Characterization and Structure–Property Relationships of Organic–Inorganic Hybrid Composites Based on Aluminum–Magnesium Hydroxycarbonate and Azo Chromophore
Abstract
:1. Introduction
2. Results and Discussion
2.1. Secondary Ion Mass Spectrometry (TOF-SIMS)
2.2. Solid State Nuclear Magnetic Resonance of 27Al (MAS NMR)
2.3. X-ray Diffraction Study (XRD)
2.4. Morphology of Hybrid Pigment (SEM/STEM)
2.5. Solvent Resistance
2.6. Thermal Analysis (TGA) and Photostability of Hybrid Pigments
3. Experimental
3.1. Materials
3.1.1. Azo Dye Synthesis
3.1.2. Hybrid Pigment Preparation
3.1.3. Preparation of Ethylene-Norbornene (EN) Composites
3.2. Characterization
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Sample Availability: Samples of the compounds are available from the authors. |
Hybrid Pigment | Solvent Resistance | ||||
---|---|---|---|---|---|
Water | Acetone | Toluene | Ethanol | Butyl Acetate | |
AlMg−LH/AD 10% | 5 | 5 | 5 | 5 | 5 |
AlMg−LH/AD 20% | 5 | 5 | 5 | 5 | 5 |
Sample | T051 (°C) | T101 (°C) | T201 (°C) | T301 (°C) |
---|---|---|---|---|
AlMg−LH | 119 | 205 | 330 | 441 |
AlMg−LH/AD 10% | 131 | 214 | 353 | 466 |
AlMg−LH/AD 20% | 145 | 217 | 370 | 488 |
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Marzec, A.; Szadkowski, B.; Rogowski, J.; Maniukiewicz, W.; Zaborski, M. Characterization and Structure–Property Relationships of Organic–Inorganic Hybrid Composites Based on Aluminum–Magnesium Hydroxycarbonate and Azo Chromophore. Molecules 2019, 24, 880. https://doi.org/10.3390/molecules24050880
Marzec A, Szadkowski B, Rogowski J, Maniukiewicz W, Zaborski M. Characterization and Structure–Property Relationships of Organic–Inorganic Hybrid Composites Based on Aluminum–Magnesium Hydroxycarbonate and Azo Chromophore. Molecules. 2019; 24(5):880. https://doi.org/10.3390/molecules24050880
Chicago/Turabian StyleMarzec, Anna, Bolesław Szadkowski, Jacek Rogowski, Waldemar Maniukiewicz, and Marian Zaborski. 2019. "Characterization and Structure–Property Relationships of Organic–Inorganic Hybrid Composites Based on Aluminum–Magnesium Hydroxycarbonate and Azo Chromophore" Molecules 24, no. 5: 880. https://doi.org/10.3390/molecules24050880