban Air Pollution)
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