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Article

Nanoarchitectonics of Fe-Doped Ni3S2 Arrays on Ni Foam from MOF Precursors for Promoted Oxygen Evolution Reaction Activity

by
Jingchao Zhang
1,*,
Yingping Bu
1,2,
Zhuoyan Li
1,
Ting Yang
1,
Naihui Zhao
1,
Guanghui Wu
1,
Fujing Zhao
1,
Renchun Zhang
1 and
Daojun Zhang
1,*
1
Henan Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, China
2
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
*
Authors to whom correspondence should be addressed.
Nanomaterials 2024, 14(17), 1445; https://doi.org/10.3390/nano14171445
Submission received: 28 July 2024 / Revised: 28 August 2024 / Accepted: 2 September 2024 / Published: 4 September 2024
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Abstract

:
Oxygen evolution reaction (OER) is a critical half-reaction in electrochemical overall water splitting and metal–air battery fields; however, the exploitation of the high activity of non-noble metal electrocatalysts to promote the intrinsic slow kinetics of OER is a vital and urgent research topic. Herein, Fe-doped Ni3S2 arrays were derived from MOF precursors and directly grown on nickel foam via the traditional solvothermal way. The arrays integrated into nickel foam can be used as self-supported electrodes directly without any adhesive. Due to the synergistic effect of Fe and Ni elements in the Ni3S2 structure, the optimized Fe2.3%-Ni3S2/NF electrode delivers excellent OER activity in an alkaline medium. The optimized electrode only requires a small overpotential of 233 mV to reach the current density of 10 mA cm−2, and the catalytic activity of the electrode can surpass several related electrodes reported in the literature. In addition, the long-term stability of the Fe2.3%-Ni3S2/NF electrode showed no significant attenuation after 12 h of testing at a current density of 50 mA cm−2. The introduction of Fe ions could modulate the electrical conductivity and morphology of the Ni3S2 structure and thus provide a high electrochemically active area, fast reaction sites, and charge transfer rate for OER activity.

1. Introduction

In the world today, conventional fossils are increasingly exhausted, and more and more researchers are devoted to developing alternative clean energy to meet increasing human needs [1,2,3,4,5,6,7,8]. Hydrogen energy is considered the most promising clean energy of the future; in all hydrogen preparation technologies, electrochemical water splitting is deemed the most prominent way to acquire green hydrogen [9,10]. Green H2 can be prepared by using the electric energy generated by solar energy and wind energy, which are difficult to connect to the grid. Oxygen evolution reaction (OER) is an anodic half-reaction of water splitting, and OER also plays an important role in oxygen-related energy conversion technologies, such as metal–air batteries and fuel cell fields [11,12,13]. In general, active electrocatalysts are needed to promote the OER process to reduce the high overpotential for the electrocatalytic splitting of water [14,15,16,17,18,19,20]. At present, noble metal compounds such as RuO2 and IrO2 are still effective OER electrocatalysts; however, the high cost and scarce reserves of these state-of-the-art catalysts prevent their widespread application in the future.
Ni3S2 structure is a notable nickel-based sulfide with a hexagonal structure constructed of Ni-Ni metal bonds and has attracted extensive attention in electrocatalytic and energy storage fields ascribed to its high conductivity, good intrinsic electrocatalytic activity, and low cost [21,22]. Although Ni3S2 structure is a promising HER and OER electrocatalyst, which exhibits a similar electrocatalytic OER performance to RuO2, the performance still does not meet the requirements of large-scale commercial applications, and the overpotential of pure Ni3S2 is always high because of its sluggish OER kinetics. Researchers are also devoted to optimizing the synergistic electronic modulation to improve the efficiency of OER. Secondary metal doping is an effective strategy to modulate the electronic Ni3S2 structure. To date, transition metals, including Cr [23], Mn [24,25,26], Cu [27], Co [28], Fe [29,30,31,32], Mo [33], V [34], Sn [35], and Ce [36], have been doped into Ni3S2 structure to enhance the intrinsic activity; especially, the Fe-Ni bimetallic synergistic effect contributed to forming key active intermediates (FeOOH-NiOOH). Through Fe ions, doping can not only adjust the surface electron distribution but also increase the charge transfer kinetics [37,38].
Ni3S2 electrocatalysts with different morphologies usually have been synthesized using the solvothermal way, chemical vapor deposition (CVD), and atomic layer deposition (ALD) technology [22,39]. Metal–organic frameworks (MOFs) assembled by metal nodes and organic ligands can be facilely synthetized, and the morphologies and structures can be easily modulated [40,41]. Therefore, micro-/nano-structured transition metal sulfides (TMSs) can be obtained from MOF precursors via a simple sulfurization conversion strategy; especially, MOFs-derived TMSs may inherit the porous structures and exhibit large surface areas [42,43,44,45].
In this work, Fe-doped-Ni3S2 nanosheet arrays derived from Ni-based MOF precursors as electrode materials were developed. In alkaline solution, the optimized Fe2.3%-Ni3S2/NF electrode exhibits small overpotentials of 233 and 378 mV for OER at 10 and 100 mAcm−2, respectively. Moreover, Fe2.3%-Ni3S2/NF delivers good stability for 12 h at 50 mA cm−2, and the as-prepared electrode also exhibits no obvious current density decay after 1000 cycles in an alkaline solution.

2. Experimental

2.1. Reagents and Materials

Nickel (II) 2,4-pentanedionate (Ni(acac)2, 95%) was purchased from Alfa Aesar (China) Chemical Co., Ltd. (Shanghai China) Ammonium iron (II) sulfate hexahydrate ((NH4)2SO4·FeSO4· 6H2O, ≥99.5%), N,N-dimethylformamide (≥99.5%, DMF), ethylene glycol (≥99.5%), and nickel foam (NF) were all purchased from Sinopharm Chemical Reagent Co., Ltd. (Shanghai China) 1,2,4,5-benzenetetra-carboxylic acid (H4BTEC) (C10H6O8, >98.0%) and thioacetamide (99%, TAA) were purchased from Shanghai Aladdin Biochemical Technology Co., Ltd. (Shanghai China) Ethanol (≥99.7%) was purchased from Tianjin Fuyu Fine Chemical Co., Ltd. (Tianjin China). It is important to note that all chemicals were of analytical grade and used directly in this work.

