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Keywords = wood substitute

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20 pages, 2327 KiB  
Article
From Climate Liability to Market Opportunity: Valuing Carbon Sequestration and Storage Services in the Forest-Based Sector
by Attila Borovics, Éva Király, Péter Kottek, Gábor Illés and Endre Schiberna
Forests 2025, 16(8), 1251; https://doi.org/10.3390/f16081251 - 1 Aug 2025
Viewed by 290
Abstract
Ecosystem services—the benefits humans derive from nature—are foundational to environmental sustainability and economic well-being, with carbon sequestration and storage standing out as critical regulating services in the fight against climate change. This study presents a comprehensive financial valuation of the carbon sequestration, storage [...] Read more.
Ecosystem services—the benefits humans derive from nature—are foundational to environmental sustainability and economic well-being, with carbon sequestration and storage standing out as critical regulating services in the fight against climate change. This study presents a comprehensive financial valuation of the carbon sequestration, storage and product substitution ecosystem services provided by the Hungarian forest-based sector. Using a multi-scenario framework, four complementary valuation concepts are assessed: total carbon storage (biomass, soil, and harvested wood products), annual net sequestration, emissions avoided through material and energy substitution, and marketable carbon value under voluntary carbon market (VCM) and EU Carbon Removal Certification Framework (CRCF) mechanisms. Data sources include the National Forestry Database, the Hungarian Greenhouse Gas Inventory, and national estimates on substitution effects and soil carbon stocks. The total carbon stock of Hungarian forests is estimated at 1289 million tons of CO2 eq, corresponding to a theoretical climate liability value of over EUR 64 billion. Annual sequestration is valued at approximately 380 million EUR/year, while avoided emissions contribute an additional 453 million EUR/year in mitigation benefits. A comparative analysis of two mutually exclusive crediting strategies—improved forest management projects (IFMs) avoiding final harvesting versus long-term carbon storage through the use of harvested wood products—reveals that intensified harvesting for durable wood use offers higher revenue potential (up to 90 million EUR/year) than non-harvesting IFM scenarios. These findings highlight the dual role of forests as both carbon sinks and sources of climate-smart materials and call for policy frameworks that integrate substitution benefits and long-term storage opportunities in support of effective climate and bioeconomy strategies. Full article
(This article belongs to the Section Forest Economics, Policy, and Social Science)
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23 pages, 1821 KiB  
Review
Beyond Peat: Wood Fiber and Two Novel Organic Byproducts as Growing Media—A Systematic Review
by Anna Elisa Sdao, Nazim S. Gruda and Barbara De Lucia
Plants 2025, 14(13), 1945; https://doi.org/10.3390/plants14131945 - 25 Jun 2025
Viewed by 776
Abstract
Environmental concerns drive the search for sustainable organic alternatives in horticultural substrates. This review critically examines three agro-industry renewable byproducts—wood fiber, coffee silverskin, and brewer’s spent grain—as partial peat substitutes. We aimed to comprehensively analyze their origin, processing methods, current applications, and key [...] Read more.
Environmental concerns drive the search for sustainable organic alternatives in horticultural substrates. This review critically examines three agro-industry renewable byproducts—wood fiber, coffee silverskin, and brewer’s spent grain—as partial peat substitutes. We aimed to comprehensively analyze their origin, processing methods, current applications, and key physical, hydrological, and chemical properties relevant to horticultural use. In soilless culture, wood fiber can be used as a stand-alone substrate. When incorporated at 30–50% (v/v) in peat mixtures, it supports plant growth comparable to peat; however, higher proportions may restrict water and nutrient availability. Coffee silverskin demonstrates high water retention and nutrient content, but its inherent phytotoxicity requires pre-treatment (e.g., co-composting); at concentrations up to 20%, it shows promise for potted ornamental crops. Brewer’s spent grain is nutrient-rich but demands careful management due to its rapid decomposition and potential salinity issues; inclusion rates around 10% have shown beneficial effects. In conclusion, when used appropriately in blends, these bio-based byproducts represent viable alternatives to reduce peat dependence in vegetable and ornamental cultivation, contributing to more sustainable horticultural practices. Future research should optimize pre-treatment methods for coffee silverskin and brewer’s spent grain, investigate long-term stability in diverse cropping systems, and explore novel combinations with other organic waste streams to develop circular horticultural substrates. Full article
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16 pages, 1027 KiB  
Article
Climate Change Mitigation vs. Renewable Energy Consumption and Biomass Demand
by Renata Dagiliūtė and Vaiva Kazanavičiūtė
Land 2025, 14(7), 1320; https://doi.org/10.3390/land14071320 - 21 Jun 2025
Viewed by 436
Abstract
The land use, land-use change, and forestry (LULUCF) sector plays a crucial role in climate change mitigation; therefore, it is included in national and international climate change policies. However, renewable energy and bioeconomy development increase the demand for biomass for energy and material [...] Read more.
