Thermo, Volume 6, Issue 1 (March 2026) – 9 articles

The development of deep eutectic solvents (DESs) is a key issue for the realization of green and efficient metal extraction processes. The present study aims to experimentally construct the phase diagram of the binary system consisting of tri-n-octylphosphine oxide (TOPO) and 4,4,4-trifluoro-1-phenyl-1,3-butanedione (HBTA) and, thus, determine its eutectic composition for the solvent extraction of Li⁺. Differential scanning calorimetry was used to characterize the phase transitions (melting temperatures and enthalpies) over the entire composition range of the binary mixture. Its eutectic composition was established at HBTA:TOPO mass ratio of 60:40. For further validation of the eutectic composition from the experimentally measured thermal effects for melting of different HBTA:TOPO mass ratios, a Tammann diagram was also constructed. Only mixtures with HBTA:TOPO mass ratios of 70:30, 60:40 (eutectic composition), and 50:50 were liquids at 30 °C, while at room temperature of 25 °C, the 70:30 mixture formed crystals. All three mixtures, which were liquids at 30 °C, were found to extract Li⁺ effectively. However, at a room temperature of 25 °C, only the eutectic mixture (60:40 mass ratio) extracted Li⁺ effectively, while the mixture with HBTA:TOPO mass ratio of 50:50 formed crystals when mechanically agitated and, therefore, was deemed as unsuitable for Li⁺ extraction. Full article

A firewood stove’s combustion chamber can withstand temperatures of 1500 °C. To prevent the deterioration of a firewood stove due to excessive heat, it is necessary to use thermal insulation materials that stop heat transfer to the walls. These materials must be economical and durable. This work examines the materials used in the construction of combustion chambers of firewood stoves in southern Mexico and Central America. This field study collects information and samples of materials used in the manufacture of firewood stoves. Heat transfer experiments are conducted, and the thermal properties of each material are analyzed. As a result, methodology and information is provided for the manufacture of future plancha-type firewood stoves used in the study area, such as pine wood (pinus chiapensis) which is mainly used as casing for firewood stoves in coniferous forest areas; in addition, the use of wood ash as thermal insulation material is proposed since it does not present direct costs and has a thermal conductivity between 0.10 and 0.20 W/m°C and a melting point greater than 1500 °C. The next layer proposed is hollow brick, a high-temperature-resistant material that can be used as support due to its mechanical strength and low thermal conductivity of 0.6 W/m°C. Finally, the use of calcium hydroxide as a coating material is proposed, applied in the form of a paste or paint to detail the imperfections of the combustion chamber construction as it resists temperatures above 1000 °C. Full article

Double complex salts (DCSs) of the composition [Co(NH₃)₆][Fe(CN)₆] are a promising precursor for the preparation of catalysts for the hydrogenation of carbon oxides (CO and CO₂) by Fischer–Tropsch synthesis. The specific surface area is an important parameter for catalysts. Our article investigates the influence of mechanochemical activation (MCA) on this DCS in order to determine the conditions for obtaining the largest specific surface area of the intermetallic compound, a product of the DCS thermolysis. In this work, the effect of MCA on the physicochemical properties of the DCS [Co(NH₃)₆][Fe(CN)₆] and the products of its thermal decomposition in an argon atmosphere were investigated. It was shown that MCA leads to partial reduction of Fe⁺³ to Fe⁺², changes in the coordination of ammonia, amorphization of the structure and a decrease in the thermal stability of DCS. Thermolysis at 650 °C of samples subjected to MCA for 10 min results in the formation of nanocrystalline intermetallic compound Co_0.5Fe_0.5. The results demonstrate the potential of using MCA to control the properties of functional materials based on DCS. Full article

This work presents a straightforward procedure for constructing the solution to the steady-state energy-transfer process in a system of two convex, opaque, gray bodies, with the aim of determining the temperature distribution within these bodies when separated by a vacuum. The methodology proposed in this work combines a sequence of elements that are functions obtained from the solution of uncomplicated, well-known linear, uncoupled heat transfer problems, thereby enabling solutions to be obtained using tools found in basic engineering textbooks. Specifically, these well-known problems resemble classical conduction-convection heat transfer problems, in which the boundary condition is described by the noteworthy Newton’s law of cooling. The limit of sequences of elements that are solutions to straightforward linear problems corresponds to the original, complex, coupled nonlinear problem. The convergence of these sequences is mathematically proven. The phenomenon (considered in this work) encompasses those involving black bodies. Since each element of the sequence arises from a well-known linear problem, numerical approximations can be used to obtain it, yielding a simple and powerful tool for simulations. Some presented results highlight the importance of considering thermal interaction between the two bodies, even in the absence of physical contact. In particular, the alterations in the temperature distributions of two separate gray bodies are explicitly shown to result from their thermal interaction. Full article

To balance the quantity of heat generated and consumed, thermal energy storage systems are crucial for power plants and district heating systems. Particularly when phase transitions and pressure variations are not adequately covered in the existing literature, their work frequently takes place under complicated, changing temperature and fluid dynamic settings. The goal of this research is to create a thermodynamic model that incorporates the effects of steam condensation, steam injection, and heating failures to describe the transient behaviour of temperature and pressure in pressure vessels containing single-phase and two-phase fluids. To account for nonlinear, temperature-dependent steam properties, as well as initial and boundary constraints, the study proposes energy balance models for hot water and saturated steam cases. Numerical simulations evaluating sensitivity to parameter changes are presented alongside analytical solutions for isochoric and isobaric systems. The model also includes direct steam injection heating and the use of a heat exchanger. It explains the changes in temperature and pressure that occur in thermal energy storage systems over time, including significant events such as steam cushion collapse and condensate drainage. According to the sensitivity analysis, the main factors influencing the system’s safety limitations and transient dynamic phenomena are thermal power, heat exchanger capacity, and thermal insulation efficiency. The proposed thermodynamic model closes a major gap in the literature by providing reliable predictions of the transient behavior needed for the safe design and reliable operation of pressure vessels utilized for heat storage in district heating networks. This model can be used by engineers and researchers to optimize system design and steer clear of risky operational situations. Full article