2.2. Synthesis of Electrocatalysts

Nickel foam (1 × 3 cm2) was soaked in 3 M HCl and acetone for 30 min and then washed by sonication to remove impurities on the surface. The thickness of the nickel foam (NF) is 1.6 mm, and the average pore size is 0.2 mm (Figure S1). The catalyst electrodes were prepared via two-step solvothermal processes. The first step is for the synthesis of MOF precursor containing Ni and Fe metal ions and H4BTEC on NF substrate. The obtained NF covered with MOF was washed with deionized H2O and ethanol and denoted as the FeNi-MOF/NF precursor. The second step is the sulfurization process; considering the low content of Fe ions in FeNi-MOF/NF precursor synthesized in the first step, only Fe0.6%-Ni3S2/NF can be obtained with the absence of Fe ions in the second solvothermal step. However, for the synthesis of the desired electrode with higher Fe ions content from 0.8% to 3.7%, Fe ions must be added extra in the second sulfurization step.

2.2.1. Synthesis of the FeNi-MOF Precursor

At first, 0.2 mmol Ni(acac)2, 0.4 mmol (NH4)2SO4·FeSO4·6H2O, and 0.8 mmol H4BTEC were dispersed in 7 mL DMF, 7 mL ethanol, and 1 mL H2O solution by stirring thoroughly for 30 min. Then, the resulting solution was transferred to a 20 mL vial along with a slice of treated NF, followed by processing at 140 °C for 12 h. After cooling, the obtained sample was repeatedly cleaned with deionized water and ethanol and vacuum-dried at 60 °C overnight. The obtained sample was denoted as FeNi-MOF/NF precursor.

2.2.2. Synthesis of the Fex-Ni3S2/NF

The samples denoted as Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF were prepared by separately dispersive mixing 0.2 mmol TAA with 0, 0.03, 0.06, and 0.12 mmol (NH4)2SO4·FeSO4·6H2O in 4 mL ethanol, 2 mL ethylene glycol, and 1 mL H2O solution under stirring thoroughly for 30 min. Then, the solution and a piece of FeNi-MOF/NF precursor was sealed and heated at 140 °C for 4 h (Scheme 1). After cooling to room temperature, the resulting sample was cleaned three times with deionized water and ethanol and vacuum-dried overnight at 60 °C, and the average mass loading of catalyst was ~1.2 mg cm−2.

2.3. Materials Characterization

The phases of the as-synthesized catalysts were studied by X-ray diffraction (XRD, PANalytical X’ Pert operated at 40 kV and 40 mA) and X-ray photoelectron spectroscopy (XPS, Thermo Scientific K-Alpha, Waltham, MA, USA). Morphologies and elemental distributions of the samples were characterized by scanning electron microscope (SEM, Hitachi SU8010, Tokyo, Japan), transmission electron microscope (TEM, Tecnai G2S-Twin F20, Hillsboro, OR, USA), and SEM equipped with energy dispersive X-ray spectroscopy (EDS) analyzer.

2.4. Electrochemical Measurements

Electrochemical tests were conducted on an electrochemical workstation (CHI 760E) using a standard three-electrode system in an alkaline solution (1 M KOH). Fe-doped Ni3S2/NF electrodes were used as working electrodes directly, avoiding the ink preparation and drop-coating process; Hg/HgO and platinum mesh were used as the reference electrode and counter electrode, respectively. The LSV curve was obtained at a sweep speed of 5 mV·s−1 in the potential range of 0–0.8 V vs. Hg/HgO without IR compensation, the size of the working electrode was tailored into 1 × 1 cm2, and the geometric surface area was used to calculate current density in LSV curves. The Nyquist plots were measured at open circuit potential in the frequency range of 0.1 Hz–1 MHz. The stability test was carried out at a potential of 0.637 V vs. Hg/HgO for 12 h. Multistep chrono-potential and long-term stability measurements were also not compensated for by IR in this work.