The land use, land-use change, and forestry (LULUCF) sector plays a crucial role in climate change mitigation; therefore, it is included in national and international climate change policies. However, renewable energy and bioeconomy development increase the demand for biomass for energy and material needs and challenge greenhouse gas (GHG) removal in LULUCF. Therefore, this study aims to analyze whether climate change mitigation and bioeconomy goals are compatible from an LULUCF perspective at the EU level. This study mainly covers the 2000–2020 period, looking at decoupling trends and LULUCF removal as well as estimating the substitution effect, which enables a broader view of the LULUCF GHG removal potential. The results reveal that decoupling is taking place at the EU level regarding economic growth and GHG, with a steady increase in renewables. The share of biomass in renewables is increasing at a slower pace, and the reduction in LULUCF GHG removal is proportionally lower compared to the pace of wood being harvested from forest land at the EU level. Still, biomass demand raises the pressure for LULUCF GHG removal, considering the sector itself is highly uncertain. Despite this, some possibilities to align climate and bioeconomy goals could remain, especially if the substitution effect is considered. Based on historical data, the estimated substitution effect is even higher (−367 mill. t CO2 eq. on average in 2000–2020) than the sector’s removal (−300 mill. t CO2 eq. on average in 2000–2020) and is dominated by material substitution (61%). Hence, LULUCF contributes to a reduction in GHG in other sectors, but it is still seldom acknowledged and not accounted for. Full article
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29 pages, 5625 KiB  
Article
Lower-Carbon Substitutes for Natural Gas for Use in Energy-Intensive Industries: Current Status and Techno-Economic Assessment in Lithuania
by Aurimas Lisauskas, Nerijus Striūgas and Adolfas Jančauskas
Energies 2025, 18(11), 2670; https://doi.org/10.3390/en18112670 - 22 May 2025
Cited by 2 | Viewed by 704
Abstract
Significant shortfalls in meeting the climate mitigation targets and volatile energy markets make evident the need for an urgent transition from fossil fuels to sustainable alternatives. However, the integration of zero-carbon fuels like green hydrogen and ammonia is an immense project and will [...] Read more.
Significant shortfalls in meeting the climate mitigation targets and volatile energy markets make evident the need for an urgent transition from fossil fuels to sustainable alternatives. However, the integration of zero-carbon fuels like green hydrogen and ammonia is an immense project and will take time and the construction of new infrastructure. It is during this transitional period that lower-carbon natural gas alternatives are essential. In this study, the industrial sectors of Lithuania are analysed based on their energy consumption. The industrial sectors that are the most energy-intensive are food, chemical, and wood-product manufacturing. Synthetic natural gas (SNG) has become a viable substitute, and biomethane has also become viable given a feedstock price of 21 EUR/MWh in the twelfth year of operation and 24 EUR/MWh in the eighth year, assuming an electricity price of 140 EUR/MWh and a natural gas price of 50 EUR/MWh. Nevertheless, the scale of investment in hydrogen production is comparable to the scale of investment in the production of other chemical elements; however, hydrogen production is constrained by its high electricity demand—about 3.8 to 4.4 kWh/Nm3—which makes it economically viable only at negative electricity prices. This analysis shows the techno-economic viability of biomethane and the SNG as transition pathways towards a low-carbon energy future. Full article
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19 pages, 7245 KiB  
Article
Nitrogen Immobilization by Wood Fiber Substrates Strongly Affects the Photosynthetic Performance of Lettuce
by Lingyi Wu, Ruohan Li, Juncheng Liu, Wenzhong Cui, Zhiyong Qi and Wanlai Zhou
Plants 2025, 14(10), 1518; https://doi.org/10.3390/plants14101518 - 19 May 2025
Cited by 1 | Viewed by 546
Abstract
Wood fiber substrates are widely used as peat substitutes in horticulture, but the impact of their high carbon-to-nitrogen ratio on nitrogen immobilization and crop photosynthetic performance remains unclear. This study systematically examined the effects of wood fiber substrates on lettuce photosynthetic performance and [...] Read more.
