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Inorganics, Volume 3, Issue 1

March 2015 - 5 articles

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Articles (5)

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Article

9 Citations

8,952 Views

15 Pages

Disulfide Competition for Phosphine Gold(I) Thiolates: Phosphine Oxide Formation vs. Thiolate Disulfide Exchange

Gamage S. P. Garusinghe,
S. Max Bessey,
Mostapha Aghamoosa,
Meaghan McKinnon,
Alice E. Bruce and
Mitchell R. M. Bruce

Inorganics2015, 3(1), 40-54;https://doi.org/10.3390/inorganics3010040

27 February 2015

Phosphine gold(I) thiolate complexes react with aromatic disulfides via two pathways: either thiolate–disulfide exchange or a pathway that leads to formation of phosphine oxide. We have been investigating the mechanism of gold(I) thiolate–disulfide e...

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Article

9 Citations

6,737 Views

13 Pages

[AuHg(o-C₆H₄PPh₂)₂I]: A Dinuclear Heterometallic Blue Emitter

José M. López-de-Luzuriaga,
Miguel Monge,
M. Elena Olmos and
David Pascual

Inorganics2015, 3(1), 27-39;https://doi.org/10.3390/inorganics3010027

11 February 2015

The heteronuclear AuI/HgII complex [AuHg(o-C6H4PPh2)2I] (1) was prepared by reacting of [Hg(2-C6H4PPh2)2] with [Au(tht)2]ClO4 (1:1) and NaI in excess. The heterometallic compound 1 has been structurally characterized and shows an unusual blue lumines...

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Communication

7 Citations

6,938 Views

6 Pages

A New Nanometer-Sized Ga(III)-Oxyhydroxide Cation

William H. Casey,
Marilyn M. Olmstead,
Caitlyn R. Hazlett,
Chelsey Lamar and
Tori Z. Forbes

Inorganics2015, 3(1), 21-26;https://doi.org/10.3390/inorganics3010021

3 February 2015

A new 30-center Ga(III)-oxy-hydroxide cation cluster was synthesized by hydrolysis of an aqueous GaCl3 solution near pH = 2.5 and crystallized using 2,6-napthalene disulfonate (NDS). The cluster has 30 metal centers and a nominal stoichiometry: [Ga3...

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Editorial

3,922 Views

2 Pages

Acknowledgement to Reviewers of Inorganics in 2014

Inorganics Editorial Office

Inorganics2015, 3(1), 19-20;https://doi.org/10.3390/inorganics3010019

8 January 2015

The editors of Inorganics would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2014:[...]

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Review

51 Citations

9,812 Views

18 Pages

Supramolecular Gold Metallogelators: The Key Role of Metallophilic Interactions

João Carlos Lima and
Laura Rodríguez

Inorganics2015, 3(1), 1-18;https://doi.org/10.3390/inorganics3010001

31 December 2014

Gold metallogelators is an emerging area of research. The number of results published in the literature is still scarce. The majority of these gels is observed in organic solvents, and the potential applications are still to be explored. In this work...

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