3. Results and Discussion

The crystalline structures of the synthesized Ni3S2 were investigated using the powder X-ray diffraction (PXRD) technique. PXRD patterns for the synthesized Fe-doped Ni3S2 electrodes are exhibited in Figure 1. The series of Ni3S2 electrodes with various Fe doping amounts have similar diffraction peaks. The two sharp diffraction peaks located at 2θ of 44.4° and 51.9° in all samples belong to the Ni foam. Other diffraction peaks in the PXRD patterns can match with Ni3S2 (JCPDS No. 044-1418) phase well, and the diffraction peaks located at 21.7, 31.1, 37.8, 49.8, 50.2, and 55.3° were attributable to (101), (110), (003), (113), (211), and (122) crystal planes of rhombohedral Ni3S2. The results suggest that the pure catalyst was successfully prepared. It is worth mentioning that the different amounts of Fe ions doped did not affect the peak intensity of the Ni3S2 phase.
The morphology of MOF precursors growing on NF was detected by scanning electron microscopy (SEM) and is shown in Figure 2. Figure 2 presents the SEM images of the Fe-Ni-BTEC MOF precursors for (a) Ni3S2/NF, (b) Fe0.6%-Ni3S2/NF, (c) Fe0.8%-Ni3S2/NF, (d) Fe3.7%-Ni3S2/NF, and (e,f) different magnifications of Fe2.3%-Ni3S2/NF images. As seen in Figure 2, NF was covered with vertically distributed and irregular MOF nanosheets.
After the second solvothermal sulfurization treatment process (Figure 3), Fex-Ni3S2/NF series electrodes were obtained. However, if only bare Ni foam was vulcanized, the irregular particles could be obtained (Figure 3a). Using the Fe-Ni-MOF-coated Ni foam as a precursor via sulfurization reaction, some branch structures appeared accompanied by a little thinner and rough Ni3S2 nanosheet structure (Figure 3b). The yield of branch structure increases with the additional Fe ions in the sulfurization step (Figure 3c–f). The unique branch structure and rough surface are not only conducive to the exposure of the catalytic active sites but also can further accelerate the electrolyte penetration and OER reaction kinetics. Xu et al. reported that Fe ions substituted Ni ions in the (101) plane of Ni3S2 and decreased the surface energy of the (101) plane [46]. Thus, the introduction of Fe ions in the Ni3S2 lattice will promote the formation of branch morphology, which was supported by the HRTEM results with the exposure of (101) crystallographic planes. SEM-EDX element mapping also confirms the incorporation of Fe ions in Fe2.3%-Ni3S2/NF. The results of Figure 3g–j show that the as-synthesized Fe2.3%-Ni3S2/NF electrode is composed of Ni, Fe, and S elements, and these elements are uniformly distributed.
In order to further determine the content of Fe element in the synthesized samples, EDX testing was performed on the Fex-Ni3S2/NF series samples, and the results are shown in Figure 4. Figure 4a shows the EDX measurement results of Fe0.6%-Ni3S2/NF. During the synthesis of Fe0.6%-Ni3S2/NF, only Fe ions were added during the first solvothermal step, and the second step was normal sulfurization treatment. Although Fe element was added during the first solvothermal process, the test results showed that the amount of Fe ions doped was very small, only 0.6%, compared to the composition of other elements. Therefore, in order to increase the amount of Fe ions doped, a small amount of Fe element was added in the second sulfurization process, with the added content being 5%, 10%, and 20% of the Fe content in the first step, respectively. Figure 4b shows the EDX test with the addition of 5% Fe, and it can be seen that the proportion of Fe element did not significantly increase, only the doped 0.8% Fe element. When 10% and 20% Fe ions were added again in Figure 4c,d, the proportion showed a significant increase, with Fe contents of 2.3% and 3.7%, respectively.
TEM characterization of the Fe2.3%-Ni3S2 sample obtained from NF via ultrasonic stripping was conducted and is shown in Figure 5. The low-magnification TEM image in Figure 5a clearly demonstrates the dendritic structure, the HRTEM image exhibits obvious lattice fringes, and the interplanar spacing of 0.40 nm may be attributed to plane (101) of the pristine Ni3S2 phase.
OER performances of bare Ni foam and the series electrodes, including Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF, with different Fe contents were evaluated in O2-saturated alkaline medium (1.0 M KOH) and are presented in Figure 6. Figure 6a exhibits the LSV curves for OER of series electrodes and the control sample of bare Ni foam. The redox peak shifting to the higher potentials indicated the Fe incorporation in Ni3S2 [47]. Compared with Fe-doped Fex-Ni3S2/NF series electrodes, Ni foam shows the weakest OER performance, Ni3S2/NF shows a small decrease in overpotential at the current density of 10 mA cm−2, and the optimized Fe2.3%-Ni3S2/NF shows the highest activity among the as-prepared electrodes. At a current density of 10 mA cm−2, the Fe2.3%-Ni3S2/NF delivers a small overpotential of 233 mV. The value of overpotential is less than that of NF (η10 = 350 mV), Ni3S2/NF (η10 = 340 mV), Fe0.6%-Ni3S2/NF (η10 = 253 mV), Fe0.8%-Ni3S2/NF (η10 = 267 mV), and Fe3.7%-Ni3S2/NF (η10 = 251 mV), and also can compare to the recently reported electrodes such as F-Ni3S2 (η10 = 239 mV) [48], Fe-Co9S8 NM/NF (η10 = 270 mV) [49], MOF-V-Ni3S2/NF (η10 = 268 mV) [50], Mo-doped Ni3S2 (η10 = 260 mV) [33], Ni3S2/NF-4 (η10 = 242 mV) [51], and Fe7.2%-Ni3S2/NF (η10 = 295 mV) [52] catalysts (Table 1). Compared with the pure Ni3S2/NF in Figure 6a, the Fe element-doped Ni3S2 electrodes have greatly enhanced the activity of OER performances. Further detailed comparison of the overpotentials of series electrodes at 10 and 100 mA cm−2 is revealed in Figure 6b, respectively. Both of the results suggest that incorporating Fe ions into the Ni3S2 host lattice can greatly improve its intrinsic OER catalytic activity. In addition, effective regulation of the doping content of Fe ions has a significant impact on the OER catalytic performance of the as-synthesized Fex-Ni3S2/NF series electrodes.
Figure 6c demonstrates the Tafel slopes of bare Ni foam, Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes, which were derived from LSV curves with values of 80, 95, 79, 78, 66, and 74 mV dec−1, respectively. It can be clearly seen from Figure 6c that the Tafel slope of Fe2.3%-Ni3S2/NF is the smallest among the series samples and suggests its quick OER reaction kinetics. The charge transfer resistance (Rct) collected by electrochemical impedance spectroscopy (EIS) is also used to explore the electron-transfer kinetics of the catalyst. The EIS curves of a series of electrodes obtained under open circuit voltage are shown in Figure 6d. There is the largest solution resistance of pure Ni foam, and the solution resistance decreased effectively via grown Ni3S2 series samples on Ni foam. The semicircle diameter of Fe2.3%-Ni3S2/NF is the smallest among the five electrodes, and its calculated Rct value is 1.57 Ω. As a comparison, the obtained Rct values of Ni foam, Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF are 19.73, 28.59, 2.67, 4.82, and 6.45 Ω, respectively. Ni3S2/NF obtained without Fe-Ni MOF precursor owns the largest Rct value among the electrodes; nevertheless, the Fe-doped series of Ni3S2/NF electrodes synthesized by Fe-Ni MOF precursors display better conductivity. Furthermore, the results suggest that an appropriate amount of Fe ions doping can improve the charge transfer efficiency, which further demonstrates the highest OER activity of Fe2.3%-Ni3S2/NF among the series electrodes.
The electrochemical active surface area (ECSA) can reflect the real OER catalytic activity of the as-prepared samples. Within the non-Faraday region of voltage windows of 0~0.1 V (vs. Hg/HgO), the capacitance of the double electric layer Cdl value was calculated through CV testing with different scan rates. Figure S2 shows the CV curves of the series electrodes at scanning rates ranging from 10 to 100 mV s−1, and Cdl was calculated by the ratio of the scan rate to the equation j = ja − jc at 0.05 V (vs. Hg/HgO). Figure 7a requires the slope of the line obtained after linear fitting of the current density at 0.974 V (vs. RHE) and the measured scan rate, which corresponds to the 2Cdl value of all the samples. The measured Cdl values of Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF are 1.55, 2.20, 2.97, 3.57, and 2.81 mFcm−2, respectively (Figure 7a), which corresponds to the ECSA values of 38.75, 55, 74.25, 89.25, and 70.25 cm2. This result indicates that the ECSA value of Fe2.3%-Ni3S2/NF exhibits the largest electrochemical active surface area among all the five electrodes. The high ECSA value of Fe2.3%-Ni3S2/NF may be related to the incorporation of appropriate Fe ions and their unique morphology. After Fe ions doping, the morphology changes from tightly arranged nanosheets to vertically arranged dendritic structures. The unique morphology and proper Fe ions doping are conducive to exposing more active sites and effectively improving the OER activity.
Stability testing is also a key indicator for estimating the performance of OER electrocatalysts. Multicurrent steps chrono-potentiometric curves of all prepared electrodes were performed and are presented in Figure 7b. Figure 7b exhibited chrono-potentiometric responses at various current densities in the range of 10 mA cm−2 to 100 mA cm−2, and the potential remained unchanged in each increment when increased by 10 mA cm−2 every 500 s, demonstrating that the electrodes have high mass transportation efficiency. The potential of Fe2.3%-Ni3S2/NF in each step is lower than that of other electrodes, indicating that it has good stability under both low and high current density. Figure 7c shows the electrochemical stability test conducted at a constant voltage of 0.637 V (vs. Hg/HgO), and the current density curves of all electrodes showed no significant attenuation after 12 h of testing. LSV curves of the optimized Fe2.3%-Ni3S2/NF electrode before and after stability testing were compared and are shown in Figure 7d, and the polarization curves are almost coincident, further suggesting that Fe2.3%-Ni3S2/NF has excellent stability for OER. As seen from SEM images in Figure S3, the morphology of all Fex-Ni3S2/NF series samples still remained dendritic after long-term stability.
Figure 8 shows the XPS plot of Fe2.3%-Ni3S2/NF before and after stability tests. It can be seen that the position of the Ni/Fe/S peaks has a low-amplitude positive shift (Table S1). The Ni, Fe, and S signals were detected in the survey shown in Figure 8a, indicating the existence of Ni, Fe, and S elements in the Fe2.3%-Ni3S2/NF sample. The Ni 2p peaks in the high-resolution spectrum can be divided into two groups of doublets peaks centered at 852.5 (855.9 eV) and 869.7 eV (873.7 eV), indicating the coexistence of Ni (II) and Ni (III). After the stability test, the peak intensity of Ni (III) increased, indicating that Ni (III) may be the active site during the OER process. In the Fe 2p spectra, the peaks located at 706 and 713 eV corresponded to Fe (II) and Fe (III) orbitals, respectively. Furthermore, the satellite of S 2p located at ~170 eV increased, which indicated the partial oxidation of the S species on Fe2.3%-Ni3S2/NF during the long-term OER stability test process. In addition, the diffraction peaks in the PXRD pattern showed little change after OER stability testing (Figure S4). All the test results of SEM, XPS, and PXRD demonstrate the good stability of the Fe2.3%-Ni3S2/NF electrode and promise its potential practical application in the future.

