Highly Enhanced Catalytic Stability of Copper by the Synergistic Effect of Porous Hierarchy and Alloying for Selective Hydrogenation Reaction
Abstract
:1. Introduction
2. Results and Discussion
2.1. Preparation of the Hierarchically Porous Alumina Supported Bimetallic Cu–Zn Catalysts
2.2. The Porous Hierarchy in Cu–Zn Supported on Hierarchically Porous γ-Al2O3
2.3. The Property of Bimetallic Cu–Zn Supported on Hierarchically Porous γ-Al2O3
2.4. Catalytic Performance for Selective Butadiene Hydrogenation in an Excess of Propene
3. Experiment
3.1. Sample Preparation
3.1.1. Materials and Chemicals
3.1.2. Preparation of Hierarchically Porous Alumina
3.1.3. Preparation of Cu–Zn/HA Catalysts
3.2. Catalysts Characterization
3.3. Butadiene Selective Hydrogenation Reaction
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | Theoretical Values | Experimental Values | Total BET Surface Area (m2/g) | Total Pore Volume (cm3/g) | Meso Pore Diameter (nm) | ||||
---|---|---|---|---|---|---|---|---|---|
Loading (wt%) | Cu:Zn | Loading (wt%) | Cu:Zn | ||||||
Cu | Zn | Cu | Zn | ||||||
HA | - | - | - | - | - | - | 394 | 0.57 | 3.8, 4.2 |
Cu/HA | 2.5 | 0 | 1:0 | 2.3 | 0 | 1:0 | 355 | 0.48 | 3.7 |
Cu1Zn1/HA | 2.5 | 2.5 | 1:1 | 2.4 | 2.2 | 1:0.9 | 315 | 0.38 | 3.7 |
Cu1Zn3/HA | 2.5 | 7.5 | 1:3 | 2.3 | 5.3 | 1:2.3 | 291 | 0.33 | 3.5 |
Cu1Zn5/HA | 2.5 | 12.5 | 1:5 | 2.3 | 8.2 | 1:3.6 | 259 | 0.33 | 3.5 |
Cu/CA | 2.5 | 0 | 1:0 | 2.3 | 0 | 1:0 | 4 | - | - |
CA | - | - | - | - | - | - | 3 | - | - |
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Yuan, H.; Wang, Z.; Jin, S.; Xiao, S.; Liu, S.; Hu, Z.; Chen, L.; Su, B. Highly Enhanced Catalytic Stability of Copper by the Synergistic Effect of Porous Hierarchy and Alloying for Selective Hydrogenation Reaction. Catalysts 2022, 12, 12. https://doi.org/10.3390/catal12010012
Yuan H, Wang Z, Jin S, Xiao S, Liu S, Hu Z, Chen L, Su B. Highly Enhanced Catalytic Stability of Copper by the Synergistic Effect of Porous Hierarchy and Alloying for Selective Hydrogenation Reaction. Catalysts. 2022; 12(1):12. https://doi.org/10.3390/catal12010012
Chicago/Turabian StyleYuan, Hao, Zhao Wang, Shunjing Jin, Shanshan Xiao, Siming Liu, Zhiyi Hu, Lihua Chen, and Baolian Su. 2022. "Highly Enhanced Catalytic Stability of Copper by the Synergistic Effect of Porous Hierarchy and Alloying for Selective Hydrogenation Reaction" Catalysts 12, no. 1: 12. https://doi.org/10.3390/catal12010012