Thermal and Kinetic Behaviors during Co-Pyrolysis of Microcrystalline Cellulose and Styrene–Butadiene–Styrene Triblock Copolymer
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Experiments
2.3. Kinetic Method
3. Results and Discussion
3.1. Pyrolysis of Single Component
3.2. Pyrolysis of Mixed Components
3.3. Interaction between MC and SBS
3.3.1. Interaction on the TG Curves
3.3.2. Interaction on the DTG Curves
3.3.3. Interaction Indices
3.4. Kinetic Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Samples | MC | SBS |
---|---|---|
Proximate analysis/wt% | ||
Ash, db | 0.00 | 5.97 |
Volatile matter, daf | 85.66 | 94.03 |
Fixed carbon, db | 14.34 | 0.00 |
Ultimate analysis/wt%, db | ||
C | 42.21 | 81.92 |
H | 6.25 | 11.42 |
O (by difference) | 51.29 | 6.37 |
N | 0.21 | 0.25 |
S | 0.04 | 0.05 |
Material | Conversion (%) | T (°C) | E (kJ/mol) | (kJ/mol) | R2 |
---|---|---|---|---|---|
MC | 20 | 336.2 | 174.8 | 183.3 | 0.9980 |
40 | 345.5 | 183.9 | 0.9999 | ||
60 | 353.0 | 183.8 | 0.9999 | ||
80 | 360.9 | 190.9 | 0.9996 | ||
90MC10SBS | 20 | 337.6 | 185.6 | 184.6 | 0.9990 |
40 | 347.9 | 189.2 | 0.9982 | ||
60 | 356.5 | 184.0 | 0.9997 | ||
80 | 367.9 | 179.7 | 0.9992 | ||
70MC30SBS | 20 | 341.9 | 171.2 | 212.0 | 0.9995 |
40 | 353.8 | 181.3 | 0.9960 | ||
60 | 368.0 | 202.5 | 0.9925 | ||
80 | 454.1 | 292.9 | 0.9952 | ||
50MC50SBS | 20 | 346.8 | 170.0 | 232.6 | 0.9980 |
40 | 363.5 | 188.2 | 0.9990 | ||
60 | 443.7 | 303.3 | 0.9080 | ||
80 | 461.7 | 268.8 | 1.0000 | ||
30MC70SBS | 20 | 356.0 | 135.7 | 224.4 | 0.9936 |
40 | 438.4 | 210.7 | 0.9842 | ||
60 | 452.7 | 254.8 | 0.9999 | ||
80 | 466.5 | 296.5 | 0.9990 | ||
10MC90SBS | 20 | 435.0 | 197.0 | 219.5 | 0.9741 |
40 | 446.7 | 239.2 | 0.9989 | ||
60 | 456.2 | 232.0 | 1.0000 | ||
80 | 467.4 | 210.0 | 0.9990 | ||
SBS | 20 | 438.1 | 263.4 | 281.2 | 0.9999 |
40 | 445.6 | 280.0 | 0.9980 | ||
60 | 454.0 | 284.6 | 0.9956 | ||
80 | 464.5 | 296.8 | 1.0000 |
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Yu, S.; Yang, X.; Zhou, H.; Tan, Z.; Cong, K.; Zhang, Y.; Li, Q. Thermal and Kinetic Behaviors during Co-Pyrolysis of Microcrystalline Cellulose and Styrene–Butadiene–Styrene Triblock Copolymer. Processes 2021, 9, 1335. https://doi.org/10.3390/pr9081335
Yu S, Yang X, Zhou H, Tan Z, Cong K, Zhang Y, Li Q. Thermal and Kinetic Behaviors during Co-Pyrolysis of Microcrystalline Cellulose and Styrene–Butadiene–Styrene Triblock Copolymer. Processes. 2021; 9(8):1335. https://doi.org/10.3390/pr9081335
Chicago/Turabian StyleYu, Shijie, Xiaoxiao Yang, Hui Zhou, Zhongchao Tan, Kunlin Cong, Yanguo Zhang, and Qinghai Li. 2021. "Thermal and Kinetic Behaviors during Co-Pyrolysis of Microcrystalline Cellulose and Styrene–Butadiene–Styrene Triblock Copolymer" Processes 9, no. 8: 1335. https://doi.org/10.3390/pr9081335