Improving the architecture and control strategies of thermal management systems (TMSs) is crucial for minimizing energy consumption in heating and cooling components, thereby enhancing the driving range of Battery Electric Vehicles (BEVs). This study presents a holistic approach for developing an Integrated Thermal Management System (ITMS) based on an Octo-valve-type architecture, designed to efficiently manage the thermal demands of both the cabin and powertrain components. Empirical data were collected under various heating and cooling scenarios across a wide operating temperature range (−20 °C to 40 °C), and these data were used to parametrize and validate key ITMS components. Experimental results demonstrated that the parametrized simulation model closely replicated the cabin and battery thermal behavior observed in vehicle tests, particularly under cooling conditions. Minor deviations, such as cabin temperature overshoot during heating scenarios, were attributed to duct thermal effects and control tuning limitations. Overall, the optimized Octo-valve-based ITMS architecture exhibited thermal trends consistent with literature references and effectively validated the proposed control strategy, demonstrating improved thermal efficiency and potential range enhancement for BEVs across diverse environmental conditions. Furthermore, ITMS energy consumption over the indicated temperature range is quantified in this research paper. Full article

This work proposes the design, construction, and field test of a vacuum seawater desalination system (VSDS) driven by an evacuated tube solar collector (with a total absorption area of 1.86 m²) under tropical climatic condition (Thailand ambient at latitude 13°43′06.0″ N, longitude 100°32′25.4″ E). The VSDS prototype was designed and constructed to be driven by hot water, which is produced by two heat source conditions: (1) an electric heater for laboratory tests and (2) an evacuated tube solar collector for field tests under real climatic conditions. A comparative experimental study to assess the ability to produce fresh water between a conventional dripping/pipe feed column and spray falling film column is proposed in the first part of the discussion. This is to demonstrate the advantage of the spray falling film distillation column. The experimental method is implemented based on the batch system, in which the cycle time (distillation time) considered is 10–20 min so that heat loss via the concentrated seawater blow down is minimized. Later, the field test with solar irradiance under real climatic conditions is demonstrated to assess the freshwater yield and the system performance. The aim is to provide evidence of the proposed vacuum desalination system in real operation. It is found experimentally that the VSDS working with spray falling film provides better performance than the dripping/pipe feed column under the specified working conditions. The spray falling film column can increase the distillated freshwater volume from 1.33 to 2.16 L under identical cycle time and working conditions. The improvement potential is up to 62.4%. The overall thermal efficiency can be increased from 33.7 to 70.8% (improvement of 110.1%). Therefore, the VSDS working with spray falling film is selected for implementing field tests based on real solar irradiance powered by an evacuated tube solar collector. The ability to produce fresh water is assessed, and the overall performance via the average distillation rate and the thermal efficiency (or Gain Output Ratio) is discussed with the real solar irradiance. It is found from the field test with solar time (8.00–16.00) that the VSDS can produce a daily freshwater yield of up to 4.5 L with a thermal efficiency of up to 19%. The freshwater production meets the requirement for international standard drinking water criteria, indicating suitability for household/community use in tropical regions. This work demonstrates the feasibility of VSDS working under real solar irradiance as an alternative technology for sustainable fresh water. Full article

In this study, the thermomechanical behavior of a variable cross-section rod with fixed ends is studied using an analytical method. A rod with a radius that varies quadratically with length is considered, and it is thermally insulated on its side surface. Heat flow is applied to the left end of the rod, and heat exchange with the environment occurs at the right end. Based on the obtained temperature distribution, the thermal strains, stresses, displacements, and total elongation are determined. The results highlight the influence of boundary thermal conditions on the thermomechanical response of the rod, which is of interest for the design and analysis of structural elements operating under conditions of uneven thermal stress. Full article

The low thermal conductivity of phase-change materials (PCMs) remains a key limitation in latent heat thermal energy storage systems, leading to slow melting and incomplete energy recovery. To address this challenge, this study explores extended Y-Fin geometries as a novel heat transfer enhancement strategy within a concentric-tube latent heat thermal energy storage configuration. Six fin designs, derived from a baseline Y-shaped structure, were numerically compared to assess their influence on the melting and solidification behavior of stearic acid. A two-dimensional transient enthalpy–porosity model was developed and rigorously verified through grid, temporal, and residual convergence analyses. The results indicate that fin geometry plays a critical role in enhancing heat transfer within the PCM domain. The extended Y-Fin configuration achieved the fastest melting time, 28% shorter than the baseline Y-Fin case, due to improved thermal penetration and bottom-region accessibility. Additionally, the thermal performance was evaluated using nano-enhanced PCMs (10% Al₂O₃ and CuO in stearic acid) and paraffin wax. The addition of Al₂O₃ nanoparticles significantly improved thermal conductivity, while paraffin wax exhibited the shortest melting duration due to its lower melting point and latent heat. This study introduces an innovative fin architecture combining extended conduction paths and improved convective reach for efficient latent heat storage systems. Full article