Abstract
In this paper, we study the simple shear flows of a class of dilatant fluids with a limited shear rate. This class of fluids is characterized by shear thickening behavior in which the apparent viscosity tends to infinity as the modulus of the stress approaches a finite threshold. The apparent viscosity function is a logarithmic type with two material parameters. We considered this specific form because it fits very well with the flow curves of some granular suspensions for specific values of the material parameters. Despite the nonlinearity of the constitutive law, it is possible to determine explicit steady-state solutions for a simple shear flow, namely (i) the channel flow; (ii) the flow between coaxial cylinders, and (iii) the flow down an inclined plane. We performed a two-dimensional linear stability analysis to investigate the onset of possible instabilities of the steady basic flow, putting into evidence the dependency of the critical Reynolds number on the material parameters.
1. Introduction
Shear thickening (or dilatant) fluids are part of a special class of non-Newtonian fluids in which the viscosity increases with the shear rate. One of the first investigations on shear-thickening fluids is probably the one by Metzner and Whitlock [1] who studied a suspension of titanium dioxide (TiO) particles in water. They showed that the relation between the shear stress and the shear rate is nonlinear with the apparent viscosity that grows with the increasing shear rate. For the elevated TiO volume fraction, the stress curve appears to almost diverge as the shear rate increases. The most dramatic scenario of this type of behavior is that of discontinuous shear thickening (DST), where viscosity becomes infinite for a finite value of the shear rate and the material goes from fluid-like to solid-like, see [2,3,4].
In the recent past, many works have investigated the nature of shear-thickening and DST fluids, see [5,6,7,8]. In particular, the crucial effects of frictional contact forces (in the framework of jamming transition) on the shear-thickening behaviors of the fluid have been observed. As observed in [9], the scale of the stress (where the stress–shear rate constitutive law starts to show large growth) can be attributed to the interfacial tension forces, which increase abruptly due to the dramatic constraint of jamming.
In general, dense mixtures of granules and liquids behave as dilatant fluids, a classical example being cornstarch and water. Some fluids, such as high-concentration suspensions, insoluble polymer systems, clay, and quicksand display shear-thickening behaviors [10]. Although a large majority of fluids exhibit pseudo-plastic (or shear-thinning) behaviors [11], shear-thickening fluids are also ubiquitous in a variety of practical applications, from damping devices to machine mounts, as well as in the manufacturing of body armor [12], where the shear-thickening properties are exploited to dampen the impacts of a bullet.
Regarding the counterintuitive behaviors of dilatant fluids, one can search the web for a video of one running on a pool filled with cornstarch and water as if it was an actual rigid surface, but sinking into it when walking or standing still. At the microscopic level, experiments have shown that dense suspensions are basically frictionless for low confining pressure, while the transition from low to high friction occurs with normal stress near the critical stress, see [13].
The constitutive law of a shear-thickening fluid is commonly represented by a function in which the shear stress is expressed as a function of the shear rate and in which the first derivative of that function increases with the shear rate. The most common example is that of power law dilatant fluids, where the apparent viscosity is a given positive power of the shear rate modulus. In the latter model, any arbitrarily large value of the shear rate can be attained if a sufficiently large shear stress is applied (the strain is not limited). This type of model is not appropriate when one considers a dilatant fluid in which the flow behavior is similar to that of a discontinuous shear-thickening fluid. In this case, we may consider a constitutive law in which there is a critical value to which the shear rate tends when the stress becomes infinite (limited strain model), see [4,14].
A very basic limited strain model is the one considered in [4] for a system formed by a mass, a dashpot, and an inextensible string; see Figure 1a. If the string is not completely extended, the response of the system is that of a Newtonian fluid, but when the string becomes fully extended, the response is that of a rigid body (the applied force produces no deformation). The constitutive relation is, thus, the one shown in Figure 1b, which can be seen as the “dual” of the Bingham constitutive law (the fluid flow only if the applied stress is below a certain threshold). The one-dimensional unsteady channel flow of a fluid with the constitutive law, as shown in Figure 1b, was studied in [4].