4. Conclusions

In summary, a series of Ni3S2 dendritic array structures doped with different trace Fe elements on NF were successfully synthesized in this work by the two-step solvothermal method. The catalysts were grown in situ on NF without using any binder and can be directly used as self-supporting electrodes. The optimized Fe2.3%-Ni3S2/NF electrode displayed excellent OER catalytic performance in an alkaline solution. The overpotential of the Fe2.3%-Ni3S2/NF electrode was only 233 mV at a current density of 10 mA cm−2, and the acquired overpotential was also small (378 mV), even at a high current density of 100 mA cm−2, better than many other reported similar electrodes. The corresponding Tafel slope of the electrode was 66 mV dec−1 and revealed fast reaction kinetics. The current density almost did not decay during the stability test for 12 h. The introduction of trace Fe element into Ni3S2 promotes the exposure of active sites by regulating the morphology of the array electrocatalyst, and the synergistic effect between Fe and Ni ions improves the intrinsic activity by combining with the conductive substrate. This work may provide an innovative method for the synthesis of low-cost micro-/nano-structured transition metal sulfide electrocatalysts to enhance OER performances.

Supplementary Materials

The following supporting information can be downloaded at https://www.mdpi.com/article/10.3390/nano14171445/s1, Figure S1: (a) The SEM image of Ni foam, (b) the corresponding pore size distribution; Figure S2: CV curves of series of electrodes at different scan rates; Figure S3: SEM images for series of electrodes after stability tests; Figure S4: PXRD patterns of as-synthesized electrodes after OER stability tests; Table S1: The comparison of XPS peak values before and after the stability tests.

Author Contributions

Author conceptualization, J.Z.; Data curation, Y.B., Z.L. and J.Z.; Formal analysis, D.Z.; Funding acquisition, R.Z.; Investigation, Y.B., F.Z. and D.Z.; Methodology, D.Z. and J.Z.; Project administration, D.Z. and J.Z.; Supervision, D.Z.; Writing—original draft, Y.B., T.Y., N.Z. and J.Z.; Writing—review and editing, G.W., D.Z. and J.Z. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported by the Key Scientific Research Project Plan of Colleges and Universities in Henan Province (No. 22A150002), the Science and Technology Research Project of Henan Province (222102240096), the National Science Foundation of China (No. 21603004, U1604119), and the Program for Innovative Research Team of Science and Technology in the University of Henan Province (18IRTSTHN006).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The raw data supporting the conclusions of this article will be made available by the authors on request.

