Electrochemical Fabrication of Inverse Opals of Silver with Cyanide-Free Electrolytes
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Substrate | Electrolyte | Element | At. % |
---|---|---|---|
glass/ITO/Au | Rhodanic | Ag | 59.2 ± 11.8 |
Si | 11.2 ± 2.2 | ||
Ca | 2.1 ± 0.4 | ||
Al | 2.0 ± 0.4 | ||
In | 8.5 ± 1.7 | ||
Au | 17.0 ± 3.4 | ||
glass/ITO/Au | Sulfitic | Ag | 35.8 ± 2.9 |
Si | 21.4 ± 1.3 | ||
Ca | 4.0 ± 0.1 | ||
In | 13.3 ± 0.6 | ||
Au | 25.5 ± 1.0 |
Substrate | Electrolyte | Binding Energy, eV (Ag 3d5/2) | Valence State of Ag | At. % (of All States of Ag) |
---|---|---|---|---|
glass/ITO | Rhodanic | 368.0, 368.4 | Ag | 68.3 |
entry 2 | data | 368.6 | Ag (I) (Ag2S) | 31.7 |
glass/ITO/Ag | Rhodanic | 368.1, 368.5 | Ag | 43.3 |
368.8 | Ag (I) (Ag2S) | 56.7 | ||
ITO/glass | Sulfite | 368.1 | Ag | 50.0 |
368.7 | Ag (I) (Ag2S) | 33.3 | ||
367.8 | Ag (I) (Ag2SO4) | 16.7 | ||
Ag/ITO/glass | Sulfite | 368.2, 368.3 | Ag | 40.0 |
368.8 | Ag (I) (Ag2S) | 43.3 | ||
367.9 | Ag (I) (Ag2SO4) | 16.7 |
Name | Ag-1 | Ag-2 | Ag-3 | Ag-4 | Ag-5 |
---|---|---|---|---|---|
Electrolyte | Rhodanic | Rhodanic | Rhodanic | Rhodanic | Sulfitic |
dexp, nm | 247 ± 19 | 256 ± 35 | 385 ± 55 | 263 ± 16 | 249 ± 17 |
D, nm | 340 ± 15 | 340 ± 15 | 440 ± 20 | 350 ± 30 | 350 ± 30 |
Charge, mC - | −16 | −211 | −181 | −11 | −133 |
Theoretical w = ttheor/D | 0.2 | 0.5 | 1 | 0.7 | 0.7 |
Experimental w = texp/D | 0.2 | 0.2 | 0.7 | 0.8 | 0.9 |
Δw/wtheor * (Δw = |wtheor − wexp|) | 0 | 0.6 | 0.3 | 0.14 | 0.29 |
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Arabov, R.I.; Komarova, M.Y.; Astafurov, M.O.; Knotko, A.V.; Maslakov, K.I.; Savilov, S.V.; Grigorieva, A.V. Electrochemical Fabrication of Inverse Opals of Silver with Cyanide-Free Electrolytes. Metals 2022, 12, 2042. https://doi.org/10.3390/met12122042
Arabov RI, Komarova MY, Astafurov MO, Knotko AV, Maslakov KI, Savilov SV, Grigorieva AV. Electrochemical Fabrication of Inverse Opals of Silver with Cyanide-Free Electrolytes. Metals. 2022; 12(12):2042. https://doi.org/10.3390/met12122042
Chicago/Turabian StyleArabov, Rustam I., Maria Y. Komarova, Mikhail O. Astafurov, Alexander V. Knotko, Konstantin I. Maslakov, Serguei V. Savilov, and Anastasia V. Grigorieva. 2022. "Electrochemical Fabrication of Inverse Opals of Silver with Cyanide-Free Electrolytes" Metals 12, no. 12: 2042. https://doi.org/10.3390/met12122042