Figure 1.
String-dashpot system (a) and constitutive law (b).
Let us suppose that the fluid is incompressible so that the Cauchy stress tensor can be written (in the paper, the starred quantities are always dimensional) as , where is the Lagrange multiplier due to the incompressibility constraint and is the deviatoric part of the stress. The constitutive equation for a Newtonian fluid with a limited shear rate can be seen in [4,14].
where is the viscosity ( Pa·s), is the critical shear stress ( Pa), and is the critical shear rate ( s). The quantities
represent the norm of the deviatoric part of the stress and the symmetric part of the velocity gradient , respectively. Looking at Figure 1b, it is evident that if we plot vs. , we obtain a graph (the stress is not determinate for ); hence, it is more natural to express vs. , so that the relation is an actual function (see [15] for a discussion on the material defined by implicit constitutive equations).
Relation (1) has a singularity in the first derivative at , which can be smoothed if one takes, for instance,
where the effective viscosity is given by
The constitutive relation (2), (3) was selected because it fits the experimental flow curves of dense suspensions, see [1,16].
In Figure 2, we plotted the relation (2), taking the norms on both sides. We normalized with and with . The parameter has the dimension of the inverse of the pressure, while the dimension of is that of a shear rate. In Figure 3, we plot the effective viscosities (3) for some values of and with . The ranges for these values are consistent with the experimental data of [16]. We notice that for sufficiently large values of , the constitutive behavior of the fluid is similar to that of an inviscid fluid (the effective viscosity is nearly zero almost everywhere in the range ) except for a small boundary layer near the critical value , where the viscosity becomes arbitrarily large (rigid body behavior). The behaviors of the fluids for small values of are similar to those of Newtonian fluids with constant viscosity
Hence, parameters and determine the “almost constant” viscosity of the fluid for small shear rates, whereas is the limiting value for the shear rate.
Figure 2.
Constitutive law (2) in which the shear rate is normalized with and the shear stress with .
The behaviors of parameters and with the particle concentration are related to the shear-thickening effects due to the particle concentrations. From [1,16], it is evident that the parameter is a decreasing function of . This is physically consistent since the limiting shear rate increases if the particle’s volume fraction decreases because the frictional effects between particles become less pronounced. The same is true for as the apparent viscosity (which is proportional to ) must decrease as the volume fraction decreases. The exact dependencies of the parameters and on will surely involve some material constants that take into account the particular suspension considered. The definition of such a dependency is beyond the scope of this paper and certainly would require more experimental data.
The constitutive law (3) does not take into account the possibility that the slope of the constitutive curve may start to decrease after a certain value of the shear stress. In practice, it does not allow one to consider the S-shaped behavior exhibited by the suspension. Here, we are only interested in the range of stresses for which the slope of the shear stress shear rate curve is monotonically increasing and tends to be infinite, such as the ones of [1,16].
Figure 3.
Plot of the effective viscosity given in (3) as a function of the shear rate for different values of and . The values of these parameters are taken from [16].
In this work, we consider the responses of types (2) and (3) since we have seen that they describe quite well the experimental flow curves of some dense suspensions. In particular, we consider Figure 4 and Figure 5, in which and are selected to fit the experimental curves of two types of suspensions, namely a TiO suspension in Figure 4 and a cornstarch suspension in Figure 5. The experimental data in Figure 4 and Figure 5 are taken from [1,16] respectively. This paper is devoted to the study of some simple shear flow of fluid with a constitutive law of types (2) and (3). In particular, we focus on three types of flow, i.e., (i) planar channel flow; (ii) the flow between coaxial cylinders; and (iii) the flow down an inclined plane. Despite the nonlinearity of (3), we shall see that in all geometrical settings considered in this paper, it is always possible to determine an analytical steady-state solution. For each problem, the flow equations are scaled appropriately so that the velocity field can be expressed in terms of the Reynolds number and other non-dimensional material (i.e., not depending on the flow) parameters. Because of the boundedness of the shear rate, in some geometrical settings, the Reynolds number happens to be bounded, meaning that the range of velocities that can be attained by increasing the force that drives the motion is limited. This is consistent with the shear thickening and limited strain nature of the fluid, where friction forces between layers (viscosity) grow with the shear stress, preventing the velocity from increasing unboundedly. Models of types (2) and (3) are useful because one can explicitly determine the velocity and stress profiles in the simple flow, but also because they allow approximating the DST models by avoiding the intrinsic singularities in the constitutive equations.