Wood fiber substrates are widely used as peat substitutes in horticulture, but the impact of their high carbon-to-nitrogen ratio on nitrogen immobilization and crop photosynthetic performance remains unclear. This study systematically examined the effects of wood fiber substrates on lettuce photosynthetic performance and underlying physiological mechanisms using pot experiments. Two substrate treatments—peat (control) and wood fiber—were combined with three nitrogen levels: low, medium, and high (63, 127, and 210 mg N·L−1). Results indicated that wood fiber substrates significantly reduced the availability of fast-acting nitrogen, leading to a substantial decrease in lettuce biomass (39.0–56.8%), total nitrogen content (7.2–39.9%), and chlorophyll content (13.7–36.2%). Chlorophyll fluorescence kinetics analysis revealed that wood fiber substrates impair photosystem function through multiple pathways. At the early stage (15 days), key effects included structural damage to the donor side of PSII(Photosystem II), indicated by L and K peaks, and inhibited electron transfer on the PSI(Photosystem I) acceptor side (δRo decreased by 15.08–27.90%, along with a reduction in WOI amplitude). The findings provide an important theoretical basis for optimising nitrogen management strategies for wood fibre substrates. Full article
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20 pages, 34946 KiB  
Article
Feasibility of Bamboo Sawdust as Sustainable Alternative Substrate for Auricularia heimuer Cultivation
by Ya-Hui Wang, Cong-Sheng Yan, Yong-Jin Deng, Zheng-Fu Zhu, Hua-An Sun, Hui-Ping Li, Hong-Yuan Zhao and Guo-Qing Li
J. Fungi 2025, 11(5), 387; https://doi.org/10.3390/jof11050387 - 17 May 2025
Viewed by 724
Abstract
With the increasing scarcity of traditional hardwood sawdust resources, developing sustainable substrates for edible fungi cultivation has become an urgent industrial priority. This study systematically evaluated the effects of bamboo sawdust substitutions (20%, 30%, 40%, and 50%) on mycelial growth, fruiting body development, [...] Read more.
With the increasing scarcity of traditional hardwood sawdust resources, developing sustainable substrates for edible fungi cultivation has become an urgent industrial priority. This study systematically evaluated the effects of bamboo sawdust substitutions (20%, 30%, 40%, and 50%) on mycelial growth, fruiting body development, and nutritional quality of Auricularia heimuer, while elucidating the underlying molecular mechanisms through transcriptome sequencing. The results demonstrated that bamboo substitution of ≤30% maintained normal mycelial growth and fruiting body differentiation, with 20% and 30% substitutions increasing yields by 5.30% and 3.70%, respectively, compared to the control. However, 50% substitution significantly reduced yield by 9.49%. Nutritional analysis revealed that 20–40% bamboo substitution significantly enhanced the contents of crude protein, polysaccharides, and essential minerals (calcium, iron, and selenium) in fruiting bodies. Transcriptome analysis identified upregulation of glycosyl hydrolase family genes and downregulation of redox-related genes with increasing bamboo proportions. Biochemical assays confirmed these findings, showing decreased oxidative substances and increased reductive compounds in mycelia grown with high bamboo content, which indicate disrupted cellular redox homeostasis. This study provides both a practical solution to alleviate the “edible mushrooms derived from lignicolous fungi–forest conflict” and fundamental insights into fungal adaptation mechanisms to non-wood substrates, thus establishing a theoretical foundation for the valorization of agricultural and forestry wastes. Full article
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13 pages, 3310 KiB  
Article
The Potential of Wood Ash to Be Used as a Supplementary Cementitious Material in Cement Mortars
by Oskars Lescinskis, Alise Sapata, Girts Bumanis, Maris Sinka, Xiangming Zhou and Diana Bajare
Buildings 2025, 15(9), 1507; https://doi.org/10.3390/buildings15091507 - 30 Apr 2025
Viewed by 572
Abstract
This study explores the application of wood ash (WA) as a partial replacement for PC in mortar. Three pre-treatment methods were applied to WA to enhance its reactivity, and it was then incorporated into mortar at two different substitution levels of 10 and [...] Read more.