Conflicts of Interest

The authors declare no conflicts of interest.

References

  1. Zhou, G.M.; Xu, L.; Hu, G.W.; Mai, L.Q.; Cui, Y. Nanowires for Electrochemical Energy Storage. Chem. Rev. 2019, 119, 11042–11109. [Google Scholar] [CrossRef]
  2. Zhang, K.; Han, X.P.; Hu, Z.; Zhang, X.L.; Tao, Z.L.; Chen, J. Nanostructured Mn-based oxides for electrochemical energy storage and conversion. Chem. Soc. Rev. 2015, 44, 699–728. [Google Scholar] [CrossRef] [PubMed]
  3. Chen, X.; Liu, Q.; Bai, T.; Wang, W.G.; He, F.L.; Ye, M.D. Nickel and cobalt sulfide-based nanostructured materials for electrochemical energy storage devices. Chem. Eng. J. 2021, 409, 127237. [Google Scholar] [CrossRef]
  4. Yu, X.Y.; Lou, X.W. Mixed Metal Sulfides for Electrochemical Energy Storage and Conversion. Adv. Energy Mater. 2018, 8, 1701592. [Google Scholar] [CrossRef]
  5. Kulkarni, P.; Nataraj, S.K.; Balakrishna, R.G.; Nagarajua, D.H.; Reddy, M.V. Nanostructured binary and ternary metal sulfides: Synthesis methods and their application in energy conversion and storage devices. J. Mater. Chem. A 2017, 5, 22040–22094. [Google Scholar] [CrossRef]
  6. Yan, D.F.; Mebrahtu, C.; Wang, S.Y.; Palkovits, R. Innovative Electrochemical Strategies for Hydrogen Production: From Electricity Input to Electricity Output. Angew. Chem. Int. Ed. 2023, 62, e202214333. [Google Scholar] [CrossRef]
  7. Chapman, A.; Ertekin, E.; Kubota, M.; Nagao, A.; Bertsch, K.; Macadre, A.; Tsuchiyama, T.; Masamura, T.; Takaki, S.; Komoda, R.; et al. Achieving a Carbon Neutral Future through Advanced Functional Materials and Technologies. Bull. Chem. Soc. Jpn. 2022, 95, 73–103. [Google Scholar] [CrossRef]
  8. Ariga, K. Nanoarchitectonics: The method for everything in materials science. Bull. Chem. Soc. Jpn. 2024, 97, uoad001. [Google Scholar] [CrossRef]
  9. Kweon, D.H.; Jeon, I.Y.; Baek, J.-B. Electrochemical Catalysts for Green Hydrogen Energy. Adv. Energy Sustain. Res. 2021, 2, 2100019. [Google Scholar] [CrossRef]
  10. Mancera, J.J.C.; Manzano, F.S.; Andújar, J.M.; López, E.; Isorna, F. Sun, heat and electricity. A comprehensive study of nonpollutant alternatives to produce green hydrogen. Int. J. Energy Res. 2022, 46, 17999–18028. [Google Scholar] [CrossRef]
  11. Guo, Y.N.; Park, T.; Yi, J.W.; Henzie, J.; Kim, J.; Wang, Z.L.; Jiang, B.; Bando, Y.; Sugahara, Y.; Tang, J.; et al. Nanoarchitectonics for Transition-Metal-Sulfide-Based Electrocatalysts for Water Splitting. Adv. Mater. 2019, 31, 1807134. [Google Scholar] [CrossRef] [PubMed]
  12. Wang, M.; Zhang, L.; He, Y.J.; Zhu, H.W. Recent advances in transition-metal-sulfide-based bifunctional electrocatalysts for overall water splitting. J. Mater. Chem. A 2021, 9, 5320–5363. [Google Scholar] [CrossRef]
  13. Jiang, W.J.; Tang, T.; Zhang, Y.; Hu, J.S. Synergistic Modulation of Non-Precious-Metal Electrocatalysts for Advanced Water Splitting. Acc. Chem. Res. 2020, 53, 1111–1123. [Google Scholar] [CrossRef] [PubMed]
  14. Suen, N.T.; Hung, S.F.; Quan, Q.; Zhang, N.; Xu, Y.J.; Chen, H.M. Electrocatalysis for the oxygen evolution reaction: Recent development and future perspectives. Chem. Soc. Rev. 2017, 46, 337–365. [Google Scholar] [CrossRef]
  15. Zhang, Y.C.; Han, C.D.; Gao, J.; Pan, L.; Wu, J.T.; Zhu, X.D.; Zou, J.J. NiCo-Based Electrocatalysts for the Alkaline Oxygen Evolution Reaction: A Review. ACS Catal. 2021, 11, 12485–12509. [Google Scholar] [CrossRef]
  16. Zhang, K.X.; Zou, R.Q. Advanced Transition Metal-Based OER Electrocatalysts: Current Status, Opportunities, and Challenges. Small 2021, 17, 2100129. [Google Scholar] [CrossRef]
  17. Ding, H.; Liu, H.F.; Chu, W.S.; Wu, C.Z.; Xie, Y. Structural Transformation of Heterogeneous Materials for Electrocatalytic Oxygen Evolution Reaction. Chem. Rev. 2021, 121, 13174–13212. [Google Scholar] [CrossRef]
  18. Yu, M.Q.; Budiyanto, E.; Tüysüz, H. Principles of Water Electrolysis and Recent Progress in Cobalt-, Nickel-, and Iron-Based Oxides for the Oxygen Evolution Reaction. Angew. Chem. Int. Ed. 2022, 61, e202103824. [Google Scholar] [CrossRef]
  19. Du, J.; Li, F.; Sun, L.C. Metal–organic frameworks and their derivatives as electrocatalysts for the oxygen evolution reaction. Chem. Soc. Rev. 2021, 50, 2663–2695. [Google Scholar] [CrossRef]
  20. Jiang, F.; Li, Y.C.; Pan, Y. Design Principles of Single-Atom Catalysts for Oxygen Evolution Reaction: From Targeted Structures to Active Sites. Adv. Mater. 2024, 36, 2306309. [Google Scholar] [CrossRef]
  21. Zhang, Y.; Zhou, Q.; Zhu, J.X.; Yan, Q.Y.; Dou, S.X.; Sun, W.P. Nanostructured Metal Chalcogenides for Energy Storage and Electrocatalysis. Adv. Funct. Mater. 2017, 27, 1702317. [Google Scholar] [CrossRef]
  22. Zhao, Y.; You, J.H.; Wang, L.; Bao, W.T.; Yao, R.Y. Recent advances in Ni3S2-based electrocatalysts for oxygen evolution reaction. Int. J. Hydrogen Energy 2021, 46, 39146–39182. [Google Scholar] [CrossRef]
  23. Hai, Y.; Tao, K.Y.; Dan, H.M.; Liu, L.; Gong, Y. Cr-doped (Co, Ni)3S4/Co9S8/Ni3S2 nanowires/nanoparticles grown on Ni foam for hybrid supercapacitor. J. Alloys Compd. 2020, 835, 155254. [Google Scholar] [CrossRef]
  24. Yang, H.; Yuan, M.W.; Sun, Z.M.; Wang, D.; Lin, L.; Li, H.F.; Sun, G.B. In Situ Construction of a Mn2+-Doped Ni3S2 Electrode with Highly Enhanced Urea Oxidation Reaction Performance. ACS Sustain. Chem. Eng. 2020, 8, 8348–8355. [Google Scholar] [CrossRef]
  25. Du, H.T.; Kong, R.M.; Qu, F.L.; Lu, L.M. Enhanced electrocatalysis for alkaline hydrogen evolution by Mn doping in a Ni3S2 nanosheet array. Chem. Commun. 2018, 54, 10100–10103. [Google Scholar] [CrossRef] [PubMed]