Figure 4.
Flow curve (shear stress vs. shear rate) for TiO suspension (47%), see Figure 2 in [1]. Experimental data (stars) and fitting curve (continuous). Fitting parameters (ft/lbr), s.
Figure 5.
Flow curve (shear stress vs. shear rate) for the cornstarch suspension (50%), see Figure 1 in [16]. Experimental data (stars) and fitting curve (continuous). Fitting parameters (Pa), s.
In addition to determining the steady-state solutions of the basic flow, we performed a modal stability analysis to investigate the onset of possible instabilities. In the flow considered here, the critical Reynolds number is an increasing function of both and . Looking at Figure 3, we may explain this behavior by observing that the increase of (this is also true for the increase of ) results in the formation of boundary layers with high viscosity near the rigid walls that tend to stabilize the flow. This type of behavior has also been put into evidence in a recent paper [17] for the stress power-law fluids.
The paper is organized as follows. In Section 2, we derive the mathematical formulation of the problem and focus on (i) planar channel flow; (ii) the flow between coaxial cylinders; and (iii) the flow down an inclined plane. In Section 3, we perform the linear stability analysis for the above-mentioned simple flow. The last section is devoted to conclusions and perspectives.
2. The Mathematical Model
Let us consider the following constitutive equation
and let us rescale the dimensional variables with
Introducing the quantities and , we write the non-dimensional mass and momentum balance (neglecting body forces) as
where is the Reynolds number. The non-dimensional constitutive equation becomes:
We notice that b and are related by
where is a non-dimensional material parameter (it does not depend on the flow). From [1,16], we know that typically .
2.1. Channel Flow Driven by a Pressure Gradient
Let us consider problems (8) and (9) for a fluid flowing in a planar channel of length and constant width driven by a pressure gradient . For simplicity, here we assume that , but minor changes allow one to consider the cases in which they are different. In this situation, it is natural to select and . We look for a stationary solution of problem (8) in the form , , so that the incompressibility constraint is automatically satisfied. The problem becomes
We immediately realize that
Integrating once more with the no-slip boundary conditions , we have
which provides the velocity profile in the whole domain. We may select the characteristic velocity so that the velocity of the fluid in the centerline is 1. Imposing , we find
where is the zero branch of the Lambert function, see [18]. Relation (15) is equivalent to setting
As one can easily realize, the increase of the pressure drop is equivalent to the increase in the characteristic velocity , but since the shear rate is limited, the velocity is bounded from above (it cannot become arbitrarily large). Indeed, for , we have , so that , no matter how strong the applied pressure drop is. We notice that
From the inequality in (17), we realize that the Reynolds number is bounded for this type of flow since from relation (16), the velocity . In particular, and are functions of the Reynolds number. Inserting (15) into (14), and rearranging, we finally find the velocity field expressed in terms of the Reynolds number
In Figure 6, we show the velocity profile (18) for , with . We observe that the velocity profile assumes a wedge-like shape as approaches the limit value .
Figure 6.
Velocity profiles (18) for various , .
We observe that
Hence, is a monotonically increasing function of . This is physically consistent since an increase in the value of means a decrease in the apparent viscosity, i.e., less resistance to the flow and, hence, a larger value of , which is always bounded by . Notice that is a function of . Hence, if increases, also increases. For the other types of flow that will be studied in the next sections, we can make analogous considerations.