This study explores the application of wood ash (WA) as a partial replacement for PC in mortar. Three pre-treatment methods were applied to WA to enhance its reactivity, and it was then incorporated into mortar at two different substitution levels of 10 and 30%. Tests on compressive and flexural strength were conducted on the hardened mortar samples. All hardened mortar samples containing WA showed a decrease in mechanical properties compared to the reference sample without WA. The highest compressive and flexural strength of the samples with WA were observed for those containing 10% of sieved and slaked WA. The compressive and flexural strength of these samples after 28 days were 56 and 9 MPa, respectively, whereas those of the reference samples were 62 and 10 MPa, respectively. Based on the results, the best-performing samples on the compressive test underwent additional testing for freeze–thaw resistance to assess their durability. The mass loss of the reference sample and that with 10% of sieved and slaked WA after 56 freeze–thaw cycles was 11,800 and 13,800 g/m2, respectively. The findings revealed that increasing the proportion of WA typically led to a decline in the mechanical properties of mortar compared to conventional mixtures. However, with appropriate pre-treatment techniques, the quality and performance of mortar containing WA were significantly improved, demonstrating its potential as a sustainable alternative in reducing the carbon footprint of PC production. Full article
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16 pages, 3199 KiB  
Article
Thin-Layer Drying Model and Antifungal Properties of Rubber Sheets Produced with Wood Vinegar as a Substitute for Formic and Acetic Acids
by Wassachol Wattana, Putipong Lakachaiworakun, Natworapol Rachsiriwatcharabul, Visit Eakvanich, Panya Dangwilailux and Wachara Kalasee
Polymers 2025, 17(9), 1201; https://doi.org/10.3390/polym17091201 - 27 Apr 2025
Viewed by 530
Abstract
Currently, workers in the ribbed smoked sheet (RSS) rubber production industry face increasing health risks, primarily due to their direct involvement in converting fresh latex into raw rubber sheets. This process involves the manual addition of appropriately diluted commercial formic acid and acetic [...] Read more.
Currently, workers in the ribbed smoked sheet (RSS) rubber production industry face increasing health risks, primarily due to their direct involvement in converting fresh latex into raw rubber sheets. This process involves the manual addition of appropriately diluted commercial formic acid and acetic acid to induce coagulation, resulting in a tofu-like consistency, which is subsequently processed into rubber sheets. Previous studies have indicated that the use of commercial formic and acetic acids poses significant health hazards to workers and contributes to environmental pollution. Therefore, this study explores the feasibility of replacing commercial formic and acetic acids with wood vinegar derived from para-rubber wood, bamboo, and eucalyptus in the RSS production process. Wood vinegar samples from the three biomass sources were analyzed for their organic compound compositions using gas chromatography and subsequently used as coagulants in the preparation of raw rubber sheets. The drying kinetics and antifungal properties of the resulting sheets were then evaluated. The results revealed that wood vinegar derived from para-rubber wood contained the highest concentration of acetic acid (41.34%), followed by bamboo (38.19%) and eucalyptus (31.25%). Rubber sheets coagulated with wood vinegar from para-rubber wood and bamboo exhibited drying kinetics comparable to those obtained using acetic acid, with the two-term exponential model providing the best fit. Conversely, rubber sheets coagulated with eucalyptus-derived wood vinegar, which had a relatively high concentration of phenolic derivatives (22.08%), followed drying behavior consistent with the Midilli et al. model, similar to sheets treated with formic acid. In terms of antifungal properties, five fungal genera—Aspergillus, Penicillium, Fusarium, Trichoderma, and Paecilomyces—were identified on the rubber sheets. Fungal growth was most pronounced in the control samples (untreated with wood vinegar), whereas samples treated with wood vinegar exhibited significantly reduced fungal colonization. These findings indicate that wood vinegar is effective in inhibiting fungal growth on the surface of rubber sheets and may serve as a safer and more environmentally friendly alternative to commercial acid coagulants. Full article
(This article belongs to the Section Polymer Networks and Gels)
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17 pages, 3911 KiB  
Article
Wood-Based Micro-Biochars in a Cement Mixture
by Minkyeong Pyo, Jongsun Kim, Seungwook Seok, Chan Ho Park and Wonchang Choi
Molecules 2025, 30(9), 1898; https://doi.org/10.3390/molecules30091898 - 24 Apr 2025
Viewed by 733
Abstract
Immediate action is required to achieve carbon neutrality within the cement industry. The integration of biochar into cement as a component of reinforced concrete has potential to mitigate carbon emissions in the construction sector by enabling carbon sequestration. In pursuit of eco-friendly practices [...] Read more.