  26. Yu, X.; Xu, S.R.; Liu, X.X.; Cheng, H.; Du, Y.S.; Wu, Q. Mn-doped NiCo2S4 nanosheet array as an efficient and durable electrocatalyst for oxygen evolution reaction. J. Alloys Compd. 2021, 878, 160388. [Google Scholar] [CrossRef]
  27. Li, G.F.; Cui, X.; Song, B.; Ouyang, H.Z.; Wang, K.L.; Sun, Y.M.; Wang, Y.Q. One-pot synthesis of Cu-doped Ni3S2 nano-sheet/rod nanoarray for high performance supercapacitors. Chem. Eng. J. 2020, 388, 124319. [Google Scholar] [CrossRef]
  28. Tong, X.; Li, Y.; Pang, N.; Qu, Y.H.; Yan, C.H.; Xiong, D.Y.; Xu, S.H.; Wang, L.W.; Chu, P.K. Co-doped Ni3S2 porous nanocones as high-performance bifunctional electrocatalysts in water splitting. Chem. Eng. J. 2021, 425, 130455. [Google Scholar] [CrossRef]
  29. Zhang, G.; Feng, Y.S.; Lu, W.T.; He, D.; Wang, C.Y.; Li, Y.K.; Wang, X.Y.; Cao, F.F. Enhanced Catalysis of Electrochemical Overall Water Splitting in Alkaline Media by Fe Doping in Ni3S2 Nanosheet Arrays. ACS Catal. 2018, 8, 5431–5441. [Google Scholar] [CrossRef]
  30. Lim, D.; Oh, E.; Lim, C.; Shim, S.E.; Baeck, S.-H. Fe-doped Ni3S2 nanoneedles directly grown on Ni foam as highly efficient bifunctional electrocatalysts for alkaline overall water splitting. Electrochim. Acta 2020, 361, 137080. [Google Scholar] [CrossRef]
  31. Xie, N.; Ma, D.D.; Wu, X.T.; Zhu, Q.L. Facile construction of self-supported Fe-doped Ni3S2 nanoparticle arrays for the ultralow-overpotential oxygen evolution reaction. Nanoscale 2021, 13, 1807–1812. [Google Scholar] [CrossRef] [PubMed]
  32. Zhang, W.X.; Jia, Q.; Liang, H.; Cui, L.; Wei, D.; Liu, J.Q. Iron doped Ni3S2 nanorods directly grown on FeNi3 foam as an efficient bifunctional catalyst for overall water splitting. Chem. Eng. J. 2020, 396, 125315. [Google Scholar] [CrossRef]
  33. Wu, C.R.; Liu, B.T.; Wang, J.; Su, Y.Y.; Yan, H.Q.; Ng, C.T.; Li, C.; Wei, J.M. 3D structured Mo-doped Ni3S2 nanosheets as efficient dual-electrocatalyst for overall water splitting. Appl. Surf. Sci. 2018, 441, 1024–1033. [Google Scholar] [CrossRef]
  34. Ma, L.Z.; Zhang, K.; Wang, S.; Gao, L.N.; Sun, Y.F.; Liu, Q.Y.; Guo, J.X.; Zhang, X. Vanadium doping over Ni3S2 nanosheet array for improved overall water splitting. Appl. Surf. Sci. 2019, 489, 815–823. [Google Scholar] [CrossRef]
  35. Jian, J.; Yuan, L.; Qi, H.; Sun, X.J.; Zhang, L.; Li, H.; Yuan, H.M.; Feng, S.H. Sn−Ni3S2 Ultrathin Nanosheets as Efficient Bifunctional Water-Splitting Catalysts with a Large Current Density and Low Overpotential. ACS Appl. Mater. Interfaces 2018, 10, 40568–40576. [Google Scholar] [CrossRef]
  36. Gao, W.; Ma, F.Y.; Wang, C.; Wen, D. Ce dopant significantly promotes the catalytic activity of Ni foam-supported Ni3S2 electrocatalyst for alkaline oxygen evolution reaction. J. Power Sources 2020, 450, 227654. [Google Scholar] [CrossRef]
  37. An, W.Y.; Lee, H.; Choi, S.R.; Choi, S.; Cho, H.-S.; Choi, M.; Park, J.-Y. Hierarchically porous Ni foam-supported Co and Sn doped Ni3S2 nanosheets for oxygen evolution reaction electrocatalysts. J. Mater. Chem. A 2023, 11, 5734–5745. [Google Scholar] [CrossRef]
  38. Li, J.Y.; Wang, X.D.; Yi, L.Y.; Fang, C.X.; Li, T.H.; Sun, W.; Hu, W.H. Plasma-assisted rhodium incorporation in nickel–iron sulfide nanosheets: Enhanced catalytic activity and the Janus mechanism for overall water splitting. Inorg. Chem. Front. 2022, 9, 6237–6247. [Google Scholar] [CrossRef]
  39. Liu, Q.; Xie, L.S.; Liu, Z.A.; Du, G.; Asiri, A.M.; Sun, X.P. A Zn-doped Ni3S2 nanosheet array as a high-performance electrochemical water oxidation catalyst in alkaline solution. Chem. Commun. 2017, 53, 12446–12449. [Google Scholar] [CrossRef]
  40. Lin, R.B.; Zhang, Z.J.; Chen, B.L. Achieving High Performance Metal−Organic Framework Materials through Pore Engineering. Acc. Chem. Res. 2021, 54, 3362–3376. [Google Scholar] [CrossRef]
  41. Cai, G.R.; Yan, P.; Zhang, L.L.; Zhou, H.C.; Jiang, H.L. Metal−Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications. Chem. Rev. 2021, 121, 12278–12326. [Google Scholar] [CrossRef]
  42. Wang, H.F.; Chen, L.Y.; Pang, H.; Kaskel, S.; Xu, Q. MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem. Soc. Rev. 2020, 49, 1414–1448. [Google Scholar] [CrossRef]
  43. da Silva, M.I.; Machado, ĺ.R.; Toma, H.E.; Araki, K.; Angnes, L.; Gonçalves, J.M. Recent progress in water-splitting and supercapacitor electrode materials based on MOF-derived sulfides. J. Mater. Chem. A 2022, 10, 430–474. [Google Scholar] [CrossRef]
  44. Liu, X.; Li, Y.Q.; Cao, Z.Y.; Yin, Z.H.; Ma, T.L.; Chen, S.R. Current progress of metal sulfides derived from metal–organic frameworks for advanced electrocatalysis: Potential electrocatalysts with diverse applications. J. Mater. Chem. A 2022, 10, 1617–1641. [Google Scholar] [CrossRef]
  45. Zhang, D.J.; Zhang, X.B.; Bu, Y.P.; Zhang, J.C.; Zhang, R.C. Copper Cobalt Sulfide Structures Derived from MOF Precursors with Enhanced Electrochemical Glucose Sensing Properties. Nanomaterials 2022, 12, 1394. [Google Scholar] [CrossRef]
  46. Sun, S.C.; Ma, F.X.; Li, Y.; Dong, L.W.; Liu, H.; Jiang, C.M.; Song, B.; Zhen, L.; Xu, C.Y. Sulfur Vacancies Promoting Fe-Doped Ni3S2 Nanopyramid Arrays as Efficient Bifunctional Electrocatalysts for Overall Water Splitting. Sustain. Energy Fuels 2020, 4, 3326–3333. [Google Scholar] [CrossRef]
  47. Manso, R.H.; Acharya, P.; Deng, S.Q.; Crane, C.C.; Reinhart, B.; Lee, S.; Tong, X.; Nykypanchuk, D.; Zhu, J.; Zhu, Y.M.; et al. Controlling the 3-D morphology of Ni–Fe-based nanocatalysts for the oxygen evolution reaction. Nanoscale 2019, 11, 8170–8184. [Google Scholar] [CrossRef] [PubMed]
  48. Xu, Q.C.; Chu, M.S.; Liu, M.M.; Zhang, J.H.; Jiang, H.; Li, C.Z. Fluorine-triggered surface reconstruction of Ni3S2 electrocatalysts towards enhanced water oxidation. Chem. Eng. J. 2021, 411, 128488. [Google Scholar] [CrossRef]