2.2. Flow between Coaxial Cylinder
In this section, we consider the flow between coaxial cylinders with inner and outer radii and , respectively. Without loss of generality, we may assume that the inner cylinder is fixed whereas the outer cylinder rotates anticlockwise with angular velocity . Distance is scaled with , velocity is rescaled with , and pressure is rescaled with . Exploiting cylindrical coordinates, we look for a steady solution of the type:
The only non-zero component of the deviatoric stress tensor is . Introducing the angular velocity , it is easy to see that
where and where , since the non-dimensional angular velocity w must be an increasing function of r ranging between 0 (inner cylinder) and 1 (outer cylinder). Therefore,
The mass balance is automatically satisfied, while the momentum balance is reduced to
Integrating the second of (22), we find
with c being a positive constant to be determined. Integrating between and 1, we find (recall and )
where
is the exponential integral. Equation (24) allows one to determine the constant c. Indeed let us rewrite (24) as
The integrand function can be rewritten as
so that
Hence, and since
we obtain
Therefore, . Finally, we observe that , so that is a positive strictly increasing function of c bounded between 0 and . The existence of a solution to (24) (or equivalently (25)) is, thus, guaranteed if , i.e., if
Recalling that , we see that the existence of the solution is guaranteed if
In conclusion, the Reynolds number is limited for this type of flow. Once c is determined, the solution to the problem becomes
where c is the unique solution of (24). From (23), we see that , so the stress in (21) is well-defined. In Figure 7, we show the angular velocities for different values of with , , and with , satisfying (30).
Figure 7.
Angular velocity (31) for various , , .
2.3. Flow down an Inclined Plane
In this section, we focus on the flow down an inclined plane whose tilt angle with the horizontal direction is . We assume that the flow is uniform in the direction so that , and we denote with the upper free surface. We take a reference system , where the axis represents the bottom plane and its normal direction. Rescaling as in the previous section, and assuming that the flow is driven by gravity, the motion equation is
where
is the Froude number. We suppose that the fluid is surrounded by a motionless ambient gas so that, neglecting the surface tension on , we can write the non-dimensional free boundary conditions as
The first two relations express the continuity of the normal and tangential stresses, respectively (dynamic conditions), while the last is a consequence of the fact that is a material surface (kinematic condition). We look for a solution of the types and , so that , and
The constant is a material parameter. The dynamic boundary conditions for the stress reduce to (the external pressure is rescaled to zero), on , while the kinematic boundary condition is automatically satisfied. The no-slip conditions on the bottom plane are and . Integration of linear momentum yields
where . After some calculation, we find
and
The thickness h of the fluid is unknown and can be determined by imposing the inlet non-dimensional flux , where is the dimensional discharge. Exploiting (38), we have
Hence, with , , . As a consequence, for any positive given Q, there exists a unique h, satisfying (39). We may select , so that the maximum velocity, which is attained at , is equal to one. From (38), setting , we find
where is again the zero branch of the Lambert function. Substituting (40) into (38), we find
Recalling that , we finally write the velocity profile for the flow down an inclined plane as
Figure 8.
Velocity (42) for various , , , . Flow down an incline.
We observe that, in this case, no limitation on is present. Indeed, from (40), we see that the increase of results in an increase in h, i.e., in practice, the height of the fluid layer can adapt to the imposed discharge.
3. Linear Stability Analysis
In this section, we consider two-dimensional perturbations of the basic solutions determined in the previous sections. In particular, let denote any of the steady solutions found in the previous sections. We write
so that is the sum of the basic function and the perturbation , where is the complex wave amplitude, is the wavenumber, c is the complex wave velocity, and we assume that , . The stress tensor can be decomposed as
The above can be linearized (neglecting terms of order and higher) to obtain
so that is linear in .