Immediate action is required to achieve carbon neutrality within the cement industry. The integration of biochar into cement as a component of reinforced concrete has potential to mitigate carbon emissions in the construction sector by enabling carbon sequestration. In pursuit of eco-friendly practices and improved physical properties of cement composites, this study investigated the properties of wood-based, micron-sized biochar as a non-carbonate raw material, including its chemical composition, morphology, and wettability. The characterization of lignocellulosic micro-biochar and its mechanical impact on cement composites was a focus of this study. Cement was partially replaced with varying weight percentages of micro-biochar (1, 3, and 5 wt%), and the effects were evaluated through compressive strength tests after 7 and 28 d. The results demonstrated that the micro-biochar could sustain strength even when substituted for cement. Notably, after 28 d, the compressive strength of the sample with only cement was 29.6 MPa, while the sample with 3 wt% biochar substitution showed 30.9 MPa, indicating a 4.4% increase. This research contributes to sustainable construction practices by offering a green solution for reducing carbon emissions in the industry. Full article
(This article belongs to the Special Issue Carbon-Based Materials for Sustainable Chemistry: 2nd Edition)
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22 pages, 3629 KiB  
Review
Replacing Sand in Concrete: Review on Potential for Utilization of Bottom Ash from Combustion of Wood in Circulating Fluidized Bed Boilers
by Anders Hedegaard Jensen, Carola K. Edvardsen and Lisbeth M. Ottosen
Recycling 2025, 10(2), 73; https://doi.org/10.3390/recycling10020073 - 14 Apr 2025
Viewed by 1287
Abstract
Aggregates such as sand and gravel are the most mined resources on Earth and are the largest component in concrete. They are essential for construction but are becoming increasingly scarce. At the same time, large amounts of biomass ashes are produced in wood-fired [...] Read more.
Aggregates such as sand and gravel are the most mined resources on Earth and are the largest component in concrete. They are essential for construction but are becoming increasingly scarce. At the same time, large amounts of biomass ashes are produced in wood-fired power plants, offering potential as a partial substitute for decreasing sand resources. Due to the combustion technology of circulating fluidized bed boilers, their bottom ash offers high potential as a viable alternative to natural sand. This review examines previous research to assess the feasibility of replacing sand in concrete with bottom ash. Specific cementitious products are identified, where the substitution could realistically be performed in the concrete industry. Benefits and issues with partial substitution of bottom ash from wood combustion are discussed, and gaps in the research regarding sand replacements with bottom ash, notably the durability of the resulting concrete, are shown. Bottom ash has positive properties relevant for use in mortar and concrete, both regarding physical and chemical properties. Although limited research exists in the field, several researchers have demonstrated promising results when substituting sand for bottom ash in mortars. For lower substitution levels, little effect on the fresh and hardened properties is found. Full article
(This article belongs to the Topic Sustainable Building Materials)
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14 pages, 6307 KiB  
Article
The Clear Choice: Developing Transparent Cork for Next-Generation Sustainable Materials
by Pedro Gil, Pedro L. Almeida, Maria H. Godinho and Ana P. C. Almeida
Macromol 2025, 5(2), 17; https://doi.org/10.3390/macromol5020017 - 8 Apr 2025
Viewed by 1195
Abstract
Many modern technologies rely on materials that harm the environment. Glass manufacturing, for instance, is both expensive and environmentally damaging. In response, scientists have developed a technique to replace glass with transparent wood, an innovative, versatile, and sustainable alternative. Wood naturally retains heat, [...] Read more.