  49. Gao, W.K.; Qin, J.F.; Wang, K.; Yan, K.L.; Liu, Z.Z.; Lin, J.H.; Chai, Y.M.; Liu, C.G.; Dong, B. Facile synthesis of Fe-doped Co9S8 nano-microspheres grown on nickel foam for efficient oxygen evolution reaction. Appl. Surf. Sci. 2018, 454, 46–53. [Google Scholar] [CrossRef]
  50. Dong, W.X.; Zhou, H.B.; Mao, B.D.; Zhang, Z.Y.; Liu, Y.S.; Liu, Y.H.; Li, F.H.; Zhang, D.Q.; Zhang, D.X.; Shi, W.D. Efficient MOF-derived V-Ni3S2 nanosheet arrays for electrocatalytic overall water splitting in alkali. Int. J. Hydrogen Energy 2021, 46, 10773–10782. [Google Scholar] [CrossRef]
  51. Zhang, J.F.; Li, Y.; Zhu, T.Y.; Wang, Y.; Cui, J.W.; Wu, J.J.; Xu, H.; Shu, X.; Qin, Y.Q.; Zheng, H.M.; et al. 3D Coral-Like Ni3S2 on Ni Foam as a Bifunctional Electrocatalyst for Overall Water Splitting. ACS Appl. Mater. Interfaces 2018, 10, 31330–31339. [Google Scholar] [CrossRef] [PubMed]
  52. Zhu, Y.; Yang, H.D.; Lan, K.; Iqbal, K.; Liu, Y.; Ma, P.; Zhao, Z.M.; Luo, S.; Luo, Y.T.; Ma, J.T. Optimization of iron-doped Ni3S2 nanosheets by disorder engineering for oxygen evolution reaction. Nanoscale 2019, 11, 2355–2365. [Google Scholar] [CrossRef] [PubMed]
Nanomaterials 14 01445 sch001
Scheme 1. Schematic illustration of the synthetic route of Fe-Ni3S2/NF electrodes.
Scheme 1. Schematic illustration of the synthetic route of Fe-Ni3S2/NF electrodes.
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Figure 1. PXRD patterns of Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes.
Figure 1. PXRD patterns of Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes.
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Figure 2. SEM images of MOF precursors (a) Ni3S2/NF, (b) Fe0.6%-Ni3S2/NF, (c) Fe0.8%-Ni3S2/NF, (d) Fe3.7%-Ni3S2/NF, and (e,f) different magnifications of Fe2.3%-Ni3S2/NF images.
Figure 2. SEM images of MOF precursors (a) Ni3S2/NF, (b) Fe0.6%-Ni3S2/NF, (c) Fe0.8%-Ni3S2/NF, (d) Fe3.7%-Ni3S2/NF, and (e,f) different magnifications of Fe2.3%-Ni3S2/NF images.
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Figure 3. (a–d) SEM images of Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF, respectively. (e,f) SEM images of Fe2.3%-Ni3S2/NF with different magnifications. (g–j) EDX elemental mapping of Ni, Fe, and S.
Figure 3. (a–d) SEM images of Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF, respectively. (e,f) SEM images of Fe2.3%-Ni3S2/NF with different magnifications. (g–j) EDX elemental mapping of Ni, Fe, and S.
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Figure 4. EDX spectra of as-synthesized samples (a) Fe0.6%-Ni3S2/NF, (b) Fe0.8%-Ni3S2/NF, (c) Fe2.3%-Ni3S2/NF, and (d) Fe3.7%-Ni3S2/NF.
Figure 4. EDX spectra of as-synthesized samples (a) Fe0.6%-Ni3S2/NF, (b) Fe0.8%-Ni3S2/NF, (c) Fe2.3%-Ni3S2/NF, and (d) Fe3.7%-Ni3S2/NF.
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Figure 5. (a) TEM and (b) HRTEM image of Fe2.3%-Ni3S2 sample obtained via ultrasonic stripping from Ni foam.
Figure 5. (a) TEM and (b) HRTEM image of Fe2.3%-Ni3S2 sample obtained via ultrasonic stripping from Ni foam.
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Figure 6. The electrochemical performance of series electrodes. (a) LSV curves, (b) comparison of overpotentials at 10 and 100 mA cm−2, (c) Tafel plots, and (d) Nyquist plots.
Figure 6. The electrochemical performance of series electrodes. (a) LSV curves, (b) comparison of overpotentials at 10 and 100 mA cm−2, (c) Tafel plots, and (d) Nyquist plots.
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Figure 7. (a) Cdl values calculated from CV curves. (b) Multistep chronoamperometric curves for Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes with the current density range of 10–100 mA cm−2. (c) OER stability measurements for Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes at a potential of 0.637 V vs. Hg/HgO for 12 h. (d) Comparison of LSV curves of Fe2.3%-Ni3S2/NF before and after stability tests.
Figure 7. (a) Cdl values calculated from CV curves. (b) Multistep chronoamperometric curves for Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes with the current density range of 10–100 mA cm−2. (c) OER stability measurements for Ni3S2/NF, Fe0.6%-Ni3S2/NF, Fe0.8%-Ni3S2/NF, Fe2.3%-Ni3S2/NF, and Fe3.7%-Ni3S2/NF electrodes at a potential of 0.637 V vs. Hg/HgO for 12 h. (d) Comparison of LSV curves of Fe2.3%-Ni3S2/NF before and after stability tests.
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Figure 8. XPS of Fe2.3%-Ni3S2/NF before and after stability tests; (a) survey spectrum, high-resolution spectra of (b) Ni 2p, (c) Fe 2p, and (d) S 2p.
Figure 8. XPS of Fe2.3%-Ni3S2/NF before and after stability tests; (a) survey spectrum, high-resolution spectra of (b) Ni 2p, (c) Fe 2p, and (d) S 2p.
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Table 1. Comparison of OER catalytic activity of Fe2.3%-Ni3S2/NF with other related catalysts.
Table 1. Comparison of OER catalytic activity of Fe2.3%-Ni3S2/NF with other related catalysts.
CatalystsOverpotential (mV)
(j = 10 mA cm−2)		Tafel Slope (mV dec−1)References
Fe2.3%-Ni3S2/NF23366This work
F-Ni3S223936[48]
Fe-Co9S8 NM/NF27070[49]
MOF-V-Ni3S2/NF26899[50]
Mo-doped Ni3S226085[33]
Ni3S2/NF-424276[51]
Fe7.2%-Ni3S2/NF29571[52]
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Zhang, J.; Bu, Y.; Li, Z.; Yang, T.; Zhao, N.; Wu, G.; Zhao, F.; Zhang, R.; Zhang, D. Nanoarchitectonics of Fe-Doped Ni3S2 Arrays on Ni Foam from MOF Precursors for Promoted Oxygen Evolution Reaction Activity. Nanomaterials 2024, 14, 1445. https://doi.org/10.3390/nano14171445