3.1. Channel Flow
In the two-dimensional setting, we have
In the context of channel flow, we find
where we indicated with the basic solution (18). The perturbed momentum equation is
Substituting (47), (48) into (49), we obtain the perturbation equation for
where and are defined in Equations (47) and (48), respectively. The boundary conditions are . Equation (50) is solved via a spectral collocation method based on Chebyshev polynomials. Notice that because of the particular constitutive equation considered here, the classical Orr–Sommerfeld equation cannot be recovered from (50). In Figure 9, we plot the neutral stability curves for some values of , while in Figure 10, we display the critical Reynolds number as a function of the parameter . Notice that the critical Reynolds number is always below the limit , which is the upper bound of , see Section 2.1. In particular, we observe that the deviation of from the limit value increases with .
Figure 9.
Neutral stability curves in the plane, channel flow. .
Figure 10.
Critical Reynolds number vs. : channel flow. Notice that the discrepancy between the and the upper bound increases with .
3.2. Taylor–Couette Flow
Here, we study the linear stability of the flow between coaxial rotating cylinders. In this case, the perturbed velocity is , where
is the complex amplitude of the perturbation of the velocity, where is the basic tangential velocity and where is the angular velocity given in (31). We are, thus, considering an axisymmetric perturbation (there is no dependence on the azimuthal coordinate ). The components of the symmetric part of the perturbation velocity gradient are
where the prime now stands for differentiation with respect to r, i.e., . The linearized momentum equation for the perturbations are
From the continuity equation, we find
The linearized constitutive Equation (45) in the cylindrical coordinates becomes
from which we derive
where
The eigenvalue problem is coupled with boundary conditions and . Problem (61) is solved by a spectral collocation method based on Chebyshev polynomials (the spatial domain is mapped in the interval ). In Figure 11, we plot the neutral stability curves for some values of . In Figure 12, we show the critical Reynolds number as a function of the parameter . Notice that the critical Reynolds number is always below the limit . In particular, we observe that the deviation of from the limit value increases with as in the channel flow.
Figure 11.
Neutral stability curves, the flow between rotating cylinders. .
Figure 12.
Critical Reynolds number vs. : flow between rotating cylinders. Notice again the discrepancy between and the upper bound as increases.
3.3. Flow down an Inclined Plane
In this section, we study the linear stability of the downhill flow presented in Section 2.3. The perturbed variables are in the form (43) and the equation for the perturbation is still (50), the spatial domain being , with given in (42). Introducing the perturbed free surface
we check that the linearized boundary conditions (32)–(34) become:
The pressure term in (62) can be written in terms of exploiting the first component of the linearized momentum equation for the perturbation, namely
with , given by (47), (48). Using (65), and eliminating from (62), (63) we find that
Conditions (66), (67), together with the no-slip conditions
provide the boundary conditions for the perturbation . In conclusion, the eigenvalue problem for the stability of the flow down an inclined plane is given by Equation (50)—in the domain -and the boundary conditions (66)–(68). The complex values of the parameter c that produce a non-trivial solution give the relation between the basic flow and the evolution of the disturbance modes. In particular, when the growth rate of the disturbance is positive, the amplitude of the disturbance becomes unbounded and the system is unstable. Here, we limit our analysis to the so-called long-wave analysis, i.e., we assume that , so that the solution can be sought in the form of expansion in powers of ,
Inserting the expansion above in the eigenvalue problem and grouping the terms of the same order, we obtain a sequence of eigenvalue problems that can be solved iteratively. In particular, it can be proved that the problem at the zero order is given by
Problem (69) is solved by
from which we immediately see that . We notice that the general eigenvalue problems (50), (66), (67), (68) are homogeneous, so that the solution is defined up to a multiplicative constant. Following the procedure used in [19], we select such a constant so that , implying for . The problem with the first order is, therefore,
Integration of (71) gives functions in which the dependencies on the integration constants are linear. The impositions of the five BCs (71)–(71) lead to a linear system whose solution provides the constants , and the eigenvalue . The calculation for the determination of the eigenvalue was checked using the symbolic software wx Maxima. We obtain
where , are functions of the parameters b, , , , , . In particular, is a pure real number (the imaginary part is zero), so that is a pure complex number. For the sake of brevity, we did not report their expressions, which are quite lengthy. In the long wavelength expansion, of the first order, we take , so that the growth rate of the amplitude disturbance is
In Figure 13, we plot the approximation of the marginal stability curves (valid for small ) for , and with . These are clearly vertical straight lines in the plane that provide the critical Reynolds above which we have instability. The dependency of the critical Reynolds number as a function of is depicted in Figure 14.