Many modern technologies rely on materials that harm the environment. Glass manufacturing, for instance, is both expensive and environmentally damaging. In response, scientists have developed a technique to replace glass with transparent wood, an innovative, versatile, and sustainable alternative. Wood naturally retains heat, is durable, and remains cost-effective, making it promising substitute for glass and plastic in window production. This innovation highlights the urgent need for eco-friendly technologies to replace or improve existing materials. This work explores cork as a sustainable alternative for producing transparent materials, potentially replacing transparent wood. Unlike wood, cork can be harvested from the same tree for up to 300 years. The process followed a method like transparent wood production, involving delignification, bleaching, and forced polymer impregnation. The choice of bleaching agent significantly impacted results—samples treated with sodium hypochlorite solution appeared whiter but became extremely fragile, whereas hydrogen peroxide preserved mechanical properties better. The resin-to-hardener ratio was crucial, with higher resin content improving polymer infiltration and transparency. While fully transparent cork was not achieved, the resulting translucent material lays the groundwork for future research in this field. Full article
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26 pages, 4555 KiB  
Article
Effects of Visual Perception of Building Materials on Human Emotional States and Cognitive Functioning in a Physical Learning Environment
by Yufeng Zhou, Xiaochen Zhao, Yongbo Feng, Changzheng Xuan, Changhan Yang and Xiaohu Jia
Buildings 2025, 15(7), 1163; https://doi.org/10.3390/buildings15071163 - 2 Apr 2025
Cited by 1 | Viewed by 941
Abstract
The influence of building materials on the physical aspects of educational spaces is significant, shaping both functionality and aesthetic appeal while directly affecting the emotional and cognitive states of students. Despite its significance, this area has not been extensively explored. This study investigated [...] Read more.
The influence of building materials on the physical aspects of educational spaces is significant, shaping both functionality and aesthetic appeal while directly affecting the emotional and cognitive states of students. Despite its significance, this area has not been extensively explored. This study investigated the effects of the visual perception of architectural materials on emotional states and cognitive functions in learning environments. Four materials, namely, red brick, concrete, wood, and white paint, were selected for a material substitution experiment conducted via VR simulations with 46 participants. To assess these effects, eye movement data and bioelectrical responses were methodically recorded, along with the participants’ self-reported emotional states through structured questionnaires. The results indicated that settings featuring wood and red bricks significantly enhanced emotional states, fostering relaxation and positive experiences that contributed to increased creativity. Conversely, settings with concrete and white paint improved cognitive functioning and promoted emotional stability and rational thinking, which enhanced focus and educational efficiency. These findings suggest the impact of visual perception of building materials on emotional and cognitive states, emphasizing the importance of material selection in creating learning spaces that balance cognitive demands with emotional activation. This study provides valuable insights for designing conducive physical learning environments and exploring the psychological and physiological effects of architectural materials. Full article
(This article belongs to the Section Architectural Design, Urban Science, and Real Estate)
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13 pages, 10341 KiB  
Article
Preparation and Modification of Sucrose-Based Non-Isocyanate Polyurethane Adhesives for Plywood Bonding
by Hongyi Zhong, Qianyu Zhang, Hong Lei, Xiaojian Zhou, Jun Zhang, Guanben Du, Antonio Pizzi and Xuedong Xi
Molecules 2025, 30(7), 1541; https://doi.org/10.3390/molecules30071541 - 30 Mar 2025
Viewed by 565
Abstract
The production of non-isocyanate polyurethane (NIPU) resins using recyclable biomass materials and no isocyanates as a substitute for traditional polyurethane (PU) materials has become a research focus in the polyurethane industry. The development of such NIPU resins for application as wood adhesives has [...] Read more.
The production of non-isocyanate polyurethane (NIPU) resins using recyclable biomass materials and no isocyanates as a substitute for traditional polyurethane (PU) materials has become a research focus in the polyurethane industry. The development of such NIPU resins for application as wood adhesives has also emerged as an interesting new research topic. In this study, sucrose was used to react with dimethyl carbonate, and then polymerized with an amine to prepare sucrose-based non-isocyanate polyurethane (SNIPU) adhesives and evaluate their suitability for use in plywood. Four amines, namely polyethylene amine (PEI) of molecular weight (MW) 10,000, PEI of MW 1800, diethylenetriamine, and hexanediamine were tested in the preparation of SNIPU adhesives to determine a more suitable amine showing optimal adhesion performance. The effect of the amount of the amine added on adhesive properties was further investigated. The results showed that the SNIPU adhesive prepared with PEI-10000 as amine presents a good bonding performance. The SNIPU prepared with a PEI-10000 content of 45% (w/w on sucrose) presented the highest bonding strength. The dry strength, 24 h cold water (23 °C) wet strength, and 3 h hot water (63 °C and 93 °C) wet strengths of its bonded plywood were 1.26 MPa, 0.90 MPa, 0.84 MPa, and 0.80 MPa, respectively. Furthermore, the addition of 13% (w/w on SNIPU adhesive) of ethylene glycol diglycidyl ether (EGDE) as a modifier showed a significant decrease of 20 °C of the curing temperature of the SNIPU adhesive. Full article
(This article belongs to the Special Issue Advances in Polymer Materials Based on Lignocellulosic Biomass)
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12 pages, 901 KiB  
Article
Novel Bio-Based Formulations for Alkyd Wood Coatings: Effects on Biodegradation and Technical Performance
by Idoia Etxeberria, Ingemar Svensson, Ana Isabel Díaz and Leire Barruetabeña
Coatings 2025, 15(4), 400; https://doi.org/10.3390/coatings15040400 - 27 Mar 2025
Viewed by 901
Abstract
Alkyd resins are still one of the most important classes of binders for paint systems. They are outstanding in terms of their versatility of formulations and applications, cost-effectiveness, and durability. Traditionally, they are synthesized using phthalic anhydride, polyalcohols with three or four functional [...] Read more.
