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Catalysts 2016, 6(5), 75;

Cu-Mo2C/MCM-41: An Efficient Catalyst for the Selective Synthesis of Methanol from CO2

International Joint Research Center of Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang Province; School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, China
Author to whom correspondence should be addressed.
Academic Editor: Andreas Martin
Received: 26 April 2016 / Revised: 12 May 2016 / Accepted: 16 May 2016 / Published: 20 May 2016
PDF [2659 KB, uploaded 20 May 2016]


Supported molybdenum carbide (yMo2C/M41) and Cu-promoted molybdenum carbide, using a mechanical mixing and co-impregnation method (xCuyMo2C/M41-M and xCuyMo2C/M41-I) on a mesoporous molecular sieve MCM-41, were prepared by temperature-programmed carburization method in a CO/H2 atmosphere at 1073 K, and their catalytic performances were tested for CO2 hydrogenation to form methanol. Both catalysts, which were promoted by Cu, exhibited higher catalytic activity. In comparison to 20Cu20Mo2C/M41-M, the 20Cu20Mo2C/M41-I catalyst exhibited a stronger synergistic effect between Cu and Mo2C on the catalyst surface, which resulted in a higher selectivity for methanol in the CO2 hydrogenation reaction. Under the optimal reaction conditions, the highest selectivity (63%) for methanol was obtained at a CO2 conversion of 8.8% over the 20Cu20Mo2C/M41-I catalyst. View Full-Text
Keywords: CO2 hydrogenation; Cu-promoted Mo2C; supported catalyst; methanol synthesis CO2 hydrogenation; Cu-promoted Mo2C; supported catalyst; methanol synthesis

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Liu, X.; Song, Y.; Geng, W.; Li, H.; Xiao, L.; Wu, W. Cu-Mo2C/MCM-41: An Efficient Catalyst for the Selective Synthesis of Methanol from CO2. Catalysts 2016, 6, 75.

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