AMA Style

Zhang J, Bu Y, Li Z, Yang T, Zhao N, Wu G, Zhao F, Zhang R, Zhang D. Nanoarchitectonics of Fe-Doped Ni3S2 Arrays on Ni Foam from MOF Precursors for Promoted Oxygen Evolution Reaction Activity. Nanomaterials. 2024; 14(17):1445. https://doi.org/10.3390/nano14171445

Chicago/Turabian Style

Zhang, Jingchao, Yingping Bu, Zhuoyan Li, Ting Yang, Naihui Zhao, Guanghui Wu, Fujing Zhao, Renchun Zhang, and Daojun Zhang. 2024. "Nanoarchitectonics of Fe-Doped Ni3S2 Arrays on Ni Foam from MOF Precursors for Promoted Oxygen Evolution Reaction Activity" Nanomaterials 14, no. 17: 1445. https://doi.org/10.3390/nano14171445

APA Style

Zhang, J., Bu, Y., Li, Z., Yang, T., Zhao, N., Wu, G., Zhao, F., Zhang, R., & Zhang, D. (2024). Nanoarchitectonics of Fe-Doped Ni3S2 Arrays on Ni Foam from MOF Precursors for Promoted Oxygen Evolution Reaction Activity. Nanomaterials, 14(17), 1445. https://doi.org/10.3390/nano14171445

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