Alkyd resins are still one of the most important classes of binders for paint systems. They are outstanding in terms of their versatility of formulations and applications, cost-effectiveness, and durability. Traditionally, they are synthesized using phthalic anhydride, polyalcohols with three or four functional groups (pentaerythritol, glycerol, and trimethylolpropane), and fatty acids or oils. In this study, new bio-alkyd resins were synthesized with the objective of increasing the bio-based content by substituting phthalic anhydride, thereby also enhancing the biodegradability of coatings. The newly synthesized alkyd resins, formulated with azelaic acid, were used to develop coatings incorporating additives while avoiding cobalt-based driers. Additional agents such as leveling, wetting, and anti-skinning agents, were also included. Paints were applied to wood substrates and dried at room temperature. The resulting films were characterized by pendulum hardness, transparency, and color by colorimetry, cross-cut test, contact angle, and gloss. Thermal properties were analyzed by Differential Scanning Calorimetry (DSC), and Total Organic Carbon (TOC) content and aerobic biodegradation were also evaluated. The resulting coating films exhibited good mechanical performance, with hardness values ranging from 132 to 148 Persoz oscillations and strong adhesion to wood substrates (smooth cross-cut edges, Class 0). Significant biodegradability (70% in less than 90 days) was demonstrated under composting conditions, which was considerably higher than that of a commercial reference alkyd coating (34.7%) under the same conditions. These findings suggest that the developed bio-alkyd coatings formulated with azelaic acid and DCO-FA without cobalt-based driers represent a promising alternative to conventional phthalic acid-based alkyds. These novel coatings move closer to fully bio-based formulations and offer enhanced biodegradability, making them a more sustainable option for coating applications. Full article
(This article belongs to the Special Issue Bio-Based and Bio-Inspired Polymers and Composites)
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21 pages, 4429 KiB  
Article
Pyrolyzed Agro-Food By-Products: A Sustainable Alternative to Coal
by Lukáš Jeníček, Jan Malaťák, Jan Velebil and Michal Neškudla
Materials 2025, 18(7), 1495; https://doi.org/10.3390/ma18071495 - 27 Mar 2025
Viewed by 706
Abstract
This study investigates the potential use of biochar derived from residues—such as spruce wood, spent coffee grounds, tea waste, and nutshells—as a sustainable coal substitute—to enhance the decarbonization of European energetic systems and decrease the dependence on fossil fuels. The biomasses were pyrolyzed [...] Read more.
This study investigates the potential use of biochar derived from residues—such as spruce wood, spent coffee grounds, tea waste, and nutshells—as a sustainable coal substitute—to enhance the decarbonization of European energetic systems and decrease the dependence on fossil fuels. The biomasses were pyrolyzed at 250–550 °C, analyzed for calorific value and composition, and evaluated for energy retention and mass loss. The results show significant energy density improvements, with optimal temperatures varying by material (e.g., spruce wood reached 31.56 MJ·kg−1 at 550 °C, retaining 21.84% of its mass; spent coffee grounds peaked at 31.26 MJ·kg−1 at 350 °C, retaining 37.53%). Economic analysis confirmed pyrolyzed biomass as a cost-effective alternative to coal, especially considering emission allowance costs. Integrating biomass pyrolysis into regional energy systems supports decarbonization, reduces emissions, and advances us towards a circular economy. Full article
(This article belongs to the Special Issue Sustainable Materials for Engineering Applications)
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