Figure 13.
First-order approximation of the neutral stability curves, downhill flow. , , .
Figure 14.
Critical Reynolds number vs. the downhill flow. , .
As observed in Section 2.3, here we have no limitation of the Reynolds number, since the quantity is not limited. We notice that the critical Reynolds for the flow down an incline is, in general, much smaller than in the other two cases considered earlier. This is due to the fact that the channel flow and the flow between concentric cylinders are wall-bounded, while the flow down an incline has a free surface. Indeed, it is well known that in the wall-bounded flow, we may have the development of boundary layers that tend to stabilize the flow, see [20]. Furthermore, the discrepancy between the critical Reynolds number of the channel flow (or Taylor–Couette flow) and the flow down an incline is evident even in the case of a Newtonian fluid. For instance, in the channel flow of a Newtonian fluid driven by a pressure drop (and in the free flow down an incline), the critical Reynolds is given by the relation, see [21]
for an angle of (as the one I have considered in the paper) gives . Finally, we remark that the critical Reynolds numbers for the free surface flow are in the same range as those obtained in [22].
4. Conclusions and Perspectives
We investigated a simple shear flow of a class of dilatant fluids in which the modulus of the deviatoric stress diverges as the modulus of the shear rate tensor tends to a finite positive value. For convenience, these fluids have been termed dilatant fluids with a limited shear rate. The constitutive equation is given by a logarithmic function with two material parameters, and , representing the characteristic apparent viscosity and the shear rate threshold, respectively. The motivation for choosing such a specific form for the apparent viscosity is that it fits (for appropriate values of and ) the flow curves of granular suspensions. The adopted constitutive equation can be viewed as a regularization of a discontinuous shear-thickening constitutive law, such as the one depicted in Figure 1b. Despite the nonlinearity of the apparent viscosity, we are able to determine steady-state solutions for some simple shear flow types. In particular, we considered the (i) planar channel flow, (ii) the flow between concentric cylinders, and (ii) the flow down an inclined plane. In the first two cases, we have shown that the Reynolds number cannot exceed a certain threshold that depends on the material parameters. This seemingly weird behavior is explained; the increase in the velocity automatically increases the resistance opposed to the flow by the increasing viscosity. In this mechanism, the acceptable velocities experienced by the fluid cannot exceed a fixed threshold. In particular, we proved that the limit threshold for the Reynolds number is an increasing function of and . To investigate the response of the basic steady-state flow to disturbances, we also performed a two-dimensional modal stability analysis for each of the three simple flow types considered. In cases (i) and (ii), the corresponding eigenvalue problems were solved by means of a spectral collocation method based on Chebyshev polynomials, allowing us to plot the neutral stability curves and detect the critical Reynolds number. For the case of the flow down an inclined plane, we limited our analysis to long-wave disturbances (i.e., small wave numbers), explicitly determining the critical Reynolds number. For the three simple shear flow types considered, we found that the critical Reynolds number is an increasing function of and . This proves that when the limit shear rate threshold is increased, or when the apparent viscosity is decreased, the fluid can be stable for a larger range of Reynolds numbers.
A natural continuation of this work would be (i) the extension to some other simple shear flow; (ii) the analysis of the flow in small-aspect ratio geometries (e.g., lubrication flow); (iii) the investigation of the effects of three-dimensional disturbances and the verification of the validity of Squire’s theorem, which is not automatically valid for non-Newtonian flow. All of these issues are currently under investigation and will be the subject of a forthcoming paper.
Funding
This research received no external funding.
Data Availability Statement
Not applicable.
Acknowledgments
This research was partially supported by the GNFM of the Italian INDAM.
Conflicts of Interest
The author declares no conflict of interest.
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